共查询到19条相似文献,搜索用时 156 毫秒
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Sn-9Zn合金无铅钎料用助焊剂研究 总被引:10,自引:1,他引:9
通过测量润湿面积和润湿角,研究不同助焊剂对Sn-9Zn焊料润湿性的影响。结果表明:助焊剂对Sn-9Zn焊料润湿性影响很大,由乳酸、聚乙二醇和SnCl2所构成的助焊剂与Sn-9Zn焊料有很好适应性;同时扫描电镜和能谱分析也表明焊料与Cu基体界面的IMC为Cu5Zn8相,比Sn-37Pb焊料具有更高的剪切强度。 相似文献
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Sn-Zn-Bi-In-P新型无铅焊料性能研究 总被引:1,自引:1,他引:0
新型无铅焊料Sn-4.5Zn-2Bi-In-P、Sn-9Zn-2.5Bi-In-P具有优异的抗氧化、抗腐蚀性能,弥补了Sn-Zn系焊料润湿性能方面的不足,具有极大的实用性。测量了共晶Sn-9Zn、两种新型Sn-Zn系无铅焊料和传统的Sn-37Pb焊料的各项物理性能:密度、熔点、线膨胀系数、电阻率及对铜基体的润湿角。实验结果表明,新型Sn-Zn系无铅焊料的密度约为传统Sn-37Pb焊料的3/4;熔点(依次为194℃,191.9℃)接近Sn-37Pb焊料,熔程仅为8℃;在25~100℃,新型Sn-Zn焊料线膨胀系数依次为20.8×10–6/℃、16.9×10–6/℃,优于Sn-37Pb焊料(21.2×10–6/℃);新型Sn-Zn焊料的电阻率依次为1.73×10–6Ω·m、1.79×10–6Ω·m,优于Sn-37Pb焊料(1.96×10–6Ω·m);新型Sn-Zn焊料对Cu基体的润湿角接近30°,满足实用化的最低要求。 相似文献
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微合金化对Sn-9Zn基无铅钎料润湿性能的影响 总被引:9,自引:2,他引:7
熔炼制备了纯的以及含微量Al、Mg、Ti、Bi、重稀土Y、混合轻稀土RE和一种富P非金属活性组元NM的Sn-9Zn基合金,通过测量这些合金以及商用Sn-37Pb焊料在铜基板上的铺展面积比较了它们对铜的润湿性能。结果表明Al、Ti和 Mg不利于提高合金在铜上的润湿性或附着力;Y的改善作用不大;而Bi、RE和NM则能明显改善Sn-9Zn合金对铜的润湿性。在此基础上进一步研究了RE和NM含量对Sn-9Zn润湿性能的影响。以铺展面积衡量,本研究所达到的最佳改善效果使Sn-9Zn合金对铜的润湿性由Sn-37Pb焊料润湿性水平的45.4%提高到了70.3%。 相似文献
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压力传感器芯片键合用低温玻璃焊料的研制 总被引:6,自引:0,他引:6
研制开发了一种用于压力传感器芯片与 1 0 1玻璃基座相封接的三元系结晶性低温玻璃焊料 ,其基本成份为 Pb O:Zn O:B2 O3 =58:1 8:2 4 (% wt)。已用 DSC分析该玻璃焊料 ,显示在 51 0℃出现主晶相的熔化吸热峰 ,其开始熔化温度为 445℃。在硅芯片背面制备一过渡层 ,然后用此低温玻璃焊料将压力传感器芯片与玻璃基座封接在一起。封接温度为 530℃ ,低于铝硅合金相的低共熔温度 577℃。用这一封接技术制备的压力传感器有良好的技术性能 ,热漂移小且能耐沸水、耐油 ,耐 1 50℃热冲击。封接强度达 7MPa。 相似文献
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液态Sn-Cu合金的恒温热氧化性研究 总被引:7,自引:2,他引:5
采用静态热氧化和撇取表面膜的方法,研究了Sn-0.7Cu无铅焊料在使用温度下的氧化行为,并与Sn-37Pb进行了比较。结果显示:Sn-0.7Cu合金在高温下的氧化明显高于Sn-37Pb,液态合金表面氧化产渣量随撇渣频率的加快而增加。在恒温条件下,氧化渣的生成随时间的变化服从抛物线规律。指出Sn-0.7Cu合金与氧的亲和力大于Sn-37Pb,且表面氧化膜疏松,是造成氧化速度快的根本原因;提高表面膜的致密度,是降低氧化反应的根本措施。 相似文献
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无铅电子钎料合金蠕变性能研究 总被引:7,自引:0,他引:7
设计制作了一种简单可靠的弯折蠕变测量装置,比较了两种无铅电子钎料合金Sn-9Zn和Sn-3.5Cu-0.7Ag与传统电子钎料合金Sn-40Pb的常温蠕变性能,以及冷却条件对其蠕变强度的影响。结果表明:两种无铅钎料的抗蠕变性能大大优于传统锡铅钎料;Sn-3.5Ag-0.7Cu合金的抗蠕变性能优于Sn-9Zn合金;冷却速率对Sn-9Zn合金和Sn-3.5Ag-0.7Cu合金组织的影响类似,然而对蠕变强度的影响却相反:水冷使两种合金的组织相对于空冷都明显细化,Sn-9Zn合金的蠕变强度因之降低,而Sn-3.5Ag-0.7Cu合金的蠕变强度却因之提高。对可能产生的原因进行了讨论。 相似文献
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稀土元素对Sn-0.2Ag-0.7Cu钎料合金物理性能的影响 总被引:1,自引:0,他引:1
在筛选出综合性能较好的Sn-0.2Ag-0.7Cu钎料合金中,添加微量混合稀土元素(RE)以提高钎料的焊接性能。研究了稀土的添加量对其熔化温度、电导率和固–液相线温差等焊接性能的影响。结果表明:添加w(RE)为0.1%~0.5%时,固–液相线温差小于15℃,符合现行钎焊工艺要求,且对钎料合金的熔化温度和电导率影响不大。 相似文献
