共查询到16条相似文献,搜索用时 750 毫秒
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对ISO 10634-1995“水质———水介质中用于难溶有机物生物降解性能评价水溶液的制备与处理指南”推荐的方法进行逐一筛选,以期建立油溶性表面活性剂生物降解度测定的标准方法。实验结果表明,将油溶性表面活性剂超声乳化后,制备成粒径200 nm~300 nm乳液后,立即分散于水体系中进行降解,结果重复性较好,并且不影响油溶性表面活性剂生物降解度。用该方法对常见的油溶性表面活性剂的生物降解度进行了测定,结果表明大部分油溶性表面活性剂具有很好的生物降解性能;其降解规律与水溶性表面活性剂类似,疏水链长决定油溶性表面活性剂的生物降解性能,而亲水基团影响其生物降解速度。 相似文献
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《中国洗涤用品工业》2017,(8)
简述了表面活性剂对环境的影响及研究进展。着重讨论了表面活性剂的研究方法及表征,各种生物降解过程、降解机理和影响表面活性剂生物降解的因素。并对表面活性剂的安全性及毒性、温和性及对皮肤和黏膜的刺激性进行了简要介绍。 相似文献
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表面活性剂生物降解和光降解技术研究进展 总被引:6,自引:0,他引:6
表面活性剂的生物降解和光降解技术正受到越来越多的关注。介绍了该两项技术在国内外的研究现状;讨论了表面活性剂生物降解和光降解的研究成果;并对近几年发展起来的表面活性剂光催化降解的催化剂、工艺组合作了简要介绍。提出了表面活性剂生物降解和光降解的今后研究方向。 相似文献
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Daisuke Ono Shingo Yamamura Masaki Nakamura Tokuji Takeda Araki Masuyama Yohji Nakatsuji 《Journal of the American Oil Chemists' Society》1995,72(7):853-856
The biodegradability of new carboxylate types of “acid-sensitive” cleavable surfactants bearing a 1,3-dioxolane ring was measured
by the biochemical oxygen demand (BOD) method in the presence of activated sludge. The result for sodium dodecanoate, measured
under the same conditions, was used as a standard for evaluating the biodegradability of these cleavable surfactants. For
cleavable surfactants derived from epoxides and oxocarboxylates, the biodegradation was considerably influenced by the length
of the lipophilic alkyl chain, the presence of the oxymethyl moiety in the lipophilic group, and the number of methylene units
between the dioxolane ring and the carboxylate group. For another type of cleavable surfactant, 2-(long-chain alkyl)-1,3-dioxolane-4,5-dicarboxylate,
the biodegradation rate for the compound, bearing a proton at position 2 in the dioxolane ring, is faster than that for the
corresponding compound bearing a methyl group at position 2. 相似文献
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表面活性剂厌氧生物降解研究进展 总被引:1,自引:0,他引:1
对表面活性剂生物降解进行了全面概述,包括表面活性剂生物降解的概念和分类,表面活性剂厌氧生物降解试验方法和分析方法,最后对常见表面活性剂的厌氧生物降解性能进行了介绍。 相似文献
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The primary aerobic biodegradation of several cationic and amphoteric surfactants has been studied by using the shaking-flask
degradation test and orange II spectrophotometric analysis. The results show that cationic and amphoteric surfactants can
be readily biodegraded, with their degradation exceeding 94%. The degradation kinetics can be accurately described by the
Boltzmann model. The relationship between structure and biodegradability is discussed. The presence of hydrophobic groups
has a strong effect on the biodegradability of these surfactants. Biodegradability decreases with increasing chain length.
The presence of hydrophilic groups mainly affects the degradation rate of these surfactants, but not their ultimate biodegradeability.
Bio-degradability is deterred and degradation is slowed as steric hindrance increases. Degradation rates increase markedly
when hydrophilic groups containing an amide bond are pres-ent. 相似文献
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Qingbin Dong Yonghong Zhao Guangliang Zhang Yingjie Ren 《Journal of surfactants and detergents》2016,19(6):1327-1332
This investigation was performed to determine the anaerobic biodegradation of alkyl ethoxy glucoside (AEG) nonionic surfactants using the OECD 311 method. The influence of different initial concentrations of AEG on the primary biodegradation rate was investigated using the anthrone analysis method. The results show that different initial concentrations have similar good biodegradability and the biodegradation rate can reach more than 90 % even at the highest initial concentration of 100 mg/l. Alkyl polyglucoside (APG) surfactants have previously been confirmed as readily biodegradable. The profile of concentration changes over the incubation time of AEG and APG had similar trends. Therefore, AEG are also considered as readily biodegradable. The gas chromatograph‐mass spectrometer analytical method was used to identify the metabolites. The content of alcohol ethoxylate (AEO) increased with decrease in the number of AEG at the initial stage of degradation. It was found that AEO with longer EO chains disappeared first. Accordingly, a degradation pathway that accounts for the experiment results was proposed. 相似文献
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Encarnación Jurado Mercedes Fernández-Serrano Manuela Lechuga Francisco Ríos 《Journal of surfactants and detergents》2012,15(1):1-7
The ultimate aerobic biodegradability and toxicity of three ether carboxylic derivative surfactants having different alkyl
chains and degrees of ethoxylation were investigated. Ultimate aerobic biodegradability was screened by means of dissolved
organic carbon determinations at different initial surfactant concentrations. For comparison, the characteristic parameters
of the biodegradation process, such as half-life, mean biodegradation rate, and residual surfactant concentration, were determined.
Increased surfactant concentrations decreased mineralization and lengthened the estimated half-life. The results demonstrate
that the ultimate aerobic biodegradability is higher for the surfactants with the shortest alkyl chain and highest degree
of ethoxylation. Toxicity values of the surfactants, and their binary mixtures, were determined using three test organisms,
the freshwater crustacea Daphnia magna, the luminescent bacterium Vibrio fischeri and the microalgae Selenastrum capricornutum. The toxicity is lower for the surfactants with the shortest alkyl chain and highest degree of ethoxylation. The toxicity
of binary mixtures of the three ether carboxylate surfactants at a 1:1 weight ratio was also measured. The least toxic mixture
is formed by the surfactants having lower individual toxicity. 相似文献
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A process coupling absorption of a gaseous pollutant in an organic phase and biodegradation was considered to treat hydrophobic volatile organic compounds (VOC). The purpose of this work was to choose the best solvent for the absorption of some VOC (dimethylsulfide, dimethyldisulfide, and toluene) and to examine solvent biodegradability as well as VOC biodegradation by activated sludge. Some experiments were carried out on some selected solvents leading to select di‐2‐ethylhexyl‐adipate (DEHA) and poly‐di‐methyl‐siloxane (PDMS) for their high absorption capacity. Biodegradation experiments showed that toluene and DMDS can be removed in solvent on water emulsions, while DMS removal by biodegradation remains to confirm owing to its high volatility. However, experiments showed DEHA biodegradation, contrarily to PDMS which was therefore selected for subsequent experiments. 相似文献