Treatment of leachate from the anaerobic fermentation of solid wastes using two biofilm support media.

Biofilms growing on different carrier media have a different response to the nutrients contained in wastewater. Biofilms have proven to be an alternative to the treatment of wastewater containing higher concentrations of contaminants. The main objective of this research was to compare two biofilm support media for the treatment of leachate from the anaerobic fermentation of solid wastes. The removal of organic matter and ammonia was achieved in two fixed bed biofilm reactors containing Kaldnes and Linpor support materials with specific surface areas of 490 and 270 m2/m3, respectively, and operating under the sequencing batch procedure during 204 days. The Linpor reactor achieved higher total COD removal than the Kaldnes reactor (47% and 39%, respectively). Linpor was shown to be less sensitive to influent COD changes than Kaldnes. The effluent total COD values of Kaldnes were higher than Linpor. The dissolved COD removal was 21% for both reactors. The average ammonia removal for Linpor was 72% and 42% for Kaldnes. The matrix of Linpor allows higher concentrations of microorganisms (as dry mass) than Kaldnes. The dry mass concentration was related to the "active" exposed surface area of the biofilm. This is considered to be the cause for the better performance of Linpor when compared with Kaldnes.     

Full scale implementation of the nutrient limited BAS process at S?dra Cell V?r?.

A combination of the suspended carrier biofilm process and the activated sludge process (biofilm-activated sludge--BAS) has been shown to be very successful for the treatment of different types of pulp and paper mill effluents. The robust biofilm pre-treatment in combination with activated sludge results in a stable, compact and highly efficient process. Recent findings have shown that nutrient limited operation of the biofilm process greatly improves the sludge characteristics in the following activated sludge stage, while minimising sludge production and effluent discharge of nutrients. The nutrient limited BAS process was implemented at full scale at the S?dra Cell V?r? kraft mill and taken into operation in July 2002. After start-up and optimisation over about 5 months, the process meets all effluent discharge limits. The removal of COD is close to 70% and the removal of EDTA greater than 90%. Typical effluent concentrations of suspended solids and nutrients during stable operations have been 20-30 mg/L TSS, 0.3-0.5 mg/L phosphorus and 3-5 mg/L nitrogen. The sludge production was 0.09 kgSS/kg COD removed and the sludge volume index was 50-100 mL/g.     

Treatment of paper mill effluent using an anaerobic/aerobic hybrid side-stream membrane bioreactor

This paper presents the design and operational performance data of an anaerobic/aerobic hybrid side-stream Membrane Bioreactor (MBR) process for treating paper mill effluent operated over a 6 month period. The paper mill effluent stream was characterized by a chemical oxygen demand (COD) range of between 1,600 and 4,400 mg/L and an average BOD of 2,400 mg/L. Despite large fluctuations in COD feed concentration, stable process performance was achieved. The anaerobic Expanded Granular Sludge Bed (EGSB) pre-treatment step effectively lowered the organic loading by 65 to 85%, thus lowering the MBR COD feed concentration to consistently below 750 mg/L. The overall MBR COD removal was consistent at an average of 96%, regardless of the effluent COD or changes in the hydraulic retention time (HRT) and organic loading rate (OLR). Combining a high-rate anaerobic pre-treatment EGSB with a Modified Ludzack-Ettinger (MLE) MBR process configuration produced a high quality permeate. Preliminary NF and RO results indicated an overall COD removal of around 97 and 98%, respectively.     

Vertical flow constructed wetlands for municipal wastewater and septage treatment in French rural area.

