Polarization-maintaining optical fibers with low dispersion over a wide spectral range

The total dispersion characteristics of the doubly clad Panda (or bow-tie) fibers have been investigated. It is shown that the contribution of the photoelastic effect to the total dispersion becomes of the order of several psec/km x nm in the 1.5-1.7-microm wavelength region. By careful adjustment of the cutoff wavelength, the total dispersion is reduced to within +/- 1 psec/km x nm over the 1.38-1.70-microm wavelength region for the HE(11)(x) mode and 1.38-1.68 microm for the HE(11)(y) mode, respectively.     

Dielectric response of polymer relaxors

Dielectric response of vinylidene fluoride type ferroelectric polymers is dominated by that of segmental motions in the amorphous phase in temperature range 200–300 K and contributions related to the local mode and ferroelectric–paraelectric transition in the crystalline phase of the polymer at higher temperatures. Diffuse and frequency-dependent dielectric anomaly observed in fast electron irradiated polyvinylidene fluoride-trifluoroethylene P(VDF/TrFE) has been related to relaxor-like behavior induced in the semicrystalline ferroelectric copolymers. As random field and the response of polar nanosize clusters determine the relaxor behavior the effects of disorder and fast electron irradiation (below and above T _C) on the three contributions to the dielectric response of PVDF, P(VDF/TrFE)(75/25) and P(VDF/TrFE)(50/50) are shown. The processes involved in radiation-induced functionalization of PVDF-type polymers are discussed on the basis of results of ESR, IR and Raman spectroscopy studies.     

Effect of low dose rate irradiation on doped silica core optical fibers

The optical attenuation induced in multimode doped silica core optical fiber waveguides by a year's exposure to low dose rate (1 rad/day) ionizing radiation was studied, allowing a characterization of fibers deployed in these environments and a determination of the permanent induced loss in the waveguides. Variations in the induced attenuation at 0.85 microm have been observed with changes in the dose rate between 1 rad/day and 9000 rads/min. These dose rate dependences have been found to derive directly from the recovery that occurs during the exposure; the recovery data predict little or no dose rate dependence of the damage at 1.3 microm. The low dose rate exposure has been found to induce significant permanent attenuation in the 0.7-1.7-microm spectral region in all fibers containing P in the core, whether doped uniformly across the diameter or constrained to a narrow spike on the centerline. Whereas permanent loss was induced at 0.85 microm in a P-free binary Ge-doped silica core fiber by the year's exposure, virtually no damage was observed at 1.3 microm.     

Evaluation of high temperature dielectric films for high voltage power electronic applications

Three high temperature films, polyimide, Teflon perfluoroalkoxy and poly-P-xylene, were evaluated for possible use in high voltage power electronic applications, such as in high energy density capacitors, cables and microelectronic circuits. The dielectric properties, including permittivity and dielectric loss, were obtained in the frequency range of 50 Hz to 100 kHz at temperatures up to 200°C. The dielectric strengths at 60 Hz were determined as a function of temperature to 250°C. Confocal laser microscopy was performed to diagnose for voids and microimperfections within the film structure. The results obtained indicate that all films evaluated are capable of maintaining their high voltage properties, with minimal degradation, at temperatures up to 200°C. However, above 200°C, they lose some of their electrical properties. These films may therefore become viable candidates for high voltage power electronic applications at high temperatures.     

Explosion dust particle size measurements

In situ measurements of the sizes and concentrations of dust particles generated by the detonation of high explosives in clay soil near Leesville, La., sandy clay soil near Huntsville, Ala., and sandy soils near Orogrande, N.M. are reported. Measurements were generally made within 1 m of the surface (in one case 10 m) at distances ranging from 10 to approximately 50 m from the detonation point with a combination of Knollenberg lightscattering counters (for particles with equivalent radius in the submicron to 15-microm range) and a Knollenberg optical array probe (for particles of 10-150 microm). Measurements were made for periods of several tens of seconds following detonation. All dust size distributions, irrespective of soil or explosive type, exhibit a bimodal character with mass mean radii of approximately 7 and 70 microm. Peak aerosol mass loadings inferred from the distributions have values ranging from 0.05 to 10 g gm-3 with the larger mode of particles contributing most to the mass loading. Predictions of dust extinction coefficients at visible (0.55-microm) and IR (10.4-microm) wavelengths were made using the measured size distributions together with estimates of dust refractive indices. These predictions suggest that extinction should be nearly neutral (wavelength independent) in agreement with transmission measurements made during some of the tests. Predicted mass extinction coefficients, under the assumption of dust material density of 2.5 g cm-3, are of the order of 0.05 m2 g-1 at both visible and IR wavelengths. This value is also in good agreement with a test-averaged measured value of 0.03 m3 g-1 (at lambda = 10.6 microm) obtained using a short path transmissometer and hi-vol sampler.     

