凝胶注模成型工艺制备SiCw/Al2O3陶瓷复合材料的性能研究

对SiC2/Al2O3陶瓷的低粘度、高固相体积分数浓悬浮体的制备以及凝胶注模成型后坯体的性能和显微结构进行了研究,着重分析了长径比不同的2种SiC晶须及其添加量对坯体性能的影响.结果表明,坯体的相对密度、抗弯强度与SiC晶须的长径比和添加量有关,浆料的粘度随着晶须长径比和添加量的增大而增加.坯体的抗弯强度随着晶须添加量的增加呈现一种先上升后下降的趋势.凝胶注模成型后坯体结构均匀、致密,相对密度为60%,抗弯曲强度达38.5 MPa.通过显微结构观察,裂纹偏转、晶须拔出和晶须桥连是晶须增强的主要机制.     

SiC_(sf)/Si_3N_(4p)混杂增强BAS陶瓷基复合材料的制备及其结构与性能的研究

采用热压烧结方法制备出致密的SiC短纤维和Si_3N_4颗粒复合增强的BAS玻璃陶瓷基复合材料.利用XRD、SEM、TEM和3点弯曲等分析测试手段研究了物相组成、显微结构、界面结构及室温力学性能.结果表明,BAS能有效地促进复合材料的致密化和实现Si_3N_4的α→β相转变.复合材料中的BAS为六方相,SiC短纤维具有热压取向性,与BAS基体之间的界面结合紧密.SiC短纤维和Si_3N_4颗粒对BAS有较为显著的强韧化效果,复合材料的室温弯曲强度和断裂韧性为298 MPa和4.38 M Pa·m~(1/2),比纯六方BAS玻璃陶瓷分别提高了247%和143%.     

SiC晶须补强莫来石基陶瓷复合材料的研究

本文主要研究了不同ＳｉＣ晶须加入量对莫来石基复合材料性能的影响，并对ＳｉＣ晶须、ＺｒＯ２颗粒在材料中的强韧性机理进行了探讨，结果表明：在０￣２５ｖｏｌ％ＳｉＣ晶须加入量范围内，材料的力学性能随ＳｉＣ晶须加入量的增加而提高，在２５ｖｏｌ％ＳｉＣ晶须加入量时，材料的致密化程度受到明显的影响；ＳｉＣ晶须、ＺｒＯ２对材料性能的贡献有叠加作用；材料中存在载荷转移、晶须拔出／解离、裂纹偏转、相变增韧等韧化机理     

STUDY ON C FIBER REINFORCED CELSIAN MATRIX COMPOSITES

１．ＩｎｔｒｏｄｕｃｔｉｏｎＶａｒｉｏｕｓｇｌａｓｓｃｅｒａｍｉｃｍａｔｒｉｘｒｅｉｎｆｏｒｃｅｄｗｉｔｈｃｏｎｔｉｎｕｏｕｓｃｅｒａｍｉｃｆｉｂｅｒｓｈａｖｅｂｅｅｎｄｅｖｅｌｏｐｅｄａｓｃａｎｄｉｄａｔｅｍａｔｅｒｉａｌｓｆｏｒｈｉｇｈｔｅｍｐｅｒａｔｕｒｅｓｔｒｕｃｔｕｒａｌａｐｐｌｉｃａｔｉｏｎｓｉｎａｅｒｏｓｐａｃｅｕｔｉｌｉｔｉｅｓａｎｄｔｒａｎｓｐｏｒｔａｔｉｏｎｉｎｄｕｓｔｒｉｅｓｏｖｅｒｔｈｅｌａｓｔｔｗｏｄｅｃａｄｅｓ〔１,２〕．Ｂａｒｉｕｍａｌｕｍｉｎｏｓｉｌｉｃａｔ…     

SiCW／Y—TZP／Al2O3复合陶瓷的显微结构及其力学性能

研究了ＳｉＣＷ／Ｙ－ＴＺＰ／Ａｌ２Ｏ３系复合陶瓷的显微结构及其力学性能，通过透射电镜拉伸试样中的裂纹扩展形态与组织变化，分析了晶须与ＺｒＯ２相变增韧机制。结果表明，陶瓷体内各相结合致密，分布较为均匀，其室温强度和断裂韧度分别为１１００ＭＰａ和１１．９ＭＰａ．ｍ＾１／２，晶须拔出，裂纹偏转及ＺｒＯ２ｔ－ｍ相变是该复合材料的主要增韧机制。ＳｉＣ晶须和Ｙ－ＴＺＰ的共同作用，对复合材料强度和断裂韧性的提高     