This paper presents the purification performance of 20 wastewater treatment plants with vertical reed bed filters (Macrophyltres), built between 1998 and 2003 by SAS Voisin, for communities of between 150 and 1400 PE. The first stage vertical reed bed (directly fed with raw wastewater by intermittent feeding) achieved high removal of SS, BOD and COD (mean respectively 96%, 98%, 92%). The second stage permitted compliance easily with effluent standards (SS < 15 mg/l, BOD < 15 mg/l, COD < 90 mg/l and mean TKN < 10 mg/l). Performance was not significantly influenced by variations of organic and hydraulic load, nor by seasonal variations. Rigorous operation and maintenance were required to obtain optimal performances. Another application of vertical reed beds is the treatment of septage (sludge from individual septic tanks). The results obtained on two sites operating for 2 and 3 years are presented. The first site achieved complete treatment of septage (solid and liquid fraction), the second permitted a pre-treatment for co-treatment of percolate with wastewater.     

A pilot-plant study of a moving-bed biofilm reactor system using PVA gel as a biocarrier for removals of organic carbon and nitrogen.

A pilot-plant study was conducted to evaluate the performance of a moving-bed biofilm reactor process using PVA-gel beads as a biocarrier. Real primary-settled wastewater was fed to the pre-denitrification system and removals of nitrogenous and organic contaminants were evaluated over a 1-year period. The results demonstrated that at a total nitrogen (TN) loading of 18 mg/L.h, a TN removal efficiency in keeping with and even exceeding the theoretical maximum efficiency based on the level of internal recycle, was possible and a nitrification rate of 15 mg/L.h was sustained with a HRT of only 2.5 h at 15 degrees C. Furthermore, soluble COD and BOD5 in the effluent of the pilot plant were reduced to levels well below most regulatory discharge limits. In addition, the possibility of using this biocarrier in a system, including the elimination of waste organic sludge, was discussed.     

Disc filtration for separation of flocs from a moving bed bio-film reactor.

A Discfilter with 10 and 18 microm filter openings, respectively, was placed in parallel to a flotation plant for separation of biological flocs from a post-denitrifying Kaldnes Moving Bed Process, the last treatment step at the municipal wastewater treatment plant at Sj?unda, Malm?, Sweden. The effluent concentrations from the 10 and 18 microm filter were 2-5 and 2-8 mg SS L(-1), respectively, which is comparable to, or better than, the flotation plant. Comparison with experiences from activated sludge plants shows that the Discfilter works especially well after the Kaldnes process. Particle size distribution (PSD) studies show that particles larger than the filter openings of 10 and 18 microm are separated with approximately 90% efficiency, whereas most of the smaller particles pass the filter. This fact indicates that the major particle separation mechanism is physical blocking. These findings point to the possibility of improving the prediction of the separation efficiency by combining measurements of turbidity and suspended solids with particle size analysis.     

Treatment of slaughterhouse plant wastewater by using a membrane bioreactor

The use of a membrane bioreactor (MBR) for removal of organic substances and nutrients from slaughterhouse plant wastewater was investigated. The chemical oxygen demand (COD), total nitrogen (TN), and total phosphorus (TP) concentrations of slaughterhouse wastewater were found to be approximately 571 mg O2/L, 102.5 mg/L, and 16.25 mg PO4-P/L, respectively. A submerged type membrane was used in the bioreactor. The removal efficiencies for COD, total organic carbon (TOC), TP and TN were found to be 97, 96, 65, 44% respectively. The COD value of wastewater was decreased to 16 mg/L (COD discharge standard for slaughterhouse plant wastewaters is 160 mg/L). TOC was decreased to 9 mg/L (TOC discharge standard for slaughterhouse plant wastewaters is 20 mg/L). Ammonium, and nitrate nitrogen concentrations of treated effluent were 0.100 mg NH4-N/L, and 80.521 mg NO3-N/L, respectively. Slaughterhouse wastewater was successfully treated with the MBR process.     

