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1.
The construction of deformation mechanism maps for a polycrystalline ionic solid in which anion and cation transport are coupled has been demonstrated. Because of anioncation ambipolar coupling, two regimes of Coble creep are possible in systems where anion grain boundary transport is rapid: (1) rate-controlled at low temperatures and small grain sizes by cation grain-boundary diffusion, and (2) rate-limited at high temperatures and large grain sizes by anion grain-boundary diffusion. A new type of deformation mechanism map was introduced in which the temperature and grain size were primary variables. This map was shown to be particularly useful for materials which deform primarily by diffusional creep mechanisms. Ambipolar diffusional creep theory was used to construct several deformation mechanism maps for polycrystalline MgO and magnesiowustite over wide ranges of stress, grain size, temperature and composition.  相似文献   

2.
The effect of simultaneous doping with manganese and titanium on diffusional creep was studied in dense, polycrystalline alumina over a range of grain sizes (4–80m) and temperatures (1175–1250° C). At a total dopant concentration of 0.32–0.37 cation %, diffusional creep rates were enhanced considerably such that the temperature at which cation mass transport was significant was suppressed by at least 200° C compared to that observed in undoped material. The Mn-Ti (and Cu-Ti) dopant couple was far more effective in enhancing creep rates and suppressing sintering temperatures than the Fe-Ti couple. The enhanced mass transport kinetics are believed to be caused by significant increases in both aluminium lattice and grain-boundary diffusion. When aluminium grain-boundary diffusion is enhanced by increasing the concentration of divalent impurity (Mn2+, Fe2+) or by creep testing at low temperatures, creep deformation is Newtonian viscous.  相似文献   

3.
The occurrence of grain-boundary sliding during creep in fine grained alumina was examined by inscribing marker lines on the tensile surfaces of specimens, prior to testing in four-point bending mode. There was considerable microstructural evidence for the occurrence of grainboundary sliding and grain rotation during creep deformation. Experimental measurements of the offsets in the marker lines at grain boundaries reveal that the grain-boundary sliding contribution to the total strain during creep deformation is 70 ± 6.2%. The extensive grain boundary sliding observed, together with the other mechanical properties, suggests that polycrystalline alumina exhibits superplastic characteristics. Several possible rate controlling mechanisms are examined critically in light of the present results and it is concluded that creep occurs either by an independent grain-boundary sliding mechanism or by an interface controlled diffusion mechanism.  相似文献   

4.
A procedure is presented which allows the determination of the relative displacement of grains across a common grain boundary during diffusional creep deformation. This relative displacement comprises the strain produced by accretion of material at the grain boundary and by grain-boundary sliding. The only measurements necessary are of marker line displacements across the grain boundary.  相似文献   

5.
An analysis of mass transport in the diffusional creep of iron-doped, polycrystalline MgO was conducted. Creep regimes in which magnesium grain boundary, oxygen grain boundary, and magnesium-lattice diffusion were rate-controlling were identified. An analytical procedure was developed for the estimation of the diffusion constants for these three processes.  相似文献   

6.
In many cases, alumina scales are assumed to grow predominantly by oxygen diffusion, but some authors have found that the growth can be controlled by aluminium diffusion. These mechanisms can be modified by active elements. The problem with alumina is that there is a lack of data about self-diffusion coefficients, and, due to the stoichiometry of alumina, diffusion data correspond to an extrinsic diffusion mechanism so that it is not possible to compare oxygen and aluminium diffusion coefficients. In order to obtain information about the alumina scale growth mechanism, oxygen (18O) and aluminium (26Al) self-diffusion coefficients in Al2O3 were determined in the same materials and in the same experimental conditions, thus allowing a direct comparison. For both isotopes, bulk and sub-boundary diffusion coefficients were determined in single crystals of undoped alumina. Grain-boundary diffusion coefficients have been computed only for oxygen diffusion in polycrystals. Oxygen diffusion has been also studied for yttria-doped -alumina in the lattice, sub-boundaries and grain boundaries. Oxygen and aluminium bulk diffusion coefficients are of the same order of magnitude. In the sub-boundaries, aluminium diffusion is slightly faster than oxygen diffusion. Yttria doping induces a slight increase of the oxygen bulk diffusion, but decreases the grain-boundary diffusion coefficients on account of segregation phenomena. These results are compared with the oxidation constants of alumina former alloys (alloys which develop an alumina scale by oxidation). It appears that neither lattice self-diffusion nor grain boundary self-diffusion can explain the growth rate of alumina scales. Such a situation is compared to the case of Cr2O3.  相似文献   

