热循环对TC4合金室温和低温拉伸性能的影响

采用热机械循环试验装置、材料万能实验机、金相显微镜和扫描电镜考察了经0,100,200和500周次热循环处理的TC4(Ti-6Al-4V)合金在室温(293K)和低温(173K、123K、78K)的拉伸性能及断裂行为。结果表明,随循环次数的增加,TC4合金的室温强度和低温强度升高,低温伸长率略有升高,但500次循环试样在78K拉伸时应力有跃升现象且伸长率显著上升;各种循环和测试条件下,TC4合金的拉伸断裂均呈现典型的塑性特征。     

热轧变形对Ti-10V-2Fe-3Al合金组织和性能的影响

研究了形变温度、形变量以及双重时效工艺对Ti-10V-2Fe-3Al合金显微组织和力学性能的影响.结果表明:随着形变温度的提高,在时效过程中析出的次生α相含量逐渐增加,合金强度升高;然而,当形变温度高于相变点时,初生α相对β晶粒的钉扎作用明显减弱,使得β晶粒迅速长大,导致合金的拉伸塑性明显下降;次生α相的体积分数主要决定于形变温度,因此应变量对Ti-10V-2Fe-3Al合金力学性能的影响较小.此外,相对于单重时效工艺,由于在低温时效(300℃×8h)时发生ω→α转变,为次生α相提供了均匀的形核点,Ti-10V-2Fe-3Al合金在低温-高温双重时效工艺中获得了更加均匀、细小的α+β显微组织,使得拉伸强度获得比较大的提高.     

钨对Ti-22Al-20Nb-2W合金拉伸性能的影响

通过铌合金化改善Ti3Al合金的室温塑性时，人们发现高铌的加入使α2相转变成一种新有序正交相，该相以Ti2AlNb(O)为基。从此，O相作为有潜力的高温结构材料的相受到广泛关注。研究表明，O相为基的O β(B2)两相合金具有较好的综合性能。高强和室温塑性比α2基合金更有竞争力，高的比强度优于镍基超合金IN718。尽管如此，高于650℃时的拉伸强度显著降低，因而限制了其高温应用。相可溶解大量β稳定元素，因此，可通过合金化来提高(O β)两相合金。日本学者研究了钨合金化的Ti-22Al-20Nb-2W的高温拉伸性能。Ti-22Al-20Nb-2W合金采用非…     

含Zr多晶Ni3Al合金在不同热处理温度下的组织与性能

研究了冷轧多晶Ni3Al-(0．2％，0．6％，1．0％，1．5％)Zr(原子分数)合金在不同热处理温度(800-1100℃)下的显微组织和力学性能，结果表明，适当的热处理温度，可使无硼Ni3Al-Zr多晶合金获得优良的室温拉伸强度和塑性，随着热处理温度的升高，不同Zr含量Ni3Al合金的再结晶体积分数增加，再结晶晶粒尺寸增大，室温拉伸强度下降．随着合金中Zr含量的增加，再结晶温度降低，再结晶晶粒尺寸减小．不同Zr含量Ni3Al合金的拉伸塑性明显依赖于热处理温度，对于低Zr(0．2％)合金，在1000℃热处理后，拉伸塑性最佳；对于中Zr(0．6％)合金，在850℃热处理后，拉伸塑性达到最大值；对于高Zr(≥1．0％)合金，拉伸塑性峰值出现在900℃热处理下，当热处理温度超过900℃，拉伸塑性显著降低。     

热处理对Ti3Al基合金板材拉伸性能与微观组织的影响

研究固溶温度、时效温度以及多重时效处理对Ti-24Al-15Nb-1Mo合金热轧板材拉伸性能的影响,对不同热处理工艺下板材的微观组织和拉伸断口形貌进行观察.结果表明:当固溶处理温度从990 ℃升高到1 010 ℃时,Ti-24Al-15Nb-1Mo合金热轧板材的室、高温强度均有所提高,塑性略有降低;当时效温度从815 ℃升高到850 ℃时,板材的室温和高温强度降低,塑性变化不明显;Ti-24Al-15Nb-1Mo合金热轧板材经990 ℃固溶处理后再进行多次时效处理,其拉伸性能变化不明显;增加时效次数,拉伸强度略微降低.     

