Numerical design of ammonia bubble absorber applying binary nanofluids and surfactants

The objectives of this paper are to analyze the combined heat and mass transfer characteristics for the ammonia bubble absorption process and to study the effects of binary nanofluids and surfactants on the absorber size. The ammonia bubble absorbers applying binary nanofluids and surfactants are designed and parametric analyses are performed. In order to express the effects of binary nanofluids and/or surfactants on the absorption performance, the effective absorption ratios for each case are applied in the numerical model. The values of the effective absorption ratio are decided from the previous experimental correlations. The kinds and the concentrations of nano-particles and surfactants are considered as the key parameters. The considered surfactants are 2-ethyl-1-hexanol (2E1H), n-octanol, and 2-octanol and nano-particles are copper (Cu), copper oxide (CuO), and alumina (Al₂O₃). The results show that the application of binary nanofluids and surfactants can reduce the size of absorber significantly. In order to reach 16.5% ammonia solution under the considered conditions, for example, the addition of surfactants (2E1H, 700 ppm) can reduce the size of absorber up to 63.0%, while the application of binary nanofluids (Cu, 1000 ppm) can reduce it up to 54.4%. In addition, it is found that the effect of mass transfer resistance is more dominant than that of heat transfer resistance. That is, the enhancement of mass transfer performance is more effective than that of heat transfer performance.     

The effect of heat transfer additive and surface roughness of micro-scale hatched tubes on absorption performance

The objectives of this paper are to investigate the effect of heat transfer additive and surface roughness of micro-scale hatched tubes on the absorption performance and to provide a guideline for the absorber design. Two different micro-scale hatched tubes and a bare tube are tested to quantify the effect of the surface roughness on the absorption performance. The roughness of the micro-scale hatched tubes ranges 0.39–6.97 μm. The working fluid is H₂O/LiBr solution with inlet concentration of 55, 58 and 61 wt.% of LiBr. Normal Octanol is used as the heat transfer additive with the concentration of 400 ppm. The absorber heat exchanger consists of 24 horizontal tubes in a column, liquid distributor at the liquid inlet and the liquid reservoir at the bottom of the absorber. The effect of heat transfer additive on the heat transfer rate is found to be more significant in the bare tube than that in the micro-scale hatched tubes. It is found that the absorption performance for the micro-hatched tube with heat transfer additive becomes up to 4.5 times higher than that for the bare tube without heat transfer additive. It is concluded that the heat transfer enhancement by the heat transfer additive is more significant than that by the micro-scale surface treatment.     

The effect of micro-scale surface treatment on heat and mass transfer performance for a falling film H2O/LiBr absorber

The objectives of this paper are to develop a new method of wettability measurement, to study the effect of micro-scale surface treatment on the wettability across horizontal tubes and to apply it for numerical analysis of heat and mass transfer in a H₂O/LiBr falling film absorber. Three types of tubes with roughness are tested in a test rig. Inlet solution temperature (30–50 °C), concentration (55–62 wt.% of LiBr) and mass flow rate (0.74–2.71 kg/min) are considered as key parameters. Reynolds number ranged from 30 to 120 by controlling the inlet mass flow rate. The wettability on the roughened tubes was higher than that for the smooth tubes. The wettability decreased linearly along the vertical location but was proportional to the solution temperature and mass flow rate. The experimental correlations of the wettability for the smooth and the roughened tubes were developed with error bands of ±20 and ±10%, respectively. These are used for the heat and mass transfer analysis of absorbers with micro-scale hatched tubes.     

Coupled heat and mass transfer during nonisothermal absorption by falling droplet with internal circulation

We considered mass and heat transfer during nonisothermal absorption of a gas by a falling droplet with internal circulation. Gas phase is assumed to be free of inert admixtures and mass transfer is liquid phase controlled. Mass flux is directed from a gaseous phase to a droplet, and the interfacial shear stress causes a fluid flow inside the droplet. Droplet deformation under the influence of interface shear stress is neglected. Absorbate accumulation and temperature increase in the bulk of liquid phase are taken into account. The problem is solved in the approximations of a thin concentration and temperature boundary layers in the liquid phase. The thermodynamic parameters of the system are assumed constant. The system of transient partial parabolic differential equations of convective diffusion and energy balance with time-dependent boundary conditions is solved by combining the similarity transformation method with Duhamel's theorem, and the solution is obtained in a form of Volterra integral equation of the second kind which is solved numerically. Theoretical results are compared with available experimental data for water vapor absorption by falling droplets of aqueous solution of LiBr.     

