共查询到18条相似文献,搜索用时 125 毫秒
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主要介绍了我国电磁屏蔽涂料的分类、相关行业标准以及对电磁屏蔽涂料的性能要求。归纳总结近年来有关不同碳系导电材料在电磁屏蔽涂料领域的研究进展,重点阐述不同结构碳系导电材料以及与其他导电材料进行复合等形式对提高涂层电磁波屏蔽性能的影响。 相似文献
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导电油墨起源于导电涂料,印刷电子行业的兴起产生了对导电油墨的研发需求。本文综述了碳系导电油墨填料的研究现状、导电机理、应用前景及其发展方向。首先概述了传统碳系导电油墨填料(石墨、炭黑、碳纤维及其混合物)以及新型碳系导电油墨填料(碳纳米管、石墨烯)的研究进展,重点分析了传统碳系填料的研究方向及手段,解释了新型碳系填料应用于导电油墨的优越性。然后从宏观和微观层面概述了当前主流的几种导电机理的基本原理和适用范围,并指出了目前对油墨导电性能的研究只能定性分析而不能定量描述的局限性。最后,重点介绍了两种新型碳系导电油墨填料的最新研究进展和应用方向,特别指出了当前对碳纳米管和石墨烯填料的研究亟需解决的问题,总结了二者今后的研究重点和研究趋势。 相似文献
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纳米导电和电磁屏蔽涂料特性表征方法为测定导电填料类型,包括金属系类型、碳系类型、金属氧化物类型以及复合物类型等;评价方法为测定漆膜的表面电阻、表面电阻率、体积电阻和体积电阻率或电磁屏蔽效能。文章对纳米涂料导电和电磁屏蔽特性的表征和评价方法进行探讨。 相似文献
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碳系填充型聚合物屏蔽材料最新进展 总被引:1,自引:1,他引:0
针对目前碳系材料作为屏蔽基元材料存在的不足,结合电磁屏蔽机理,介绍了炭黑、石墨、碳纤维、碳纳米管等碳系屏蔽复合材料的最新研究情况。为克服碳系填料无磁性这一不足,最近几年碳系材料在包覆金属纳米层,磁控溅射镀镍等方面有了长足的发展,使得碳系填充型屏蔽材料的应用越来越广。此外介绍了纳米纸、石墨烯等新型碳系材料的发展趋势。最后指出了碳系屏蔽复合材料向着多功能、宽频带、高吸收等方向的发展趋势。 相似文献
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This paper shows the wide application range (such as electrical self‐heating and electromagnetic shielding effectiveness) of composites consisting of conductive carbon black/aluminum flakes (CBA) filler and epoxy insulative matrix. The effect of CBA content on the network structure of epoxy matrix was investigated in detail. Static electrical conductivity increases linearly with the increase of filler concentration at the interface in epoxy composites. The large decrease of the conductivity as a function of the temperature is analyzed in terms of the negative temperature coefficient of conductivity (NTCC) effect. The influence of viscosity, surface energy and barrier highest energy on the NTCC behaviour in the composite is also considered. Based on these results, a new interpretation is proposed to explain the NTCC phenomena by computing the swelling force among conductive phases. The correlations of conductivity during the temperature cycling and activation energy were analyzed. The effects of dynamic ageing at various temperatures on the resistivity are reported. Current–voltage–temperature characteristics for epoxy with different contents of CBA were examined in detail. A model based on the law of energy conservation is proposed to calculate the specific heat and amount of heat dissipation. The static charge of the epoxy–CBA composites was estimated. The correlation between electromagnetic wave‐shielding effectiveness (EMS), conductivity and frequency of epoxy composites with different filler contents is also discussed. Furthermore, the effect of annealing on EMS of epoxy composites was examined. © 2002 Society of Chemical Industry 相似文献
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Conductive polymer composites (CPCs) have demonstrated significant potential in the aerospace, electronics, and communications industries. In this study, polypropylene (PP)/multiwalled carbon nanotubes (MWCNTs) binary composites and in situ fiber reinforced multicomposites made from PP/MWCNTs were fabricated by microcellular injection molding. In addition to crystallization behavior, foam morphology, mechanical properties, dielectric properties, and electromagnetic shielding properties of the composites were analyzed. According to the results, microporous structures can facilitate the distribution of conductive fillers, thereby enhancing the electromagnetic shielding performance and mechanical properties of the composite. In situ microfiber networks display a heterogeneous nucleation effect, resulting in an increase in foam density, which improves composite performance. In situ fiber-reinforced microporous multicomposites are capable of exhibiting higher elongation at break and electromagnetic shielding properties than binary systems, and the multicomposites can achieve greater electromagnetic shielding effectiveness (SE) with fewer conductive fillers. Ultimately, fiber-reinforced microporous composites with an elongation at break of 194.40%, an electromagnetic shielding effect of >20 dB, and an absorption mechanism are produced. A feasible method is presented in this study for preparing CPCs that produce light weight, excellent mechanical properties, and high electromagnetic SE at low filler levels. 相似文献
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Li Jiang Jia Ajit Dattatray Phule Yue Geng Shibao Wen Lin Li Zhen Xiu Zhang 《大分子材料与工程》2021,306(4):2000759
In this study, a lightweight microcellular carbon-based filler/poly(vinylidene fluoride) (PVDF) composite foam is fabricated with a 3D conductive network that is thermally insulating, electrically conductive, and fabricated on a large scale. This composite can be used for high-efficiency thermal insulation and electromagnetic interference (EMI) shielding applications. The prepared composite demonstrates low density, high electrical conductivity, and excellent thermal insulation properties. The structure and density of the conductive network and the carbon-based filler content has a significant influence on the electrical conductivity of the prepared composite foam. Although the composite comprises microcellular PVDF beads of the same density, the conductivity of the composite-comprising strip beads is greater than that comprising spherical beads. In the same conductive network structure, as the size of the microcellular PVDF beads decrease, the conductive network becomes denser, which results in a higher conductivity. Furthermore, with an increase in the conductive filler content, the conductivity improves significantly. Excellent EMI shielding materials with optimal filler content and particle shapes, exhibiting EMI shielding effectiveness of up to 40–50 dB, are developed. The prepared composite foam possesses excellent application potential in the fields of ultra-light thermal insulation, conductivity, and EMI shielding. 相似文献