超细晶粒Ti（C，N）基金属陶瓷刀具切削性能

利用真空烧结工艺制备了两组含有不同TiN成分的超细晶粒Ti(C,N)基金属陶瓷可转位刀片,用不同的切削速度和进给量切削正火45钢,分析了刀具的耐用度、磨损和失效方式等切削性能.结果表明:高速切削时刀具的磨损形式以氧化磨损和扩散磨损为主;在高速进给量大的切削条件下,含TiN低的刀片切削性能好于TiN高的刀片;切削速度对刀具寿命的影响很大;进给量在切削速度较低时对刀具寿命的影响程度要大于切削速度较高时.     

后角对纳米TiN改性Ti(C,N)基金属陶瓷刀具磨损性能的影响

采用粉末冶金法制备了用纳米TiN改性的Ti(C,N)基金属陶瓷刀具。研究了后角对刀具使用寿命及前、后刀面磨损的影响。结果表明,后角为6°的刀具使用寿命最长,后角大于8°的刀具因崩刃而失效,这主要是由于切削刃强度降低和散热条件恶化所致。增大后角会使后刀面的边界磨损加剧,而过大的后角则使前刀面磨损加剧。纳米TiN改性Ti(C,N)基金属陶瓷刀具的后刀面磨损是磨粒磨损、氧化磨损、扩散磨损和黏着磨损共同作用的结果。     

渗硼对Ti(C,N)基金属陶瓷刀具性能的影响

采用粉末冶金法制备了Ti(C,N)基金属陶瓷,并用固体渗硼法对其进行了渗硼处理。研究了渗硼后金属陶瓷的微观组织和力学性能以及渗硼对切削性能的影响。结果表明:Ti(C,N)基金属陶瓷的渗硼层组织由硼化物层、扩散层和基体区组成。渗硼使金属陶瓷的表面硬度提高,抗弯强度降低。渗硼使金属陶瓷刀具在切削速度为200 m/min时的使用寿命提高约1倍;在300 m/min切削速度下,渗硼对延长金属陶瓷刀具的使用寿命没有明显作用;切削速度增至400 m/min时,渗硼使金属陶瓷刀具的使用寿命变短。强烈的热冲击是导致高速切削条件下渗硼层耐磨性降低的主要原因。渗硼层有效地减轻了金属陶瓷刀具表面发生的粘结,并抑制了刀具的扩散磨损和氧化磨损。     

Ti(C,N)基金属陶瓷刀具的切削性能

利用真空烧结工艺和表面氮化处理工艺制备纳米复合Ti(C,N)基金属陶瓷可转位刀片和功能梯度可转位刀片,并对刀片的切削性能进行分析。结果表明:切削正火态45#钢、淬火态45#钢和奥氏体不锈钢时,与YT15、YG8、TN20相比,制备的刀具皆表现出较优的切削性能和较高的耐磨性,表面经氮化处理后,刀具的表面硬度提高了HRA2.2,大幅度提高了刀具的抗热冲击性能。具有梯度结构的金属陶瓷刀片切削正火钢、铸铁和不锈钢时的切削性能比无梯度结构金属陶瓷刀片的切削性能优良,具有更高的耐磨性。     

Ti(C,N)基金属陶瓷的摩擦磨损研究

本文对Ti(C,N)基金属陶瓷材料的摩擦磨损行为及其磨损机理进行了研究.试验结果表明:与具有相同硬度的WC-Co合金和钢结硬质合金相比,Ti(C,N)金属陶瓷具有优异的耐磨性和较低的摩擦系数,其耐磨性随粘结相含量的增加而降低.Ti(C,N)基金属陶瓷磨损过程中,首先由表面微凸体间相互滑过,发生粘着,犁削,引起磨损,跑合一定时间后磨损由硬质相晶粒剥落控制.     

Ti(C,N)基金属陶瓷刀具切削加工有限元模拟

介绍了本课题组研制的一种新的刀具材料--T(iC,N)基金属陶瓷的成分组成及其力学性能;基于大变形-大应变理论、增量理论以及更新拉格朗日算法、采用几何断裂分离准则,建立了二维弹塑性金属正交切削有限元模型,对金属正交切削过程进行了数值模拟;改变刀具前角,得出在不同的刀具前角下T(iC,N)基金属陶瓷刀具在正交切削过程中切削力以及刀具后刀面等效应力变化;分析了切削力、刀具表面等效应力对刀具磨损的影响;模拟结果与相关研究的实验数据吻合。本文的研究为后期研制新的刀具材料提供了理论依据,降低实验成本。     

金属陶瓷刀具切削淬火钢的磨损机理研究

利用真空烧结工艺制备了纳米复合TI(C,N)基金属陶瓷刀片.进行淬火态45#钢的单因素切削试验,并利用SEM,EPMA对金属陶瓷刀具的磨损失效机理进行了研究.结果表明纳米复合TI(C,N)基金属陶瓷刀片在切削淬火态45#钢时表现出较高的耐磨性和切削性能,其主要的磨损失效机理是压应力下的挤压变形和粘附磨损,同时伴随一定的氧化磨损和扩散磨损.     