Theoretical analysis of the thermal performance of a plate heat exchanger at various chevron angles using lithium bromide solution with nanofluid

Nanofluids technology has been rapidly developing over the last two decades. In this paper, the performance of a lithium bromide (LiBr) solution with and without nanoparticles in plate heat exchanger (PHE) for various chevron angles and mass flow rates was investigated. As a result, the heat transfer rate and the overall heat transfer coefficient in 60°/60° PHE is over 100% higher than that of 30°/30° PHE, and the effectiveness of the PHE in 60°/60° PHE is about 70% higher than that of 30°/30° PHE. By using nanoparticle in the working fluid, the heat transfer performance can increase significantly. The heat transfer rate of 3 vol.% nanofluids increased about 3–8% compare to that of LiBr solution for all chevron PHEs. Besides, the 60°/60° PHE using 3 vol.% nanofluids produced the largest heat transfer rate and heat exchange effectiveness under given operating conditions.     

Model for absorption of water vapor into aqueous LiBr flowing over a horizontal smooth tube

A model for absorption of water vapor into aqueous LiBr flowing over a horizontal smooth tube is developed. The flow is divided into three regimes: (1) falling film in contact with the tube, (2) drop formation at the bottom of the tube, and (3) drop fall between the tubes. Governing equations are formulated for each flow regime, and the variations of solution temperature, LiBr mass fraction, mass absorption rate and heat transfer rate are discussed including the effect of inlet subcooling. It is shown that the temperature variation across the film exhibits a nonlinear profile near the top of the tube and this effect leads to the necessity of a two-dimensional formulation in the falling film regime for accurate prediction. As has been observed previously, the mass fraction boundary layer at the vapor/liquid interface is found to be very thin and this explains the low absorption flux. The model predicts that significant absorption takes place in the drop formation regime with a considerable variation of temperature and mass fraction.     

Experimental correlation of falling film absorption heat transfer on micro-scale hatched tubes

The objectives of this paper are to investigate the effect of surface roughness of micro-hatching tubes on the absorption performance and to develop an experimental correlation of Nusselt number as a function of the roughness. Two different micro-scale hatched tubes and a bare tube are tested to quantify the effect of the surface roughness on the absorption performance. The roughness of the micro-scale hatched tubes ranges 0.386–11.359 μm. The working fluid is H₂O/LiBr solution with inlet concentration of 55, 58 and 61 wt.% of LiBr. The absorber heat exchanger consists of 24 horizontal tubes in a column, liquid distributor at the liquid inlet and the liquid reservoir at the bottom of the absorber. It was found that absorption performance of micro-hatching tubes was improved up to two times compared with the bare tube. An experimental correlation of Nusselt number was developed as a function of the film Reynolds number and the roughness with an error band of ±25%.     

Thermodynamic properties for the quaternary system H2O + CH3OH + LiBr + ZnCl2

The thermodynamic properties (solubility, vapour pressure, density, viscosity, heat capacity and heat of mixing) of the H₂O + CH₃OH + LiBr + ZnCl₂ (9:1 H₂O:CH₃OH and 1:1 LiBr:ZnCl₂ by mass) system using H₂O + CH₃OH as the working media and LiBr + ZnCl₂ as the absorbents were measured. The solubility data were obtained in the temperature range from 270.35 to 389.55 K. The measurements of vapour pressure, density, viscosity and heat capacity were carried out at various temperatures and absorbent concentrations. The differential heat of dilution and differential heat of solution at 298.15 K were measured for solutionw with absorbent concentrations from 0 to 75.2 wt%. The integral heat of mixing data at 298.15 K were obtained from both sets of experimental data. The integral heats of mixing for this quaternary system showed exothermic behaviour. The vapour pressure data were correlated with an Antoine-type equation. An empirical formula for the heat capacity was obtained from experimental data. The experimental data for the basic thermodynamic properties of this quaternary system were compared with those of the basic H₂O + LiBr system.     

