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铝合金化学镀镍前处理工艺的探讨与实践 总被引:6,自引:2,他引:4
结合铝和钛在性质上的相似性,探讨了对铝合金化学镀镍前处理工艺的改进,以及在实践中的应用,这样,不但使工艺简化,提高了生产效率,而且对铝合金产品的广泛应用具有一定的实际意义。 相似文献
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AZ91D镁合金化学镀镍前处理工艺及腐蚀行为研究 总被引:1,自引:1,他引:0
为了改进传统的镁合金化学镀镍前处理工艺和确定以硫酸镍为主盐的镁合金化学镀镍的最佳工艺.采用碱性焦磷酸盐进行浸蚀代替铬酸浸蚀,去除合金表面的油污和氧化物;然后用氢氟酸溶液进行活化.通过正交试验确定了化学镀镍的最佳工艺.结果表明:采用碱性焦磷酸盐浸蚀的前处理工艺、在最佳施镀条件下镀2h,镀层厚度达到20μm,与基体结合良好;镀层为Ni-P微晶,表面平整、致密,磷的质量分数达11.7%.在质量分数为3.5%的NaCl溶液中的动电位极化测试结果表明,镀层可对AZ91D镁合金起到良好的防护作用. 相似文献
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为了优化镁锂合金化学镀镍前处理工艺,采用磷酸、硝酸和磷酸+硝酸混合溶液3种工艺对镁锂合金进行酸洗,采用氢氟酸、氟化氢铵和磷酸+氟化氢铵混合溶液3种工艺对镁锂合金进行活化,并对活化后的镁锂合金进行镀镍处理。使用金相显微镜、扫描电子显微镜(SEM)、能谱仪(EDS)和X射线衍射仪(XRD)对处理后试样进行表面分析。结果表明:经硝酸+磷酸混合处理的试样表面氧化皮去除完整、有光泽,3种工艺活化后的试样表面均有氟化镁膜生成,经氟化氢铵活化后的试样表面制得的镍磷合金颗粒均匀,排列致密。最优前处理工艺为:酸洗H3PO42mL/L,HNO310mL/L,NaF 1g/L,室温浸蚀5~30s;活化NH4HF220g/L,室温活化1~3min。 相似文献
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Zincating is used as a pre-treatment for aluminium prior to electroless nickel deposition during preparation of magnetic computer memory discs. Four immersion zincating solutions were evaluated at 22°C using single step or double zincating followed by electroless nickel deposition from a high phosphorus hypophosphite bath at 90°C. The coating process was monitored by potential vs. time curves obtained under open-circuit conditions during zincating then electroless nickel plating. The surface morphology of the aluminium, at various stages, was imaged by scanning electron microscopy and atomic force microscopy. Zero resistance ammetry was used to record galvanic currents between the aluminium and an inert platinum counter electrode during zincating. This, together with potential-time measurements, provided simple and valuable methods for following the zincating process and subsequent electroless Ni plating. Double zincating enabled a shorter induction time for electroless Ni deposition and resulted in a more complete coverage of the surface by Zn. 相似文献
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镁合金在镀液中的腐蚀行为 总被引:7,自引:2,他引:7
摘要:通过腐蚀实验和阳极极化曲线研究了硫酸镍主盐配制的化学镀镍液成分和温度对AZ91D镁合金的腐蚀行为的影响,比较了碱式碳酸镍主盐和硫酸镍主盐两种镀镍液的腐蚀性以及施镀后的镀层质量。结果表明:硫酸镍镀液的腐蚀性比碱式碳酸镍镀液大,在低温下,镁合金在硫酸镍镀液中表面的氟化镁膜不致密,镀液对基材的腐蚀性高;而在高温下,Mg^2 与F^-的反应性增强,氟化反应完全,形成的氟化镁钝化膜致密性高,可保护镁合金基体免遭镀液的腐蚀。在施镀温度下,镀液中F^-的缓蚀作用,可使SO4^2-离子对镁合金的腐蚀速率大大降低。 相似文献
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The current research processes of electroplating and electroless Ni-P alloy plating on magnesium alloys were reviewed. Theoretically, the reason for difficulties in electroplating and electroless plating on magnesium alloys was given. The zinc immersion, copper immersion, direct electroless Ni-P alloy plating and electroplating and electroless plating on magnesium alloys prepared by chemical conversion coating were presented in detail. Especially, the research development of magnesium alloy AZ91 and AZ31 was discussed briefly. Based on the analysis, the existing problems and future research directions were then given. 相似文献