SiC(w)-ZrO2改性MoSi2复相陶瓷的组织与性能

通过热压烧结制备SiC(W)-ZrO2-MoSi2复相陶瓷,利用X射线衍射仪、图像分析仪、透射电镜对复相陶瓷试样组织结构进行了研究,探讨了SiC(W)-ZrO2协同作用对MoSi2陶瓷性能的影响.结果表明:纳米ZrO2颗粒的加入对材料的细化作用较SiC晶须明显,复相协同作用细化效果更好.SiC(W)-ZrO2协同作用的综合机制有利于提高复相陶瓷的抗弯强度和断裂韧性,ZrO2量的增加对提高复相陶瓷断裂韧性的作用更明显;ZrO2粒子钉扎位错,导致可动位错绕过,强化材料基体.弥散分布的SiC晶须阻碍位错运动,使位错缠结、交割,阻碍晶界迁移;粒子周围出现孪晶以及SiC晶须引起的层错,阻碍其晶粒长大.     

预制块制备对挤压铸造SiCW／ZM5复合材料性能的影响

制备了含不同粘结剂的ＳｉＣ晶须预制块,并采用挤压铸造法制备出含不同粘结剂的ＳｉＣｗ／ＺＭ５镁基复合材料,对其组织结构和力学性能进行了研究。结果表明,采用含酸性磷酸铝粘结剂制备的ＳｉＣｗ／ＺＭ５镁基复合材料的性能最佳,这可能和粘结剂与晶须以及基体合金的界面反应有关     

Load transfer mechanism and mechanical properties of SiCw/Al metal matrix composites

The load transfer mechanism and mechanical properties of SiC whisker reinforced aluminum matrix composites were investigated. A generalized shear-lag model was proposed to analyze the effects of the aspect ratio, misorientation angle and volume fraction of SiC whisker on the mechanical properties of SiCw/Al composites. A new concept on effective aspect ratio was suggested, combining the effects of aspect ratio and alignment of whiskers, to calculate the effective stress acting on the aluminum matrix in SiCw/Al composites. The magnitude and anisotropy of the yield strength of the SiCw/2124Al composite can be estimated more accurately by substituting the average aspect ratio with the effective aspect ratio based on the generalized shear-lag model. The SiCw/2124Al composite with the largest effective aspect ratio showed the lowest minimum creep rate which decreased with increasing effective aspect ratio of SiC whisker, but were found to be almost similar under the same effective stress acting on the Al matrix. It is suggested that the role of SiC whisker is to improve the mechanical properties by reducing the effective stress acting on the Al matrix in the SiCw/Al metal matrix composite. This article is based on a presentation made in the symposium “The 1^st KIM-JIM Joint Symposium: High Strength Ratio Aluminum Alloys”, held at Inha University, Inchon, Korea, October 22. 1999 under the auspices of The Korean Institute of Metals and Materials and The Japanese Institute of Metals.     

Influence of AlN addition on thermal and mechanical properties of cordierite-based glass/ceramic composites

Cordierite-based glass/ceramic composites doped with different volume fractions of AlN particles were successfully prepared by hot-pressing process. Thermal and mechanical properties of the composites were also investigated. Results show that the thermal conductivity, the flexural strength and fracture toughness of cordierite-based glass/AlN composites increase with increasing AlN content. The thermal conductivity of the composite doped with 50 vol.% AlN reaches 6.5 W/m K. By incorporation of 40 vol.% AlN, the flexural strength and fracture toughness of the composites increase 81 and 139% compared to the unreinforced cordierite-based glass matrix, respectively. XRD analysis indicated that no chemical reaction occurred between cordierite-based glass and AlN. The main strengthening and toughening mechanisms is load transfer and crack deflection.     

弥散质点和SiC颗粒复合强化Al基复合材料 Ⅱ．性能和断裂特征

对机械合金化制备的Ａｌ_４Ｃ_３、Ａｌ_２Ｏ_３弥散质点和ＳｉＣ颗粒复合强化Ａｌ基复合材料进行了拉伸试验和断口分析，并测定了弹性模量和热膨胀系数．研究表明，在ＳｉＣ_ｐ／Ａｌ复合材料中引入弥散的Ａｌ_４Ｃ_３和Ａｌ_２Ｏ_３质点可以明显提高复合材料的室温和高温强度，随加入Ｃ含量的增加或Ａｌ粉氧化时间的加长，复合材料的强度提高．在Ａｌ_４Ｃ_３／Ａｌ复合材料的基础上加入ＳｉＣ颗粒可以提高复合材料的弹性模量并进一步降低其热膨胀系数．复合材料断口为大韧窝加细小韧窝的混合断口，随复合材料基体强度的增加，拉伸断口上断裂的ＳｉＣ颗粒数量增多．     