200-mW-average power ultraviolet generation at 0.193 microm in K2Al2B2O7

K2Al2B2O7 has been found to be phase matchable for type-1 sum-frequency generation (SFG) at 0.193 microm by mixing the Nd:YAG laser wavelength at 1.0642 microm and the SFG output of the RbTiOAsO4 optical parametric oscillator tuned at 0.2358 microm. An average power of 200 mW at 10 kHz was obtained in a 7-mm-long crystal. In addition, the Sellmeier equations and the thermo-optic dispersion formula, which predict well the phase-matching conditions and temperature phase-matching bandwidths (FWHM) for second-harmonic generation and SFG in the 0.193-0.669-microm range, are presented.     

Effect of atmospheric attenuation on temperature measurements made using IR scanning systems

The atmosphere attenuates IR radiation in certain frequency bands even at distances as short as 1 m. Within the 3-5-microm range used by many IR thermographic systems, H20 and CO2 absorb a finite fraction of the source radiation. To achieve reliable quantitative IR thermography, it is necessary to correct the received signal for this attenuation. This paper develops a simple model and presents numerical calculations of the attenuation expected at a few meters distance for one typical thermographic imaging system. (The extension to other equipment could easily be done by substituting different numerical data for the detector response.) The attenuation factors due to CO2 and H20 are 6 and 8%, respectively, at a 10-m range. A wide variety of target temperature and ambient humidity conditions were examined; representative curves selected from this output are presented. Because of the importance of precise IR measurements for industrial applications, the effect of varying CO2 concentrations was also studied.     

Ac conductivity, dielectric losses, permittivity behavior of BaxSr1?xFe0.8Co0.2O3?δ (x?=?0, 0.5 and 1) ceramics

In this paper, we have investigated ac conductivity, dielectric losses, permittivity of Ba _x Sr_1−x Fe_0.8Co_0.2O_3−δ (x = 0, 0.5, 1) ceramics. It has been observed that increase in barium content decreases activation energy (i.e. conductivity increases) in the higher temperature region (550–770 K). In the lower temperature region system with x = 0 shows metallic conductor behavior and system with x = 1 shows thermally activated behavior. The ferroelectric peak temperatures are observed at 700, 750 and 723 K for x = 0, 0.5 and 1, respectively. This peak temperature can be attributed to the oxygen-vacancy-related dielectric relaxation. With the increase of barium content the dielectric dispersion tend to diminishes. Partial substitution of strontium with barium (for x = 0.5) reduces dielectric losses by 50%.     

Synthesis and characterization of tetraethylammonium tetrachlorocobaltate crystals

Single crystals of tetraethylammonium tetrachlorocobaltate were grown by solution method and characterized through single crystal X-ray diffraction, thermogravimetric analysis (TGA), differential scanning calorimetric studies (DSC) and infrared spectroscopic technique (IR). The crystals were bright, transparent and blue coloured. The unit cell parameters were found to bea =b = 90363 Å andc = 14.9879 Å and α = β = γ = 90°, showing tetragonal lattice from the XRD data. Thermogravimetric analysis showed a loss of weight at 683 K from which the decomposition reaction was formulated. Thermal anomalies were found for this crystal at temperatures 200 K, 220 K in the cooling cycle and at temperatures 200 K, 240 K in the heating cycle, respectively which showed that this crystal was associated with first order phase transition. All the vibrational frequencies corresponding to (TEA)⁺ ions and CoCl ₄ ^2? ions were assigned from the IR spectral data of this crystal.     

