Experimental investigations of porous bearings under vertical sinusoidally fluctuating loads

There are many papers on the experimental investigations of porous bearings under static loads but there is no paper on the experimental investigations under dynamic loads. In the present paper, the results of experimental investigation of porous bearings under vertical sinusoidally fluctuating loads are presented. The friction force was measured under various conditions of fluctuating load/steady load ratio, journal frequency and load frequency. The investigations were carried out in the hydrodynamic lubrication regime in a specially designed and fabricated test rig. It was found that at any given rpm, as the fluctuating specific load/steady specific load ratio, P_f/P_s, increases, the mean coefficient of friction μ_m increases. It was also found that the mean coefficient of friction is not affected by the load frequency even when the load frequency is half of the journal frequency.     

Wear of a single asperity using Lateral Force Microscopy

This report describes an observation of alternating transitions between linear (Amontons) and non-linear friction-load behavior during Lateral Force Microscope experiments using a silicon tip sliding on a quartz surface. Initially, a transition from linear to non-linear behavior was attributed to nanoscale ‘running-in’ of the tip to form a single contact junction at the interface. Once this had occurred, a non-linear relationship between friction and applied load was observed during a number of loading and unloading cycles. For higher compressive loads, a further transition to a more linear friction-load behavior was attributed to nanoscale wear in the contact zone. Notably, when applied load was reduced below this ‘high-load’ transition point, the same non-linear friction-load behavior was again observed, but with a larger (friction per load) magnitude than seen previously. This cycle was repeated five times in these experiments, and each time, switching between non-linear and linear friction-load behavior occurred, along with a progressive increase in friction (per load) each time load was reduced below the transition point. The progressive increase in friction is attributed to an increased area of contact, caused by nanoscale wear at higher applied loads. An increase in tip size was confirmed by tip profiling before and after experiment. By progressively wearing the asperity at higher loads, the (interfacial or true) contact area, A, between the surfaces could be progressively increased, and as a result, a progressive increase in interfacial sliding friction, F _f , was obtained at lower loads (according to F _f = τA).     

The comparisons of sliding speed and normal load effect on friction coefficients of self-mated Si3N4 and SiC under water lubrication

The effects of sliding speed and normal load on friction coefficients of self-mated Si₃N₄ and SiC sliding in water after running-in in water were investigated with pin-on-disk apparatus at sliding speeds of 30 to 120 mm/s, normal loads of 1 to 14 N in ambient condition. The results showed that, after running-in in water, for two kinds of self-mated ceramics, friction coefficient increases with both decreasing sliding speed and increasing normal load when normal load is larger than a critical normal load. Friction coefficient was independent of normal load when normal load is smaller than the critical load. The lubrication film of Si₃N₄ under water lubrication exhibited larger load carrying capacity than that of SiC did. Stribeck curves indicated that, for self-mated Si₃N₄ ceramics, hydrodynamic lubrication will change into boundary lubrication abruptly when the sommerfeld number is less than a critical value; while for self-mated SiC ceramics, hydrodynamic lubrication will change into mixed lubrication and then into boundary lubrication gradually when the sommerfeld number is below critical value.     

Load Induced Microstructure Evolution and Friction in an Organic Monolayer Self-assembled on a Silicon Substrate

In sliding of organic self-assembled monolayer against a probe the friction force is generally found to vary linearly with normal load. Here, lateral force microscopy is used to track the physical changes at the interface brought about when an octadecyltrichlorosilane monolayer, self-assembled on a silicon wafer, is slid against a Si₃N₄ tip in the 0–30 nN load range. Regarding a morphologically heterogeneous monolayer domain to be made up of tiles of characteristic friction forces, each tile is in a unique physical state; the variation of area fraction (in a scan area) of each tile is tracked as a function of normal load. The area averaged friction force at a load is obtained by summing the fractional forces of constituent friction tiles. The friction force obtained thus, is found to vary linearly with normal tip load. It is observed that this force is dominated by the low-friction crystalline tiles at low loads and by the high friction more amorphous tiles at high loads. This suggests that for a self- assembled monolayer the load governance of friction as implied by the Amontons Law may be attributed to the physical changes that are brought about at the interface by changing the normal load.     