7.
Creep in pure and two phase nickel-doped alumina has been investigated in the stress range 0.70 to 4.57 kgf mm–2 (1000 to 6500 psi), and temperature range 1450 to 1800° C, for grain sizes from 15 to 45 m (pure alumina) and 15 to 30 um, (nickel-doped alumina). The effect of stress, grain size and temperature on the creep rate suggests that diffusion controlled grain-boundary sliding is the predominant creep mechanism at low stresses and small grain sizes. However, the stress exponents show that some non-viscous boundary sliding occurs even at the lowest stresses investigated. This mechanism is confirmed by metallographic evidence, which shows considerable boundary corrugation in the deformed aluminas. At higher stresses and larger grain sizes the localized propagation of microcracks leads to high stress exponents in the creep rate equation. The nickel dopant, which introduces an evenly distributed spinel second phase into the alumina matrix, increases the creep rate and enhances boundary sliding and localized crack propagation. The weakening effect of the second phase increases with grain size, and tertiary creep occurs at strains of 0.5% and below in large grained material.  相似文献   

8.
The typical grain boundary cracks are often formed at the grain-boundary triple junction as a result of blocking of grain-boundary sliding. However, a theoretical discussion has not fully been made on the nucleation of grain corner cracks at high temperatures where diffusional recovery occurs. In this study, a continuum mechanics model which incorporated the recovery effect by diffusion of atoms has been developed to explain the initiation of wedge-type cracking during high-temperature creep. A good agreement was found between the result of calculation based on this model and experimental results in austenite steels. It was considered that there is a critical creep rate for wedge-type cracking. The model was also applied to the prediction of the rupture life in creep.  相似文献   

9.
Ionic and electronic conductivity and compressive creep of hot-pressed polycrystalline acceptor-dominated Al2O3 were measured as a function of oxygen partial pressure and grain size varying from 3 to 200 m. Hole conduction shows a slight preference for grainboundaries; ionic conduction is slightly hindered by grain boundaries, indicating that fast oxygen grain-boundary diffusion involving charged species does not occur. Conductivity and creep are accounted for on the basis of a model in which there is fast grain-boundary migration by a neutral oxygen species.  相似文献   

10.
Ambipolar diffusion gives rise to four distinct types of diffusion creep in ceramic materials, depending on whether the processes of lattice and grain-boundary diffusion creep are controlled by the anions or cations, respectively. These four processes are incorporated in a deformation mechanism map for diffusion creep in pure Al2O3, using a new form of map which is independent of the selected stress level. This map may be used to determine the rate-controlling mechanism for diffusion creep under any selected experimental conditions. By superimposing dislocation creep on to the map, it is possible to estimate the highest permissible stress and the lowest feasible temperature for experimental observation of any of the diffusion creep processes.  相似文献   

11.
添加稀土氧化物热压氮化硅陶瓷的蠕变机制   总被引:2,自引:0,他引:2  
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12.
We investigate by means of periodic density functional theory the mechanism of grain boundary sliding along the α-alumina Σ11 tilt grain boundary. We identify minimum and maximum energy structures along a preferential sliding pathway for the pure grain boundary, as well as for grain boundaries doped with a series of early transition metals, as well as barium, gadolinium, and neodymium. We predict that the segregation of those dopants results in a considerable increase in the grain boundary sliding barrier. Grain boundary sliding occurs by a series of bond breaking and forming across the grain boundary. Our results suggest that the presence of large cations inhibits the regeneration of bonds during sliding, which results in a decrease in total number of bonds across the grain boundary interface, thereby raising the barrier to sliding. Trends in predicted grain boundary sliding energies are in good agreement with recently measured creep activation energies in polycrystalline alumina, lending further credence to the notion that grain boundary sliding plays a dominant role in alumina creep.  相似文献   

13.
Hydrogen attack (HA) is the development of grain-boundary porosity by cavities filled with high-pressure methane that originates from the reaction of carbides with hydrogen at high temperatures. The cavities grow by grain-boundary diffusion and by creep of the adjacent grain material till they coalesce with neighbouring cavities to form a microcrack. Earlier work on HA has focussed on unit cells containing a single cavity, using average cavitation properties. Here, non-uniform cavitation properties on the grain-size scale are assumed in a polycrystalline aggregate, and unit cell analyses are performed to investigate the influence of the adjacent grains on the development of the grain-boundary HA. The numerical results are explained in terms of two simplified models which highlight the key parameters governing the grain deformation-grain boundary cavitation interaction process.  相似文献   

14.
Crampon  J.  Escaig  B. 《Journal of Materials Science》1978,13(12):2619-2626
Creep deformation in ultrafine-grained (0.1 to 1μm) Fe-doped magnesia polycrystals is studied in compression, at temperatures of 700 to 1050° C, and constant loads of 50 to 140 MPa. The stress exponent observed to be nearly unity and the strong grain size sensitivity (ėd −2.85) suggest that diffusional creep mechanisms dominate the deformation. In the grain size range of the present study the grain boundary diffusion contribution is significantly more important than lattice diffusion. Magnesium is tentatively identified as the rate-controlling species along grain boundaries from an analysis of the diffusivities inferred from the present work and from other authors for Fe-doped magnesia. Associated with the CNRS.  相似文献   