Electromechanical properties of fine-grain, 0.7 Pb(Mg(1/3)Nb(2/3))O3-0.3PbTiO3 ceramics

A fine grain, relaxor-based piezoelectric ceramic 0.7 Pb(Mg(1/3)Nb(2/3))O3-0.3PbTiO3 (PMN-30% PT) has been investigated, which was fabricated using the columbite precursor method. The complete set of electromechanical properties of the piezoceramic at room temperature is determined using a combination of ultrasonic and resonance techniques. This fine-grain ceramic (grain size < or = 2.5 microm) exhibits ultra-high dielectric permittivity (epsilon33(T)/epsilon0 approximately 7000) and a high coupling coefficient k(33) (= 0.78). Ultrasonic spectroscopy was used to measure the dispersion of the phase velocity and attenuation for the longitudinal wave propagating in the poling direction. Lower attenuation and smaller velocity dispersion were observed compared to modified Pb(Zr(x)Ti(1-x)O3 (PZT-5H) ceramics. The measurement results show that this fine-grain PMN-30% PT ceramic is a very good material for making ultrasonic array transducers.     

Processing and characterization of silver films used to fabricate hollow glass waveguides

Hollow glass waveguides are an increasingly popular fiber for the delivery of high-power IR laser radiation. At CO(2) laser wavelengths the measured and theoretical losses agree, but at the 3-microm Er:YAG laser wavelength the losses remain higher than expected. The reason for this is the surface roughness of the silver film used to form the first layer of the Ag/AgI thin-film structure. We found that the roughness of the silver film increases fivefold as silvering times increase from 5 to 80 min. This increased surface roughness produces a concomitant linear increase in the attenuation coefficient for the silver-only guides for wavelengths shorter than approximately 5 microm.     

Sample filtration,concentration, and separation integrated on microfluidic devices

Microfabricated devices integrating sample filtration, solid-phase extraction, and chromatographic separation with solvent programming were demonstrated. Filtering of the sample was accomplished at the sample inlet with an array of seven channels each 1 microm deep and 18 microm wide. Sample concentration and separation were performed on channels 5 microm deep and 25 microm wide coated with a C18 phase, and elution was achieved under isocratic, step, or linear gradient conditions. For the solid-phase extraction, signal enhancement factors of 400 over a standard injection of 1.0 s were observed for a 320-s injection. Four polycyclic aromatic compounds were resolved by open channel electrochromatography in under 50 s. Chip operation was unaffected by the presence of the 5-microm silica particles at the filter entrance.     

Acoustic Properties of Normal Liquid 3He in 98% Aerogel

We have performed longitudinal ultrasound (9.5 MHz) attenuation and sound velocity measurements in the normal state of liquid ³He in 98% aerogel. The absolute attenuation and sound velocity were determined by direct propagation of sound pulses through the medium in a wide range of temperatures, 2 mK<T<200 mK. Due to the scattering off the aerogel, the sound excitation remains as first sound over the entire range of temperatures and pressures studied. Unlike pure liquid ³He, the sound attenuation shows a minimum around 30–50 mK, depending on the pressure. We report our results of absolute sound attenuation measurements at 29 bars of sample pressure.     

Carbon aerogel: a new nonreflective material for the infrared

We present directional hemispherical reflectance (DHR) and bidirectional reflectance distribution function (BRDF) measurements of a carbon aerogel in the 2.5-14.3-microm infrared spectral region. The measured DHR is 1.0-1.2 +/- 0.2% throughout the 2.5-14.3-microm infrared wavelength region. When the incidence angle is increased from 8 degrees to 30 degrees off normal, the DHR increases by only 0.2%; i.e., performance does not significantly degrade as a result of illumination by off-normal infrared radiation. BRDF measurements, obtained at a wavelength of 10.6 microm, indicate that carbon aerogel exhibits Lambertian behavior. The carbon aerogel's BRDF value of 4 x 10(-3) sr(-1) is consistent with its measured DHR values. Gas adsorption and transmission-electron microscopy indicate a structure dominated by particles and pores of 相似文献   

Dielectric anomalies in orthorhombic YMnO3 thin films

We report on the magnetodielectric characterization of orthorhombic (001) oriented YMnO₃ thin films grown by PLD on Nb-doped SrTiO₃. Detailed temperature, magnetic field and frequency dependent measurements are used to determine dielectric and magnetodielectric response and to analyse its origin. A dielectric peak below the Néel temperature is observed. We show that this peak signals a magnetoelectric coupling as inferred from a magnetocapacitance of about 2% at 8 T and 25 K. A careful analysis of the impedance spectroscopy allows concluding that both the dielectric peak and the measured magnetocapacitance are intrinsic properties of YMnO₃. At higher temperatures (> 200 K) another dielectric feature (a strong frequency dependency and a peak in the dielectric losses) is observed, which is ascribed to the Maxwell-Wagner behaviour and thus it is not a genuine response of stoichiometric YMnO₃.     

