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The possibility of fractal benzenoids built upon a (deterministically) regular self-similar structure are proposed. Of various possibilities considered a simpler class of “trigonal” structures is identified. Possible directed synthetic schemes are described. Further, Kekulé structure counts are made as well as conjugated-circuits estimates of resonance energies. Results, for the general trigonal class as well as for particular cases are given. 相似文献
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分形论在无机材料研究中的应用 总被引:2,自引:0,他引:2
介绍了分形论在无机材料表面研究、无机薄膜材料、梯度功能材料及无机材料断裂研究等方面的应用情况,并展望了其在玻搪材料中的应用前景. 相似文献
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The morphology of a novel diblock copolymer, poly(norbornene methanol)-b-poly(norbornene dicarboxylic acid), was investigated before and after metal oxide doping by transmission electron microscopy (TEM) using a novel iodine vapor staining method to image the undoped polymer. A lamellar morphology was observed by TEM after staining the undoped diblock copolymer with iodine vapor. Thin film surface doping resulted in a confinement of the iron oxide nanoparticles within the lamellar domains. Spherical nanoparticle aggregates were observed through a bulk solution doping method. It was observed that the particles were templated by the underlying lamellar structure of the copolymer when the thin film surface doping method was used. 相似文献
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根据分形理论,对某油田区块的离心毛管压力曲线进行分形研究及分形维数的计算结果表明,离心毛管压力曲线具有很好的整体分形特征,比较驱替毛管压力曲线和吸入毛管压力曲线的分维值,发现两者相差很小,具有很好的一致性,说明它们都能较好的描述该区块的孔隙特征;另外,对驱替毛管压力曲线进行分段线性回归后发现,分段分形线性回归相关性好于整体分形,但整体分形更能反映储层岩心的孔隙结构特征。计算的驱替毛管压力分维值和岩样的渗透率有较好的对数关系,和孔隙度具有一定的线性相关性。 相似文献
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CaCO3阻垢剂的分形评价 总被引:6,自引:0,他引:6
1前言自从Mandelbrot[‘]在研究不规则形状和过程中提出分形概念以来,分形理论已广泛地应用于自然科学的许多领域。CaCO。结晶垢由于在生长过程中受诸多因素的影响,垢表面存在着许多晶体缺陷、凹凸和破语,呈现出复杂的表面形态;阻垢剂的加人,使得CaCO3垢晶格发生畸变l‘],表面不规性增加。并且CaCO。结晶垢表面形貌具有自相似的特点,已不能用传统的欧几里德几何加以描述。本文运用分形概念,对模拟循环冷却水系统中常用的CaCO。阻垢剂PBTCA(2一磷酸了烷一l,2,个三核酸)、HEDP(羟基… 相似文献
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Fractal characteristic of three Chinese coals 总被引:1,自引:0,他引:1
Experimental and theoretical investigation about coal/char structure is presented. Surface structures of parent coal and char with different burn-off ratios were analyzed. We introduced the fractal theory into Scanning Electron Microscopy image analysis and utilize the particle surface fractal dimension (Dps) to quantitatively describe the surface character of coal/char particles. Dps of three Chinese coals reach their maximum in the 35-45 wt% char burn-off interval and then decrease with increasing carbon burn-off ratio. The inner-pore information of coal/char particles was determined by N2 isotherm adsorption/desorption. Using fractal BET model, internal surface fractal dimension (Ds) of coal/char particles was calculated. The Ds change trend of three Chinese coals is similar to their SBET development. It means the Ds can quantitatively describe the inner pore structure character of coal/char particles. 相似文献
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Lech Gmachowski 《Polymer》2007,48(15):4316-4321
A fractal aggregate model is presented for chain molecules which are described by different statistics on different length scales. It describes the macromolecular chains as aggregates composed either of non-porous monomers or thermal blobs. The mass of non-porous monomer and the thermal blob mass are both dependent on the solvent quality. The blob mass can be calculated knowing the non-porous monomer mass in a solvent under consideration and that at the theta condition. Both the quantities can be deduced from the solution properties. The values of thermal blob mass normalized by that of monomer, deduced from intrinsic viscosity data for several polymers, form a dependence on Mark-Houvink-Sakurada exponent. This dependence is confirmed by the solvent quality dependence of the polymer mass at the onset of excluded volume behavior and some values obtained from sedimentation coefficients. 相似文献
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积炭催化剂再生的分形维模型 总被引:3,自引:0,他引:3
将分形维理论引入积炭催化剂与再生气体的烧炭反应系统,提出了积炭催化剂的分形维模型。在拟稳态条件下,按缩核模型求得解析解,并在此基础上分析了当反应受气膜扩散控制、灰层扩散控制和化学反应控制时,分形维对再生过程的影响。通过实验和参数估计确定了积炭催化剂表面的分形维数在2~3之间,从而验证了模型的正确性。 相似文献