Development of an ecologically sustainable wastewater treatment system

The present study aimed mainly for the development of a wastewater treatment system incorporating enhanced primary treatment, anaerobic digestion of coagulated organics, biofilm aerobic process for the removal of soluble organics and disinfection of treated water. An attempt was also made to study the reuse potential of treated water for irrigation and use of digested sludge as soil conditioner by growing marigold plants. Ferric chloride dose of 30 mg/l was found to be the optimum dose for enhanced primary treatment with removals of COD and BOD to the extent of 60% and 77%, respectively. Efficient anaerobic digestion of ferric coagulated sludge was performed at 7 days hydraulic retention time (HRT). Upflow aerobic fixed film reactor (UAFFR) was very efficient in removals of COD/BOD in the organic loading rate (OLR) range of 0.25 to 3 kg COD/m(3)/day with COD and BOD removals in the range 65-90 and 82-96, respectively. Photo-oxidation followed by disinfection saved 50% of chlorine dose required for disinfection of treated effluent and treated water was found to be suitable for irrigation. The result also indicated that anaerobically digested sludge may be an excellent soil conditioner. From the results of this study, it is possible to conclude that the developed wastewater treatment system is an attractive ecologically sustainable alternative for sewage treatment from institutional/industrial/residential campuses.     

MBR工艺处理城镇污水处理厂污泥水中试研究

将平板膜组件与传统脱氮除磷工艺相结合,构建了膜生物反应器强化生物脱氮除磷中试系统,并用于处理城镇污水处理厂的污泥系统废水。结果表明,出水CODCr、BOD5、NH3—N、TN和TP的平均浓度分别为70.8 mg/L、8.7 mg/L、15.1 mg/L、29.7 mg/L和0.38 mg/L,达到或接近了《城镇污水处理厂污染物排放标准》(GB 18918—2002)的一级标准。     

高浓度制药废水处理工艺的调试运行

某制药厂生产废水水质变化大,污染物浓度高,毒性大.采用气浮—兼氧-CASS工艺进行处理.实践表明,处理出水COD 450～650 mg/L,氨氮20～35 mg/L,BOD5≤100 mg/L,SS50～100mg/L,可达《污水综合排放标准》(GB 8978-1996)三级排放标准.     

Effect of recirculation on organic matter removal in a hybrid constructed wetland system

This research project aimed to determine the technologically feasible and applicable wastewater treatment systems which will be constructed to solve environmental problems caused by small communities in Turkey. Pilot-scale treatment of a small community's wastewater was performed over a period of more than 2 years in order to show applicability of these systems. The present study involves removal of organic matter and suspended solids in serially operated horizontal (HFCW) and vertical (VFCW) sub-surface flow constructed wetlands. The pilot-scale wetland was constructed downstream of anaerobic reactors at the campus of TUBITAK-MRC. Anaerobically pretreated wastewater was introduced into this hybrid two-stage sub-surface flow wetland system (TSCW). Wastewater was first introduced into the horizontal sub-surface flow system and then the vertical flow system before being discharged. Recirculation of the effluent was tested in the system. When the recirculation ratio was 100%, average removal efficiencies for TSCW were 91 +/- 4% for COD, 83 +/- 10% for BOD and 96 +/- 3% for suspended solids with average effluent concentrations of 9 +/- 5 mg/L COD, 6 +/- 3 mg/L BOD and 1 mg/L for suspended solids. Comparing non-recirculation and recirculation periods, the lowest effluent concentrations were obtained with a 100% recirculation ratio. The effluent concentrations met the Turkish regulations for discharge limits of COD, BOD and TSS in each case. The study showed that a hybrid constructed wetland system with recirculation is a very effective method of obtaining very low effluent organic matter and suspended solids concentrations downstream of anaerobic pretreatment of domestic wastewaters in small communities.     

生物过滤氧化反应器处理生活污水中试研究

以生活污水为处理对象 ,研究了生物过滤氧化反应器 (BIOFOR)在高滤速、高负荷、小的气水比情况下 ,用非常短的水力停留时间 (6 0～ 80min) ,取得了很好的出水水质的机理 ,主要水质指标 (COD、BOD、SS、氨氮 )可达到国家《污水综合排放标准》或《生活杂用水水质标准》。同时探讨了滤速及容积负荷对出水水质的影响 ,分析了主要污染物的去除规律。     

High-rate wastewater treatment combining a moving bed biofilm reactor and enhanced particle separation.