Characterization of fine grain Ba0.995Y0.005TiO3 ceramics obtained from gel-precursor nanopowder

Using an acetate-alkoxide sol-gel route in which the precursors are barium acetate, yttrium isopropoxide and titanium diisopropoxide bis-acetylacetonate, we prepared a ferroelectric material with the formula: Ba1-xYxTiO3, x = 0.005. SEM analysis showed a polymeric microstructure of the gel due to the chelated titanium alkoxide precursor used as starting materials. The evolution of the structure and microstructure of the precursor gel heated at temperatures up to 1000 degrees C was studied by various techniques. The powder obtained by heating the gel at 1100 degrees C presented a homogeneous structure consisting of submicronic particles (approximately 200 nm). XRD and SAED analyses revealed that Ba0.995Y0.005TiO3 nanocrystals of about 5-10 nm appeared at 600 degrees C, together with BaCO3. The presence of barium carbonate was identified also by IR spectroscopy and thermal analyses. The ceramics obtained from the as-prepared powder presented good dielectric properties (capacitance = 840 pF/dielectric constant = 3860 and dielectric loss (tandelta) = 0.078 at Curie temperatures of 120-121 degrees C).     

Gradually tapered hollow glass waveguides for the transmission of CO2 laser radiation

Hollow glass waveguides with bores tapered from 1000 to 500 microm and from 700 to 500 microm over a length of 2 m were coated with silver and silver iodide inner films. These waveguides were designed for low attenuation at the 10.6-microm CO2 laser wavelength. The straight losses, which were measured to be 0.8 and 1.6 dB/m, respectively, decreased when the guides were bent. A simple ray-trajectory model is presented to explain this unexpected behavior.     

Prestructured MALDI-MS sample supports

Prestructured MALDI-MS sample supports have been developed that simplify high-throughput analysis of biomolecules and improve the detection sensitivity. The mass spectrometric sample support is coated with a thin layer of hydrophobic Teflon that carries an array of 200-microm gold spots, which provide hydrophilic sample anchors. Each transferred sample droplet contacts one anchor, on top of which, after solvent evaporation, the sample is exclusively deposited due to the strongly water repellent nature of the Teflon surface. The initial matrix concentration is kept low, enabling sample up-concentration by more than 2 orders of magnitudes before crystallization commences. As a result, the detection sensitivity is improved as documented by mass spectra recorded from 100 amol of various peptides, 1 fmol of a DNA 20 mer, and 5 fmol of a 130 bp PCR product. Size and spacing of the hydrophilic anchors are optimized for MALDI-MS performance (sample spot size approximately = laser irradiation spot size), for short analysis times (predetermined sample coordinates), and for high throughput sample preparation (sample anchor array according to the 1536 microtiter plate format).     

Temperature dependence of elastic and dielectric properties of (Bi2O3)1 − x(CuO)x oxide glasses

Oxide glasses with the general formula (Bi₂O₃)_{1 - x}(CuO)_x have been prepared by quick quenching technique. Their longitudinal and shear elastic moduli have been determined by measuring the corresponding ultrasonic wave velocities between 300 and 470 K, which are well below the glass transition temperature of this system. Temperature variation of ultrasonic velocity and attenuation exhibit anomalies around 435 K in glasses with x 0.3. A nonlinear behaviour is also reflected in the CuO concentration dependent dielectric constant curve around x = 0.3. These anomalies are interpreted in terms of a structural softening (or transformation) taking place in samples having CuO concentration above the critical value. The high dielectric constant of these glasses show very little increase with increase of temperature. Anomalies are also found in the temperature dependence of dielectric constant around 435 K. This behaviour is again considered to be associated with the softening of the glass network.     

Physicotechnical properties of wurtzitic AlN-based ceramics and composites with ceramic matrix

Wurtzitic aluminum nitride-based ceramic materials having the following high characteristics: structural ceramics with a Vickers hardness of HV = 16.8 GPa, fracture toughness K _Ic = 4.7?4.9 MPa·m^1/2, bending strength σ = 370–430 MPa; functional ceramics for heatsinks with a thermal conductivity of 140 W/(m·K) and for microwaves absorption with dielectric constant ? = 23, dielectric loss tangent tan δ = 0.025, coefficient of the electromagnetic energy attenuation L to 36.3 dB/cm (at a frequency of 3 GHz) have been obtained using pressureless sintering and hot pressing.