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1.
Ageing characteristics of an extruded eutectoid Zn-Al based alloy were investigated using X-ray diffraction and scanning electron microscopy techniques. The extruded alloy consisted of Al rich phase and Zn rich E and phases. The original cast eutectoid Zn-Al alloy was extruded at 250 °C. Both supersaturated s and s phase decomposed during extrusion and appeared as fine and coarse lamellar structures. The E and phases particles formed in the original interdendritic region. It was found that two Zn rich phases E and decomposed sequentially during ageing at 170, 140 °C. The decomposition of the E phase occurred as a discontinuous precipitation in the early stage of ageing and the decomposition of the phase took place in a four phase transformation: + T + in the prolonged ageing. Two typical morphologies of the decomposition of the Zn rich phases E and were distinctive in back-scattered scanning electron microscopy. 相似文献
2.
Multiphase Ni-Al-(Fe)-(Cr)-(Co)-based intermetallics with (B2)- (A1)/(L12), - or - microstructures can exhibit significant room-temperature tensile ductility. In the case of Ni-Al-Cr-based alloys, microstructural development is complicated by the precipitation of -Cr, which can supplant the -phase during ageing of three-phase -/ microstructures. An investigation of the stability, during ageing, of cast Ni-Al-Cr-(Co) alloys with microstructures derived from -/ is reported. In the as-cast condition, the materials investigated consisted of a dendritic matrix containing L10 type martensite and interdendritic /. Extensive intra- and interdendritic -Cr precipitation was also observed. The stability during ageing of the interdendritic / microstructure is also considered and transformation of the L10 martensite is examined. 相似文献
3.
B. A. El-Sayed S. M. Shaaban M. M. El-Desoky M. A. Ahmed 《Journal of Materials Science: Materials in Electronics》1991,2(1):11-13
Correlation of the molecular structure and thermal study of the electrical conductivity of benzaldazine (BA) and its NO2-derivatives were carried out. The values of the activation energies, obtained from the electrical conductivity measurements, as well as the energy gaps calculated from ultra violet (u.v.) and visible spectra obtained either in liquid or in solid forms indicate that all compounds behave like a semiconducting material. Both n*s and *s were found to be the main sources participatiog in the cooduction processes. 相似文献
4.
The present work was performed on an Al–2.5 wt% Li alloy produced by melt spinning. The ribbons were aged in the temperature range 180 to 310° C for times between 1 min and 120h. The kinetics of coarsening of (Al3Li) and (AlLi) phase particles were investigated using transmission electron microscopy and hardness measurements. The results show that coarsening of (Al3Li) follows a simple linear relation with the cube root of Me, whereas coarsening of (AlLi) does not follow the same trend. We believe that the (AlLi) phase nucleates at the (Al3Li)/matrix interface and grows by the dissolution of the nearby (Al3Li) particles. The mechanical properties of the powder metallurgy alloy show that a large volume fraction of PFZ contributes to the alloy ductility, 11 %, in the aged condition. Also, the yield strength is greatly improved due to refinement effects enhanced by rapid solidification. 相似文献
5.
Minor quantities of Ag have been added to Al–Li–Cu–Mg–Zr alloys. Their microstructure has been studied by means of optical metallography, transmission electron microscopy and X-ray diffraction. In the high Li, low Cu : Mg ratio alloys the main phases found were , , S and T1, while fewer T2 and Al7Cu2Fe precipitates were also observed. The addition of up to 0.5 wt% Ag diminishes the and T1 precipitates size. This is attributed to a small increase of Li solubility in the matrix. In the low Li, high Cu : Mg ratio alloy the addition of 0.2 wt % Ag resulted in the precipitation of phase simultaneously with , , S and T1 phases. Due to the low Li concentration an unusual growth of the / precipitates at the expense of the precipitates was also observed. 相似文献
6.
