The rapid formation and dispersion of flammable zones within cylindrical vertical enclosures following the release of a fixed mass of hydrogen and other gaseous fuels into air

The release of a certain mass of fuel gas into the ambient atmosphere with negligible pressure difference whether deliberately or inadvertently results in the transient formation of flammable mixture zones for a period of time that represent a potential fire and explosion hazard. A numerical model based on the simultaneous solution of the equations of conservation of mass, momentum and energy has been developed to describe the development of such flammable zones when a finite quantity of fuel is released into the overlaying air within cylindrical vertical enclosures open to the outside atmosphere. Hydrogen disperses into the air extremely quickly with a strong temporal dependency on both horizontal and vertical directions. Comparison of the typical behavior of hydrogen dispersion with that of the lighter than air methane, the nearly buoyancy neutral ethylene and the much heavier than air propane is made. Some guidelines for reducing the fire and explosion hazards in such situations are presented.     

Non-homogeneous hydrogen deflagrations in small scale enclosure. Experimental results

University of Pisa performed hydrogen releases and deflagrations in a 1.14 m³ test facility, which shape and dimensions resemble a gas cabinet. Tests were performed for the HySEA project, founded by the Fuel Cells and Hydrogen 2 Joint Undertaking with the aim to conduct pre-normative research on vented deflagrations in enclosures and containers used for hydrogen energy applications. The test facility, named Small Scale Enclosure (SSE), has a vent area of 0,42 m² which can host different types of vent; plastic sheet and commercial vent were tested. Realistic levels of congestion are obtained placing a number of gas bottles inside the enclosure. Releases are performed from a buffer tank of a known volume filled with hydrogen at a pressure ranging between 15 and 60 bar. Two nozzles of different diameter and three different release directions were tested, being the nozzle placed at a height where in a real application a leak has the highest probability to occur. Three different ignition locations were investigated as well. This paper is aimed to summarize the main features of the experimental campaign as well as to present its results.     

Detailed simulations of the transient hydrogen mixing,leakage and flammability in air in simple geometries

During an accidental release, hydrogen disperses very quickly in air due to a relatively high density difference. A comprehensive understanding of the transient behavior of hydrogen mixing and the associated flammability limits in air is essential to support the fire safety and prevention guidelines. In this study, a buoyancy diffusion computational model is developed to simultaneously solve for the complete set of equations governing the unsteady flow of hydrogen. A simple vertical cylinder is considered to investigate the transient behavior of hydrogen mixing, especially at relatively short times, for different release scenarios: (i) the sudden release of hydrogen at the cylinder bottom into air with open, partially open, and closed tops, and (ii) small hydrogen jet leaks at the bottom into a closed geometry. Other cases involving the hydrogen releases/leaks at the cylinder top are also explored to quantify the relative roles of buoyancy and diffusion in the mixing process. The numerical simulations display the spatial and temporal distributions of hydrogen for all the configurations studied. The complex flow patterns demonstrate the fast formation of flammable zones with implications in the safe and efficient use of hydrogen in various applications.     

Study of a post-fire verification method for the activation status of hydrogen cylinder pressure relief devices

To safely remove from its fire accident site a hydrogen fuel cell vehicle equipped with a carbon fiber reinforced plastic composite cylinder for compressed hydrogen (CFRP cylinder) and to safely keep the burnt vehicle in a storage facility, it is necessary to verify whether the thermally-activated pressure relief device (TPRD) of the CFRP cylinder has already been activated, releasing the hydrogen gas from the cylinder. To develop a simple post-fire verification method on TPRD activation, the present study was conducted on the using hydrogen densitometer and Type III and Type IV CFRP cylinders having different linings. As the results, TPRD activation status can be determined by measuring hydrogen concentrations with a catalytic combustion hydrogen densitometer at the cylinder's TPRD gas release port.     

Dispersion and catalytic ignition of hydrogen leaks within enclosed spaces

An experimental investigation is conducted into the nature of catalytic ignition of leaked hydrogen gas within an enclosure, and the nature of hydrogen dispersion under varied venting conditions. Using a 1/16th linear scale two-car garage as a model, and a platinum foil as a catalytic surface, it is found that for all conditions tested, catalytic ignition is observed after the leaked hydrogen comes in contact with the catalytic surface, which is initially at or near room temperature. After ignition, these surface reactions lead to steady-state surface temperatures in the range of 600–800 K, dependent on inlet conditions in terms of mixture composition and flow rate. In addition, varying the venting opportunities from the garage walls suggests that not only total area, but also the number and position of vents may impact the nature of hydrogen accumulation within an enclosed structure.     