15.
The change in the fractal dimension of the grain boundaries during creep was investigated using an austenitic SUS304 steel at 973 K. The fractal dimension of the grain-boundary surface profile (the fractal dimension of the grain boundaries, D, 1 < D < 2) in the plane parallel to the tensile direction (in the parallel direction) and in the transverse direction, was examined on specimens deformed up to rupture (about 0.30 creep strain). Grain boundaries became serrated and the fractal dimension of the grain boundaries increased with increasing creep strain, because the density of slip lines which formed ledges and steps on grain boundaries increased as the creep strain increased. The increase in the fractal dimension due to creep deformation was slightly larger under the higher stress (118 MPa) than under the lower stress (98 MPa), while the increase of the fractal dimension with strain was a little larger in the specimens tensile-strained at room temperature (293 K) than in the crept specimens. These results were explained by the grain-boundary sliding and the diffusional recovery near grain boundaries, which lowered the increase of the fractal dimension with the creep strain. The fractal dimension of the grain boundaries in the parallel direction was slightly larger than that in the transverse direction in both creep at 973 K and tensile deformation at room temperature, especially at the large strains. This could be correlated with the shape change of the grains by creep or plastic deformation. Grain-boundary cracks were principally initiated at grain-boundary triple junctions in creep, but ledges, steps and carbide precipitates on serrated grain boundaries were not preferential nucleation sites for the cracks.  相似文献   

16.
The rate of diffusional creep varies with grain size x, either as 1/x 2 or 1/x 3, depending on whether lattice or grain boundary diffusion is dominating. Since the rate of grain growth is proportional to 1/x p, where p1, the creep and grain growth relationships can be combined to predict the transient creep that results from the two processes operating concurrently. An important result is obtained for grain boundary diffusion creep (Coble creep), where two regimes of behaviour are predicted depending on the value of p. For normal grain growth (p=1) and up to a critical value p=2, the transient gives rise to an upper limit to the grain boundary diffusional creep strain. For p>2, no limiting strain is predicted. The role of the limiting strain is discussed in the context of the various experimental attempts that have been made to verify the Coble mechanism.  相似文献   

17.
Continuous creep cavity nucleation by stochastic grain-boundary sliding   总被引:1,自引:0,他引:1  
Creep cavitation in metals and ceramics is generally considered to occur by the nucleation, growth, and coalescence of grain-boundary cavities. By considering grain-boundary slidings as the process driving force, a stochastic model is proposed for continuous cavity nucleation in metals and ceramics subjected to creep loading. The nucleation rate is shown to be directly proportional to the number of grain-boundary sliding events. The dependence of the number of cavities on grain boundary sliding displacement, creep strain, and time are established and compared with available experimental data of alumina, copper, and copper alloys. This comparison supports the contention that creep cavity nucleation in metals and ceramics does originate from stochastic grain-boundary sliding.  相似文献   

18.
Al2O3掺杂对YSZ固体电解质烧结及电性能的影响   总被引:5,自引:0,他引:5  
研究了用常规共沉淀法掺杂Al2O3对YSZ固体电解质的烧结及电性能的影响.结果表明:适量的Al2O3能提高YSZ材料的烧结性能,促使其致密化,但过量的Al2O3对材料的致密化不利;同时,材料的晶界电导随Al2O3含量的增大表现出先增大后减小的变化趋势,这与Al2O3对YSZ晶界两方面的不同影响有关,Al2O3偏析于晶界一方面能清除晶界上对氧离子电导不利的SiO2,但另一方面也会降低晶界空间电荷层中的自由氧离子空穴的浓度.  相似文献   

19.
Silicon is a model material for studying the sintering of covalently bonded non-oxide ceramics. The sintering of silicon has direct applications as well to polycrystalline photovoltaics and the reaction sintering of silicon nitride. Surface diffusion is found to be the dominant mass transport path for pure silicon of all particle sizes of interest. Both boron and oxygen are surface-active and effective in inhibiting surface transport, thereby allowing shrinkage to occur by either grain-boundary or lattice diffusion.  相似文献   

20.
The effect of a transition in creep behaviour in non-ductile ceramics (i.e. those with limited slip systems available) from diffusion controlled creep, to a mechanism involving non-viscous grain-boundary sliding and localized crack propagation is examined. Localized crack propagation is considered as a transition between diffusional creep and instantaneous fracture, and the fracture strength is used as a guide to predict the conditions necessary for the onset of this high strain-rate creep mechanism. In this way the variation in stress, temperature and grain size dependencies of creep rate reported in the literature for these materials may be explained and experimental evidence in support of the present hypothesis is presented.  相似文献   

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