不完全再结晶Fe40Mn10Cr25Ni25高熵合金的室温及低温力学性能

采用冷轧和退火热处理工艺制备了不完全再结晶结构的Fe₄₀Mn₁₀Cr₂₅Ni₂₅高熵合金,分析了合金的室温(298 K)及低温(77 K)拉伸时的力学性能。结果表明,合金具有优良的室温及低温力学性能,合金在低温拉伸时强度和塑性均得到了提高,其室温强度和断后伸长率分别为880 MPa和18%,低温强度和断后伸长率分别为1360 MPa和36%。合金在室温变形以位错滑移为主,低温变形以位错滑移和孪生为主。室温拉伸时,粗晶晶粒先于细晶晶粒变形,导致试样内部产生了应变梯度,提高了合金的加工硬化率,使合金在室温下具有良好的强塑性。低温拉伸时,粗晶晶粒中形成了大量的变形孪晶,从而提高了合金的低温力学性能。     

Nb含量对铸造高铝TiAl合金高温强度和室温塑性的影响

研究了Nb含量对铸造高铝Ti Al合金高温强度和室温塑性的影响。结果表明,合金900℃的抗拉强度随Nb含量的增加先升高后降低,Nb含量在4%~9%(原子分数)之间的高铝合金表现出优异的高温强度水平,其中7%Nb合金最高,达587 MPa。分析认为,在高Nb合金化固溶强化的基础上,Al/Ti反位缺陷造成的强化效应、层片组织处于拉伸硬取向以及应变诱发的形变孪晶强化也有可能是高Nb含量高铝铸造Ti Al合金900℃具有优异强度水平的重要机制。合金室温塑性随Nb含量的增加而呈线性下降,由2%Nb合金的1.2%降为9%Nb合金的0.3%,这可能是由于B2相随Nb含量的增加而显著增加所致。     

Zr,Cr和B对Ni3Al合金组织和力学性能的影响

本文研究了含Zr(0—0.6at.-％),Cr(0—7.7at.-％)和B(0—2.22at.-％)的Ni_3Al合金的组织和室温至1050℃拉伸性能。结果表明,Ni_3Al合金的屈服强度随温度升高而增加,表现出反常的温度关系。到达峰值后,随温度升高,屈服强度降低。Zr和Zr+Cr在整个试验温度范围都增加Ni_3Al合金的屈服强度,并改善高温抗张强度和塑性。硼增加Ni_3Al合金的抗张强度和屈服强度,同时改善塑性。但当硼含量超过1.37at.-％时,则降低强度和塑性。当硼含量超过溶解度极限时,Ni_3Al合金中形成岛状和球状的Ni_(20)Al_3B_6和Ni_3Al的共晶组织,对强度和塑性都是有害的。     

热轧温度对低密度Nb-Ti-Al-V-Zr-C合金性能的影响

对经挤压开坯的一种低密度铌合金分别在1000,1100,1200℃下进行了热轧,并利用光学显微镜、扫描电镜和场发射透射显微镜对试样的组织形貌进行了表征;对合金的室温和高温拉伸强度、延伸率进行了测试。结果表明:在1200和1100℃温度下热轧时,合金均具有优良的室温和高温性能,室温强度在600MPa以上,室温塑性大于12%,高温下的强度在80MPa以上,高温塑性大于30%,且随轧制温度升高,抗拉强度降低,塑性增大;而在1000℃下热轧时,室温和高温力学性能均较低,且室温拉伸断口表现为脆性断裂。     

Zr和Mn元素微合金化增强耐高温铝铜合金的热稳定性和力学性能

系统研究Al?5％Cu(AC)和Al?5％Cu?0.2％Mn?0.2Zr％(ACMZ)合金在温度为573～673 K的高温热稳定性和力学性能.结果表明,微合金化添加Zr和Mn元素对573 K主要强化相θ′相的稳定起到至关重要的作用.同时,高温拉伸结果表明,573 K热暴露200 h后,ACMZ合金强度为(88.6±8....     

Oxygen effects on the mechanical properties and lattice strain of Ti and Ti-6Al-4V

The effects of oxygen on the mechanical properties and the lattice strain of commercial pure CP) Ti and Ti-6Al-4V alloys are discussed here in terms of the Vickers hardness, tensile strength and elongation. The Vickers hardness and tensile strength of the CP Ti and the Ti-6Al-4V alloys increased with an increase in the oxygen concentration. On the other hand, the elongation of the CP Ti decreased considerably as the oxygen concentration increased, while that of the Ti-6Al-4V alloys gradually decreased as the oxygen concentration increased. Thus, the oxygen concentration has a greater effect on the mechanical properties of CP Ti compared to its effects on the Ti-6Al-4V alloy. This can be explained in terms of the difference in the solid solution effect of oxygen between the CP Ti and the Ti-6Al-4V alloy. Where, the mechanical properties of Ti-6Al-4V alloy were previously affected by an earlier lattice expansion caused by an increment in the c/a ratio of the Ti-6Al-4V during the Al and V alloying process.     