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Characterization of floc size, strength and structure under various coagulation mechanisms 总被引:7,自引:0,他引:7
Flocs generated by various coagulation mechanisms exhibit different size, strength and structure. The properties and fractal dimensions of flocs formed under three common coagulation mechanisms, i.e. charge neutralization, sweep and bridging, were investigated at various hydraulic conditions. The results showed that the floc size decreased with the increasing average velocity gradient G and the stable floc size exponent γ was of the following hierarchy: charge neutralization (0.6107) > sweep (0.5618) > bridging (0.3674). Furthermore, fractal dimensions of flocs were the highest when formed by sweep and the lowest when generated by bridging flocculation. The mass fractal dimensions measured by light scattering were between 2.0 and 3.0 and the floc strength was between 0.01 and 0.58 N m− 2. An intrinsic unity of the relationship among floc size, fractal dimensions, floc strength under the three coagulation mechanisms was demonstrated. 相似文献
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Dongming Tang Alejandro G. Marangoni 《Journal of the American Oil Chemists' Society》2008,85(6):495-499
The microstructure of fat crystal networks is closely related to rheological properties of fat products, and thus is of particular
interest to food scientists. The fractal dimensions of fat crystal networks calculated by microscopy methods such as box-counting,
D
b, particle-counting, D
f, and mass fractal dimension, D
m, have been extensively employed to quantify the microstructure of fats. This work revealed the microstructural basis of D
b, D
f, and D
m in 3D space through both computer simulation and experiments on the high melting fraction of milk fat crystal networks. Similar
to our previous simulation study on the fractal dimensions of fat crystal networks in 2D space, D
b is sensitive to crystal size, area fraction, and not sensitive to distribution orderliness of crystals, which is the percentage
of evenly distributed fat crystals within the simulated fat crystal networks. D
f and D
m were not affected by any of the microstructural factors studied in the simulation. 相似文献
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Fractal geometry has been widely used in various dried materials and drying processes. This review summarizes the related studies and identifies the opportunities for future investigation. The application of fractal concept on drying can be categorized into describing microscopic and macroscopic structure of material in drying with fractal geometry and theoretical models with fractal theory for drying mechanism. And also, the capillary and network models for drying of capillary porous media are discussed and a fractal tortuous capillary model for drying of capillary porous media is proposed. From the selected examples, it is clear that the fractal theory has many advantages for identifying the complex structure of products and investigating drying mechanism. At last, some comments are made for the current investigations and also some prospects for the future development of this field are pointed out. 相似文献
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Fractal Pore Network Simulation on the Drying of Porous Media 总被引:2,自引:0,他引:2
Based on the knowledge of fractal geometry, physics of flow through porous media, and transport process principle, a fractal pore network model for the drying process of a natural porous body was established in this article. This model takes various factors into consideration, such as liquid-phase flow, vapor-phase diffusion, temperature gradient, and pore microstructure characteristic. The drying dynamics characteristics of potato slices were obtained by the simulation of a fractal pore network model. The simulation results of the fractal pore network model were contrasted with those of a regular one and the experimental data, respectively. The wet patches were observed on the potato slices during the drying experiments, and it was validated by the drying simulation. The results indicate that the drying kinetics from the fractal pore network model, as well as the distributions of moisture and temperature inside the porous body, are more consistent with that of the drying experiments than that of the regular one, and the throat size distribution in the pore network of the porous media has a notable influence on the drying process. 相似文献