Effect of bonding process on the properties of isotropic epoxy resin-bonded Nd-Fe-B magnets

Bonded NdFeB magnets were prepared by compression molding. The effect of preparation technology on their magnetic and mechanical properties was studied through the analysis of density, Br Hcj, (BH)max, bending strength, and compressive strength of the bonded magnets. The results showed that the magnetic properties decreased with increasing binder content, whereas the mechanical properties increased. Brand (BH)max increased with rising pressure, whereas Hcj decreased. For a fixed mass fraction of the binder, the optimal pressure was 620 MPa and the best thermosetting temperature was 160℃. These conditions made the bonded magnets have the optimal mechanical properties. Scanning electron microscopy (SEM) analyses of the fracture surfaces indicated that the epoxy resin bonded magnets exhibited brittle behavior.     

温压工艺对粘结NdFeB磁体性能的影响

采用温压工艺制备粘结NdFeB磁体,发现温压技术可以有效地提高牯结磁体的密度.改善磁体磁性能.研究表明:温压效果与温压温度的选择和温压压力密切相关.通过对温压机理的分析,发现最佳温压温度由粘结剂的软化点、粘度和固化点三个因素共同决定.而随着温压压力的升高,粘结NdFeB磁体的密度和磁件能增大,并在压力为650 MPa时得到了粘结磁体磁能积的最大值(50.43 kJ/m~3).     

Magnetic properties and thermal stability of anisotropic bonded Nd-Fe-B magnets by warm compaction

Anisotropic bonded magnets were prepared by warm compaction using anisotropic Nd-Fe-B powder. The forming process, magnetic properties, and temperature stability were studied. The results indicate that the optimal temperature of the process, which was decided by the viscosity of the binders, was 110℃. With increasing pressure, the density of the magnets increased. When the pressure was above 700 MPa, the powder particles were destroyed and the magnetic properties decreased. The magnetic properties of the anisotropic bonded magnets were as follows: remanence Br = 0.98 T, intrinsic coercivity iHc=1361 kA/m, and maximum energy product BHmax = 166 kJ/m3. The magnets had excellent thermal stability because of the high coercivity and good squareness of demagnetization curves. The flux density of the magnets was 35% higher than that of isotropic bonded Nd-Fe-B magnets at 120℃ for 1000 h. The flux density of the bonded magnets showed little change with regard to temperature.     

放电等离子烧结-热变形技术制备NdFeB永磁材料

采用放电等离子烧结(SPS)方法烧结HDDRNdFeB粉末,研究烧结温度对制备NdFeB永磁材料密度和磁性能的影响。随着烧结温度在650～900℃范围内升高,剩磁、内禀矫顽力及最大磁能积均呈现先升后降的趋势。800℃烧结所获得磁体的磁性能最佳:Br=0.78T,Hcj=577kA/m,(BH)max=78kJ/m3,其致密度达到了99%。微观组织、XRD图谱及磁性能均表明800℃烧结的磁体出现了一定程度的各向异性。900℃烧结时,晶粒长大明显。进而选择具有最佳磁性能的磁体在800℃进行热变形(HD)处理,制备出各向异性磁体。热变形制备的磁体中,大部分晶粒为扁平片状且c轴取向与热压方向一致;少量异常长大晶粒会使细小Nd2Fe14B晶粒的c轴偏离压力方向。各向异性磁体沿c轴的磁性能为:Br=1.09T,Hcj=384kA/m,(BH)max=114kJ/m3。     

放电等离子烧结-热变形各向异性Nd-Fe-B磁体的微观组织及磁性能

采用放电等离子烧结及后续热变形技术制备各向异性Nd-Fe-B磁体,研究烧结温度对放电等离子烧结Nd-Fe-B磁体微观组织和磁性能的影响。随着烧结温度在650~900°C范围内的升高,烧结态Nd-Fe-B磁体的剩磁、内禀矫顽力及最大磁能积呈现先升后降的趋势。在800°C下烧结所获得磁体的磁性能最佳。随后,对800°C烧结后具有最佳磁性能的磁体采用放电等离子烧结技术进行后续热变形处理。与初始吸氢-歧化-脱氢-再复合粉末和烧结态磁体相比,热变形磁体拥有更显著的各向异性和更好的磁性能。当热变形温度为800°C且压缩比为50%时,热变形磁体中的Nd2Fe14B晶粒呈扁平片状且不发生异常长大;磁体沿热压方向具有最佳的磁性能：Br、Hcj和（BH）max分别为1.16 T、449 k A/m和178 k J/m3。     

