快速凝固Cu-Cr-Zr-Mg合金的时效析出与再结晶

对快速凝固Ｃｕ０．６Ｃｒ０．１５Ｚｒ０．０５Ｍｇ合金伴随时效析出的再结晶过程进行了观察和研究。发现该合金在形变后的时效过程中,析出相非常细小、弥散,阻碍了再结晶的进行,出现了原位再结晶与不连续再结晶同时发生的现象。在再结晶的形核和长大过程中,析出相在晶界前沿快速粗化或重新溶解,并在再结晶区域中重新析出,导致更加弥散的析出相分布。     

EFFECT OF COLD WORKING ON THE AGING PROPERTIES OF Cu-Cr-Zr-Mg ALLOY BY ARTIFICIAL NEURAL NETWORK

A developmental research has been carried out to deal with the high performance of Cu-Cr-Zr-Mg lead frame alloy by artificial neural network (ANN). Using the cold working to assist in the aging hardening can improve the the hardness and electrical conductivity properties of Cu-Cr-Zr-Mg lead frame alloy. This paper studies the effect of different extent of cold working on the aging properties by a supervised ANN to model the non-linear relationship between processing parameters and the properties. The back-propagation (BP) training algorithm is improved by Levenberg-Marquardt algorithm. A basic repository on the domain knowledge of cold worked aging processes is established via sufficient data mining by the network. The predicted values of the ANN coincide well with the tested data.So an important foundation has been laid for prediction and optimum controlling the rolling and aging properties of Cu-Cr-Zr-Mg alloy.     

Recrystallization and Precipitation Behavior of Cu-Cr-Zr Alloy

Recrystallization and precipitation behaviors after cold rolling and aging are investigated for Cu-0.7Cr-0.13Zr alloy. The processed alloy was characterized using the measurement of Vickers hardness, scanning electron microscopy, and transmission electron microscopy. The resultant complex microstructures are interpreted in terms of the interactions between precipitation and recrystallization. Upon aging at 500 °C for 1 h, the 45% rolled alloy exhibits a retarded recrystallization process and therefore an efficient hardening response, which are attributed to the pinning effect of fine dispersed precipitates on the dislocation. When heavily deformed and aged at high temperature, the alloy shows an accelerated process of recrystallization, and precipitates are found to coarsen.     

Prediction and analysis of the aging properties of rapidly solidified Cu-Cr-Sn-Zn alloy through neural network

It is known that the strength of a metal can be successfully improved by rapid solidification. The hardness of the rapidly solidified Cu-Cr-Sn-Zn alloy is much higher than that of the solution heat-treated and aged alloy. In this study, multiple-layer, feed-forward, artificial neural network (ANN) modeling has been used to study the hardness and electrical conductivity behavior of a rapidly solidified Cu-Cr-Sn-Zn alloy. The ANN model shows how the aging parameters influence the hardness and electrical conductivity of a rapidly solidified Cu-Cr-Sn-Zn alloy. The ANN modeling also provides encouraging predictions for information not included in the trained set samples, indicating that a backpropagation network is a very useful and accurate tool for property analysis and prediction.     

利用神经网络建立快速凝固Cu-Cr-Zr合金时效知识库

根据人工神经网络(ANN)的BP(back propagation)算法，建立了快速凝固Cu-Cr-Zr铜合金时效温度和时间与硬度和导电率的神经网络映射模型。预测值与实际情况吻合良好，硬度和导电率最大误差分别为4．1％和1．9％。通过对样本集的学习，建立了快速凝固时效工艺知识库，对预测和控制该工艺性能非常有益。     

快速凝固Al－Cu－Mg合金的时效特征

对离心雾化法制得的快速凝固Ａｌ－Ｃｕ－Ｍｇ合金的时效特征进行了研究。结果表明,随时效温度的升高,快速凝固Ａｌ－Ｃｕ－Ｍｇ合金的时效硬度峰值增加,且达峰值后硬度下降缓慢。在连续加热时效过程中,快速凝固Ａｌ－Ｃｕ－Ｍｇ合金有Ｓ”相形成过程,且Ｓ’相形成长大过程比较缓慢。从时效析出激活能、连续加热过程分析等方面进行了解释和验证。     

SUPERPLASTICITY OF A RAPIDLY SOLIDIFIED AI-Li ALLOY

A rapidly solidified microcrystalline Al-Li-Cu-Mg-Zr alloy and its superplasicity have beeninvestigated.An optimum tensile elongation of 585% was obtained at 540℃ and strain rate1.67×10~(-2)s~(-1).The superplastic Al-Li alloy is manufaetured using thermomechanical pro-cessing:solution,overaging,warm rolling and recrystallization.Microstructural changes inthermomechanical processing and cavitation occurred during superplastic deformation havebeen observed.The superplastic failure of alloy may be caused mainly by nucleation andgrowth of cavities as well as the linkage around grains.     