Experimental studies on wind influence on hydrogen release from low pressure pipelines

At the DIMNP (Department of Mechanical, Nuclear and Production Engineering) laboratories of University of Pisa (Italy) a pilot plant called HPBT (Hydrogen Pipe Break Test) was built in cooperation with the Italian Fire Brigade Department. The apparatus consists of a 12 m³ tank connected with a 50 m long pipe. At the far end of the pipeline a couple of flanges have been used to house a disc with a hole of the defined diameter. The plant has been used to carry out experiments of hydrogen release. During the experimental activity, data have been acquired about the gas concentration and the length of release as function of internal pressure and release hole diameter. The information obtained by the experimental activity will be the basis for the development of a new specific normative framework arranged to prevent fire and applied to hydrogen. This study is focused on hydrogen concentration as function of wind velocity and direction. Experimental data have been compared with theoretical and computer models (such as CFD simulations).     

Flame interactions and smoke containment by downward displacement ventilation

Smoke contamination even from small fires of sensitive components in telephone central offices (TCO) and semiconductor clean rooms has caused disastrous disruptions in services and excessive financial repercussions. Containment and removal of smoke can be achieved by downward displacement ventilation, also used for other purposes in large floor area semiconductor facilities. Downward ventilation reverses the upward flow from the fire and removes the smoke and other combustion products through the floor. Small-scale model experiments under turbulent fire plume conditions investigate the physical parameters such as downward velocity, ceiling clearance, and size of the fire that control the extent of the smoke containment around the fire. The extent of smoke contamination is mapped by measuring the temperatures in several locations on the vertical axis and in the space around the fire. The downward velocities cause oscillation of the fire plume and the flames around the vertical axis. By combining the experimental data with similarity analysis, a characteristic length scale and nondimensional relations are deduced for the extent of the smoke containment and the onset of plume oscillations. These relations allow design of displacement ventilation effective to contain the smoke but not cause fire spread owing to the leaning of the flames. Previously reported discrepancies in the apparent width and behavior of the plume are resolved by examining the experimental data and assessing the suitability of steady state computational fluid dynamics to model the present flow.     

The possibility of an accidental scenario for marine transportation of fuel cell vehicle: Hydrogen releases from TPRD by radiant heat from lower deck

In case fires break out on the lower deck of a car carrier ship or a ferry, the fuel cell vehicles (FCVs) parked on the upper deck may be exposed to radiant heat from the lower deck. Assuming that the thermal pressure relief device (TPRD) of an FCV hydrogen cylinder is activated by the radiant heat without the presence of flames, hydrogen gas will be released by TPRD to form combustible air-fuel mixtures in the vicinity. To investigate the possibility of this accident scenario, the present study investigated the relationship between radiant heat and TPRD activation time and evaluated the possibility of radiant heat causing hydrogen releases by TPRD activation under the condition of deck temperature reaching the spontaneous ignition level of the tires and other automotive parts. It was found: a) the tires as well as polypropylene and other plastic parts underwent spontaneous ignition before TPRD was activated by radiant heat and b) when finally TPRD was activated, the hydrogen releases were rapidly burned by the flames of the tires and plastic parts on fire. Consequently it was concluded that the explosion of air-fuel mixtures assumed in the accident scenario does not occur in the real world.     

Fire prevention technical rule for gaseous hydrogen transport in pipelines

This paper presents the current results of the theoretical and experimental activity carried out by the Italian Working Group on the hydrogen fire prevention safety issues in the field of the hydrogen transport in pipelines [Grasso N, Ciannelli N, Pilo F, Carcassi M, Ceccherini F. Fire prevention technical rule for gaseous hydrogen refuelling stations. Proceedings of the International Conference on Hydrogen Safety, 8–10 September 2005, Pisa, Paper 420064]. From the theoretical point of view a draft document has been produced beginning from the Italian regulations in force on the natural gas pipelines; these have been reviewed, corrected and integrated with instructions suitable to use with hydrogen gas. From the experimental point of view a suitable apparatus has been designed and installed at the University of Pisa; this apparatus will allow simulations of hydrogen releases from a pipeline with or without ignition of the hydrogen–air mixture. The experimental data will help the completion of the above-mentioned draft document with the instructions about the safety distances. However, in the opinion of the Group, the work on the text contents is concluded and the document is ready to be discussed with the Italian stakeholders involved in the hydrogen applications.     