Effect of Zr addition on microstructures and mechanical properties of Ni-46Ti-4Al alloy

The microstructures and mechanical properties of Ni-(46-x)Ti-4Al-xZr (x = 0-8, at.%) alloys have been investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and mechanical tests. The results show that the Ni-Ti-Al-Zr alloys are composed of TiNi and (Ti, Al) 2 Ni with Zr as a solid solution element in both phases, and the third phase, (Zr, Ti, Al) 2 Ni, appears in Ni-40Ti-4Al-6Zr and Ni-38Ti-4Al-8Zr alloys. The compressive yield strength at room temperature increases with the increase of Zr content due to the solid-solution strengthening of Zr and precipitation strengthening of (Ti, Al, Zr) 2 Ni phase. However, the Ni-42Ti-4Al-4Zr alloy exhibits the maximum compressive yield strength at 873 and 973 K because of the softening of (Zr, Ti, Al) 2 Ni phase in the alloys with more Zr addition. The tensile stress-strain tests and the SEM fracture surface observations show that the brittle to ductile transition temperature of Ni-42Ti-4Al-4Zr alloy is between 873 and 923 K.     

High-Temperature Oxidation Behavior of Ti-22Al-27(Nb, Zr) Alloys

研究了Ti2Al Nb基合金Ti-22Al-(27-x)Nb-x Zr(x=0,1,6,at%)在650~800℃的氧化行为。采用XRD和SEM等测试技术对此温度区间形成的氧化层特征进行了分析。结果表明,相比Ti-22Al-27Nb,含锆合金具有较好的抗氧化性能。Ti-22Al-(27-x)Nb-x Zr合金在650℃氧化100 h,主要氧化产物为Ti O2,而在800℃氧化100 h,Ti O2,Al2O3和Al Nb O4为主要产物,但是在Ti-22Al-21Nb-6Zr合金中还有Zr O2生成。Ti-22Al-26Nb-1Zr合金具有优异抗氧化性能,归因于氧化产物细化形成了致密的氧化层,而Ti-22Al-21Nb-6Zr合金,虽然在800℃也形成了较多Al2O3,但是氧化层中的Zr O2为氧的快速扩散提供通道,进而导致该合金氧化增重明显。     

Study of microstructure and mechanical properties of Ti-45Al-(Fe,Nb) (at. %) alloys

In the present work, the microstructure and compression properties of two novel γ(TiAl) based alloys, Ti-45Al-5Fe and Ti-45Al-5Fe-5Nb, have been investigated. Both alloys had a relatively fine as-cast structure generally consisting of the γ(TiAl) and τ₂(Al₂FeTi) phases with a minor amount of the α₂(Ti₃Al) and β(B2) phase. The compression properties of the novel alloys were measured at room and elevated temperatures. The Ti-45Al-5Fe-5Nb alloy showed higher room temperature ductility and similar strength at room and elevated temperatures as well as improved workability at elevated temperatures as compared to β-solidifying γ(TiAl) alloys of last generation (TNM alloys).     

Effects of deviations from stoichiometry on the strength anomaly and fracture behavior of B-doped FeAl

Tensile tests were conducted at temperatures ranging from 145–1123 K on four different FeAl alloys, containing 40, 43, 45, and 48 at.% Al, each doped with 0.12 at.% B. The alloys were initially heat treated to obtain a relatively large grain size (˜200 μm), after which they were given a long, low-temperature anneal (673 K for 5 d), to minimize, respectively, the effects of grain boundary strengthening and thermal vacancies on the measured yield strengths. Each alloy displayed bcc-type behavior at low temperatures (yield strength decreasing with increasing temperature), followed by a strength anomaly at intermediate temperatures (yield strength increasing with increasing temperature), and a sharp drop in yield strength at elevated temperatures (beyond the anomalous strength peak). Thermal vacancies that are generated during the hold time at the test temperature may contribute to the production of the strength anomaly. In specimens not given the vacancy-minimizing anneal, quenched-in vacancies were found to substantially increase low-temperature strength, thereby masking the yield strength anomaly. As the Al concentration of FeAl increased, the prominence of the yield strength anomaly decreased. Ductility also exhibited a peak at elevated temperatures, first increasing with temperature until it reached a maximum value and then decreasing with further increases in temperature. The peak in ductility occured at lower temperatures as the Al content increased. The fracture mode in all four alloys was mixed (intergranular + transgranular) at cryogenic temperatures, predominantly intergranular at around room temperature, dimpled rupture at peak ductility, and intergranular cavitation at elevated temperatures where the ductility dropped.     