Many cities around the world are looking for compact wastewater treatment alternatives since space for treatment plants is becoming scarce. In this paper development of a new compact, high-rate treatment concept with results from experiments in lab-scale and pilot-scale are presented. The idea behind the treatment concept is that coagulation/floc separation may be used to separate suspended and colloidal matter (resulting in > 70% organic matter removal in normal wastewater) while a high-rate biofilm process (based on Moving Bed biofilm reactors) may be used for removing low molecular weight, easily biodegradable, soluble organic matter. By using flotation for floc/biomass separation, the total residence time for a plant according to this concept will normally be < 1 hour. A cationic polymer combined with iron is used as coagulant at low dosages (i.e. 1-2 mg polymer/l, 5-10 mg Fe/l) resulting in low sludge production (compared to conventional chemical treatment) and sufficient P-removal.     

Equalization characteristics of an upflow sludge blanket-aerated biofilter (USB-AF) system.

Equalization characteristics of the upflow sludge blanket-aerated bio-filter (USB-AF) were investigated with the fluctuated raw domestic sewage. Recycle of nitrified effluent from AF to USB triggered the equalization characteristics of the sludge blanket on both soluble and particulate organic matter. Increment of EPS in sludge blanket by nitrate recycle was detected and removal of turbidity and particulates increased at higher recycle ratios by bio-flocculation. Increased TCOD removal in the USB was due to both denitrification of recycled nitrate and entrapment of the particulate organic matter in sludge blanket. Capture of both soluble and particulate organic matter increased sludge blanket layer in the USB, which improved the reactor performances and reduced the organic load on the subsequent AF. Overall TCOD and SS removal efficiencies were about 98% and 96%, respectively in the USB-AF system. Turbidity in the USB effluent was about 44, 20 and 5.5 NTU, at recycle ratios of 0, 100 and 200%, respectively. Particle counts in the range 2-4 microm in the USB effluent were higher than those in influent without nitrate recycle, while particle counts in the range of 0.5-15 microm in the USB effluent decreased 70% at recycle ratio of 200%. The major constituent of EPS extracted from anaerobic sludge was protein and total EPS increased from 109.1 to 165.7 mg/g-VSS with nitrate recycle of 100%. Removal efficiency and concentration of T-N in the UBS-AF effluent was over 70% and below 16 mg/L, respectively.     

Biological nitrogen removal with three different SBBR.

In order to compare the performance of biofilms growing on different support media, three reactors were fed with municipal wastewater from the city of Garching, Germany, and operated under the sequencing batch procedure. The support media tested have the commercial names of Kaldnes, polyethylene special support for moving bed reactors with approximate diameter of 12 mm; Liapor, ceramic spheres with diameters between 4 and 6 mm; Linpor, plastic foam cut in cubes of 15 mm. The bench-top reactors were tested for COD, TSS and ammonia nitrogen removal. During 452 days runs with organic loads between 0.5 and 8.0 gCOD/m2 x d were tested. Thin biofilms (Kaldnes and Liapor) perform better for COD and ammonia removal under lower organic loading values (< 2.5 gCOD/m2 x d). For organic loads over 3.0 gCOD/m2 x d, the reactor packed with Linpor (thick biofilm) showed a better COD and ammonia nitrogen removal than the other two. Linpor achieved the highest NOx-N production reaching values between 15 and 20 mg/l. For low organic loading rates Linpor and Liapor present similar average NOx-N concentrations. Kaldnes shows the lowest concentrations throughout the whole experimental period. The difference between ammonia nitrogen removal and NOx-N generation is simultaneous denitrification inside the deep biofilms. The average mean cellular retention times were 5.4 days for Liapor, 10.0 days for Kaldnes and 22.9 days for Linpor. This is the reason why Linpor achieved complete nitrification even with higher organic loads.     

