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文章研究了有机硅聚氨酯低聚物对丁腈橡胶CKH-26M等硫化胶硫化网络结构形成的影响.由于在高温作用下,有机硅聚氨酯低聚体能够积极地参与丁腈橡胶等合成橡胶的热硫化过程,从而对橡胶硫化网络的形成产生积极的影响.具体表现为能提高橡胶硫化网络的密度和力学性能,并且在高温下能较长时间的保持橡胶的弹性和强度性能.这就为制造在高温下... 相似文献
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聚酯纤维高温高压染色中助剂和染料对表面低聚物含量的影响 总被引:2,自引:0,他引:2
本文通过大量实验研究了聚酯纤维高温高压染色中染色助剂和染料对染色后纤维表面低聚物含量的影响。结果表明:表面活性剂能在一定程度上减少表面低聚物含量,其中具有苯环结构和聚氧乙烯醚结构的非离子表面活性剂中加入某些阴离子表面活性剂能增强其在高温下去除表面低聚物效果;分散染料的结构和性能对表面低聚物含量也有一定程度的影响。 相似文献
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α—甲基苯乙烯低聚物的表征及其在塑料加工中的应用研究 总被引:3,自引:0,他引:3
本文表征了α-甲基本乙烯(α-MS)低聚物(DP=2-3)的结构及性质,深入研究了α-MS 低聚物作为加工助剂在聚烯烃树脂加工中的应用。结果表明,α-MS 低聚物可明显改善树脂流变性能、减少能耗、改善制品的抗冲击性能,是一类性能良好的加工助剂。 相似文献
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在调研和试验的基础上,为潮差区混凝土涂装防护设计了硅烷浸渍与湿面固化的复合涂装方案,并在现场试验中取得了较好的防护效果,在此基础上形成了嘉绍大桥钢筋混凝土工程的涂装配套设计方案。 相似文献
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Yutaka Kawahara Masaki Kamo Kiyoshi Yamamoto Satoshi Ogawa Douhiko Terada Takeshi Kikutani Masaki Tsuji 《大分子材料与工程》2006,291(1):11-15
Summary: Spin‐drawing yarn (SDY) and high‐speed spun (HSS) fibers were produced from recycled poly(ethylene terephthalate) pellets, and the oligomer deposition on the surface of fiber in supercritical carbon dioxide fluid was compared. The oligomer deposition was obvious for SDY, which corresponded to the fact that the amount of imperfect small crystallites generated in amorphous regions through s‐CO2 treatment was much smaller for SDY as compared to that with HSS. The imperfect small crystallites generated in amorphous regions will work as a barrier to the oligomer migration. In order to suppress the deposition of oligomer for SDY, the combination of a heatset treatment and an alkaline etching was useful. At a heatset process, the oligomer migration to the surface layer tends to occur, and the layer becomes rich in oligomer. The following topochemical hydrolysis reaction at alkaline etching removes such layer. Accordingly, the total content of oligomer in etched fiber is reduced. As a result, the oligomer deposition in s‐CO2 treatment becomes not so serious. In addition, the heatset treatment gives the shrinkproof property to SDY, and the property is still retained after the alkaline etching.
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