Atomistic Insights into the Running-in,Lubrication, and Failure of Hydrogenated Diamond-Like Carbon Coatings

The tribological performance of hydrogenated diamond-like carbon (DLC) coatings is studied by molecular dynamics simulations employing a screened reactive bond-order potential that has been adjusted to reliably describe bond-breaking under shear. Two types of DLC films are grown by CH₂ deposition on an amorphous substrate with 45 and 60 eV impact energy resulting in 45 and 30% H content as well as 50 and 30% sp³ hybridization of the final films, respectively. By combining two equivalent realizations for both impact energies, a hydrogen-depleted and a hydrogen-rich tribo-contact is formed and studied for a realistic sliding speed of 20 m s⁻¹ and loads of 1 and 5 GPa. While the hydrogen-rich system shows a pronounced drop of the friction coefficient for both loads, the hydrogen-depleted system exhibits such kind of running-in for 1 GPa, only. Chemical passivation of the DLC/DLC interface explains this running-in behavior. Fluctuations in the friction coefficient occurring at the higher load can be traced back to a cold welding of the DLC/DLC tribo-surfaces, leading to the formation of a transfer film (transferred from one DLC partner to the other) and the establishment of a new tribo-interface with a low friction coefficient. The presence of a hexadecane lubricant leads to low friction coefficients without any running-in for low loads. At 10 GPa load, the lubricant starts to degenerate resulting in enhanced friction.     

Aqueous Lubrication of SiC and Si<Subscript>3</Subscript>N<Subscript>4</Subscript> Ceramics Aided by a Brush-like Copolymer Additive,Poly(<Emphasis Type="SmallCaps">l</Emphasis>-lysine)-<Emphasis Type="Italic">graft</Emphasis>-poly(ethylene glycol)

We have examined the adsorption properties of poly(l-lysine)-graft-poly(ethylene glycol) (PLL-g-PEG)—a brush-like polymer—on Si₃N₄ and SiC surfaces and determined its impact on the aqueous lubrication of Si₃N₄ and SiC at various speeds and applied loads. The addition of PLL-g-PEG in aqueous solution reduces the interfacial friction forces significantly for self-mated sliding contacts of these two ceramics, as compared to lubrication with water or buffer solution alone. For SiC, the improved lubricating performance by addition of PLL-g-PEG was apparent for all tested speeds (from 1.4 to 185 mm/s under 2 N load). For Si₃N₄, the effect was more apparent in the slow-speed regime (≤20 mm/s under 2 N load) than in the high-speed regime (>100 mm/s), where extremely low coefficients of friction (μ ≤ 0.006) are readily achieved by aqueous buffer solution alone. It was further observed that the optimal lubricating effect with Si₃N₄ is achieved when the tribopairs are first run-in in polymer-free aqueous buffer to render the sliding surfaces smooth, after which the PLL-g-PEG copolymer is added to the buffer solution.     

Boundary lubrication additives for aluminium: A journey from nano to macrotribology

The tribology of two potential additive molecules for aluminium has been studied in the self assembled monolayer state at low loads (10⁻⁹–10⁻² N) and in dispersion state in n-hexadecane at high load (60 N). The two additive molecules are 1H, 1H, 2H, 2H-perfluorooctyltrichlorosilane (FOTS), which has a rigid rod-like helical structure and octadecyltrichlorosilane (OTS), which has a zigzag backbone configuration. The adhesion, friction and wear performance have been investigated. Molecular conformational order and stiffness were found to play major roles in frictional dissipation and wear resistance, recorded in a nanotribometer and a pin-on-disc machine, while for very low load measurements (LFM), adhesion was found to have a significant role on friction along with molecular entropy.     

Tribological Properties of Self-Assembled Monolayers and Their Substrates Under Various Humid Environments

Using friction force microscopy (FFM) under controlled environments, we have systematically investigated the humidity effect on the frictional properties of two important classes of self-assembled monolayers (SAMs), i.e., N-octadecyltrimethoxysilane (OTE, CH₃(CH₂)₁₇Si(OCH₃)₃) on SiO₂(OTE/SiO₂), and N-alkanethiols on Au(111), together with their respective substrates. Experimental results show that both OTE and alkylthiol SAMs can decrease the friction force between a Si₃N₄ atomic force microscope (AFM) tip and substrates. The nearly humidity-independent friction of the two kinds of SAMs indicates that these SAMs are ideal lubricants in applications of micro-electro-mechanical systems (MEMS) under different environments. The humidity dependence—as the humidity increases, the friction first increases and then decreases—of the two substrates, SiO₂ and Au(111), can be explained by the adsorption of water. The decrease in the friction at high humidity is attributed to the low viscosity in the multilayers of water, while the increase in the friction at low humidity can be explained by the high viscosity between the water monolayer and the surfaces (AFM tip and sample), possibly due to the confinement effects. The effect of modification of the AFM tip with alkanethiol molecules on the humidity dependence of Au(111) friction has also been investigated.     