厌氧附着膜膨胀床反应器处理乳品废水的研究

研究厌氧附着膜膨胀床反应器中温处理乳品废水的运行工况。讨论在不同水力停留时间、容积负荷、pH值条件下对COD去除率的影响,并对进出水总氮及氨氮的变化情况进行研究。试验表明:厌氧附着膜膨胀床反应器处理乳品废水,在水力停留时间为8h、中温35℃条件下,COD去处率达到80%以上,对总氮的去除约为8%,出水有机氮的氨化率达70%以上,ρ(BOD)/ρ(COD)由进水的0 5提高到0 8以上。     

粕滤慢滤技术在西北村镇集雨窖水处理中的应用研究

针对西北村镇集雨窖水污染现状,采用粗滤慢滤组合净水工艺进行了现场试验研究.通过自然挂膜确定了膜的生物稳定期,并对其影响因素进行了分析.结果表明:粗滤慢滤小型净水装置能有效地处理西北村镇集雨窖水.对窖水的浊度、有机物、氨氮及微生物学指标有良好的去除效果.在粗滤慢滤装置滤速控制在0.1 m/h的情况下,生物膜生长期为40～50 d.在生物膜形成之后,出水氨氮平均0.285 mg/L,氨氮去除率最高达78.35％;出水CODMn平均2.27 mg/L,CODMn去除率最高达到61.58％.出水浊度平均0.56 NTU,浊度去除率最高达到98.99％.该净水技术工艺简单,无需投药,操作管理方便,适用于西北村镇等以户为单位的分散式窖水处理.     

林可霉素高浓度有机废水处理技术

采用厌氧颗粒和好氧活性污泥分别对内循环厌氧反应器(IC)和间歇式活性污泥法(SBR)进行污泥接种培养,研究水解酸化-IC-SBR工艺在林可霉素生产废水处理方面的运行效果。结果表明:在进水COD的质量浓度为6 000~9 000 mg/L,IC和SBR反应器中有机负荷分别为0.82 kg/(kg.d)和0.26 kg/(kg.d)左右的情况下,IC和SBR反应器分别运行60 d和7 d,COD平均去除率分别达到91%和61%,出水COD的质量浓度在300 mg/L以下,达到GB 8978—1996《污水综合排放标准》二级标准。     

Coarse filters for pond effluent polishing: comparison of loading rates and grain sizes.

A system comprising a UASB reactor, shallow polishing ponds and shallow coarse filters, treating actual wastewater from the city of Belo Horizonte, Brazil, has been evaluated. The main focus of the research was to compare grain sizes and hydraulic loading rates in the coarse filters. Two filters operating in parallel were investigated, with the following grain sizes: Filter 1: 3 to 10 cm; Filter 2: 8 to 20 cm. Two hydraulic loading rates were tested: 0.5 and 1.0 m3/m3.d. The filter with the lower rock size had a better performance than the filter with the larger rock size in the removal of SS and, as a consequence, BOD and COD. A better performance was obtained with the hydraulic loading rate of 0.5 m3/m3.d, as compared to the rate of 1.0 m3/m3.d. The effluent quality during the period with the lower loading rate was very good for discharge into water bodies or for agricultural reuse (median effluent concentrations from Filter 1: BOD: 20 mg/L; COD: 106 mg/L; SS: 28 mg/L; E. coli: 528 MPN/100 mL).     

水解-气浮-曝气生物滤池工艺在印染废水处理中的应用

采用水解 气浮 曝气生物滤池工艺处理印染废水的运行结果表明 :在原废水COD为830mg/L ,色度为 560倍 ,BOD为 2 90mg/L的条件下 ,其去除率分别为 82 % ,94 %和 93% ,出水达标排放。