The oxidation of dispersed aluminium oxynitride particles in an alumina matrix has been studied. The kinetics law of this reaction is linear and the activation energy is 420±40 kJ mol–1 (100±10 kcal mo–1). A-alumina layer is formed and leads to-alumina above 1200° C. The-alumina formation produces surface compressive stresses, and thus the mechanical properties (
f, HV) are improved. We have proved that the formation of-alumina in the Al2O3-AION composite can lead to the best properties for this ceramic. A-alumina layer has a very interesting effect on the wear resistance of this material. 相似文献
7.
Ductile L20-type wires and+L12-type duplex wires with high strengths and large elongation in the Ni-Al-Fe and Ni-Al-Co ternary systems have been manufactured directly from the liquid state by an in-rotating-water spinning method. The wire diameter was in the range 80 to 180m and the average grain size was 2 to 4m for the wires and 0.2 to 1.0m for the+ wires.
y,
f and
p of the wires were found to be about 360 to 760 MPa, 560 to 960 MPa, and 0.2 to 5.5%, respectively, for the Ni-Al-Fe system, those of the+ wires were about 395 to 660 MPa, 670 to 1285 MPa, and 3.5 to 17%, respectively, for the Ni-Al-Fe system, and about 260 to 365 MPa, 600 to 870 MPa, and 4.0 to 7.0%, respectively, for the Ni-Al-Co system. Cold-drawing caused a significant increase in
y and
f and the values attained were about 1850 and 2500 MPa, respectively, for Ni-20Al-30Fe and Ni-25Al-30Co wires drawn to about 90% reduction in area. The high strengths, large elongation and good cold-workability of the melt-quenched and+ compound wires have been inferred to be due to the structural change into a low-degree ordered state containing a high density of phase boundaries, suppression of grain-boundary segregation and refinement of grain size. 相似文献
8.
Prof. Y. Kohama 《Acta Mechanica》1987,66(1-4):21-38
Summary Three-dimensional boundary layer transition on axisymmetric rotating bodies is the subject of a comprehensive experimental study. Based on this study, hypotheses are made on the mechanism of cross-flow instability for swept wing flow. These new results are combined with past explanations to provide a rough sketch for the entire flow field over the swept wing. From this new viewpoint there appears the mechanism of traveling waves, being induced by a stationary disturbance. Some uncertainties appearing in recent papers concerning this flow field are discussed. Among these uncertainties for which an explanation is provided, is the discrepancy of frequencies between the hot wire signal and the visualized flow pattern.Nomenclature
x
direction along a potential flow stream line
-
y
direction normal to a potential flow stream line
-
z
direction normal to bothx andy directions
-
U
mean velocity inx-direction
-
V
mean velocity iny-direction
-
x
direction along a disturbance
-
y
direction normal tox direction
-
u, v, w
fluctuating velocity components inx, y, z directions
-
U
velocity inx-direction with wall fixed coordinate
-
U
e
velocity of outer edge of boundary-layer
-
U
uniform flow velocity normal to leading edge
-
V
uniform flow velocity parallel to leading edge
-
Q
upstream velocity
-
N
rotation speed of an axisymmetric body
-
P
arbitrary point on a disk surface
-
r
radius to a pointP
-
R
0
radius of a disk or a cylinder
-
U
p
phase velocity of ring like vortices
-
T
position where wall streaks appear in the case of oil flow visualization
- Re
c,t
critical and transitional Reynolds numbers
-
angle of the spiral disturbance
-
boundary-layer thickness
-
angular velocity
-
sweep angle of a body
-
wave length of disturbance
-
kinematic viscosity of a fluid
With 11 Figures 相似文献
9.
