单原子层沉积原理及其应用

传统的薄膜材料制造方法已不能满足未来元器件和集成电路制造的要求,原子层沉积技术由于具有精确的厚度控制、沉积厚度均匀性和一致性等特点,已成为解决微电子制造相关超薄膜材料制造问题的主要解决方法之一,也将成为新的纳米材料和纳米结构的制造方法之一。综述了原子层沉积技术的原理、技术设备要求和应用。     

原子层沉积技术研究及其应用进展

原子层沉积(ALD)技术是制备复杂纳米结构材料以及材料表面改性的关键技术,该技术已得到了国内外学术界的大量研究。简单介绍了ALD技术、沉积过程、该技术的优点以及该技术可以沉积的薄膜材料,重点论述了ALD技术的应用进展,主要包括半导体方面(如IC互连技术、电容器、太阳电池晶体硅表面钝化)以及纳米结构材料方面(如催化剂与燃料电池、光催化、太阳电池、分离膜)。最后,指出了目前ALD在材料制备和生产工艺方面所面临的挑战,并对其未来发展进行了展望。     

基于ALD技术的高性能光电探测器研究进展

采用原子层沉积(ALD)技术制备的薄膜具有致密性高、保形性高、平滑性好、缺陷密度低、厚度可精准调控等优势,被广泛应用于各类光电器件中.利用ALD技术制备的功能薄膜可以明显改善光电探测器的暗电流、探测率和线性动态范围等性能.以基于ALD技术的高性能光电探测器为主题,首先详细介绍了热ALD生长薄膜的基本原理,同时简要介绍了等离子体增强ALD技术生长薄膜的基本原理.然后依据光电探测器中薄膜的功能不同,依次总结了基于ALD技术制作的活性层、钝化层、界面层、电荷传输层等实现高性能光电探测器的研究进展.最后对ALD技术在光电探测器领域的发展趋势和挑战进行了展望.     

等离子体增强原子层沉积原理与应用

等离子体增强原子层沉积(PEALD)是一种低温制备高质量超薄薄膜的有效手段,近年来正受到工业界和学术界广泛的关注。简要介绍了PEALD的发展历史和生长原理。描述了PEALD常见的三种设备构造:自由基增强原子层沉积、直接等离子体沉积和远程等离子体沉积,比较了它们的优缺点。着重评述了PEALD的特点,主要具有沉积温度低、前驱体和生长材料种类广、工艺控制灵活、薄膜性能优异等优势,但也面临着薄膜三维贴合性下降和等离子体损伤等挑战。列举了PEALD的一些重要应用,如在金属薄膜制备、铜互连阻挡层、高介电常数材料、薄膜封裹等领域的应用。最后展望了PEALD的发展前景。     

原子层沉积制备ZnO薄膜研究进展

随着半导体技术的发展,ZnO作为第三代半导体材料,具有禁带宽度大、载流子漂移饱和速度高和介电常数小等优点,更适合制作蓝光和紫外光的发光器件。与传统的薄膜制备技术相比,原子层沉积技术(ALD)在膜生长方面具有生长温度低、厚度高度可控、保形性好和均匀性高等优点,逐渐成为制备ZnO薄膜的主流方法。综述了ALD制备ZnO薄膜的反应机制、生长机制和掺杂方面的研究进展,针对当前ZnO薄膜p型掺杂的难点,指出了V族元素中的大半径原子(磷和砷等)掺杂有可能成为制备高质量、可重复和稳定的p型ZnO的潜力研究点,最后总结和展望了ALD制备ZnO薄膜的应用前景和研究趋势。     

厚度与带隙可调、原子层沉积的超薄五氧化二钒纳米晶薄膜

利用原子层沉积方法制备V_2O_5纳米片晶薄膜.薄膜厚度可以被精确控制,并对纳米晶V_2O_5薄膜的结构形貌、光学带隙和拉曼振动有显著影响.原子层沉积过程中V_2O_5薄膜生长的两个阶段导致薄膜具有两个光学带隙,这将有助于理解超薄薄膜生长与功能应用.     