Thermal conductivity measurement of oil in Water (O/W) nanoemulsion and oil in H2O/LiBr (O/S) binary nanoemulsion for absorption application

Binary nanoemulsions, oil-droplet suspensions in binary solution (H₂O/LiBr), are developed to enhance the heat and mass transfer performance of absorption refrigeration systems. In this study, a novel four-step method is used to prepare the stable oil-in-binary solution (O/S) emulsion. To stabilize the nanoemulsions in a strong electrolyte, four different polymers are used as a steric stabilizer. The droplet size and the thermal conductivity of binary nanoemulsions are measured by the dynamic light scattering method and the transient hot-wire method, respectively. It is found that the measured thermal conductivities of the oil in water (O/W) nanoemulsion and binary nanoemulsion (O/S) with a stabilizer enhance up to 6.4 and 3.6%, respectively compared with the Maxwell’s model. It is also found that GA (Gum Arabic) gives the highest thermal conductivity enhancement. It is finally confirmed that the initial stable condition of the O/S nanoemulsion can be recovered by the re-dispersion in actual absorption systems.     

Interfacial mass transfer and mass transfer coefficient in aqua ammonia packed bed absorberTransfert de masse à l'interface et coéfficient de transfert de masse dans un absorbeur à matelas dispersant eau–ammoniac

A mathematical model was given to predict the mass transfer between flow of a mixture of ammonia vapor and water vapor and a flow of aqua ammonia solution at any interface within a packed bed absorber (PBA). The model used the molal mass and heat transfer coefficients in both the liquid and gas phases, the interface molal solution concentration, interface molal vapor mixture concentration, interface temperature, and the heat transfer coefficients in the liquid and gas phases in both sides of the interface. The heat transfer coefficient was corrected to account for the mass transfer. The model was also used to derive a convenient mass transfer coefficient which was based on the bulk mass concentration, not on the molal concentration, and not directly dependent on the concentration at the interface. To complete the model, mathematical correlations were derived for several thermodynamic and physical properties of aqua ammonia solution and vapor mixture. A computer program was developed to demonstrate the use of the model to predict the rate of absorption of ammonia vapor at an interface within the packed bed at various operating conditions.     

Experimental researches on characteristics of vapor–liquid equilibrium of NH3–H2O–LiBr system

An improved system of NH₃–H₂O–LiBr was proposed for overcoming the drawback of NH₃–H₂O absorption refrigeration system. The LiBr was added to NH₃–H₂O system anticipating a decrease in the content of water in the NH₃–H₂O–LiBr system. An equilibrium cell was used to measure thermal property of the ternary NH₃–H₂O–LiBr mixtures. The pressure–temperature data for their vapor–liquid equilibrium (VLE) data were measured at ten temperature points between 15–85 °C, and pressures up to 2 MPa. The LiBr concentration of the solution was chosen in the range of 5–60% of mass ratio of LiBr in pure water. The VLE for the NH₃–H₂O–LiBr ternary solution was measured statically. The experimental results show that the equilibrium pressures reduced by 30–50%, and the amount of component of water in the gas phase reduced greatly to 2.5% at T=70 °C. The experimental results predicted much better characteristics of the new ternary system than the NH₃–H₂O system for the applications.     

Experimental study on LiCl solution falling-film generation process outside a vertical tube

For the purpose of the development of a generator with higher performance utilizing LiCl/H₂O as the working pair in a two-stage absorption refrigeration system, an experimental investigation of LiCl solution falling film generation outside a vertical tube as the high-pressure stage solution cycle was conducted. An experimental setup was established to study heat and mass transfer process in a falling-film generator for LiCl/H₂O using low-temperature heat source. The experiments showed effect of the flow rates of hot water and falling film solution, temperature of heat source, concentration of the solution and generation pressure on the LiCl/H₂O generation process. To compare with conventional LiBr/H₂O solution, some comparative experiments of falling film generation were tested in order to discuss the mass transfer performance of two different working pairs in a high-pressure generator. The results showed that the two working pairs had similar mass transfer rate. The LiCl/H₂O solution had a similar mass transfer rate to that of the LiBr/H₂O solution, while the concentration of LiCl/H₂O solution was much lower with smaller circulation ratio of the solution, and it could make for possible improvement in the thermal performance of the absorption refrigeration system.     