DISPERSOID AND SiC PARTICULATE STRENGTHENED Al COMPOSITES Ⅱ. PROPERTIES AND FRACTURE BEHAVIOUR

对机械合金化制备的Ａｌ_４Ｃ_３、Ａｌ_２Ｏ_３弥散质点和ＳｉＣ颗粒复合强化Ａｌ基复合材料进行了拉伸试验和断口分析，并测定了弹性模量和热膨胀系数．研究表明，在ＳｉＣ_ｐ／Ａｌ复合材料中引入弥散的Ａｌ_４Ｃ_３和Ａｌ_２Ｏ_３质点可以明显提高复合材料的室温和高温强度，随加入Ｃ含量的增加或Ａｌ粉氧化时间的加长，复合材料的强度提高．在Ａｌ_４Ｃ_３／Ａｌ复合材料的基础上加入ＳｉＣ颗粒可以提高复合材料的弹性模量并进一步降低其热膨胀系数．复合材料断口为大韧窝加细小韧窝的混合断口，随复合材料基体强度的增加，拉伸断口上断裂的ＳｉＣ颗粒数量增多．     

Failure mechanisms of TiB2 particle and SiC whisker reinforced Al2O3 ceramic cutting tools when machining nickel-based alloys

In this paper, Al₂O₃/TiB₂/SiC_w ceramic cutting tools with different volume fraction of TiB₂ particles and SiC whiskers were produced by hot pressing. The fundamental properties of these composite tool materials were examined. Machining tests with these ceramic tools were carried out on the Inconel718 nickel-based alloys. The tool wear rates and the cutting temperature were measured. The failure mechanisms of these ceramic tools were investigated and correlated to their mechanical properties. Results showed that the fracture toughness and hardness of the composite tool materials continuously increased with increasing SiC whisker content up to 30 vol.%. The relative density decreased with increasing SiC whisker content, the trend of the flexural strength being the same as that of the relative density. Cutting speeds were found to have a profound effect on the wear behaviors of these ceramic tools. The ceramic tools exhibited relative small flank and crater wear at cutting speed lower than 100 m/min, within further increasing of the cutting speed the flank and crater wear increased greatly. Cutting speeds less than 100 m/min were proved to be the best range for this kind of ceramic tool when machining Inconel718 nickel-based alloys. The composite tool materials with higher SiC whisker content showed more wear resistance. Abrasive wear was found to be the predominant flank wear mechanism. While the mechanisms responsible for the crater wear were determined to be adhesion and diffusion due to the high cutting temperature.     

The effect of thermal cycling on the mechanical properties of sic whisker reinforced magnesium alloy-based composites

The effect of thermal cyclings on mechanical properties at room and some elevated temperatures of SiC whisker-reinforced magnesium-matrix composites produced by squeeze casting and hot extrusion are clarified. Subsequent thermal cycling produces internal stress at the matrix/SiC whisker interfaces causing fatigue. The mechanical properties of composites are more influenced by the low thermal cycling of 298 K— 77 K than the high thermal cycling 673 K—298 K. The high thermal cycling of 673 K—298 K has only a slight affect on such mechanical properties as tensile strength and proof stress at temperatures lower than 473 K. However, at 473 K and 573 K, the thermal cyclings there almost no influence on the mechanical properties of SiC whisker reinforced AE42 alloy-matrix composites.     

球磨工艺对Mg2B2O5w/6061Al基复合材料微观组织演变及力学性能的影响

采用粉末热挤压法制备了硼酸镁晶须增强铝基复合材料,对球磨工艺参数、粉末特性及热挤压态复合材料间的相互关系进行了研究。研究结果表明,在球磨过程中,增强体晶须的添加促进了基体合金的变形,加快了铝粉颗粒的焊合与断裂过程的发生。在球磨过程中,经过适当时间的高速球磨后,铝合金基体晶粒尺寸减小,增强体晶须在基体中的分布得到显著改善,从而使热挤压态复合材料力学性能得到大幅度的提高。     

Characterization of hot pressed SiC whisker reinforced TiB2 based composites

TiB₂–SiC ceramic composites, with different contents of SiC whiskers (SiC_w), as a ceramic sinter-additive, were prepared by the hot pressing process at 1850 °C for 2 h under a pressure of 20 MPa. For comparison, a monolithic TiB₂ ceramic was also fabricated under the identical temperature, pressure, atmosphere, and holding time by the hot pressing process. The effects of fabrication process and SiC whiskers on microstructural features, phase evolution and mechanical properties were investigated. Hardness measurements revealed an initial increase in hardness for TiB₂–SiC compared to TiB₂. Also the improvement of the fracture toughness was attributed to the toughening and strengthening effects of SiC whiskers such as crack deflection. The results showed that promoted densification of TiB₂–SiC ceramic composites is due to addition of SiC whiskers and reduction of oxide impurities by reacting with SiC whiskers and removing them from the surface layer of TiB₂ particles. The reaction between TiB₂ particles and SiC whiskers led to in-situ formation of TiC phase in the matrix as well. In general, it is concluded that the sinterability of TiB₂-based composites was remarkably improved by introducing SiC whiskers compared to the single phase TiB₂ ceramic.     

