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1.
Joaquín Quesada 《European Journal of Lipid Science and Technology》2003,105(6):281-287
Fatty acid methyl esters from low‐erucic and low‐linolenic rapeseed oil were used to produce alkenyl succinic anhydrides. A second‐order Doehlert uniform network design was used to investigate the influence of the reaction temperature and the molar ratio between the maleic anhydride and the main unsaturated rapeseed oil methyl esters on the yield of alkenyl succinic anhydride from methyl oleate. Further subjects of investigation were the conversion of methyl oleate, the formation of side reaction products, the Gardner color of the product and its viscosity, and finally the content of maleic anhydride remaining in the medium after the reaction. Alkenyl succinic anhydride from methyl oleate was isolated by column chromatography and analyzed by IR, 1H‐ and 13C‐NMR and MS. The optimal reaction conditions for obtaining the maximum yield of alkenyl succinic anhydride from methyl oleate in the experimental domain (80%) were 210‐220 °C and a maleic anhydride/rapeseed oil methyl ester molar ratio of 1.5. However, the products synthesized in these conditions showed a high degree of viscosity (0.45 kg m?1 s?1), a very dark color (18 Gardner color) and a high content of undesirable side products (6%), which could hinder their industrial use. A molar ratio of less than 1.5 led to a clearer and less viscous product, although with a lower alkenyl succinic anhydride content. 相似文献
2.
Laure Candy Carlos Vaca-Garcia Elisabeth Borredon 《European Journal of Lipid Science and Technology》2005,107(1):3-11
Alkenyl succinic anhydrides (ASA) have been prepared by ene‐reaction of high‐oleic sunflower oil methyl esters with maleic anhydride in a 50% xylene medium. Response surface methodology (RSM) was used to investigate the influence of two factors: reaction temperature and molar ratio between maleic anhydride (MA) and methyl esters (SME). The studied parameters in 8‐h reactions were the methyl oleate conversion, the distillation yield in ASA, and responses allowing the indirect estimation of side reaction products: clarity index and dynamic viscosity. The highest yield in ASA (>70%; clarity index ≈10) was reached for a temperature of 240–250 °C with a molar ratio of 1.5–1.7. But for an industrial application requiring minimized side products (clarity index >40), the optimal synthesis conditions were: temperature between 220 and 235 °C and molar ratio of 1.2–1.35 (yield ≈55%). Such conditions did not provide a medium free of side products, even if xylene decreased their formation. Compared to solvent‐free synthesis, conversion was lower with xylene. With solvent, higher temperatures were needed to reach the same yields. Supplementary heating compensated the reagent dissolution effect that slows down the kinetics of the ene‐reaction. The influence of reaction time at 220 °C with a MA/SME ratio of 1.2 in a 50% xylene medium was studied. A reaction time of 8–10 h provided a good compromise between ASA yield and side products. 相似文献
3.
A new process for catalyst-free production of biodiesel using supercritical methyl acetate 总被引:1,自引:0,他引:1
Production of glycerol is unavoidable in the conventional processes for biodiesel fuel (BDF) production. In this research, therefore, we investigated conversion of rapeseed oil to fatty acid methyl esters (FAME) and triacetin (TA) by processing of supercritical methyl acetate. As a result, it was discovered that the trans-esterification reaction of triglycerides with methyl acetate can proceed without catalyst under supercritical conditions, generating FAME and triacetin. In order to study the effect of the triacetin addition to FAME, its effect was investigated on various fuel characteristics. It was, consequently, discovered that there were no adverse effects on the main fuel characteristics when the molar ratio of methyl oleate to triacetin was 3:1, corresponding to the theoretically derived mole ratio from the trans-esterification reaction of rapeseed oil with methyl acetate. Moreover, the addition of triacetin to methyl oleate improved the pour point and triacetin has high oxidation stability. Therefore, by defining BDF as a mixture of methyl oleate with triacetin, we can obtain an improved yield of 105% of BDF by the supercritical methyl acetate, in excess of the yield of the conventional process. 相似文献
4.