Effect of vapor flow on the falling-film heat and mass transfer of the ammonia/water absorber

Falling-film heat and mass transfer in an absorber can be influenced by the motion of the surrounding refrigerant vapor. In this study, the effect of the vapor flow direction on the absorption heat and mass transfer has been investigated for a falling-film helical coil absorber which is frequently used in the ammonia/water absorption refrigerators. The heat and mass transfer performance was measured for both parallel and countercurrent flow. The experiments were carried out for three different solution concentrations (3, 14, and 30%). The vapor in equilibrium with the solution is supplied to the test section. It is found that the falling-film heat and mass transfer is deteriorated in the countercurrent flow if the specific volume of the vapor solution is large. For the countercurrent flow, the high velocity of the vapor due to large specific volume seems to cause the unfavorable distribution of falling-film and reduce the heat and mass transfer performance of the ammonia absorber. The effect of vapor flow direction decreased with increasing concentration of ammonia solution since the specific volume of the ammonia vapor which is in equilibrium with the solution becomes smaller and the vapor velocity becomes lower.     

Experimental correlation of combined heat and mass transfer for NH3–H2O falling film absorptionCorrélation expérimentale entre le transfert de chaleur et de masse pour de l'absorption au NH3–H2O à film tombant

In this article, experimental analysis was performed for ammonia–water falling film absorption process in a plate heat exchanger with enhanced surfaces such as offset strip fin. This article examined the effects of liquid and vapor flow characteristics, inlet subcooling of the liquid flow and inlet concentration difference on heat and mass transfer performance. The inlet liquid concentration was selected as 5%, 10% and 15% of ammonia by mass while the inlet vapor concentration was varied from 64.7% to 79.7%. It was found that before absorption started, there was a rectification process at the top of the test section by the inlet subcooling effect. Water desorption phenomenon was found near the bottom of the test section. It was found that the lower inlet liquid temperature and the higher inlet vapor temperature, the higher Nusselt and Sherwood numbers are obtained. Nusselt and Sherwood number correlations were developed as functions of falling film Reynolds Re₁, vapor Reynolds number Re_v, inlet subcooling and inlet concentration difference with ±15% and ±20% error bands, respectively.     

Vapor absorption by LiBr aqueous solution in vertical smooth tubes

Heat and mass transfer in a falling film vertical in-tube absorber was studied experimentally with LiBr aqueous solution. The presented results include the effect of solution flow rate, solution subcooling and cooling water temperature on the absorption in a smooth copper tube 16.05 mm I.D. and 400 mm long. The experimental data in the previous report for a 1200-mm-long tube was also re-examined and compared. It was demonstrated by the observation of the flow in the tube that the break down of the liquid film into rivulets leads to deterioration of heat and mass transfer at lower film Reynolds number or in longer tubes. An attempt to evaluate physically acceptable heat and mass transfer coefficients that are defined with estimated temperature and concentration at the vapor–liquid interface was also presented.     

Absorption performance enhancement by nano-particles and chemical surfactants in binary nanofluids

The objectives of this paper are to visualize the bubble behavior during the NH₃/H₂O absorption process with chemical surfactant and nano-particles and to study the effect of nano-particles and surfactants on the absorption characteristics. Binary nanofluid which means binary mixture with nano-sized particles is tested to apply nanofluid to the absorption system. Cu, CuO and Al₂O₃ nano-particles are added into NH₃/H₂O solution to make the binary nanofluids, and 2-ethyl-1-hexanol, n-octanol and 2-octanol are used as the surfactants. The concentration of ammonia in the basefluid, that of nano-particles in the nanofluid, and that of surfactants in the nanofluid are considered as the key parameters. The results show that the addition of surfactants and nano-particles improves the absorption performance up to 5.32 times. It can be concluded that the addition of both surfactants and nano-particles enhances significantly the absorption performance during the ammonia bubble absorption process.     