硫化锌薄膜的原子层沉积生长及表征

为满足硫化锌(ZnS)薄膜在光学薄膜领域进一步应用的要求,基于原子层沉积(Atomic Layer Deposition, ALD)技术在130℃温度下以二乙基锌(DEZ)和硫化氢(H2S)为反应源,在砷化镓(GaAs)衬底表面沉积了ZnS薄膜。用扫描电子显微镜(Scanning Electron Microscope, SEM)分析了样品的表面形貌和膜界面特性,用X射线衍射仪(X-ray Diffraction, XRD)分析了薄膜的结构特性,并通过X射线光电子能谱(X-ray Photoelectron Spectroscopy, XPS)分析了薄膜的化学成分。研究了厚度对薄膜结构和形貌的影响。结果表明,得到的ZnS薄膜为多晶结构,薄膜的厚度随循环数线性增加,速率为1.45 ?/cycle。对在75℃温度下烘烤48 h后的薄膜进行了XPS分析,得出的Zn/S比为1.07:1,表明烘烤除去了薄膜中残存的H2S。以较短生长时间得到的较薄的薄膜具有更好的表面平整度和更致密的结构。     

退火处理对锑化铟MIS器件C-V特性的影响

采用原子层沉积技术制备Al2O3薄膜作为InSb材料介电层,制备了MIS器件,研究了金属化后不同退火温度对界面特性的影响.利用C-V测试表征了MIS(metal-insulator-semiconductor)器件的界面特性,结果表明Al2O3介电层引入了表面固定正电荷,200℃和300℃退火处理可有效减小慢界面态密度...     

热型ALD技术制备镍薄膜及其金属硅化物

金属硅化物材料具有较低的接触电阻,并且与硅材料有较好的兼容性,所以在互补金属氧化物半导体(CMOS)器件中被看作是重要的电极材料。形成镍金属硅化物的关键是镍金属单质的淀积工艺。如何在大深宽比纳米尺度的三维结构中沉积保形性好、纯度高、导电性好的镍金属单质薄膜是亟需解决的问题。利用热法原子层沉积(ALD)技术,以一种新型脒基镍前驱体[Ni(iPr-MeAMD)]_2,在深宽比为10:1的硅基底沟槽中沉积得到纯度高、保形性好、连续平滑的镍薄膜。对薄膜进行了X射线衍射(XRD)测试,为单一的α六方晶体结构。考察了不同退火温度下镍金属硅化物的形成,利用扫描电子显微镜(SEM)、能量色散谱(EDS)和XRD进行了物相相变的分析。退火温度400℃下得到NiSi相,其薄膜电阻率最低,约为34μΩ·cm。     

原子层沉积法制备微通道板发射层的性能

随着微通道板的不断发展与完善,通过改善传统工艺提升其性能越来越困难,开发提升微通道板性能的新技术迫在眉睫。纳米薄膜材料的发展及其制备技术的成熟为微通道板的发展提供了契机,利用原子层沉积技术在通道内壁沉积一层氧化铝纳米薄膜,作为二次电子发射功能层,可以增强通道内壁的二次电子发射能力,从而提升微通道板的增益性能。通过优化原子层沉积工艺参数可以在微通道板的通道内壁沉积厚度均匀的氧化铝薄膜。研究结果表明,微通道板增益随沉积氧化铝厚度的变化而变化,在氧化铝厚度为60 cycles时,施加偏压800 V时增益可达56 000,约为正常微通道板增益的12倍。     

Top injection reactor tool with in situ spectroscopic ellipsometry for growth and characterization of ALD thin films

Ta-N based thin films were grown by thermal atomic layer deposition (ALD) with an alternating supply of the reactant source TBTDET (tert-butylimidotris(diethylamido)tantalum) and NH₃ (ammonia). The films were deposited using a newly designed and constructed atomic layer deposition prototype tool combined with several in situ metrology. It was observed that thin films were successfully deposited on a 300 mm Wafer with a saturated growth rate of approximately 0.55 Å/cycle at 270 °C. The as deposited films resulted in the formation of Ta(C)N consisting of 38 at% Ta, 32 at% N and 10 at% C. With in situ spectroscopic ellipsometry (SE) the growing behaviour of the film was investigated and compared to atomic force microscopy (AFM) images.     

Sub-100 nm ALD-assisted nanoimprint lithography for realizing vertical organic transistors with high ON/OFF ratio and high output current

We introduced a conformal atomic-layer-deposited aluminum oxide layer to cover the imprint mold to reduce the feature size and to strengthen the mold durability. A nano-hole array pattern with diameter down to 85 nm was successfully transferred to sample substrate to fabricate a vertical organic transistor. The Imprint vertical organic transistor exhibited high output current density as 4.35 cm²/V s and high ON/OFF current ratio as 11,000 at a low operation voltage as 1.5 V.     