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The microstructures and mechanical properties of Sn-8.55Zn-0.5Ag-0.45Al-yGa (wt.%) lead-free solders were investigated. The
y content of the solders investigated was 0.5–3.0 wt.%. The results indicate that Ga exhibits prominent influence in the microstructure
as well as mechanical properties of the solders. By increasing Ga, the fraction of the Sn/Zn eutectic region decreases and
the Sn-matrix region increases. An increase in the Ga content from 0.5 wt.% to 2.0 wt.% enhances the tensile strength while
degrading the ductility. The mechanical properties and differential scanning calorimetry (DSC) behavior have been compared
with that of the 63Sn-37Pb solder. Gallium lowers the melting point of the Sn-8.55Zn-0.5Ag-0.45Al-yGa solders. The Sn-8.55Zn-0.5Ag-0.45Al-0.5Ga
solders exhibit greater tensile strength and better ductility than the 63Sn-37Pb solder. 相似文献
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Nanoparticles of the Lead-free Solder Alloy Sn-3.0Ag-0.5Cu with Large Melting Temperature Depression
Chang Dong Zou Yu Lai Gao Bin Yang Xin Zhi Xia Qi Jie Zhai Cristina Andersson Johan Liu 《Journal of Electronic Materials》2009,38(2):351-355
Due to the toxicity of lead (Pb), Pb-containing solder alloys are being phased out from the electronics industry. This has
lead to the development and implementation of lead-free solders. Being an environmentally compatible material, the lead-free
Sn-3.0Ag-0.5Cu (wt.%) solder alloy is considered to be one of the most promising alternatives to replace the traditionally
used Sn-Pb solders. This alloy composition possesses, however, some weaknesses, mainly as a result of its higher melting temperature
compared with the Sn-Pb solders. A possible way to decrease the melting temperature of a solder alloy is to decrease the alloy
particle size down to the nanometer range. The melting temperature of Sn-3.0Ag-0.5Cu lead-free solder alloy, both as bulk
and nanoparticles, was investigated. The nanoparticles were manufactured using the self-developed consumable-electrode direct
current arc (CDCA) technique. The melting temperature of the nanoparticles, with an average size of 30 nm, was found to be
213.9°C, which is approximately 10°C lower than that of the bulk alloy. The developed CDCA technique is therefore a promising
method to manufacture nanometer-sized solder alloy particles with lower melting temperature compared with the bulk alloy. 相似文献