退火过程对高温Sm2Co17磁体性能的影响

对Sin（Coba1Fe0.07Cu0.088Zr0.025）7.6烧结磁体在不同回火工艺下的室温和高温磁学性质进行了系统研究。结果表明,不同的等温时效温度回火时,磁体剩余磁通密度B,和最大磁能积（BH）max的在室温下不会有太大变化。然而,在高温（500℃）情形下却有很大区别,在790~810℃,获得了最高的（BH）max和矫顽力。所以回火工艺对磁体的高温性能产生了很大影响。通过调整回火工艺,所得到的样品在500℃性能可以达到Hct=5．48kOe,（BH）max12．45MGOe。     

纳米晶复合NdFeCoZrB永磁合金磁性能和温度稳定性的研究

利用熔体快淬法和品化退火工艺制备了纳米晶复合NdFeB永磁粘结磁体,研究了添加Zr元素对磁体室温磁性能和温度稳定性的影响.结果表明,添加3at%Zr元素能明显提高磁体的矫顽力和最大磁能积.在淬速18 m/s、退火温度640℃下制备的Nd_(9.5_Fe_(76)Co_5Zr_3B_(6.5)粘结磁体具有良好的综合磁性能,即剩磁为0.71 T,矫顽力为652 kA/m,最大磁能积为80kJ/m~3.适量添加Zr元素可以有效改善磁体的温度稳定性,在20～150℃,纳米晶复合Nd_95Fe_(76)Co_5Zr_3B_(6.5)粘结磁体的剩磁温度系数为-0.13%/℃,内禀矫顽力温度系数为-0.35%/℃;在150℃时效100h后,不可逆磁通损失为-4.50%.     

Structure and magnetic properties ofhigh-performanced Sm2（Co, Fe, Cu, Zr）17 alloys

ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｈｉｇｈＣｕｒｉｅｔｅｍｐｅｒａｔｕｒｅａｎｄｌｏｗｅｓｔｔｅｍｐｅｒａ ｔｕｒｅｃｏｅｆｆｉｃｉｅｎｔｏｆｔｈｅＳｍ2 Ｃｏ17ｐｅｒｍａｎｅｎｔｍａｇｎｅｔｓｍａｋｅｔｈｅｍｂｅｉｄｅａｌｃａｎｄｉｄａｔｅｓｆｏｒｈｉｇｈｔ     

电场烧结法制备纳米复相Nd2Fe14B／α-Fe永磁块体材料

采用电场烧结法制备出纳米复相Nd10．5Dy0．5Fe76．9Nb1Co586．1永磁块体，研究了电场烧结温度对其磁性能和抗压强度的影响，采用XRD，SEM等方法分别对其相结构、显微组织进行了分析。结果表明：非晶合金压制成型后，经823K，300S电场烧结制得的纳米晶永磁块体具有最佳磁性能：Br=0．6498T，Hcj=714kA／m，（BH）max=63kJ／m^3。随着烧结温度的升高，块体的抗压强度增加。     

Dy元素对纳米复合(Nd,Pr)_(10.5-x)Dy_xFe_(83.5)B_6合金磁性能与显微结构的影响（英文）EI北大核心CSCD

采用快淬法制备了镨基(Nd,Pr)10.5-x Dyx Fe83.5B6(x=0.0,0.5,1.0,1.5,2.0,2.5)系列粘结磁体,研究了Dy元素添加对快淬合金显微组织结构、磁性能及快淬薄带热稳定性的影响。与Nd2Fe14B相比,硬磁相Dy2Fe14B具有较高的磁晶各向异性场HA和较低的饱和磁极化强度Js,因此,Dy元素添加能显著提高合金的内禀矫顽力Hcj,但会降低合金的剩磁Br。Dy元素替代Nd/Pr元素,增强了快淬薄带的热稳定性,提高了晶化退火温度。较高的晶化退火温度,使快淬薄带中已经形成的微晶更容易长大,形成一些粗大晶粒,降低了粘结磁体的磁性能。1.0%是较佳的Dy元素添加量,(Nd,Pr)9.5Dy1Fe83.5B6合金快淬粘结磁体的最大磁能积(BH)max为71.6 k J/m3,剩磁Br为0.638 T,内禀矫顽力Hcj为611 k A/m。     

