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Several simple equations of state, requiring only two input properties, have been studied in order to determine the liquid
saturation density of 144 fluids of different kinds. This study includes old and new simple modifications of the van der Waals
equation of state, and the Carnahan–Starling–Yelash–Kraska and Carnahan–Starling–Dieterici equations. The new simple modifications
of the van der Waals equation give better overall results than some other more complex proposed equations, especially near
the critical point. The recent equation proposed by Eslami including the boiling temperature and density as input parameters
was also checked, and was found not to reproduce the critical point, but to give excellent results at intermediate or low
temperatures. As a reference, the behavior of the well-known Soave– Redlich–Kwong and Peng–Robinson equations, and the more
recent expression proposed by Mohsen-Nia et al. that requires three input parameters were also checked. The latter does not
improve the accuracy of the Peng–Robinson equation, and very simple van-der-Waals type equations give better overall results. 相似文献
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本文比较了-30℃至65℃湿空气饱和水蒸气压与温度的各个关系式以及露点温度与水蒸气分压力各关系式的精度,供空调有关工作者选用. 相似文献
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湿空气饱和水蒸气压力与温度关系式的改进与应用 总被引:1,自引:0,他引:1
比较了-30~65℃湿空气饱和水蒸气压力与温度的各个关系式,以及露点温度与水蒸气分压力各关系式的精度,举例说明了这些关系式的应用. 相似文献
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Density of Liquid Ni-Cr Alloy 总被引:7,自引:0,他引:7
F.Xiao 《材料科学技术学报》2003,19(1):16-18
The density of liquid Ni-Cr alloy was measured by a modified sessile drop methold.The density of liquid Ni-Cr alloy was found to decrease with increasing temperature and Cr concentration in the alloy,The molar volume of liquid Ni-Cr alloy increases with increasing the Cr concentration in the alloy ,The molar volume of Ni-Cr alloy determined in the present work shows a positive deviation from the linear molar volume. 相似文献
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除湿溶液蒸汽压的研究 总被引:7,自引:0,他引:7
除湿溶液表面蒸汽压的大小直接影响液体除湿空调系统的性能,在常用的除湿剂中由于氯化钙的价格低廉,是一种比较经济的除湿剂,但它的缺点是蒸气压比较高,除湿效果不稳定,而氯化锂的价格高,水蒸气压较低且稳定,是一种性能非常优良的除湿剂.为了提高除湿溶液的除湿性能和降低其价格,可以把两种除湿剂按不同的比例进行混合,就可以得到性价比比较好的除湿溶液.文中应用经典热力学理论研究了常用除湿溶液表面蒸汽压的形成机理.对氯化钙、氯化锂及其混合溶液表面蒸汽压进行了计算,计算结果和实验结果非常接近,认为该方法可以用来较准确的估算各类除湿溶液的蒸汽压,为液体除湿空调系统中除湿剂的选择提供理论依据. 相似文献
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A primary transducer is described for the density and viscosity of a liquid, which employs a ferromagnetic float and oscillates vertically in response to an alternating magnetic force. The viscosity and density are determined from the times taken for the float to rise and fall a set distance. 相似文献
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The density of liquid Cu-Au alloys is measured using the technique of electromagnetic levitation, which entails producing a shadow image of the sample. The shadow is recorded by a digital CCD-camera, and the volume of the sample is calculated by an image processing algorithm. The density and thermal expansion of several alloys and the pure elements copper and gold are investigated at various temperatures above their melting points. In addition, the densities are also investigated as a function of the gold concentration at constant temperature. The measured values agree with literature data and with predictions obtained by molecular dynamics. It was found from data analysis that the ideal solution model applies. 相似文献
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A. J. Queimada S. E. Quiñones-Cisneros I. M. Marrucho J. A. P. Coutinho E. H. Stenby 《International Journal of Thermophysics》2003,24(5):1221-1239
Although a large body of viscosity data exists for simple mixtures of lighter n-alkanes, available information for heavy or asymmetric systems is scarce. Experimental measurements of viscosity and liquid densities were performed, at atmospheric pressure, in pure and mixed n-heptane, n-hexadecane, n-eicosane, n-docosane, and n-tetracosane from 293.15 K, or above the melting point, up to 343.15 K. The measured densities were correlated using the Peng–Robinson equation of state, and viscosities were modelled using the friction theory. 相似文献