G. Silverstone C. I. Atherton J. W. Breakey 《European Journal of Lipid Science and Technology》1968,70(6):426-429
Dehydration and splitting of hydrogenated castor oil produces a mixture of fatty acids containing about 80% of the iso-oleic acids having the double bond in 11 and 12 positions in approximately equal proportions (as demonstrated by periodate/permanganate scission) and largely in the trans configuration. This technical iso-oleic acid reacts as expected with maleic anhydride to produce a mixture of isomeric iso-oleyl succinic anhydrides. When the oleate is reacted as the methyl ester the crude product can be distilled to produce methyl iso-oleyl succinic anhydride (M. O. S. A.) free from polymeric material. The yields of product under different conditions of time, temperature and ratio of maleic anhydride to fatty esters have been studied. 相似文献
5.
A new kind of silicon-based biological lubricating base oil with good viscosity-temperature behavior,viscosity index,thermostability,oxidation stability and wear resistance performance was synthesized as a derivative of methyl oleate.Trimethylsilylation reaction was introduced to further improve methyl oleate oxidation stability and lubricity after epoxidation and open-ring reactions.The order of effectiveness of acid binding agent was N,N-diisopropylethylamine(DIEA) pyridine diethylamine triethylamine,and the effects of various parameters on the trimethylsilylation reaction as well as on the silicon-oxygen bond stability and reaction yield were studied.A maximum yield of 34.54%was achieved at hydroxyl/trimethyl chlorosilane/DIEA molar ratio of1:1.25:1,reaction temperature 40℃,reaction time 1.5 h. 相似文献
6.
Hem Joshi Joe Toler Bryan R. Moser Terry Walker 《European Journal of Lipid Science and Technology》2009,111(5):464-473
Canola oil was transesterified using a 1 : 1 molar mixture of methanol and ethanol (M/E) with potassium hydroxide (KOH) catalyst. The effects of catalyst concentration (0.5–1.5 wt‐%), molar ratio of M/E to canola oil (3 : 1 to 20 : 1) and reaction temperature (25–75 °C) on the percentage yield measured after 2.5 and 5.0 min were optimized using a central composite design. A maximum percentage yield of 98% was obtained for a catalyst concentration of 1.1 wt‐% and an M/E to canola oil molar ratio of 20 : 1 at 25 °C at 2.5 min, whereas a maximum percentage yield of 99% was obtained for a catalyst concentration of 1.15 wt‐% and all molar ratios of reactants at 25 °C at 5 min. Statistical analysis demonstrated that increasing catalyst concentration and molar ratio of reactants resulted in curvilinear and linear trends in percentage yield, both at 2.5 and 5 min. However, reaction temperature, which affected the percentage yield at 2.5 min linearly, was insignificant at 5 min. The resultant mixed methyl/ethyl canola esters exhibited enhanced low‐temperature performance and lubricity properties in comparison to neat canola oil methyl esters and also satisfied ASTM D6751 and EN 14214 standards with respect to oxidation stability, kinematic viscosity, and acid value. 相似文献
7.
Continuous production of palm methyl esters 总被引:4,自引:0,他引:4
A system for continuous transesterification of palm oil was developed using a continuous stirred-tank reactor (CSTR) and pumps
for continuous delivery of oil and catalyst and for continuous removal of product. Potassium hydroxide was used as the catalyst,
the methanol-to-oil molar ratio was 6∶1, and reaction temperature was 60°C. The yield of methyl esters increased from 58.8%
of theoretical yield at a residence time of 40 min to 97.3% at a residence time of 60 min. However, higher residence times
decreased the production rate. During long-term continuous operation, the CSTR displayed steady state conditions in terms
of product profile and methyl ester concentration. This process has good potential in the manufacture of biodiesel. 相似文献
8.
9.
In this study, transesterification of rapeseed oil using subcritical methanol conditions was studied. The objective of the work was characterizing the methyl esters for its use as biodiesel in compression ignition motors. The variables affecting the methyl ester yield during the transesterification reaction, such as, the catalyst type and content, reaction temperature and pressure, the presence of hexane as co-solvent, the methanol oil molar ratio and the methanol hexane molar ratio were investigated to optimize the reaction conditions. The evolution of the process was followed by gas chromatography, determining the concentration of the methyl esters at different reaction times. The biodiesel was characterized by its density, viscosity, saponification value, iodine value, acidity index and water content, according to ISO norms. High methyl ester yield and fast reaction rate could be obtained even if the reaction pressure was relatively low, which is quite favorable to the production of biodiesel in industry. 相似文献
10.
11.