急冷Cu30Al70合金的结构及催化特性

本文研究了急冷Cu30Al70合金及其制成的急冷骨架铜催化剂，并与工业上广泛应用的Cu30Al70合金催化剂进行了对比，结果表明：急冷Cu30Al70合金组织较均匀，单质Al相较少，CuAl元素分布均匀，急冷骨架铜催化剂比表面积较小，孔径大，孔容积较大，急冷骨架铜催化剂在木糖加氢反应中的催化活性高于普通的骨架铜催化剂。     

Establishing the knowledge repository of rapidly solidified aging Cu-Cr-Zr alloy on the artificial neural-network

The non-linear relationship between parameters of rapidly solidified aging processes and mechancal and electrical properties of Cu-Cr-Zr alloy is available by using a supervised artificial neural network (ANN). A knowledge repository of rapidly solidified aging processes is established via sufficient data learning by the network. The predicted values of the neural network are in accordance with the tested data. So an effective measure for foreseeing and controlling the properties of the processing is provided.     

Recrystallization developed in the largely undercooled Ni54.6Pd45.4 alloy

The structure evolution driven by recrystallization in the bulk undercooled Ni_54.6Pd_45.4 alloy was investigated by quenching the sample at different cooling stages. It is found that recrystallization of the solid beyond the critical undercooling for grain refinement starts at the end of rapid solidification, and develops during the slow solidification and the subsequent cooling process. At the initial stage of recrystallization, nuclei successively form in the sample, leading to a decrease in grain size. At the later stage, annexation of grains dominates the recrystallization, due to which the grain size increases. As undercooling prior to solidification increases, the deformation degree in the rapidly solidified dendrite net rises, and the recalescence temperature as well as the duration at high temperature decreases. Consequently, the grain size of the recrystallization structure decreases.     

快速凝固(2024Al)-20Si-5Fe合金的磨损行为

采用双级雾化水冷快凝与粉末冶金技术制备了（2024Al)-20Si-5Fe(质量分数.%)耐磨合金。分析了合金的微观组织。利用磨损实验研究了合金的耐磨性和磨损失效形式。结果表明：快凝粉末冶金合金具有比铸造合金更细小的微观组织。更高的耐磨性和减磨性。耐磨性是铸造合金的2．5－4倍。快凝合金的磨损失效形式主要是磨粒磨损和疲劳磨损。耐铸造合金的磨损失效形式主要是磨粒磨损、粘着磨损和部分氧化磨损。     

快凝AlFeVSi合金的高温退火行为

对比研究了冷变形前后的快凝ＡｌＦｅＶＳｉ合金高温退火时性能与显微组织的变化规律，结果表明，冷变形未促进合金退火时的性能与组织变化，这可能是该合金表现出的低加工硬化效应，退化时位错大量增殖，弥散相对再结晶的阻碍以及冷变形态合金的退火现象有关。     

冷轧Cu-Cr-Zr-Co-Si合金的时效行为

通过测量Cu-Cr-Zr-Co-Si冷轧合金在等温时效过程中导电率的动态变化,基于合金导电性能与析出相转化率间的近似线性关系,建立了不同冷变形量下合金时效析出过程的动力学Avrami方程及曲线,在此基础上分析了再结晶与时效析出的相互影响。结果表明:Cu-Cr-Zr-Co-Si合金形变时效过程中,随变形量和时效时间的增加,导电率及析出相转化率均增加,这是时效过程中再结晶与时效析出相互影响、共同作用的结果。随冷变形量增加,强化相析出进程明显加快,但时效析出没有明显阻止或延缓再结晶软化过程的发生,因此大冷变形+短时时效使合金获得更高的硬度峰值,但无法同时获得最优的导电性能。只有在时效析出提前于再结晶启动,且形成的第二相对再结晶存在明显阻碍的前提下,采用冷变形+时效工艺,时效强化型铜合金才能达到最佳效果。     

快速凝固粉末冶金Mg_(80)Cu_(10)Y_(10)合金的组织与力学性能

采用快速凝固粉末冶金技术制备热挤压Mg_(80)Cu_(10)Y_(10)合金棒材,研究了快速凝固Mg_(80)Cu_(10)Y_(10)合金薄带及热挤压后合金的相结构,并对热处理工艺对合金棒材组织结构及力学性能的影响进行了分析.研究表明,采用单辊快速凝固法在辊速为1800 r/min下制备的Mg_(80)Cu_(10)Y_(10)合金薄带为完全非晶态;在热挤压过程中Mg_(80)Cu_(10)Y_(10)合金中有Mg_2Cu和Mg晶体相析出,其显微硬度比薄带有所提高,这与合金中细小Mg_2Cu颗粒的弥散析出有关;在450 ℃保温4 h后的热挤压Mg_(80)Cu_(10)Y_(10)合金中没有新相析出;随着热处理温度的升高或保温时间的延长,由于Mg_2Cu颗粒出现重溶及聚集长大现象,使得热挤压Mg_(80)Cu_(10)Y_(10)合金的显微硬度表现出逐渐下降的变化趋势.     

