汽车用AZ31镁合金的激光熔覆工艺研究

对汽车用AZ31合金进行激光熔覆表面改性处理,通过改变激光熔覆工艺参数的方法研究了基体材料和熔覆层的微观组织、硬度和耐磨性的变化趋势。结果表明,激光熔覆316L涂层的熔覆层硬度得到了极大提高,约为基体硬度的2.7倍。AZ31合金熔覆层的磨损机制主要为磨粒磨损和氧化磨损。     

AZ91D镁合金表面激光熔覆Al-Si合金涂层

用Nd:YAG脉冲激光器在镁合金AZ91D表面激光熔覆Al-Si合金,运用XRD、SEM、EDS等分析测试手段对合金层进行组织分析,并对合金层进行了显微硬度、耐磨性、耐腐蚀性等性能测试.研究表明激光熔覆Al-Si能够提高镁合金的硬度、耐磨性和耐腐蚀性.     

镁合金激光表面熔覆技术

镁及镁合金具有良好的物理和力学性能,是一种极具发展潜力的材料,但镁合金的耐蚀性较差,采用激光表面熔覆技术,可显著提高其表面的耐蚀性。本文综述了镁合金激光表面熔覆技术,并对今后镁合金激光表面熔覆技术的发展作出展望。     

镁合金激光表面熔覆技术

镁及镁合金具有良好的物理和力学性能，是一种极具发展潜力的材料，但镁合金的耐蚀性较差，采用激光表面熔覆技术，可显著提高其表面的耐蚀性。本文综述了镁合金激光表面熔覆技术。并对今后镁合金激光表面熔覆技术的发展作出展望。     

汽车用AZ31镁合金激光熔覆Al-Si涂层的组织与性能

通过激光熔覆Al-Si涂层的方法对AZ31镁合金表面进行了改性,研究了熔覆层的物相组成、显微组织、显微硬度、耐磨性和耐腐蚀性能。结果表明,熔覆层主要由Mg₂Si、Mg₁₇Al₁₂、Al₃Mg₂、Al₂Mg相组成,与基体呈冶金结合,硬度最高达到152 HV;耐磨性和耐腐蚀性较好,磨损失重及腐蚀速率分别为基体的1.75倍和1.88倍。     

镁合金表面激光熔覆研究现状

总结了镁合金表面激光熔覆的特点,介绍了镁合金表面激光熔覆技术的处理工艺和熔覆体系及各种熔覆层的组织特征及性能的研究现状,提出了今后镁合金激光熔覆工艺的发展趋势.     

AZ91D镁合金表面激光熔覆Al60Si40涂层研究

采用预置涂层法,通过5kW横流C02激光器在AZ91D镁合金表面激光熔覆A160Si40合金粉末,以达到改善镁合金表面性能的目的。利用扫描电镜（SEM）和x射线衍射仪（XRD）分析熔覆层的微观组织,利用显微硬度计测量熔覆层深度方向上的显微硬度,利用MM-200摩擦磨损实验机测试熔覆层的耐磨性能。研究表明：表面激光熔覆层的组织呈现亚共晶组织特点,主要由α-Mg,β—Mg17Al12和Mg2Si组成;熔覆层的最高显微硬度（270HV）是基体（90HV）的3倍,其耐磨性也明显提高。     

热处理对激光熔覆合金层组织性能的影响

本文用横流式CO_2气体激光器在碳钢基材表面上熔覆四种牌号的硬面合金层(NiWC25,Ni55,Fe450,Stellitel2),并对激光熔覆合金层进行不同温度下的回火热处理,然后用金相显微镜,耐磨试验机等对激光熔覆合金层回火前后的显微组织,硬度及耐磨性能进行了较详细的研究。结果表明:(1)四种牌号合金层的耐磨性均远大于碳钢的耐磨性,并且还具有良好的抗高温性能;(2)高温回火热处理可以细化合金层的组织,因而进一步提高其耐磨性。     

AZ31B镁合金表面喷熔Al涂层的组织和性能

目的提高AZ31B镁合金的耐蚀性。方法采用氧乙炔在AZ31B镁合金表面喷熔Al涂层,对喷熔的Al涂层进行扫描电镜(SEM)分析,采用能谱仪(EDS)对涂层进行面扫描检测涂层元素的分布情况。利用电化学分析法、浸泡试验检测喷熔涂层的耐蚀性,用维氏硬度计测试喷熔涂层的硬度。结果喷熔的Al涂层与AZ31B镁合金基体结合良好,呈现冶金结合。喷涂过程中,喷熔的Al涂层呈等轴晶生长。通过面扫描结果可知,喷熔涂层中发现Mg元素,说明基体中的Mg元素发生了扩散。通过电化学测试可知,喷熔Al涂层的自腐蚀电压为-1.45 V,比AZ31B镁合金的自腐蚀电压(-1.5 V)降低了0.05 V;喷熔Al涂层的自腐蚀电流密度为1.58×10~(-4) A/cm~2,约为AZ31B镁合金自腐蚀电流密度(8.66×10-4 A/cm2)的1/5。由浸泡实验可知,喷熔Al涂层的平均腐蚀速率约为AZ31B镁合金的1/5倍。喷熔Al涂层的显微硬度是AZ31B镁合金基体硬度的2.9倍。结论喷熔Al涂层的组织较好,性能比镁合金基体有所提高。     