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Experimental values of covering power at diffuse saturation density of a range of commercial emulsions an energetic chemical development are compared with those expected on the basis of the Nutting expression for density. employing in the latter the grain-size characteristics of the undeveloped emulsions. For the size range investigated (0.07 to 2µ2) there is reasonable prediction of the variation of covering power with grain size, but the predicted values are too small. Apparently the average ratio of effective developed mean grain projective area to undeveloped mean area is about 2-6, this factor decreasing at a significant rate with increasing grain size. This ratio represents the product of two factors: the increase in geometric area of grains as a result of the development process, and the effective increase in size owing to light-scatter effects within the layer. Experimental observations indicate that the factorial increase of projective area on energetic chemical development is about 1-3 times. In turn this means that the factorial increase in effective size owing to light-scatter effects within the layer must be about 2-6/1-3, or twice. 相似文献
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H. M. T. Avelino J. M. N. A. Fareleira W. A. Wakeham 《International Journal of Thermophysics》2003,24(2):323-336
A vibrating-wire densimeter described previously has been used to perform simultaneous measurements of the density and viscosity of toluene at temperatures from 222 to 348 K and pressures up to 80 MPa. The density measurements are essentially based on the hydrostatic weighing principle, using a vibrating-wire device operated in forced mode of oscillation, as a sensor of the apparent weight of a cylindrical sinker immersed in the test fluid. The resonance characteristics for the transverse oscillations of the wire, which is also immersed in the fluid, are described by a rigorous theoretical model, which includes both the buoyancy and the hydrodynamic effects, owing to the presence of the fluid, on the wire motion. It is thus possible, from the working equations, to determine simultaneously, both the density and the viscosity of the fluid from the analysis of the resonance curve of the wire oscillation, the density being related essentially to the position of the maximum and the viscosity to its width. New results of measurements of the density and viscosity of toluene in the compressed liquid region are presented, and compared with literature data. The density results extend over a temperature range 222 KT348 K, and pressures up to 80 MPa. The viscosity results cover a temperature range of 248 KT348 K and pressures up to 80 MPa. The uncertainty of the present density data is estimated to be within ±0.1% at temperatures 298 KT350 K, and ±0.15% at 222 KT273 K. The corresponding overall uncertainty of the viscosity measurements is estimated to be ±2% for temperatures 298 KT350 K, and ±3% for 248 KT273 K. 相似文献
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Density Measurement of Liquid Metals Using Dilatometer 总被引:2,自引:0,他引:2
Lianwen WANG Qingsong MEI Shenyang National Laboratory for Materials Science Institute of Metal Research Chinese Academy of Sciences Shenyang China 《材料科学技术学报》2006,22(4):569-571
The dilatometer method for density measurement of liquid metals was improved to give a high measurement accuracy with simple operation. The density of liquid tin was measured and the results are in agreement with values in literature. The melting point density of liquid Sn was measured to be 6.966×103 Kg·m-3 and the temperature (T) dependence of the density (ρ) for liquid Sn can be well described by a polynomial equation ρ(T)=7.406 - 9.94 × 10-4T 2.12 × 10-7T2. 相似文献
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We investigate vortex line density fluctuations of quantum turbulence generated by an oscillating grid in superfluid 3He-B. The scenario of quantum turbulence experimentally suggested by the Lancaster group is confirmed in the numerical simulation. The spectrum of the vortex line density fluctuations with respect to frequency obeyed a ?5/3 power law, which is consistent with the experiment of the Lancaster group. Based on the argument of time scales experienced by vortex rings with different sizes and on the power spectrum, the connection between the self-similar structure of the vortex tangle and the power spectrum is discussed. 相似文献
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描述了核电及核化工中密闭容器内介质密度变化时的液位测量原理、安装要求、仪表组态、调试数据和方法。使该项难度较大的调试工作有了切实可行的操作性。 相似文献