Powders of Si3N4, Al2O3 and SiO2 were mixed with Y2O3 as sintering aid and hot-pressed to form o- sialon. During sintering, the o phase preferentially precipitated in the temperature region of 1550 to 1600 °C, and the phase precipitated at temperatures of 1700 °C and above. The resultant microstructure consisted of dual phases of o and . The mechanical properties of o- sialon were improved with increasing amount of the phase. When SiO2 required for the formation of the o phase was all included in the grain boundary phase, o- sialon exhibited a three-point bending strength as much as 1400 MPa. The oxidation resistance of o- sialon is expected to improve due to the presence of the o phase, but actually was not so good due to the presence of the grain-boundary glassy phase and impurities. 相似文献
10.
The dielectric properties of Y(HCOO)3 · 2H2O and Er(HCOO)3 · 2H2O are studied. The frequency dependences (0.01 Hz to 20 kHz) of the real () and imaginary () parts of dielectric permittivity ( = – i) are shown to follow a fractal scaling law for the dielectric response of solids. In the tan versus temperature curves, a number of maxima are revealed in a narrow temperature range. The experimental data are used to evaluate the activation energies of relaxation processes. The observed anomalies are assumed to be associated with changes in the dynamics of protons in hydrogen bonds. 相似文献
11.
J. S. Thorp A. B. Ahmad B. L. J. Kulesza S. V. J. Kenmuir 《Journal of Materials Science》1984,19(10):3211-3216
Recently developed coaxial line techniques [1] have been used to determine, at room temperature, the values of the real () and imaginary (') parts of the dielectric constants for some Mg-Al-Si, Ca-Al-Si and Y-Al-Si oxynitride glasses over the frequency range 500 MHz to 5 GHz. The frequency dependencies of and ' are consistent with the universal law of dielectric response in that (-t8)(n–1) and '(n–1) for all glass compositions; the high experimental value of the exponent (n=1.0±0.1) suggests the limiting form of lattice loss [2] situation. In this frequency range, as previously reported [3] at longer wavelengths, the addition of nitrogen increases the dielectric constant, (); in both the oxide and oxynitride glasses is also influenced by the cation, being increased with cation type in the order magnesium, yttrium, calcium as at lower frequencies. 相似文献
12.
An investigation has been made of the reversion of martensite () to austenite () in two stainless steels (i) Fe-16 wt% Cr-12 wt% Ni (of low interstitial content) (ii) Fe-15 wt% Cr-8 1/2 wt% Ni-2 wt% Mo-0.09 wt% C. The alloys were refrigerated to produce 12 to 15% martensite () and then heated for short times at various temperatures ranging from below A
s to above A
f. With rapid heating the reversion of to occurs largely by a shear mechanism. In the Fe-16Cr-12Ni alloy individual grains of transform to grains of reversed of similar size and shape. In the carbon-containing alloy there is evidence of break-up of the grains on reversion. An increase in the strength results from reversion and this is attributable mainly to the high dislocation density of the reversed . 相似文献
13.
AC electrical properties of 410 nm think 30 at.wt% Cu-70 at.wt% GeO2 thin films are reported for the frequency range 104 to 106 Hz and temperature range 150 to 425 K. The loss tangent (tan ) and the dielectric loss (/0) are found to show striking minima around a cut-off frequency 105 Hz. In the lower frequency range (105 Hz), 1()
s
T
n
is obeyed with s (0 to 0.51) increasing as a function of temperature and n (0.10 to 0.14) showing a very weak temperature dependence. In the higher frequency region (105 Hz), 1() and /0 increase sharply leading to the quadratic behavior of 1() with s equal to 2. These processes are discussed by analyzing an equivalent circuit which shows that at lower frequencies, the effects of series resistance in leads and contacts can be neglected, while at higher frequencies such effect give rise to spurious 2 dependance for the conductance. A weakly activated AC conductivity and a frequency exponent s that increases with increasing temperature suggest that the low frequency behavior originates from carrier migration by tunneling process. 相似文献
14.