Fe含量对高温稀土永磁Sm(CobalFexCu0.1Zr0.03)7.5 (x=0.09～0.21)磁性能的影响

采用粉末冶金工艺制备了高温稀土永磁Sm(CobalFexCu0.1Zr0.03)7.5 (x=0.09～0.21),研究了Fe含量对磁体磁性能的影响.结果表明:随着Fe含量的增加,剩磁Br和最大磁能积(BH)max逐渐增加,在x=0.21时获得最大值,分别为0.96 T和176.7 kJ/m3;内禀矫顽力Hci先增加后降低,在x=0.15时获得峰值2276.6 kA/m.最佳工艺制备(x=0.15)的磁体温度稳定性良好,B-H退磁曲线在温度为500 ℃时保持为直线;内禀矫顽力温度系数β为-0.16%/℃,最高使用温度(OT)max达到533 ℃.     

热处理对烧结NdFeB磁体微观结构和磁性能的影响

系统研究了热处理对烧结NdFeB磁体微观结构和磁性能的影响.结果表明：二级回火热处理后,磁体微观组织结构得到明显改善,晶界变得更加规整、平滑,富Nd相均匀弥散地分布于晶粒周围,晶界相成分趋于稳定、均匀;磁体的内禀矫顽力显著提高,剩磁及最大磁能积也有一定程度的提高,极大地改善了磁体的热稳定性.     

钛掺杂无氢类金刚石薄膜疏水性能研究

利用X射线衍射分析（XRD）和BH测试仪分别研究了元素Tb、Zr的添加对HD法制备NdFeB永磁体的微结构及磁性能的影响规律。微结构研究表明,元素Tb、Zr添加前后的磁体都主要由四方相Nd2Fe14B（P42/mnm）和微量的富Nd相构成;但Tb和Zr的添加明显改变了永磁体的取向特性和磁性能;采用HORTA法计算表明,Tb和Zr的添加虽然都使永磁体的（004）、（006）、（008）极密度因子减小,但是室温下磁性能测试表明,Zr的添加降低了磁体的矫顽力,而Tb添加后永磁体的矫顽力有了明显的提升,从2038 kA/m提升到2302 kA/m;Kronmüller-Plot关系曲线表明,3种合金的矫顽力机理均为磁畴成核反转机制。     

Influence of zirconium addition on the microstructure and magnetic properties of nanocomposite Nd10.1Fe78.2-xCo5ZrxB6.7 permanent magnets

Nanocomposite Nd10.1Fe78.2-xCo5ZrxB6.7 （x= 0, 1.5, 2.5, 2.7, 3, 4） permanent magnets were prepared by melt-spun and annealing. The microstructure and magnetic properties of the permanent magnets were investigated. The resuits reveal that the addition of Zr element significantly reduces the grain size and improves the thermal stability of the amorphous phase. A fme nanocomposite microstructure with an average grain size of about 35 nm can be developed at a wheel speed of 16 m·s^-1 with the content of Zr up to 2.7 at.%. After optimal annealing （710℃ x 4 min）, the magnetic properties of the Ndl0.1Fe75.5Co5Zr2.TB6.7 bonded magnets were achieved as follows： Br= 0.72 T, jHc = 769 kA·m^-1, and （BH）max = 85.0 kJ·m^-3.     

热变形温度对纳米晶Nd-Fe-B磁体性能的影响

为了研究纳米晶Nd-Fe-B磁体的热变形机理,在不同温度下对快淬粉进行热压热变形处理.通过分析不同温度下热变形过程中应力和磁体应变的变化,以及磁性能和SEM测试,研究了温度对热变形磁体性能和微观结构的影响,分析了热变形过程的热变形机理.结果表明,纳米晶磁体存在最佳的热压温度和热变形温度.当热压温度为550℃,热变形温度...     

SPS制备各向异性微米晶SmCo_5烧结磁体的研究

采用放电等离子烧结技术制备了各向异性微米晶SmCo_5磁体,研究了磁体的烧结工艺及添加Fe纳米粉对磁体结构和磁性能的影响。研究发现,SmCo_5烧结磁体的最佳烧结温度为830℃,此时磁体的室温磁性能最佳:B_r=8.19 kGs,H_(cj)=10.6 kOe,(BH)_(max)=13 MGOe;而添加Fe纳米粉的烧结磁体,饱和磁化强度升高,但剩磁和矫顽力降低。XRD结果表明,未添加Fe纳米粉的烧结磁体具有单相CaCu_5结构,而添加Fe纳米粉的烧结磁体出现了2∶17相和Fe-Co软磁相。SEM及能谱分析发现,添加的Fe纳米粉扩散进入了1∶5相,形成Sm(Fe,Co)_5和Sm_2(Fe,Co)_(17))。     

