共查询到20条相似文献,搜索用时 109 毫秒
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1~#高压氨合成装置的氨合成塔原采用DN 1 000 mm二轴一径型内件,其在使用后期存在产量低、系统压力高、催化剂床层同平面温差大等问题,为此,将氨合成塔内件更换为一轴二径型。改造后,合成氨产量由260 t/d提高至300 t/d,氨合成塔阻力由0.83 MPa降至0.55 MPa,系统阻力由2.30 MPa降至1.80 MPa,年可降低生产成本约316万元。 相似文献
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介绍云南天安化工有限公司氨合成装置自开车投产以来的运行控制情况.合成氨采用KBR塔后分氨15.5MPa低压氨合成工艺,使用了新型卧式合成塔、组合式氨冷器,缩短了工艺流程,提高了热利用率。降低了系统阻力,应用辽宁盘锦南方化学辽河催化剂有限公司生产的Amomax-10/10H型氨合成催化剂.提高了合成效率。该回路还具有无弛放气、能耗低、操作简便等特点。 相似文献
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<正>0前言河南心连心化肥有限公司一厂氨合成塔原采用DN800 mm和DN1000 mm合成系统各1套并联操作运行,日产合成氨300 t,操作压力30.0~31.0 MPa,压缩机能耗高,维修量较大,系统泄漏 相似文献
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<正> 现代化合成氨系统其合成压力为150~250atm(1470×10~4~1961×10~4pa),在这种压力下操作的传统的氨厂其吨氨能耗高达6.7百万cal/t,有的甚至更高。高能耗推动了改造的进行,诸如改造合成塔或新设计合成塔内套改造老塔。 相似文献
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设计生产能力1 200 t/d大型合成氨生产装置采用低压合成氨生产工艺,其GC-R023型氨合成塔(Ф2 600 mm)是目前完全采用国内专利技术、自主设计、自主制作的大型设备。氨合成塔内件为三径向结构,装填DNCA(A207型)催化剂,介绍了催化剂的升温还原和生产运行情况。目前,该装置在粉煤流量为42~46 t/h时,合成氨产量32~36 t/h,氨合成系统压力10.8~11.2 MPa,系统压差0.55~0.60 MPa,合成塔压差0.15~0.16 MPa,氨净值14.6%~14.8%(体积分数)。 相似文献
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0 前言。四川宜宾金岭化工有限公司目前合成氨年生产能力为4万t,合成系统原流程中冷交、废热锅炉配置偏小,原Φ800氨合成塔内件使用过程中压力经常高于30MPa而需放空操作,且能耗也比较高。为解决以上问题,于2002年的年度大修时将原合成塔内件更换为湖南安淳公司设计制造的Φ800、ⅢJ-99型三轴一径式内件,同时换用高效换热管制作的冷交、循环气预热器芯子,换用更大换热面积的废热锅炉,并对系统流程做了部分更改,部分主管线放大。自大修后系统投入运行以来,合成系统压力明显降低,取得显著的增产节能效果。 相似文献
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为提高合成氨生产能力、降低吨氨能耗,我厂合成系统除了中置锅炉回收余热及改进合成塔内件以外,重点抓了节能型氨触媒的应用。1985年底大检修时,将~#4合成塔氨触媒由原来的无定型改为郑州大学生产的球形触媒。至1988年5月份因合成塔内件漏气进行检修时,卸出触媒。使用近两年半的时间,生产合成氨9.50万吨与第3炉无定型触媒相比,多产合成氨4.4万吨,使用寿命延长1年,吨氨节电25.11度,吨氨能耗下降29.73×10~4kJ。下面就我厂具体应用情况作一介绍。 相似文献
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通过对合成塔内件使用过程中存在的合成塔塔壁温度高、催化剂第一层平面温差大、第二层反应量大而使温度偏高等问题进行分析,提出改进措施并实施,同时采用新的氨合成催化剂还原理念对催化剂快速彻底还原.改进后,平面温差小于10℃,合成系统压力由31.0
MPa降至28.5 MPa,吨氨电耗下降55 kWh,氨产量由395.6t/d提高至425.0t/d,系统工艺指标得到优化,达到了稳定操作、提高产量、降低能耗的效果. 相似文献
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苯乙烯是重要的石油化工原料。本文介绍了国内外苯乙烯生产的发展概况,合成乙苯,苯乙烯所用的催化剂种类,并就苯乙烯生产及催化剂的发展趋势提出了自己的观点。 相似文献
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Synthesis and characterization of homopolymers and copolymers of various acrylates and acrylonitrile
Various homopolymers and copolymers of methyl acrylate, ethyl acrylate, butyl acrylate, and acrylonitrile in different feed ratios were synthesized. These were characterized by IR, 13C-NMR, DSC, DTA, and TGA. Spectroscopic characterization helped in differentiating copolymers of different mol ratios. Thermal analysis revealed different degradation patterns for homopolymers and copolymers. The temperature and energy changes associated with various phase transitions were dependent on the chemical composition of homo- and copolymers, as expected. © 1993 John Wiley & Sons, Inc. 相似文献