Friction and wear of carbon steel near T1-transition under dry sliding

The wear phenomenon of metals under dry sliding is, generally, divided into two modes of severe and mild wear. A discontinuous transition between the wear modes often takes place in a certain load range. The T₁-transition is usually observed at lower levels of load or sliding velocity. There is a great difference in wear rate between severe and mild wear. This indicates that the occurrence of severe wear should be avoided, especially in the field of machine design to prevent energy loss, occurrence of noise and vibration, and life reduction of machines and their components. Therefore, it is important for machine designers to know the relationship between friction and wear and the difference in properties of the wear surfaces in the two wear modes. In this study, wear tests of 0.35% C steel in contact with itself under constant load were conducted in moist air at various contact loads under dry sliding. The friction and wear were measured continuously throughout each test. After the tests, the relationship between friction and wear and the difference in properties of the wear surfaces were investigated in each wear mode. From the results, the upper and lower critical loads (P_acr and P_Acr) appeared between severe and mild wear. The phenomenon of zero wear has been newly found in the early period at very low loads. The zero wear continued for a long sliding distance and then changes to mild wear. The critical load between zero wear and mild wear is defined as P_zerowear. The load was changed once in a step-wise manner from low to high levels in process of test. Since the rubbing history under mild wear condition at the low load in the first stage affected the properties of wear surface, the wear mode at the high load in the second stage changed from ‘mild wear’ to ‘quasi-mild wear’ having a low rate. From the relationship between sliding distance necessary for the appearance of quasi-mild wear and contact load in the first stage, the boundary curve between severe wear and quasi-mild wear in the second stage is hyperbolic. This curve gradually approaches P_zerowear with decreasing contact load. Thus, P_zerowear is one of the important critical loads for elucidating the test results under varying load.     

Friction of ultrathin Si,F-containing coatings

The friction of an ultrathin coating (~5 nm) formed as a result of the modifier segregation towards the surface of modified epoxy polymer in the form of multiple short chains of Si, F modifier has been investigated in a range of loads from 0.1000 to 0.0005 N. During the investigation of the reverse friction of ceramic (Al₂O₃) ball on the coating, the sharp decrease in coefficient of friction at a load of less than 0.002 N has been shown, which is probably caused by the change in the mechanism of friction during the transition of friction to the zone of a self-lubricating coating. Under these conditions, the difference between the static coefficient of friction (stop effect) and dynamic coefficient of friction increases.     

Kinetic frictional behaviour of alumino-silicate ceramics

The frictional behaviour was experimentally investigated of alumino-silicate ceramics (3Al₂O₃, 2SiO₂) rubbing against a hard steel surface under static and kinetic friction conditions. Tests were carried out on a pin-on-disc machine under both dry and wet contact conditions. Results showed that the frictional behaviour under either static or kinetic conditions was highly dependent on the ceramic body phase transformation which in turn was controlled by the firing temperature during ceramic processing and treatment. Lower friction values were evident when using specimens of ceramic bodies containing a high mullite crystalline phase, which are attained at high firing temperatures. Both the running speed and applied loads had insignificant effects at high loads.During kinetic friction tests lower frictional values were displayed than for static friction tests under wet contact conditions, and under dry conditions when using high mullite ceramic bodies. For specimens of ceramics fired at relatively low temperatures, kinetic friction tests produced higher frictional values than static friction tests.     