AZ33M镁合金激光熔覆Al-Si涂层的组织与性能

利用激光熔覆技术在AZ33M镁合金表面制备了 Al-Si涂层,通过采用腐蚀电化学测试结合X射线衍射仪(XRD)、扫描电镜(SEM)及显微硬度计等对熔覆层微观组织和性能进行了表征.结果表明,熔覆层主要由Mg和Mg17Al12、Mg2Si及Mg2Al3相组成.熔覆层显微组织由柱状树枝晶和方向各异的树枝晶组成.由于第二相强化...     

AZ31B镁合金及其纳米复合材料的滑动磨损行为(英文)

采用复合铸造工艺制备AZ31B镁合金及其纳米复合材料,再对所得材料在350°C进行热挤压。采用标准的销-盘式摩擦磨损试验机对AZ31B镁合金及其纳米复合材料的室温滑动磨损行为进行研究。实验条件为法向载荷10N、滑移速度0.60~1.2m/s、滑移距离2000m。采用SEM观察来研究磨损表面的磨损机理。通过构建一个线性回归模型来研究试验参数对磨销磨损率的影响。与AZ31B镁合金相比,由于增强体的作用而导致的硬度增强使复合材料表现出低的磨损率。犁削、犁沟、分层和氧化构成混合的磨损机理。     

Study on microstructure and properties of laser surface melted layer of AZ31B magnesium alloy

An attempt has been made to improve the surface properties of AZ31B magnesium alloy through solid solution hardening and refinement of microstructures using a CO_2 laser as a heat generating source. X-ray diffraction (XRD) was used to identify the phases. Microstructure and properties of laser melted layer of AZ31B magnesium alloy were observed or tested by means of optical microscope (OM), scanning electron microscope (SEM), micro-hardness equipment and electrochemical corrosion equipment etc. The results show that the microstructure of laser melted layer becomes finer significantly and uniform. Compared with the substrate, the content of β-Mg_(17)Al_(12) phase of melted layer decreases comparatively. Microhardness of the laser melted layer is improved to 50-95HV_(0.05) as compared to 40-45HV_(0.05) of the AZ31B Mg alloy substrate. The results of electrochemical corrosion show that the corrosion resistance of laser surface melted layer has been improved.     

AZ31B镁合金在模拟流动海水中的腐蚀行为

利用质量损失法及X射线衍射（XRD）、扫描电镜（SEM）测试手段研究了铸态和挤压态AZ31B镁合金在模拟流动海水中浸泡12 h的腐蚀行为及随流速变化的规律。试验结果表明,AZ31B铸态镁合金试样的耐蚀性要远大于挤压态试样,且二者的腐蚀速率随搅拌速度增加的变化趋势有所不同：铸态试样的腐蚀速率随搅拌速度的增加近似呈线性上升,而挤压态试样的腐蚀速率随搅拌速度的增加而先增大后下降。     

AZ31镁合金表面碱性化学镀镍工艺研究

试验研究了AZ31镁合金表面碱性化学镀镍工艺。采用扫描电镜(SEM)、能谱成分分析(EDS)和X射线衍射(XRD)等方法对镀镍层的表面形貌、镀层成分及物相结构进行了分析,并测定了AZ31镁合金及镀层在w(NaCl)=3.5%的水溶液中的腐蚀电位和极化曲线,以此评价镀层的耐腐蚀性能。结果表明,预镀镍层为晶格畸变的晶态低磷镀层,二次镀镍层为非晶态高磷镀层,镁合金表面腐蚀电位在化学镀镍后明显升高,二次镀镍后钝化电位范围明显扩大,其耐腐蚀性能明显优于预镀镍层的。     

