共查询到20条相似文献,搜索用时 140 毫秒
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超分散剂是近几年来发展起来的一种新型聚合物型分散剂,日益受到重视。本文以超分散剂的应用现状为主线,简要回顾了近几年来超分散剂的研究进展,并对其发展前景进行了简要展望。 相似文献
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K. W. Allen 《The Journal of Adhesion》2013,89(3-4):261-277
The once distinct and independent theories of adhesion have been losing their isolation and converging. Ideas of the effects of surface roughness, once dismissed as irrelevant except in the case of textiles, have been revised; albeit on a smaller scale as details of surfaces have been revealed by sophisticated techniques. Electrostatic interactions across an interface have been more deeply explored and their significance recognised and expounded. Diffusion of groupings and chain segments within a polymer have been related to the possibilities of interaction with a variety of surfaces. Perhaps most important, theories of adsorption have been extended in depth. The precise nature of the molecular interactions have been recognised and quantified. In doing this the contribution of diffusion and elastoplastic phenomena have been integrated. These developments are collated and analysed to present the present understanding of the concepts. 相似文献
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A Review of Contemporary Views of Theories of Adhesion 总被引:2,自引:0,他引:2
K. W. Allen 《The Journal of Adhesion》1987,21(3):261-277
The once distinct and independent theories of adhesion have been losing their isolation and converging. Ideas of the effects of surface roughness, once dismissed as irrelevant except in the case of textiles, have been revised; albeit on a smaller scale as details of surfaces have been revealed by sophisticated techniques. Electrostatic interactions across an interface have been more deeply explored and their significance recognised and expounded. Diffusion of groupings and chain segments within a polymer have been related to the possibilities of interaction with a variety of surfaces. Perhaps most important, theories of adsorption have been extended in depth. The precise nature of the molecular interactions have been recognised and quantified. In doing this the contribution of diffusion and elastoplastic phenomena have been integrated. These developments are collated and analysed to present the present understanding of the concepts. 相似文献
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Graft copolymers of chlororubber-20-g-(ethylacrylate-co-acrylonitrile (2:1)) and chlororubber-20-g-(styrene-co-vinyl acetate-co-acrylonitrile [1:1:1]) have been synthesized by solution precipitation polymerization technique. The graft copolymers have been characterized by elemental analysis, IR spectroscopy, and viscometry. The graft copolymers have been melt blended with PVC. The mechanical properties, such as flexural, tensile strength, and impact strength, of the blends have been studied to evaluate the relative performance of various graft copolymer blends of PVC as impact modified systems. Mechanical properties of the blends have been discussed in terms of morphology of impact fractured samples. 相似文献
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Dr. Wanyama Peter Juma Dr. Dubekile Nyoni Prof. Dean Brady Prof. Moira L. Bode 《Chembiochem : a European journal of chemical biology》2022,23(7):e202100527
The Morita-Baylis-Hillman (MBH) reaction affords highly functionalised allylic alcohols containing a new stereogenic centre. These MBH adducts are very versatile and have been transformed into a large range of products, some of which have medicinal potential. Several examples of asymmetric syntheses of MBH adducts have been reported, although a generally applicable method remains to be developed. Biocatalytic approaches for the synthesis and enzymatic kinetic resolution of MBH adducts have been reported, and are discussed in detail in this review. Enzymes able to catalyse the asymmetric MBH reaction have been identified, but selectivity and efficiency have generally been low. Lipases, esterases and nitrile-converting enzymes have all been successfully applied in the resolution of MBH adducts, with excellent selectivity being realised in most cases. 相似文献
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The processes of electrochemical deposition of zirconia from nonaqueous electrolytes on different substrates have been investigated. Cyclic voltammetry and linear sweep voltammetry have been used to investigate the oxygen and hydrogen reduction processes preceding/accompanying the discharge of the zirconium complex being identified. On the basis of simultaneous XPS and SEM analyses, the potential region of zirconia layer formation has been defined. The kinetic parameters of successive and parallel reduction processes have been determined. The factors hindering the formation of thick zirconia layers have been discussed. 相似文献
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《Ceramics International》2019,45(1):665-673
The present study has been related to synthesis and characterization of ZnO films growth by chemical spray pyrolysis technique. Variation in the characteristics of ZnO film has been evaluated as a function of Cobalt content. The influence of cobalt content on structural, morphological, optical and electrical features have been observed by XRD, SEM, AFM, UV–vis spectroscopy and I-V measurement, respectively. Structural measurements of the samples indicate that all samples have polycrystalline nature with (002) preferential orientation. SEM and AFM images have indicated that films have smooth and uniform morphology. Changes in the surface morphology of the samples have been explained by taking Cobalt incorporation into consideration. Optical studies reveal that the band gap values of the samples exhibit decreasing tendency with Cobalt content. Performance of ZnO films in Schottky diode application has been conducted by evaporation Au contact on ZnO:Co films. From I-V curves of the devices, it has been observed that all devices exhibit good rectifying properties. Also, some diode parameters such as ideality factor, barrier height have been calculated by considering thermionic emission theory (TE) and have been found in the range of 1.89–1.57 and 0.57–0.62 eV, respectively. Additionally, these results and series resistance values of the diodes have been checked and calculated by using Cheung's function. Results showed that all diode parameters highly depended on cobalt concentration. All results have been discussed in detail depending on cobalt incorporation. 相似文献
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S. M. Danov A. V. Sulimov A. V. Ovcharova 《Theoretical Foundations of Chemical Engineering》2013,47(5):563-569
Vapor-Liquid equilibrium (VLE) data have been calculated for systems made up by glycidol synthesis products and have been compared with data available from the literature. The VLE data reported for the systems have been optimized using the NRTL and UNIQUAC models, and the model parameters and their accuracy have been estimated. The VLE in binary and multicomponent systems has been simulated. 相似文献
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Pradip S. Patel Praful P. Shah Shanti R. Patel 《Polymer Engineering and Science》1986,26(17):1186-1190
Bisphenolic resins have been prepared by alkali catalyzed condensation of bisphenol-F, bisphenol-A, and bisphenol-C, respectively, with furfural. The resin samples have been characterized by elemental analysis, dilute solution viscosity measurement, and measurement of number-average molecular weight. Curing reactions of these bisphenolic resins with hexamine have been investigated by differential scanning calorimetry. The overall apparent activation energies for the curing have been found to be 24 ± 2, 34.2 ± 1.9, and 36.8 ± 2.3 kcal/mole for bisphenol-F-furfural, bisphenol-A-furfural, and bisphenol-C-furfural resin, respectively. The curing reactions have been found to follow an overall first-order kinetics. 相似文献
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Bachan S. Rawat Indar B. Gulati 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1976,26(1):425-435
Liquid-liquid equilibrium studies have been carried out on 11 solvents using two binary hydrocarbon mixtures for selective extraction of aromatics. The solvents used have been compared on the basis of selectivity, solvent capacity and tie line correlation curves. Tie line data have been determined for 18 systems. The selectivity and solvent power of solvents as obtained from limiting activity coefficient and tie line data have been compared. The selectivity and capacity of solvents have been related to their structure through an empirical parameter. 相似文献
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The problems of the rheology of oil disperse systems, which are accompanied by asphaltene particles being set into nanoaggregates and clusters of nanoaggregates and viscoelastic framework have been analyzed. The models of the coagulation of asphaltene particles and the calculation of the nanoaggregate size have been suggested. The conditions of the destruction of the structure have been considered and the rheological models of the filtration of oil disperse systems have been considered with the assumption of the Maxwell equation and model of the change of viscosity and mobility. The results have been compared with the experimental data. 相似文献