高速切削用金属陶瓷刀具的制备及磨损机理研究

以微米级TiN和TiC粉为主要原料,添加金属Mo、Ni,采用传统烧结工艺制备了机床高速切削用Ti(C,N)金属陶瓷刀具。研究表明,制备的K2金属陶瓷刀具的弯曲强度为1 215 MPa,洛氏硬度为131.5 HRA,断裂韧度为12.3 MPa·m1/2,切削性能优于商用M4陶瓷刀具。K2金属陶瓷刀具的物相主要为Ti(C,N)、NiCr、WC以及MoC。切削过程主要以扩散磨损和氧化磨损为主,同时伴随轻微的粘结磨损。     

Ti(C,N)_w/Ti(C,N)基金属陶瓷的组织与力学性能研究

采用Ti(C,N)晶须和颗粒复合粉末(Ti(C,N)w+Ti(C,N)p)制备Ti(C,N)w/Ti(C,N)基金属陶瓷。研究了复合粉末对金属陶瓷组织及性能的影响。结果表明,Ti(C,N)w的加入,金属陶瓷的各项力学性能都得到了提高。组织表现为环形相结构特征,与Ti(C,N)基金属陶瓷相比,双层环形相结构所占比例增大,且尺寸加厚。烧结组织中Ti(C,N)w的长径比大于临界长径比,在强化金属陶瓷方面起着重要的作用。环形相使Ti(C,N)w与基体界面结合紧密,增韧机制主要表现为裂纹桥联和裂纹偏转,拔出效应不明显。     

Ti(C,N)基金属陶瓷添加成分的研究进展

简要介绍了Ti(C,N)基金属陶瓷的典型结构,着重概述了化学成分对Ti(C,N)基金属陶瓷组织和力学性能的影响。     

Microstructure and cutting performance of Ti（C, N）-based cermets heat-treated in nitrogen

Ti（C, N）-based cermets were treated using hot isostatic pressing （HIP） at 1423 K in nitrogen. The microstructures compared with the as-sintered cermets were investigated using X-ray diffraction, scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray analysis, and electron microprobe analysis. It was found that high nitrogen activity in the surface zone resulted in the formation of gradient structure. Approximately 20-1am-deep, nitrogen-rich and titanium-rich hard surface zone was introduced by the heat treatment. The nitrogen activity was the driving force that caused the transportation of the atoms through the binder, titanium towards the surface, and tungsten and molybdenum inwards. In the surface zone, the particle size became fine, the inner rim disappeared, and the volume fraction of the outer rim and the binder phase considerably reduced. Small grains of TiN, WC, Mo2C, and nitrogen-rich carbonitlide phases formed in the surface zone during the heat treatment, improving the tlibological property of the heat-treated cermet.     

Ti (C,N)-based cermets sintered under high pressure

In this study, high pressure and high temperature sintering (HPHT) is adopted in the cermet fabrication process, and the microstructure and mechanical properties of cermets with TiC_0.5N_0.5–15WC–10Mo₂C–5TaC–10Ni–10Co (wt%) sintered under 5 GPa and different temperatures (900–1600 °C) using 6 × 14 MN cubic press are investigated. Results show that the densities of samples can reach up to 7.00 g/cm³. Vickers hardness and fracture toughness of the products are over 1727 HV30 and 7.2 MPa m^1/2 respectively. In addition, the sintering results are compared with the data that obtained from commercial samples which produced via conventional sintering technique. The conclusion is that high density and high hardness cermets can be obtained through HPHT sintering.     

Mo element-induced wear behavior evolution of self-lubricant Ti(C,N)-based cermets

In the work, Mo element is used to adjust composition and distribution of the lubricating phase of the self-lubricant Ti(C, N)-based cermets. Ring-block wear test of self-mate pairs is conducted. The microstructure and wear behavior evolution of the cermets are investigated. The results indicate by adjusting the content of Mo, the distribution of graphite on the surface of the self-lubricant cermets changes. With the increase of Mo content, the volume of graphite decrease, and the undissolved Mo increase. During self-mate pair sliding wear, the tribolayer transform from graphite to graphite+MoOx and then to MoOx. The cermets with 4 wt%. Mo show the best tribological properties, which shows a smooth and dense composite tribolayer formed mainly by graphite and MoOx.     