CFD modeling and consequence analysis of an accidental hydrogen release in a large scale facility

In this study, the consequences of an accidental release of hydrogen within large scale, (>15,000 m³), facilities were modeled. To model the hydrogen release, an LES Navier–Stokes CFD solver, called fireFoam, was used to calculate the dispersion and mixing of hydrogen within a large scale facility. The performance of the CFD modeling technique was evaluated through a validation study using experimental results from a 1/6 scale hydrogen release from the literature and a grid sensitivity study. Using the model, a parametric study was performed varying release rates and enclosure sizes and examining the concentrations that develop. The hydrogen dispersion results were then used to calculate the corresponding pressure loads from hydrogen-air deflagrations in the facility.     

The spread of fire from adjoining vehicles to a hydrogen fuel cell vehicle

Two vehicle fire tests were conducted to investigate the spread of fire to adjacent vehicles from a hydrogen fuel cell vehicle (HFCV) equipped with a thermal pressure relief device (TPRD) : – 1) an HFCV fire test involving an adjacent gasoline vehicle, 2) a fire test involving three adjoining HFCV assuming their transportation in a carrier ship. The test results indicated that the adjacent vehicles were ignited by flames from the interior and exterior materials of the fire origin HFCV, but not by the hydrogen flames generated through the activation of TPRD.     

Experimental study on elevated fires in a ceiling vented compartment

The impacts of elevation on fires in a ceiling vented compartment were investigated experimentally. The flame behavior of elevated fires was recorded. Various parameters including the fuel mass loss rate, the light extinction coefficient, the oxygen concentration and the gas temperature were measured. Results indicated that the variations of the flame behavior were consistent with that of the fuel mass loss rate. The fire location significantly impacted the light extinction coefficient, the oxygen concentration and the gas temperature, which all showed distinct stratification phenomena. For a higher elevated fire, the average fuel loss rate and the overall light extinction coefficient were smaller, the oxygen concentration was higher and the gas temperature was lower. In addition, the smoke descending was slower. From the perspective of those parameters the fire was less hazardous if the fire was elevated higher, which was totally different from the elevated fires in closed compartments.     

Determination of key parameters responsible for polymeric liner collapse in hyperbaric type IV hydrogen storage vessels

Depressurization tests at a laboratory scale, coupled with numerical modelling, are used to determine the key parameters responsible for the polymeric liner collapse in hyperbaric type IV hydrogen storage vessels. X-ray tomography allows to determine the damages suffered by the sample during the depressurization step. Results show that the differential pressure induced during the depressurization step between the liner/composite interface and the free surface of the liner is the main factor responsible for the collapse of the liner. For a given temperature, this pressure gradient can be modified by changing the maximum H₂ pressure, the emptying rate or by adding a residual pressure plateau. Temperature is also of prime importance by influencing the yield point of the liner, the interface resistance and the amount of gas dissolved into the vessel. Thus, increasing temperature also increases the risk of liner collapse for the same gas exposure conditions.     

Hydrogen jet fires in a passively ventilated enclosure

This paper describes a combined experimental, analytical and numerical modelling investigation into hydrogen jet fires in a passively ventilated enclosure. The work was funded by the EU Fuel Cells and Hydrogen Joint Undertaking project Hyindoor. It is relevant to situations where hydrogen is stored or used indoors. In such situations passive ventilation can be used to prevent the formation of a flammable atmosphere following a release of hydrogen. Whilst a significant amount of work has been reported on unignited releases in passively ventilated enclosures and on outdoor hydrogen jet fires, very little is known about the behaviour of hydrogen jet fires in passively ventilated enclosures. This paper considers the effects of passive ventilation openings on the behaviour of hydrogen jet fires. A series of hydrogen jet fire experiments were carried out using a 31 m³ passively ventilated enclosure. The test programme included subsonic and chocked flow releases with varying hydrogen release rates and vent configurations. In most of the tests the hydrogen release rate was sufficiently low and the vent area sufficiently large to lead to a well-ventilated jet fire. In a limited number of tests the vent area was reduced, allowing under-ventilated conditions to be investigated. The behaviour of a jet fire in a passively ventilated enclosure depends on the hydrogen release rate, the vent area and the thermal properties of the enclosure. An analytical model was used to quantify the relative importance of the hydrogen release rate and vent area, whilst the influence of the thermal properties of the enclosure were investigated using a CFD model. Overall, the results indicate that passive ventilation openings that are sufficiently large to safely ventilate an unignited release will tend to be large enough to prevent a jet fire from becoming under-ventilated.