Yu. A. Buevich N. A. Kolesnikova S. M. Éllengorn 《Journal of Engineering Physics and Thermophysics》1979,37(5):1282-1289
The distribution of gas flows in the vicinity of the jet is discussed and the conditions of disruption of the static equilibrium of the bed, the formation and growth of a cavity, and the jet breakthrough of the bed are investigated qualitatively.Notation
a, b
functions calculated in [11]
- C, C
constants in (7)
- F
derivative of the complex potential
- f
function in (6)
- G
function defined in (19)
- H
dimensionless height of bed
- h
height of cavity
- k
coefficient introduced in (15)
- p, po
pressure inside bed and in cavity
- p
dimensionless pressure drop
- Q, q
dimensional and dimensionless jet flow rates
- q1, q2
critical values
- T
dimensionless height of cavity
- T0, T1 T1, T2
characteristic values of T
-
u,v
filtration velocities
- u, u*
initial filtration velocity in the bed and minimum fluidization velocity
- uo
velocity scale introduced in (14)
- u *
velocity scale introduced in (14)
- u*
velocity of fictitious flow defined in (15)
- U
complex velocity
- Z=X+iY, z=x+iy
dimensionless coordinates
- z=x+iy
dimensional coordinates
-
coefficient of hydraulic resistance
-
parameter from (5)
-
specific weight of particles' material
-
porosity
- =+i
coordinates in the plane obtained from z=x+iy as a result a of conformai transformation
-
m
value of giving a minimum of the function G
-
f complex and real flow potentials
-
angle of internal friction
-
stream function
-
angle of inclination of boundaries of the region of plastic flow to the vertical
Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 37, No. 5, pp. 804–812, November, 1979. 相似文献
15.
Assistant Prof. M. E. Erguven 《Acta Mechanica》1986,61(1-4):165-174
Summary The problem of torsion of a transversely isotropic nonhomogeneous and elastic semiinfinite solid due to certain distributions of shearing forces prescribed on the plane boundary has been considered. The elastic properties of the material are continuous function of position. The shear moduli of the material are chosen asC
ii
(z) =
ii
cosh2
(kz), i=4, 6 where
ii
andk are constants. The aim of this paper is to determine the torsional deformation and shear stresses in the semi-infinite solid.With 1 Figure 相似文献
16.
Yttria-stabilized hafnia-zirconia thermal barrier coatings: The influence of hafnia addition on TBC structure and high-temperature behaviour 总被引:1,自引:0,他引:1
The search for more reliable and durable thermal barrier systems is a key factor for future aircraft turbine engines success. Hafnia is therefore an attractive ceramic component due to its similarity to zirconia and its elevated structural transformation temperatures. We report here structural and thermomechanical investigations of various plasma-sprayed coatings composed of ZrO2+x mol% HfO2 (x=0, 25, 50 and 100), partially stabilized by 4.53 mol% yttria. X-ray diffraction studies show that, a metastable, non-transformable, high yttrium content, tetragonal solid solution is the only phase observed on the as-sprayed samples. This phase is crystallographically equivalent to the t phase described for classical yttrium-partially stabilized zirconia (Y-PSZ) thermal barrier coatings (TBCs). Upon high-temperature annealing in air (T=1200C), however, the return of this t phase to equilibrium differs from the classical tt+c reaction. According to literature data, reactions of the type tt+c+m should prevail at the highest hafnia contents (x50). Indeed, important quantities of monoclinic phase are accordingly being observed upon cooling. Thermal cycling of TBC samples in air has been performed at 1100C. The Young's modulus of the ceramic coating, which progressively increases when hafnia is substituted for zirconia, has a strong influence on TBC thermomechanical resistance. 相似文献
17.