ALD-grown seed layers for electrochemical copper deposition integrated with different diffusion barrier systems

The deposition of Cu seed layers for electrochemical Cu deposition (ECD) via atomic layer deposition (ALD) of copper oxide and subsequent thermal reduction at temperatures between 110 and 120 °C was studied on different diffusion barrier systems. While optimization of the process is required on TaN with respect to reduction and plating, promising results were obtained on blanket PVD Ru. The plating results on layers of ALD Cu with underlying Ru even outperformed the ones achieved on PVD Cu seed layers with respect to morphology and resistivity. Applying the processes to via and line patterns gave similar results, suggesting that a combination of ALD Cu with PVD or ALD-grown Ru could significantly improve the ECD Cu growth.     

电子能量损失谱磁手性二向色性研究进展

电子能量损失谱磁手性二向色性技术是近年发展起来的实验方法,它与X射线磁圆二向色性一样可以测量特定元素的自旋与轨道磁矩的信息,由于其高空间分辨率、实验方法多样和对设备要求简单,因此有望应用于对微观材料的磁性测量和研究。本文简要介绍了该方法的背景、理论基础、实验方法、研究进展和应用。     

贴附技术分析

随着智能设备的不断普及,平板显示技术和触控技术得到飞速发展。在平板显示器件和触摸面板的制造过程中,都会大量用到贴附工艺技术,将两种材料相互贴附在一起。材料不同,贴附方式和贴附压力也会不一样。不同的贴附技术具有各自特点,适用的贴附材料也有差别。     

New selector based on zinc oxide grown by low temperature atomic layer deposition for vertically stacked non-volatile memory devices

We report on the fabrication of Schottky diodes based on n-type zinc oxide (ZnO) grown by atomic layer deposition (ALD) at low temperature (100 °C). These structures are suitable as selector elements in highly integrated non volatile memories based on crossbar architecture. The junctions are fully realized by optical lithography and the smallest investigated structures are 3 × 3 μm² area. Several metals have been tested to single out the most suitable ohmic and Schottky contact materials. The electrical characterisation shows good properties with a forward current above 10⁴ A/cm² and a rectifying ratio of 10⁵.     

喷墨打印在液晶用彩色滤光片制造中的应用

彩色滤光片是液晶显示器件的重要组件,为了降低生产成本并提高显示性能,新型彩色滤光片制造技术的研发成为热点。喷墨打印具有快速、精准、材料利用率高等一系列优点,成为替代传统颜料分散法的新一代彩色滤光片制备技术。文章介绍了喷墨打印的基本原理,比较了喷墨打印成膜与传统涂布成膜的优缺点,分析了喷墨法制备彩色滤光片的技术关键,并根据目前的产业现状提出了努力方向。     

改善大功率LED散热的关键问题

考虑热导率与散热方式的影响,使用大型有限元软件ANSYS10．0模拟并分析了大功率LED热分布。通过分析不同封装、热沉材料及散热方式对LED热分布与最大散热能力的影响,指出解决LED散热问题的关键不是寻找高热导率的材料,而是改变LED的散热结构或者散热方式。     

Fabrication of tunable [Al2O3:Alucone] thin-film encapsulations for top-emitting organic light-emitting diodes with high performance optical and barrier properties

The optical and barrier properties of thin-film encapsulations (TFEs) for top-emitting organic light-emitting diodes (TEOLEDs) were investigated using TFEs fabricated by stacking multiple sets of inorganic–organic layers. The inorganic moisture barrier layers were prepared by atomic layer deposition (ALD) of Al₂O₃ using trimethylaluminum (TMA) and O₃ as precursors and are shown to be efficient barriers against gases and vapors. The organic alucone layers were produced by molecular layer deposition (MLD) using TMA and ethylene glycol as precursors. The [Al₂O₃:Alucone] ALD/MLD films were used because their adjustable inorganic–organic nanolaminate composition allows for the tuning of the optical properties, thereby enhancing their application potential for the design and fabrication of high performance light out-coupling structures for TEOLEDs. By carefully adjusting the relative thickness ratio of the inorganic–organic encapsulation materials, optimized light extraction was achieved and the films not only maintained their high moisture barrier strength but also showed excellent optical performance.