Effect of MoO3 Tabular Crystals on TiAl Matrix Composites under Different Test Loads

The friction and wear behavior of TiAl matrix self-lubricating composites (TMSCs) with MoO₃ tabular crystals (MTCs) sliding against a GCr15 steel ball is tested using a constant speed of 0.2 m/s at room temperature under different loads from 6.65 to 16.65 N. The result reveals that TMSCs show a consistently lower friction coefficient in a certain range from 0.2 to 0.6 and less wear rate from 0.29 × 10^?4 mm³ N^?1 m^?1 to 0.49 × 10^?4 mm³ N^?1 m^?1 compared to TiAl-based alloy. Moreover, the friction coefficient and wear rate of TMSCs decrease with an increase in test load. MTCs in the deformed layer will be refined to produce interfacial shear slip and reduce the shear stress because of the weak binding force of MTCs in the sliding process, which can facilitate the formation of a deformed layer and protect the deformed layer from spalling failure. In addition, MTCs on the worn surface of TMSCs can reduce the shear stress directly. Hence, MTCs can promote antiwear of the deformed layer and reduce the friction on the worn surface of TMSCs. MTCs can play a better role in antiwear and antifriction when the test load is higher.     

Assessments of the kinetic and dynamic loads sustained by stationary tools during high rate plastic forming

A systematic method for evaluating the kinetic and dynamic loads sustained by stationary tools (as opposed to moving tools for which methods already exist) during high rate plastic forming is examined and exemplified by examples. It is essentially based on the momentum theorem for continua for incompressible flow, utilizing kinematically admissible velocity fields. In steady state forming processes (such as rolling, wire drawing, etc.), the difference between the active load (imposed or calculated a priori) and the reactive load, is formulated rigorously, whereas for non-steady processes (forging, impact extrusion, etc.) the formulation gives merely an approximation to the dynamic effects on the tools. The resulting velocity-dependent reactions on the tools are given in terms of two nondimensional numbers, namely, the “kinetic head” (u₀²/σ₀) (called the Euler Number) and the “dynamic head” (ú₀L/σ₀), which includes the machine speed (u₀), machine acceleration ( ), material density , yield strength ₀ and a characteristic dimension of the product, L. The same two non-dimensional heads emerged previously from energy-balance consideration in Ref. [1], while approximating dynamic loads on moving tools, hence a consistency is demonstrated. These heads are unavoidably multiplied by geometrical functions, which typify the specific process under consideration and may amplify (or diminish) the intensity of the dynamic effects. The present work is focussed on quantifying, by the above method, the inherent difference between the reactive load sustained by the non-moving tool (say, a die) and the acting load carried by the moving tool (piston, ram, etc.) In particular cases of very slow processes, these loads are equal by static equilibrium. In some practical processes (like rolling) their difference appears to be relatively small, whereas in others (like impact extrusion) it appears extremely large.     

<Emphasis Type="Italic">In situ</Emphasis> examinations of the friction properties of chromium coated tools in contact with wet wood

The study is concerned with in situ examinations of the friction coefficient () of various kinds of wet wood in contact with the active faces of a low-alloy steel cutting tools non-modified and covered with a chromium coating. The variable parameters were: the sliding speed (V) and the normal force (F_N). In all the material pairs examined in friction, the coefficient appeared to decrease with increasing V and increasing F_N. Its variation is described by an exponential function. The Cr coating reduces apparently the friction coefficient compared with that of uncoated steel, especially in static friction. The advantageous tribological properties of chromium coating covered with native chromium oxide can be attributed to its weak water wettability and high hardness.     

Reciprocating Sliding Friction and Wear Property of Fe<Subscript>3</Subscript>Si Based Alloys Containing Cu in Water Lubrication

Fe₃Si, Fe₃Si alloys containing Cu were fabricated by arc melting followed by hot-pressing. The friction and wear behaviors of Fe₃Si based alloys with and without Cu addition against Si₃N₄ ball in water-lubrication were investigated. The friction coefficient and the wear rates of Fe₃Si based alloys decreased as the load increased. The wear rate of Fe₃Si was higher than that of AISI 304. The addition of Cu can significantly improve the friction and wear properties of Fe₃Si based alloys and substantially reduce the wear rates of Si₃N₄ ball. The wear rate of Fe₃Si–10%Cu was 2.56 × 10⁻⁶ mm³ N⁻¹ m⁻¹ at load of 20 N and decreased to 1.64 × 10⁻⁶ mm³ N⁻¹ m⁻¹ at load of 90 N. The wear rate of Si₃N₄ ball against Fe₃Si–10%Cu was 1.41 × 10⁻⁶ mm³ N⁻¹ m⁻¹, while the wear rate of Si₃N₄ ball against AISI 304 was 5.20 × 10⁻⁶ mm³ N⁻¹ m⁻¹ at load of 90 N. The wear mechanism was dominated by micro-ploughing. The combination of mechanical action (i.e., shear, smear and transference of Cu) and tribochemical reaction of Si₃N₄ with water was responsible for the improved tribological behavior of Fe₃Si alloys containing Cu under high loads.     