An investigation is reported of the constitution of the 75 at % nickel section of the Ni-Cr-Al-Mo system in the temperature range 1523 to 1073 K. Alloys in the region 10 to 20 at % Al were annealed at 1523, 1273, and 1073 K, respectively, and subjected to electron microprobe analysis, X-ray diffraction, and microscopical and hardness examination. Constitutional data are presented as partial isothermal sections and as vertical sections. At 1523 K the section consists only of fields containing ,+ and , the last mentioned phase being predominant. With decreasing temperature the and + fields increase in extent. Also, the NiMo and Ni3Mo phases were encountered in the ternary Ni-Al-Mo alloy studied. The quaternary + alloys showed small lattice mismatch values, i.e. up to 0.25%. Raft like morphologies of were found in the quaternary alloys, resulting from directional coarsening. Observations of as-cast structures are also reported. 相似文献
18.
Akira Tominaga 《Journal of Low Temperature Physics》1974,16(5-6):571-589
We present measurements of the critical opalescence of helium-4. The results are analyzed by the Einstein and Ornstein-Zernike theory and the power laws. We obtain ==1.17±0.02, ==0.62±0.1,/=4.5±0.3,P
c
=1706.008 mm Hg, andT
c
=5,189.863 mK (T
58
). The critical behavior of helium-4 is almost the same as that of classical fluids and the influence of the quantum nature of helium-4 is not as evident as has been claimed. 相似文献
19.
Martensitic transformations in Ti-Mo alloys 总被引:5,自引:0,他引:5
A detailed investigation has been made of the structure of alloys of the Ti-Mo system containing up to 10wt% Mo, water-quenched from the-phase region. With increase in molybdenum content, the martensite structure changes from hexagonal () to orthorhombic () at 4 wt% Mo, and at 10 wt% Mo, the structure is completely retained . For alloy compositions <4 wt% Mo, there is a diffusional component in the transformation of the -phase at the quench rates employed. There is a transition, with increase in molybdenum content, in morphology (from massive to acicular) and in substructure (from dislocations to twins). However, the transitions in crystallography, morphology and sub-structure are not directly related to one another except for an abrupt loss of dislocation substructure at the/ transition. The to crystallographic transition has the characteristics of a second order transformation, and evidence has been obtained of the existence of a spinodal within the metastable orthorhombic system. The orthorhombic martensites of Ti-6 and 8 wt% Mo decompose during quenching producing a fine modulated structure within the martensite plates, consistent with a proposed spinodal mode of decomposition. 相似文献
20.
S. Kalachandra R. J. Minton T. Takamata D. F. Taylor 《Journal of materials science. Materials in medicine》1995,6(4):218-222
Although there is a significant clinical interest in suitable polymer-based soft liners, none have proven fully satisfactory in actual use. As a result there has been continued interest in the development of new materials. One major weakness in the development of improved materials has been the lack of clear understanding of structure/property relationships. This paper deals with the determination of visco-elastic properties such as E (Storage modulus) and tan (damping factor) of four commercial materials. They represent the broad range of chemical types available for denture base soft liners. A DMA study of four materials: (1) Molloplast B (silicone); (2) Novus (phosphazine); (3) Kurepeet (fluropolymer); and (4) Super Soft (acrylic) was made using a Perkin-Elmer DMA-7. Samples were made following the manufacturers' instructions, in the form of sheets 1.5 mm thick and 15.0 mm square. The samples were tested compressively using a 3 mm flat tip probe cycled at a frequency of 1 Hz. Wet and dry specimens were evaluated for E and tan over a 5–95°C temperature range. Water sorption was determined gravimetrically at 37°C. Changes in E between the wet and dry conditions for Molloplast (B), Kurepeet and Super Soft were insignificant. A significant increase in tan for wet Novus was observed, suggesting that the material is capable of dissipating more energy. The wet modulus (E) is about 42% lower than the dry modulus (E). This difference may be attributed to the very high water sorption (34%) of Novus. i.e. the significant decrease in E indicates plasticization due to sorbed water. Changes in visco-elastic properties seem to occur for materials which take up large amounts of water at 37°C. DMA is found to be a useful supplement for the evaluation of soft lining materials in conjunction with the standard mechanical test methods. 相似文献