高矫顽力的低钕Nd9(FeCoZrAl)85B6纳米晶合金的制备

采用单辊快淬工艺制备了一种低钕含量Ｎｄ９（ＦｅＣｏＺｒＡｌ）８５Ｂ６纳米晶合金,研究了快淬工艺与热处理工艺对该合金纳米晶的形成及磁性的影响。结果表明快淬速度和热处理温度都明显地影响低钕含量Ｎｄ９（ＦｅＣｏＺｒＡｌ）８５Ｂ６纳米晶的形成及其磁性（内禀矫顽力ｊＨｃ,矫顽力ｂＨｃ,剩磁Ｂｒ和最大磁能积（ＢＨ）ｍ）。快淬速度２３ｍ／ｓ制备的非晶态合金,在６８５℃处理３０ｍｉｎ,可获得最佳的磁性,其粘结磁体的密度为６．０１ｇ／ｃｍ３时,Ｂｒ＝６５５ｍＴ,ｊＨｃ＝６３９．２ｋＡ／ｍ,ｂＨｃ＝３８１．６ｋＡ／ｍ,（ＢＨ）ｍ＝６５．６８ｋＪ／ｍ３。     

放电等离子烧结制备纳米晶双相耦合(NdDy)11.5(FeCoNb)82.4B6.1致密磁体

使用放电等离子烧结(SPS)制备致密的纳米晶交换耦合Nd_2Fe_(14)B/α-Fe永磁合金.研究烧结温度、时间、压力对合金磁性能和显微组织的影响.结果表明,随温度、压力的升高,密度增大,磁能积增加;但温度过高或时间过长,使得晶粒长大,导致矫顽力降低.在烧结压力为500 MPa,烧结温度为700 ℃保温3 min后,得到密度为7.6 g/cm~3,晶粒细小的致密块体,其磁性能为:B_r=0.81 T,H_(ci) =856 kA·m~(-1),(BH)_m =106 kJ·m~(-3),其晶粒大小约20 nm.     

粘结剂含量对粘结NdFeB磁体力学性能和磁性能的影响

粘结剂作为粘结NdFeB磁体制备过程中的重要组成部分,其作用是提高磁粉颗粒的流动性和粘结强度,保证产品的力学性能和磁性能的稳定。采用理论与实验相结合的方法,研究了粘结剂含量对粘结NdFeB磁体力学性能和磁性能的影响。在此基础上,制备了高性能粘结NdFeB磁体。利用扫描电子显微镜（SEM）对磁体的结构和形貌进行了表征。在NIM-200C磁滞回线仪和电子万能试验机（AG-X plus）上分别测定了环形粘结NdFeB磁体（RSM）的磁性能和力学性能。结果表明,当粘结剂含量为3%（质量分数）时,粘结NdFeB磁体密度最高（5.59 g/cm³）,抗压强度最高（159 MPa）,磁性能最佳。     

Possible methods of recycling NdFeB-type sintered magnets using the HD/degassing process

With the rapid growth in the use of NdFeB-type magnets and with the growing environmental need to conserve both energy and raw materials, the recycling of these magnets is becoming an ever important issue. In this paper it is demonstrated that hydrogen could play a vital role in this process. Fully dense sintered NdFeB-type magnets have been subjected to the hydrogen decrepitation (HD) process. The resultant powder has been subsequently processed in one of two ways in order to produce permanent magnets. Firstly, the powder was subjected to a vacuum degassing treatment over a range of temperatures up to 1000 °C in order to produce powder that would be suitable for the production of anisotropic bonded or hot pressed magnets. Secondly, the HD-powder has been used to produce fully dense sintered magnets; in which case optimisation of the milling time, sintering temperature and time was carried out. The optimum degassing temperature for coercive powder was found to be 700 °C, giving powder with a remanence (Br) of 1350 mT (±50 mT) and an intrinsic coercivity (Hcj) of 750 kA m⁻¹ (±50 kA m⁻¹). The best sintered magnet was produced by very lightly milling the powder (30 min, roller ball mill), aligning, pressing and vacuum sintering at 1080 °C for 1 h. The magnetic properties of this magnet were: (BH)_max = 290 kJ m⁻³ (±5 kJ m⁻³), Br = 1240 mT (±50 mT) and Hcj = 830 kA m⁻¹ (±50 kA m⁻¹); representing decreases of 15%, 10% and 20%, respectively, from the properties of the initial magnet.