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The possibility of citrate precipitation by excess metal ions in alkaline solutions suggests the use of Ni(II) together with OH? to precipitate a Ni(II)-citrate complex from spent electroless plating solutions. After treatment of the precipitate with acid, excess Ni(II) can be removed in the form of insoluble Ni(OH)2. The solution of the Ni(II)-citrate complex can then be reused for electroless nickel plating. During this procedure the additive adipate is not regenerated. For decontamination of spent electroless nickel plating solutions Fe(III) can be used as Ni(II)-citrate complex precipitant. 相似文献
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Electroplating zinc transition layer for electroless nickel plating on AM60 magnesium alloys 总被引:1,自引:0,他引:1
Electroplating zinc coating as transition layer of electroless nickel plating on AM60 magnesium alloys was investigated. The zinc film can be deposited in a pyrophosphate bath at 50-60 ℃ under current density of 0.5-1.5 A/dm^2. A new fore treatment technology was applied by acid cleaning with a solution containing molybdate and phosphorous acid, by alkaline cleaning in a bath containing molybdate and sodium hydroxide. The subsequent electroless plating was carried out in nickel sulfate bath. The SEM observation shows that the deposition is uniform and compact. The polarization curve measurements show that the corrosion potential of the zinc plating in 3.5% NaCl is about -1.3 V(vs SCE) which is noble than that of magnesium substrate. The zinc eleetroplating can be applied as the pretreatment process for electroless nickel plating on magnesium alloys. 相似文献
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研究采用硫酸镍铵复盐结晶从铜电解液中分离回收镍的方法。研究发现,在相同温度的溶液中,硫酸铜的溶解度小于硫酸镍的溶解度,而硫酸铜铵的溶解度大于硫酸镍铵的溶解度。因此,加入(NH4)2SO4可使铜电解液中的镍选择性结晶析出。按(NH4)2SO4/NiSO4摩尔比≤0.8加入(NH4)2SO4,在-15℃冷冻结晶10 h,可使其中的镍以Ni(NH4)2(SO4)2·6H2O的形式结晶析出。将所得结晶物热解,再将热解产物加水溶解,最后将溶解液浓缩结晶得到合格的NiSO4·6H2O产品。复盐结晶法是一种清洁环保、经济高效的从铜电解液中分离回收镍的方法。 相似文献
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高功率输入耦合器是为自由电子激光装置的超导腔传输微波功率的部件.为了提高传输性能,需要在耦合器上镀铜膜.本研究基于2种不同镀铜膜工艺实验,通过EDS线扫描、粗糙度、XRD和残余电阻率(RRR)对比分析在室温(25℃)以及200、400、600和910℃等4种不同温度退火后镀铜膜的性能变化,确定出适合特殊环境条件下高功率... 相似文献
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针对6063铝合金不耐碱腐蚀的问题,对其表面进行了碱性化学镀镍处理以提高其在碱性溶液中的耐腐蚀性能.采用扫描电镜(SEM)、能谱分析仪(EDS)和X射线衍射仪(XRD)分别分析了镀镍层的表面微观形貌、成分和物相结构;采用电化学和全浸蚀腐蚀试验方法测试了铝合金化学镀镍前后在w(NaOH)=4%的NaOH溶液阳极极化曲线和腐蚀失重.研究结果表明,铝合金化学镀镍处理后其表面获得了致密的非晶态高磷镀镍层,化学镀镍后的铝合金阳极极化电位达到析氧过电位时,镀层依然没有破坏,并且该镀层在w(NaOH)=4%的NaOH溶液中基本不发生腐蚀. 相似文献