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The variation of the Au 4f binding energy of Au clusters with the cluster size has been established by measuring the binding energies of clusters whose size distributions were independently determined by HREM and STM. The binding energy increases significantly when the cluster size is less than 2 nm. Au-Cu bimetallic clusters of the composition Cu3Au have been deposited for the first time on carbon substrates. The shifts in the core level binding energies of the bimetallic clusters show the effect of alloying in the case of large clusters, but show effects of both alloying and cluster size in the case of the small clusters. The interaction of CO with Cu3Au clusters is stronger than with a bulk Cu metal. The interaction of CO with small Cu clusters also seems to be stronger than with bulk Cu or with large Cu clusters. 相似文献
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《国际聚合物材料杂志》2012,61(1-4):113-122
Abstract Kinetics and mechanisms of oxidation of 6 acetals by molecular oxygen and ozone in liquid phase have been studied. Reaction with molecular oxygen (70°C, 15–16 hr) leads to the formation monoethers of the corresponding glycols with 68–90% selectivity. Salts of metals and complexes with crown-ethers have increased the reaction rate significally. Ozone have reacted with acetals with formation similar products. The mechanisms of intermediate stages have been proposed. 相似文献
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G. R. Hamed 《The Journal of Adhesion》1983,16(1):31-39
A substantially greater detachment energy is required to strip a polyethylene tereph-thalate (Mylar) film from a styrene-butadiene-styrene (SBS) triblock copolymer compared to that for peeling from a random styrene-butadiene (SBR) copolymer. This is true even though the intrinsic interaction between the Mylar and each elastomer is expected to be similar because of their virtually identical chemical composition. It is proposed that this difference in peel strength (between the SBS and SBR) is a consequence of the much higher dissipative capacity of the former elastomer. Another manifestation of this is the higher cohesive tear strength of the SBS compared to the SBR. Extents of energy dissipation within each elastomer during detachment of the Mylar adherend are consistent with the hypothesis that the average maximum stress experience before detachment is some similar fraction of each elastomer's tensile strength. 相似文献
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Polypentafluorostyrene (PPFS), polymethylacrylate (PMA), and poly(pentafluorostyrene-co-methylacrylate), poly(PFS-co-MA) were prepared and the wetting characteristics of polymer blends of PPFS and PMA were compared with that of poly(PFS-co-MA) via contact angle measurements. The critical surface tension of polypentafluorostyrene was found to be 22.6 dyne/cm, which is comparable to the value reported for polytrifluoroethylene (22 dyne/cm). The critical surface tension of poly(PFS-co-MA) is not linearly related to its composition. The polymer blends of PPFS and PMA exhibit significant surface enrichment of the fluoropolymer. The harmonic-mean method1 was employed to determine surface tensions of these polymers and many known polymers. It is found that the method produces useful surface tension data provided the contact angle values are derived from testing liquids of dissimilar polarity. 相似文献
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