Alum has been taken beyond its traditional roles as a water treatment chemical and a confectionary additive to a new role as a catalytic precursor in biodiesel production. Its catalytic potentials were empirically proved via palm oil transesterification with methanol and application of solid state instrumental characterization techniques. The catalyst was very clean, efficient, simple and cheap to produce, and could be clearly separated from the reaction products. When the reaction was carried out under the conditions of catalyst to oil ratio of 7.09 wt%, reaction time of 12 h and temperature of 170 °C, methanol to oil molar ratio of 18:1 and catalyst preconditioned at 550 °C, the yield of fatty acid methyl ester (FAME) obtained was 92.5 wt%. 相似文献
12.
以酸化油为原料,自制离子液体为催化剂,采用甲酯化方法制备脂肪酸甲酯。通过考察甲醇与脂肪酸物质的量比、离子液体催化剂加入量、反应温度和反应时间对甲酯化反应的影响,最佳反应条件:甲醇与脂肪酸物质的量比9∶1,离子液体催化剂用量为甲醇与游离脂肪酸总质量的25%,反应温度65 ℃,反应时间2.0 h。通过测量原料酸化油与产物的含水量,证明离子液体催化剂具有良好的带水性,有利于甲酯化反应的进行。该方法不仅可降低生产成本,减少环境污染,也能避免油脂资源问题,具有较高经济效益和社会效益。 相似文献
13.
固体碱催化黄连木籽油制备生物柴油 总被引:1,自引:1,他引:1
制备了K2CO3/Mg(A l)O固体碱催化剂,适宜制备条件为:K2CO3负载量30%、在700℃下焙烧4 h。用比表面积测定仪、X射线衍射仪、红外光谱仪对其进行了表征。以黄连木籽油为原料,开展了酯交换法制备生物柴油的研究,考察了主要影响因素:醇油摩尔比、催化剂用量、反应时间和反应温度对酯交换反应的影响,得到的酯交换反应适宜条件为:以黄连木籽油0.01 mol计,醇油摩尔比12∶1、催化剂用量为黄连木籽油质量的4.0%、反应时间2.5 h、反应温度68℃。在该条件下生物柴油的收率可达99%以上。催化剂经4次循环使用,生物柴油收率仍可保持在96%以上。用FTIR1、HNMR对所制备的产品进行了表征,证明产品中含有饱和脂肪酸甲酯和不饱和脂肪酸甲酯。 相似文献
14.
根据盘锦原油的性质,成功研制了以甲基丙烯酸、十四醇、马来酸酐为原料的共聚物ME-TA-MA降凝降粘剂。单因素实验确定了合适的工艺条件。酯化:n(十四醇)∶n(甲基丙烯酸)=1.25∶1,m(催化剂):m(甲基丙烯酸+十四醇)=2%,m(溶剂)∶m(甲基丙烯酸+十四醇)=50%;聚合:n(马来酸酐)∶n(酯化产物)=1∶1,m(引发剂):(甲基丙烯酸十四酯+马来酸酐)=1.5%,m(溶剂)∶m(甲基丙烯酸十四酯+马来酸酐)=50%,聚合温度80℃,聚合时间3h。IR结果表明,所制备产物的官能团结构与设计的目标产物相符。将最佳条件下合成的产物以m(降凝剂)∶m(原油)=0.23%的加剂量加入到盘锦原油中,凝点可降低13℃,粘度可降低61.33%。 相似文献
15.
This paper evaluates the production of methyl esters from Oreochromis niloticus (Nile tilapia) oil and methanol. The reaction was carried out applying low-frequency high-intensity ultrasound (40 kHz) under atmospheric pressure and ambient temperature. Response surface methodology (RSM) was used to evaluate the influence of alcohol to oil molar ratio, catalyst concentration (sulfuric acid) and temperature on the yield of O. niloticus oil into methyl esters. Analysis of the operating conditions by RSM showed that the most important operating condition affecting the reaction was the alcohol to FFA molar ratio. The highest yield observed was of 98.2% after 90 min of reaction. The optimal operating condition was obtained applying an alcohol to oil molar ratio of 9.0 and a catalyst concentration of 2.0% w/w and temperature of 30 °C. 相似文献
16.