Evolution of ordered ω phases in (Zr3Al)–Nb alloys

Microstructural investigations on rapidly solidified Zr₃Al based alloys (binary Zr₃Al and ternary Zr₃Al–3Nb and Zr₃Al–10Nb) have revealed some unusual phase transformation sequences. The Zr₅Al₃ phase (D8₈ structure) has been found to occur in both the rapidly solidified ternary alloys unlike in the rapidly solidified stoichiometric Zr₃Al alloy in which the Zr₂Al phase (B8₂ structure) has been found to be present. The evolution of the D8₈ phase, which could be regarded as one of the ordered derivatives of the ω phase, could be described in terms of a superimposition of replacive and displacive ordering waves in the β phase. The orientation relationship between the β and the D8₈ phases has been established. The microstructural changes occurring in the rapidly solidified Zr₃Al–Nb alloys during aging have been examined. It has been found that on aging the D8₈ phase gets transformed into the B8₂ phase which, on continued aging, transforms to other metastable and equilibrium phases, depending upon the aging temperature. The observed sequence of phase transformations involving different structurally related phases has been along the direction of progressively close packed structures. The symmetry changes associated with the sequence of ω related transformations have been summarized in the form of a symmetry tree.     

Effect of trace rare earth element Er on Al-Zn-Mg alloy

1 Introduction Remarkable effects of rear-earth elements on aluminium alloys, such as eliminating impurities, purifying melt, refining as-cast structure, retarding recrystallization and refining precipitated phases, have been widely researched for a long…     

快速凝固Al－8．32Fe－3．4Ce合金中弥散合金相的TEM测定

用常规电子显微术及ＥＤＡＸ能谱分析方法，对压制的快速凝固Ａｌ－８．３２Ｆｅ－３．４Ｃｅ合金热暴露过程中存在的弥散合金相进行了测定，确定出一种新相属于三角晶系，点阵常数为ａ＝１．ｎｍ，ｃ＝０．７ｎｍ（用六角点阵表示），ＥＤＡＸ能谱定量分析表明此相相组成约为Ａｌ_８Ｃｅ。     

快速凝固Cu—Cr合金时效析出的共格强化效应

采用单辊快速凝固的方法制备Ｃｕ－Ｃｒ合金微晶薄带,经适当的时效处理,可以在导电率不降低的前提下,显著提高合金的强度和硬度,强度和硬度的提高主要是由晶粒细化和共格弥散析出强化所造成,共格硬化效果与采用Ｇｅｒｏｌｄ公式计算的结果非常接近,与常规固溶处理的Ｃｕ－Ｃｒ合金相比,峰值硬度提高了１．６倍,其中２７％由细晶强化产生,７３％则由时效析出的共格强化提供,固溶强化和空位强化对快速凝固Ｃｕ－Ｃｒ合金强度     

Microstructures and mechanical properties of high strength Mg-Zn-Mn alloy

The microstructures and mechanical properties of a new Mg-6%Zn-1%Mn(mass fraction) wrought magnesium alloy were studied,which could be extruded smoothly at 310-330℃with a complete dynamic recrystallization.After solution treatment one and two-step aging techniques were used.All as-aged microstructures contained two types of dispersed phases:β' phases and pureα-Mn particles.The two-step aging had a better strengthening effect than the traditional one-step aging,and the strength value achieved by the two-s...     

Microstructure and thermal stability behavior of a rapidly solidified Al—Ti—Fe—Cr alloy

A rapidly solidified Al-2.5Ti-2.5Fe-2.5Cr(mass fraction in%) alloy was prepared by melt spinning.Asquenched and as-annealed microstructures were studied by X-ray diffractometry(XRD),transmission electron microseopy(TEM),high-resolution transmission electron microscopy(HREM) and energy dispersive spersive spectrum(EDS) analysis,The microhardness of the alloy at different annealing temperatures was measured.The results obtained indicate that the microhardness of the rapidly solidified Al-2.5Ti-2.5Fe-2.5Cr alloy does not vary with differnet annealing temperatures.The as-quenched microstructure of the alloy includes two kinds of dispersed primary phases:Al3Ti and Al13(Cr,Fe)2,After annealing at 400℃ for 10h,the stable phase Al13Fe4 appears in the microstructure.