The effect of nano-particles on the bubble absorption performance in a binary nanofluid

The objectives of this paper are to examine the effect of nano particles on the bubble type absorption by experiment and to find the optimal conditions to design highly effective compact absorber for NH₃/H₂O absorption system. The initial concentrations of NH₃/H₂O solution and the kinds and the concentrations of nano particles are considered as key parameters. The results show that the addition of nano particles enhances the absorption performance up to 3.21 times. Moreover, the absorption rate increases with increasing concentration of nano particles and the nano particles are more effective for lower absorption potential solution. The potential enhancement mechanism for binary nanofluid is suggested. The experimental correlations of the effective absorption ratio for each nano particles, Cu, CuO, and Al₂O₃, are suggested within ±10% error-band.     

Review of advanced absorption cycles: performance improvement and temperature lift enhancement

The objective of this study is to propose and evaluate advanced absorption cycles for the coefficient of performance (COP) improvement and temperature lift enhancement applications. The characteristics of each cycle are assessed from the viewpoints of the ideal cycle COP and its applications. The advanced cycles for the COP improvement are categorized according to their heat recovery method: condensation heat recovery, absorption heat recovery, and condensation/absorption heat recovery. In H₂O–LiBr systems, the number of effects and the number of stages can be improved by adding a third or a fourth component to the solution pairs. The performance of NH₃–H₂O systems can be improved by internal heat recovery due to their thermal characteristics such as temperature gliding. NH₃–H₂O cycles can be combined with adsorption cycles and power generation cycles for waste heat utilization, performance improvement, panel heating and low temperature applications. The H₂O–LiBr cycle is better from the high COP viewpoints for the evaporation temperature over 0°C while the NH₃–H₂O cycle is better from the viewpoint of low temperature applications. This study suggests that the cycle performance would be significantly improved by combining the advanced H₂O–LiBr and NH₃–H₂O cycles.     

Development of a slug flow absorber working with ammonia–water mixture: part II—data reduction model for local heat and mass transfer characterization

This study deals with a data reduction model for clarifying experimental results of a counter-current slug flow absorber, working with ammonia–water mixture, for significantly low solution flow rate conditions. The data reduction model to obtain the local heat and mass transfer coefficient on the liquid side is proposed by using the drift flux model to analyze the flow characteristics. The control volume method and heat and mass transfer analogy are employed to solve the combined heat and mass transfer problem. As a result, it is found that the local heat and mass transfer coefficient on the liquid side of the absorber is greatly influenced by the flow pattern. The heat and mass transfer coefficient at the frost flow region is higher than that at the slug flow region due to flow disturbance and random fluctuation. The solution flow rate and gas flow rate have influence on the local heat and mass transfer coefficient at the frost flow region. However, it is insignificant at the slug flow region.     

CO2 flow condensation heat transfer and pressure drop in multi-port microchannels at low temperatures

CO₂ flow condensation heat transfer coefficients and pressure drop are investigated for 0.89 mm microchannels at horizontal flow conditions. They were measured at saturation temperatures of −15 and −25 °C, mass fluxes from 200 to 800 kg m⁻² s⁻¹, and wall subcooling temperatures from 2 to 4 °C. Flow patterns for experimental conditions were predicted by two flow pattern maps, and it could be predicted that annular flow patterns could exist in most of flow conditions except low mass flux and low vapor quality conditions. Measured heat transfer coefficients increased with the increase of mass fluxes and vapor qualities, whereas they were almost independent of wall subcooling temperature changes. Several correlations could predict heat transfer coefficients within acceptable error range, and from this comparison, it could be inferred that the flow condensation mechanism in 0.89 mm channels should be similar to that in large tubes. CO₂ two-phase pressure drop, measured in adiabatic conditions, increased with the increase of mass flux and vapor quality, and it decreased with the increase of saturation temperature. By comparing measured pressure drop with calculated values, it was shown that several correlations could predict the measured values relatively well.