Continuous transmethylation of palm oil in an organic solvent 总被引:6,自引:0,他引:6
Kanit Krisnangkura Ratchadaporn Simamaharnnop 《Journal of the American Oil Chemists' Society》1992,69(2):166-169
Palm oil was transmethylated continuously at 70°C in an organic solvent with sodium methoxide as a catalyst. The optimum ratio
of toluene to palm oil is 1∶1 (v/v). When the methanol-to-oil molar ratio was 13∶1, transmethylation was 96% complete within
60 seconds. At higher molar ratio (17∶1), transmethylation was 99% complete in 15 seconds. For lower molar ratios of methanol-to-oil
(9∶1 and 5.8∶1), yields of palm oil methyl ester (POME) were 84 and 58%, respectively. Benzene was also a good solvent for
transmethylation, but the yield of POME was slightly lower than toluene. Tetrahydrofuran did not accelerate transmethylation. 相似文献
17.
In recent years, vegetable oils, as renewable raw materials, became a promising feedstock for chemicals and biodiesel production. The main products derived from oils are esters of fatty acids, especially methyl esters, obtained by their transesterification with methanol, in presence of acid or alkaline catalysts. The use of such catalysts implies the need for washing operations, which leads to environmental pollution. In the present paper, the response surface methodology based on a central composite design, has been developed to optimize the process of transesterification of corn oil. Ba(OH)2 in presence of diethyl ether was used as catalyst. A quadratic polynomial equation was obtained. It correlates the reaction parameters [methanol/oil molar ratio (x r), reaction time (x t) and catalyst concentration (x c)] with methyl esters yield. Analysis of variance analysis showed that only methanol/oil molar ratio and catalyst concentration have had the most significant influences on the conversion. The maximum methyl esters yield was obtained using the following optimum parameters: methanol/corn oil ratio of 11.32, reaction time of 118 min and catalyst concentration of 3.6 wt%. 相似文献
18.
A fractionally distilled C14−C16 fatty acid methyl ester, derived from palm oil, was sulfonated with gaseous SO3 in a falling film reactor to form an α-sulfo fatty acid methyl ester (α-SF; unbleached and unneutralized form). The included
dark-colored impurities were then separated from α-SF as a diethyl ether-insoluble matter. After purification by thin-layer
chromatography, the colored species were analyzed by ion-exchange chromatography, gel-permeation chromatography, and nuclear
magnetic resonance spectrometry. These data suggested that the colored species were polysulfonated compounds with conjugated
double bonds. Minor components in the raw fatty acid methyl ester, found by gas chromatography/mass spectrometry, were spiked
into the purified methyl palmitate and then sulfonated. The unsaturated methyl ester and hydroxy ester showed the worst color
results. The methyl oleate and methyl 12-hydroxystearate were then sulfonated and analyzed. Deep black products were obtained,
which showed the same properties as the colored species in α-SF. It was concluded that low levels of unsaturated fatty acid
methyl esters and hydroxy esters in the fatty acid methyl ester are the main causes of the coloring. 相似文献
19.
20.
Structural changes occurring in the rapeseed oil methyl ester upon catalytic oxidation at 200 °C were examined. Oxidative decomposition of fatty acid chains to lower molecular weight compounds and the formation of oligomers were the major oxidation pathways at 200 °C. FT-IR and 1H NMR examinations, as well as the fall in iodine number, revealed the disappearance of double bonds. Quantitative analysis of the rapeseed oil methyl ester and the liquid products of its oxidation showed that oxidation of fatty acid methyl esters possessing three and two double bonds was practically complete whereas for structures possessing one double bond the loss of unsaturation amounted to 25% only. The decrease in iodine number from about 110 to about 65 and the 1.5-fold increase in molecular weight of the liquid products in the course of 25-h oxidation suggest that only a part of the unsaturated bonds in the fatty acid methyl ester was engaged in the formation of liquid oligomers and volatile oxidation products. The addition of dicumyl peroxide promoted the formation of organic peroxides during the initial stage of oxidation, which resulted in a higher molecular weight of the liquid products. The volatile oxidation products were found to contain lower molecular weight aldehydes, ketones, free fatty acids and their methyl esters, alkylfurans, lactones, n- and isoalkanes. The reaction schemes for their formation were presented. The results of the study are of importance to the optimization of the conditions for oxidation of the ester in order to obtain a quality ecological bitumen flux. 相似文献