不同激光功率下镁合金表面激光熔覆Ni60合金涂层的显微组织和磨损性能

为提高镁合金表面的耐磨性,利用5kW横流连续CO2激光器在AZ31B镁合金表面熔覆Ni60合金粉末,制备了无裂纹、气孔等缺陷的熔覆层。分析讨论了不同激光功率下熔覆层的显微组织和磨损性能。结果表明:熔覆层的显微组织为典型的枝晶状态,且随着激光功率的增加,枝晶尺寸增加;不同的激光功率下,熔覆层都由Mg、MgNi2、Mg2Ni3Si、Mg2Ni、Mg2Si和FeNi组成,但当激光功率增加时,Mg相含量逐渐减小,其它相含量逐渐增多。在枝晶细化和各种金属间化合物的共同作用下,熔覆层的显微硬度和耐磨性能都得到提高,且激光功率P=3 000W时,提高程度最大,即显微硬度提高了840%～1 102%,磨损失量是原始AZ31B镁合金的8.57%。     

AZ31镁合金表面液相渗铝的工艺与性能

采用液相扩渗技术在挤压态AZ31镁合金表面快速渗入铝，在合金表面获得过共晶渗层，并对渗层的成分、相组成、扩渗过程、纳米硬度和腐蚀性能进行分析。结果表明：AZ31镁合金在480℃热扩渗铝过程中发生了“熔化—凝固”变化，渗层为典型的过共晶组织：渗铝层含有Mg17A112相和镁的铝饱和固溶体，这种渗层具有较高的纳米硬度和较好的耐腐蚀性能；通过提高扩渗温度进行液相扩渗可以大大提高扩渗速度，但由于快速凝固收缩会造成表层产生起伏现象，控制冷却速度可以将表层起伏控制在可接受的范围。     

Enhanced corrosion performance of magnesium phosphate conversion coating on AZ31 magnesium alloy

Magnesium phosphate conversion coating (MPCC) was fabricated on AZ31 magnesium alloy for corrosion protection by immersion treatment in a simple MPCC solution containing Mg²⁺ and PO^3?₄ ions. The MPCC on AZ31 Mg alloy showed micro-cracks structure and a uniform thickness with the thickness of about 2.5 µm after 20 min of phosphating treatment. The composition analyzed by energy dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy revealed that the coating consisted of magnesium phosphate and magnesium hydroxide/oxide compounds. The MPCC showed a significant protective effect on AZ31 Mg alloy. The corrosion current of MPCC was reduced to about 3% of that of the uncoated surface and the time for the deterioration process during immersion in 0.5 mol/L NaCl solution improved from about 10 min to about 24 h.     

Wear behaviour of hot rolled AZ31B magnesium alloy as candidate for biodegradable implant material

Surface integrity and tribological behaviour of implant materials have a critical impact on their performance in the body. To understand wear behaviour well, the present article focuses on the sliding wear behavior of hot rolled AZ31B magnesium alloy which is a good candidate for biodegradable implant material. Dry-sliding conditions which include pin-on disc method with heat-treated high-carbon steel disc as counterface were used. Wear rates at a fixed sliding distance of 5000 m were measured at sliding velocities of 0.25, 0.5, 1 and 2 m/s, and loads of 10, 20, 40 and 80 N. Microstructure of worn surfaces of pins was characterized using SEM/EDS. Wear mechanism maps of the investigated materials were composed to understand comprehensively. According to test results, abrasive wear occurred at load of 20 N and sliding speed of 0.25 m/s while melting wear was predominant at load of 80 N and sliding speed of 2 m/s. Results show that ultra-severe plastic deformation is the main wear mechanism at the highest applied load and sliding velocity speed for the investigated alloy. Consequently, hot rolled AZ31B magnesium alloy exhibited a good wear resistance due to fine microstructure and high hardness.     

Effect of Na2B4O7 on iron reduction in magnesium alloys AZ31 and AZ91

Effect of Na2B4O7, a new iron reduction agent, on iron reduction in magnesium alloys AZ31 and AZ91 was studied. The iron contents in the magnesium alloy AZ31 and AZ91 reduce dramatically to less than 0.002% （mass fraction） with the increasing addition of Na2B4O7, and the corrosion resistance of the alloys was greatly improved. According to the thermodynamic analysis and the iron and boron distributions in different parts of the alloy melts, it can be inferred that the mechanism for iron reduction in magnesium alloys by Na2B4O7 processing is that boron atoms combine with iron atoms and settle down in the melting sludge. The XRD result confirms it.     

AZ31B镁合金再结晶过程的动力学

对AZ31B镁合金热轧板材退火处理的静态再结晶进行了动力学分析。结果表明:AZ31B镁合金再结晶晶粒分数与退火时间的关系可以用JMAK方程进行描述,由实验数据计算得到AZ31B镁合金再结晶激活能为59.6~69.3 kJ/mol,在200,250,300,350℃和400℃时再结晶完成的时间分别为373~389,72.1~87.2,18.0~26.3,5.6~9.6 min和2.1~4.1 min,计算同时得到AZ31B镁合金再结晶动力学曲线,该曲线可以为制定AZ31B镁合金退火处理工艺提供参考。