TiN/TiAlN涂层Ti(C,N)基金属陶瓷刀具的切削性能

采用多弧离子镀技术在Ti(C,N)基金属陶瓷基体上沉积了TiN/TiAlN多层涂层,通过扫描电镜、涂层附着力自动划痕仪对其显微组织形貌和涂层的结合强度进行了分析,并对涂层和未涂层金属陶瓷铣刀以及硬质合金铣刀进行了切削0Cr18Ni9钢的试验.结果表明,多弧离子镀TiN/TiAlN涂层均匀,TiN/TiAlN多层涂层与金属陶瓷之间的结合强度高达57.52 N.TiN/TiAlN涂层金属陶瓷的切削性能明显优于未涂层金属陶瓷和硬质合会YW2,其平均寿命为硬质合金刀具的2倍.TiN/TiAlN涂层金属陶瓷刀具的失效形式主要是磨损和崩刃,没有涂层剥落现象,TiN/TiAlN涂层与基体的结合强度很好.未涂层金属陶瓷刀具的磨损形式主要是磨损和粘着.     

Microstructure and cutting performance investigation of Ti(C, N)-based cermets containing various types of secondary carbides

In this paper, the effects of type and amount of various secondary carbides on the microstructure and cutting performance of Ti(C_0.7N_0.3)–12Co system have been investigated. Nine alloys with different amounts of WC, Mo₂C and Ta_0.7Nb_0.3C additives were studied, using scanning electron microscopy (SEM), Vickers hardness (HV), transverse rupture strength (TRS) and continuous turning tests. Alloys including Mo₂C and WC presented finer carbonitride grain structure, as well as higher wear resistance resulting from their higher hardness and highly solution hardened binder phase.     

Preparation of self-lubricating Ti(C,N)-based cermets by solid carburization and wear behavior

In this work, self-lubricating Ti(C,N)-based cermets were prepared by solid carburization. The sintered cermets were wrapped by carburizing agent and sintered again at 1440 °C with different time. The microstructure and composition of cermets were studied. The wear behavior of cermets containing graphite phase was also evaluated using a block-on-ring tribometer. The results showed that the carbon content increased gradually in binder phase with carburizing time. When the carburizing time was 3 h, the carbon got saturated in binder phase. When the carbon content exceeded the solubility in the binder, excessive carbon precipitated and formed graphite phase. Uniformly distributed graphite clusters formed in cermets after carburization for 4 h. The graphite clusters consisted of flocked graphite particles. With the carburizing time extended to 5 h, the graphite clusters became large and some of them interlaced together. Besides, the wear results indicated that the volume loss of cermets containing graphite phase was half of that without graphite due to the formation of smooth tribofilm on the worn surface of cermets.     

Early high temperature oxidation behaviour of Ti(C,N)-based cermets in air

Isothermal oxidation behaviour of two Ti(C,N)-based cermets (TiC-10TiN-16Mo-6.5WC-0.8C-0.6Cr₃C₂-(32-x)Ni-xCr, x = 0 and 6.4 wt%) was investigated in air at 800-1100 °C up to 2 h. Mass gains exhibited neither linear nor parabolic law during isothermal oxidation. The oxide scales formed at 800-1100 °C were multi-layered, consisting of NiO outerlayer, NiTiO₃ interlayer and TiO₂-based innerlayer. The internal oxidation zones formed at 1000-1100 °C consisted of Ti-based, Ni-based and Mo-based complex oxides. Cermet with 6.4 wt% Cr exhibited superior oxidation resistance, due to the presences of Cr_0.17Mo_0.83O₂ in TiO₂-based innerlayer of the oxide scale and Cr-rich Ti-based complex oxide in the internal oxidation zone.     

纳米TiN改性Ti（C, N）基金属陶瓷的组织和性能

采用真空烧结法制备纳米TiN改性的Ti（C, N）基金属陶瓷,研究不同金属相对纳米改性Ti（C, N）基金属陶瓷组织和力学性能的影响。结果表明：除经典的黑芯/灰壳组织外,添加纳米TiN的金属陶瓷在黑芯内还出现灰芯结构;纳米TiN主要分布在陶瓷相颗粒的晶界处;相对于未添加纳米TiN的金属陶瓷,添加纳米TiN粉末能明显提高金属陶瓷的抗弯强度、硬度与断裂韧性;对纳米TiN改性的金属陶瓷而言,金属相Ni能提供更好的抗弯强度与断裂韧性,而金属相Co则能带来更高的硬度。     

Cutting performances, mechanical property and microstructure of ultra-fine grade Ti(C, N)-based cermets

The two cutting tools obtained from ultra-fine grade Ti(C, N)-based cermets were tested in the dry cutting of a medium carbon steel (AISI1045). Microstructure and mechanical properties were studied. Wear mechanisms (mainly diffusion and oxidation) were investigated in detail and compared each other in order to better understand key aspects due to thermal wear mechanisms. Comparing tool A with B, under the adopted cutting conditions, the tool A has a better resistance to oxidation deformation in machining medium carbon steel due to the higher hardness, although tool B has higher bending strength and fracture toughness.