Effect of microstructure on tensile properties and fracture behavior of intermetallic Ti2AlNb alloys

The tensile properties and fracture behaviors of Ti-22Al-27Nb and Ti-22Al-20Nb-7Ta alloys were investigated in the temperature range of 25-800℃ Three typical microstructures were obtained by ifferent thermomechanical processing techniques.The results indicate that the duplex microstructure has an optimum combination of tensile yield strength and ductility both at room and elevated temperatures.Adding Ta to Ti2AlNb alloy can improve the yield strength,especially at high temperature while retain a good ductility.The study on crack initiation and propagation in dedformed microstructure of Ti2AlNb alloys indicates that microstructure has ikmportant effect on the tensile fracture mechanism of the alloys.The cracks initiate within primary O/α2 grains along O/B2 boundaries or O phase laths in B2 matrix,and propagate along primary B2 grain boundaries for the duplex microstructure.The fracture mode is transgranular with ductile dimples for the duplex and the equiaxed microstructures,but intergranular for the lath microstructure.     

Effect of enamel coating on long-term oxidation and hot corrosion behavior of Ti-24Al-17Nb-0.5Mo alloys

The effect of enamel coating on long-term isothermal oxidation at 700 ℃ and cyclic oxidation at 800 ℃ in air and hot corrosion resistance of Ti-24Al-17Nb-0. 5Mo in 75% (Na2SO4 K2SO4 ) 25% NaCl (mass fraction) molten mixed salts at 700 ℃ was investigated. The results indicate that Ti-24Al-17Nb-0.5Mo alloy exhibits relatively poor long-term oxidation resistance due to the formation of Al2O3 TiO2 Nb2O5 mixed scales and poor hot corrosion resistance due to the spallation of scales formed in molten (Ns, K)2 SO4 NaCl. Enamel coating can effectively protect Ti-24Al-17Nb-0.5Mo alloy from long-term oxidation at high temperature in air and remarkably improve the hot corrosion resistance of Ti-24Al-17Nb-0. 5Mo alloy, and can act as the barrier to suppress the migration of oxygen and corrosive ions into the substrate.     

Ti811和TC4合金的热盐应力腐蚀行为研究

研究了Ti811(Ti-8Al-1Mo-1V)和TC4(Ti-6Al-4V)两种钛合金对热盐应力腐蚀(HSSC)的敏感性.结果表明:Ti811合金对HSSC非常敏感,在相同条件下其热盐应力腐蚀临界应力(σHSSC)明显低于TC4合金,且低于同温度的蠕变强度,而TC4合金的σHSSC高于同温度的蠕变强度;两种合金在HSSC暴露过程中,明显遭受到盐腐蚀,腐蚀产生的氢扩散到基体中,致使合金发生脆化,从而降低合金的室温塑性.     

两种Ti—Al金属间化合物基合金ISM熔炼过程中Al元素挥发控 …

对水冷铜坩埚真空感应熔炼过程中合金元素的挥发动力学进行了深入的分析,并在此基础上建立了ＩＳＭ熔炼过程中Ａｌ元素挥发控制方式的判断模型。对Ｔｉ－４８Ａｌ－２Ｃｒ－２Ｎｂ（ａｔ％）和Ｔｉ－２４Ａｌ－１１Ｎｂ（ａｔ％）合金中Ａｌ元素挥发控制方式的判断结果表明：随着熔体温度的升高和外压的增大,Ａｌ元素的挥发由低温和高压时的界面挥发控制向高温和低压时的界面挥发和液相中扩散同时起作用的双重控制方式转变,只是对     

V/Nb对Ti-45Al-9(V, Nb, Y)合金抗氧化性能的影响

βγ-TiAl合金具有良好的高温变形能力,为TiAl合金的发展开辟了新的途径。成功制备了不同x=V/Nb(x=1,1.5,2,3.5)的βγ-TiAlTi-45Al-9(V,Nb,Y)合金,研究了上述合金在800℃静止空气中的氧化行为。结果表明:当x=1时,Ti-45Al-9(V,Nb,Y)合金中形成条带状、连续致密的Al2O3氧化层,显著提高了合金的抗氧化能力。随着x=V/Nb的增加,Al2O3氧化层厚度变薄,合金的抗氧化能力下降。