Surface Friction of Poly(dimethyl Siloxane) Gel and Its Transition Phenomenon

The surface sliding friction of chemically cross-linked poly(dimethyl siloxane) (PDMS) swollen with linear PDMS as an oligomer is investigated. The friction force f increases with the normal pressure P in a power-law relation fP , where the exponent changes in a range of 0-1, depending on the degree of polymerization, N _poly, of the linear PDMS oligomer. When N _poly is in a range of 240-320, a dramatic decrease in friction force is observed at a critical normal pressure, P _c, leading to a very low friction coefficient on the order of 10^–3 at high-pressure ranges. The P _c increases with decreasing network size N _netof the gel and also with increasing polymer length related to N _poly. One possible explanation for this transition phenomenon in friction is that linear PDMS molecules are exuded from the gel network beyond a certain pressure and behave as polymer brushes, which are able to reduce the friction.     

Synthesis of boride coatings on steel using plasma transferred arc (PTA) process and its wear performance

Boriding of the surface of a tool steel using boron powder and the plasma transferred arc process was investigated. It was shown that this method is an easy and effective technique in producing uniform alloyed layers with a thickness of about 1.5 mm and a hardness between 1000 and 1300 HV.The microstructure of the borided surfaces consists of primary Fe₂B-type borides and a eutectic mixture of borides and martensite. Some cracks are observed in the eutectic regions but they do not seem to critically affect the behaviour of the coatings in sliding wear.The wear rate of pin on disc tests is primarily affected by the applied load and it lies between 10⁻⁵ mm³/m for low loads and 10⁻² mm³/m for high loads. Two distinct regimes of mild and severe wear are obtained separated by a critical load. Mild wear is due to the load supporting effect of borides and severe wear is due to their breakage above a critical load. The wear rate is not significantly affected by the sliding velocity and is consistent with the friction coefficient.The friction coefficient varies from 0.13 to 0.23 and depends strongly on the oxidation status of the wear track. The sliding velocity affects the sliding distance where the coefficient of friction reaches equilibrium.     

Ultralow Friction Behaviors of Hydrogenated Fullerene-Like Carbon Films: Effect of Normal Load and Surface Tribochemistry

Friction and wear behaviors of hydrogenated fullerene-like (H-FLC) carbon films sliding against Si₃N₄ ceramic balls were performed at different contact loads from 1 to 20 N on a reciprocating sliding tribometer in air. It was found that the films exhibited non-Amontonian friction behaviors, the coefficient of friction (COF) decreased with normal contact load increasing: the COF was ~0.112 at 1 N contact load, and deceased to ultralow value (~0.009) at 20 N load. The main mechanism responsible for low friction and wear under varying contact pressure is governed by hydrogenated carbon transfer film that formed and resided at the sliding interfaces. In addition, the unique fullerene-like structures induce well elastic property of the H-FLC films (elastic recovery 78%), which benefits the high load tolerance and induces the low wear rate in air condition. For the film with an ultralow COF of 0.009 tested under 20 N load in air, time of flight secondary ion mass spectrometry (ToF-SIMS) signals collected inside and outside the wear tracks indicated the presence of C₂H₃ ⁻ and C₂H₅ ⁻ fragments after tribological tests on the H-FLC films surface. We think that the tribochemistry and elastic property of the H-FLC films is responsible for the observed friction behaviors, the high load tolerance, and chemical inertness of hydrogenated carbon-containing transfer films instead of the graphitization of transfer films is responsible for the steady-state low coefficients of friction, wear, and interfacial shear stress.     

Cellular automata method for macroscopic surface and friction dynamics in brake systems

The friction dynamics in the boundary layer of a brake system is closely linked with the growth and the destruction of typical structures on the brake pad. These processes are caused by an interaction of friction and wear and determine the (as well measured) time-dependence of global parameters, such as the friction coefficient μ or the temperature. Based on the simulation with a set of differential equations, this equilibrium of flow has also already been described with a cellular-automaton-discretization. This paper will show new results and fundamental conclusions with respect to the surface topography dynamics and the friction behaviour of a brake system.