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无铅焊料在清华大学的研究与发展 总被引:2,自引:0,他引:2
清华大学材料科学与工程系电子材料与封装技术研究室研制了6个系列的无铅焊料:Sn-3.5Ag添加Cu或Bi; Sn-3.5Ag-1.0Cu添加In或Bi; Sn-Ag-Cu-In添加Bi; Sn-Ag-Cu添加Ga; Sn-Zn添加Ga; Sn-Zn添加多种元素。重点介绍了Sn-Zn添加多种元素。对6个系列无铅焊料的研究取得了较好的实验结果,得到比较理想的低温焊料体系,有的合金熔点已非常接近铅锡共晶焊料熔点183℃。 相似文献
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表面封装用无铅软钎料的接头强度及熔点范围的研究 总被引:6,自引:1,他引:5
研究了Bi的添加量,对电子表面封装(SMT)用Sn-Ag近共晶无铅软钎料钎焊接头抗拉强度和熔点及熔点范围的影响。随着Bi含量的增加,钎焊接头抗拉强度也随着增加,同时钎料的液固相线温度均降低。当Bi的含量达到5%时,抗拉强度增加快;Bi的添加量大于5%时,抗拉强度上升缓慢。在Bi的含量增加时,熔点温度范围也逐渐变宽,使得凝固时间变长,这对于表面组装中的电子元件与器件的焊接是非常不利的。故在Sn-Ag近共晶无铅软钎料中Bi的添加量,应加以适当的控制。 相似文献
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The microstructures of the Sn-Zn-Al lead-free solders have been investigated using scanning electron microscopy. The Al and
Zn contents of the solders investigated were 0.45%∼4.5% and 8.55%∼85.5%, respectively. The solders were prepared from the
Zn-5Al master alloy and Sn. The precipitates formed in these solders were analyzed for their compositions with energy dispersive
spectroscopy. The eutectic temperature and the transition temperatures of these solders upon cooling were identified with
cooling curves as well as with differential scanning calorimetry. 相似文献
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The formation and growth of intermetallic compounds and shear strength at Sn–Zn solder/Au–Ni–Cu interfaces 总被引:2,自引:2,他引:0
The microstructures and shear strength of the interface between Sn–Zn lead-free solders and Au/Ni/Cu interface under thermal aging conditions was investigated. The intermetallic compounds (IMCs) at the interface between Sn–Zn solders and Au/Ni/Cu interface were analyzed by field emission scanning electron microscopy and transmission electron microscopy. The results showed the decrease in the shear strength of the interface with aging time and temperature. The solder ball with highly activated flux had about 8.2% increased shear strength than that with BGA/CSP flux. Imperfect wetting and many voids were observed in the fracture surface of the latter flux. The decreased shear strength was influenced by IMC growth and Zn grain coarsening. In the solder layer, Zn reacted with Au and then was transformed to the β-AuZn compound. Although AuZn grew first, three diffusion layers of γ-Ni5Zn21 compounds were formed after aging for 600 h at 150 °C. The layers divided by Ni5Zn21 (1), (2), and (3) were formed with the thickness of 0.7 μm, 4 μm, and 2 μm, respectively. 相似文献