改善颗粒增强金属基复合材料塑性和韧性的途径与机制

评述了影响颗粒增强金属基复合材料塑性和韧性的各种因素,在此基础上深入研究了颗粒形状对ＳｉＣｐ／ＬＤ２复合材料塑性和断裂韧性的影响规律。采用有限单元法分析不同形状的ＳｉＣ颗粒增强的ＬＤ２复合材料的微区力学环境和整体力学行为,结果表明颗粒的尖锐化导致基体内应变集中和颗粒尖端断裂的可能性加剧,因而降低材料的塑性;而在外加载荷的作用下,由于复合材料基体整体均处于较高的加工硬化状态,因此颗粒形状对材料断裂韧     

SiCf/SiC复合材料表面Si/Yb2Si2O7双层涂层结合强度分析

目的 通过选择合适的复合材料拉伸方向和涂层制备工艺,在SiCf/SiC复材上获得高结合强度的Si/Yb2Si2O7双层涂层.方法 采用真空等离子喷涂技术在2.5D编织的SiCf/SiC复合材料表面制备Si涂层、Si/Yb2Si2O7双层涂层.采用金相、XRD、SEM和EDS对试样进行表征,采用拉伸试验测试涂层的结合强度...     

Investigation of the effect of Al2O3–Y2O3–CaO (AYC) additives on sinterability,microstructure and mechanical properties of SiC matrix composites: A review

Appropriate properties of SiC ceramic such as high hardness, low density, high melting point and high elastic modulus make this material as a favorite candidate for different industrial applications. Although some disadvantages including high sintering temperature, low sinterability, and low fracture toughness have restricted the use of this material, previous studies showed that using Al₂O₃-Y₂O₃ additives plays an effective role in the improvement of sinterability as well as the enhancement of the properties of these composites. Moreover, the addition of CaO results in the acceleration of the formation of molten phase and the improvement of sinterability. In addition, the use of these additives cause the formation of the intermetallic phases of Al₅Y₃O₁₂ (YAG) and CaY₂O₄ and by activating the mechanisms of crack deflection, crack bridging, phase transformation, strengthening the grain boundary and changing the fracture mode from intergranular to transgranular results in improved mechanical properties. This paper attempts to investigate the effect of using Al₂O₃–Y₂O₃–CaO (AYC) additives on sinterability, microstructure, and mechanical properties of SiC matrix composites including the composites reinforced with SiC fibers and SiC matrix nano-composites. Finally, the effect of the post-sintering annealing process under two conditions i.e., with and without applying pressure (pressureless sintering) on microstructure and mechanical properties has been studied.     

Microstructure and mechanical properties of Alborex+SiCp/AS52 hybrid metal matrix composites

Abstract

AS52 based hybrid composites reinforced with aluminium borate whiskers and SiC particulates were fabricated by a squeeze casting method. In a hybrid preform, the volume fraction of the aluminium borate whisker was 15% and that of the SiC particulate was 5%. Microstructures of the specimens were observed using OM and SEM. In the hybrid composites, the Alborex whiskers were uniformly distributed in the matrix and a few agglomerations or clusters of SiC particulates were observed. Hardness and three point bending tests were carried out to measure the mechanical properties of the specimens. The mechanical properties of the hybrid composites were higher than those of whisker reinforced composites and the hybrid composite with finer size particulates showed higher strength than the one with coarse particulates.     

模压压力对2D-Cf／SiC复合材料性能的影响

以聚碳硅烷、SiC微粉为原料，二维碳纤维织物为增强体，采用先驱体转化法制备了2D-Cf／SiC复合材料，考察了模压压力对2D-Cf／SiC复合材料常温力学性能的影响。结果表明，随着模压压力的增加，纤维体积分数明显提高，但材料的力学性能未能随之提高，主要原因在于随着压力增加，SiC微粉对碳纤维的损伤加剧。模压压力的增加导致纤维体积分数增加和纤维损伤的加剧，两方面的原因造成模压压力对材料的力学性能影响不大。有压成型比无压成型制得的材料的高温抗氧化性要好，主要原因是在0MPa压力下，材料基体更容易出现裂纹，从而使得高温条件下氧化气氛更容易对材料性能造成损害。