大理石粉对水泥基胶凝材料性能影响研究

研究了大理石粉对水泥基胶凝材料流动性、强度和干缩的影响。研究得出,大理石粉增加了水泥胶砂的流动性,大理石粉掺量越大其流动度越大。水泥胶砂1 d和3 d抗折和抗压强度随大理石粉掺量增加先增大后减小,大理石粉掺量为5%其抗折和抗压强度最大;水泥胶砂7、28、56 d抗折和抗压强度随大理石粉掺量增加而减小。水泥胶砂干缩随大理石粉掺量增加呈现先减小后增大的规律,大理石粉掺量为20%时其干缩最小。     

石灰石粉掺量对水泥性能的影响

为了研究石灰石粉掺量对水泥性能的影响,测试0％、5％、10％、20％、35％掺量的石灰石粉对水泥胶砂3d、7d、28d的抗压强度、抗折强度及收缩率变化情况,利用X射线衍射分析的方法分析了水泥浆体水化产物的变化情况.研究表明,随着石灰石粉掺量的增加,水泥砂浆的抗压强度、抗折强度及干燥收缩率均先增加后减少.掺量为10％时,...     

黏土及石灰石粉对水泥浆体性能的影响

通过不同掺量的黏土及石灰石粉对水泥浆体性能的影响研究,探讨石灰石粉对掺入黏土的水泥浆体性能的改善效应。结果表明:随着黏土掺量的增加水泥净浆流动度明显降低,随着石灰石粉掺量的增加水泥净浆流动度明显增加。当黏土与石灰石粉复掺时,掺入石灰石粉能够改善黏土对水泥净浆流动性不利的影响,提高水泥净浆流动度。当黏土等质量替代机制砂时,黏土掺量小于4%时,水泥胶砂3、28d的抗折、抗压强度并没有降低,当黏土掺量大于4%时,水泥胶砂3、28d的抗折、抗压强度随着黏土掺量的增加明显降低。当石灰石粉等质量替代机制砂时,水泥胶砂各龄期的抗折、抗压强度随着石灰石粉掺量的增加而降低。当掺入2%黏土,石灰石粉的掺量对于水泥胶砂3、28d抗折强度影响较小,水泥胶砂3、28d抗压强度随着石灰石粉掺量的增加而降低。综合水泥净浆流动度和水泥胶砂强度的变化规律,当有黏土存在时,石灰石粉的掺量小于12%时水泥净浆流动度和胶砂强度综合效果较好。     

复合掺合料对水泥胶砂流动度和长期强度的影响

采用粉煤灰(F)、矿渣粉(Sl)、硅灰(Si)和石灰石粉(L)复合组成5种复合矿物掺合料,研究了复合掺合料的组成和掺量对水泥胶砂流动度、长期抗压强度和抗折强度的影响。结果表明:掺粉煤灰和石灰石粉的FSlL和FL复合掺合料流动性较好,流动度比达到110%以上;掺硅灰的FSlSi和SlSiL复合掺合料流动性较差,流动度比在80%左右;5种复合掺合料在30%、40%、50%掺量下,胶砂试件720 d抗压强度和抗折强度均达到纯水泥试件的110%~120%;FSlSi、FSl和FL复合掺合料随着掺量的提高,长龄期胶砂抗压强度有所增加,抗折强度发展趋势与抗压强度相同;SlL和SlSiL复合掺合料随着掺量的提高,长龄期胶砂抗压和抗折强度均略有下降。     

石灰石粉与粉煤灰作为胶凝材料的力学性能互补研究

采用相同质量的胶凝材料配制石灰石粉水泥砂浆和粉煤灰水泥砂浆,研究石灰石粉以不同掺量取代水泥后对水泥砂浆抗折、抗压强度的影响。结果表明,单掺10%~20%石灰石粉时,对水泥砂浆3d抗折和抗压强度提高较大,28d抗折强度增长较大,抗压强度提高较小。通过对粉煤灰取代部分水泥的胶砂强度试验显示,粉煤灰对混凝土的早期强度贡献很小,单掺10%~30%粉煤灰时,28d强度增长很大。论证石灰石粉与粉煤灰力学性能的互补性,石灰石粉与粉煤灰双掺作为胶凝材料性能更加优越。     

石灰石粉与活性矿物掺合料的协同效应

针对石灰石粉与不同活性矿物掺合料协同效应的问题,分析石灰石粉分别与粉煤灰、矿渣、硅灰复掺对水泥胶砂抗折、抗压强度的影响,并采用XRD微观测试方法分析其机理。试验结果表明:石灰石粉与活性掺合料协同作用有助于提高水泥胶砂强度,石灰石粉掺量为10%、活性掺合料掺量为20%时强度最大;微观测试分析发现粉煤灰、矿渣与硅灰能促进石粉的水化反应,其水化产物为碳铝酸钙(Ca_4Al_2O_6·CO_3·11H_2O);石粉可以更好地激发活性掺合料的活性,为水化产物提供成核基底。     

表面改性废旧轮胎橡胶粉对水泥胶砂力学性能的影响

为解决废旧轮胎橡胶粉与水泥等材料的融合能力差和掺入水泥胶砂中会导致试件强度降低等问题,选用司班40(山梨糖醇酐单棕榈酸酯)对废旧轮胎橡胶粉进行表面改性。通过水泥胶砂力学性能试验和微观角度分析,研究了不同粒径和掺量的改性、未改性橡胶粉对不同龄期水泥胶砂的抗折强度和抗压强度的影响。结果表明:水泥胶砂试件强度随橡胶粉掺量的增加而减小,且抗压强度的减小幅度大于抗折强度;改性橡胶粉的亲水性明显增强,表面更圆润、连续,与水泥胶砂的融合能力有所提高;改性橡胶粉水泥胶砂试件的抗压强度和抗折强度有所提高。     

掺可再分散乳胶粉自流平水泥基道路修复砂浆的研究

在研究了添加剂乳胶粉对水泥净浆物理和胶砂力学性能基础上,配制得增强型水泥基道路自流平修补砂浆配方。性能测试表明:掺可再分散乳胶粉的水泥胶砂样抗折强度高于空白样,并随乳胶粉掺量增加而上升,其1d抗折强度均>3.5MPa;抗压强度在整个测试龄期内比空白样略为降低,但随乳胶粉掺量增加而减小;掺入乳胶粉后凝结时间增加,并随掺量增加而相应的延长,这与其水泥净浆早期水化的电阻率测定结果相符。此外,自流平道路快速修补砂浆配方样初始流动度157mm,1d抗折强度为4.35MPa、抗压强度达21.32MPa;28d抗折强度为10.34MPa、抗压强度达51.53MPa,且抗收缩性和耐磨性能优良。     

镍铁渣粉对水泥基复合材料性能的影响研究

研究了镍铁渣粉掺量对镍铁渣粉-水泥复合胶凝材料标准稠度用水量、凝结时间的影响,分析了镍铁渣粉-水泥胶砂试件的抗压强度、抗折强度,探讨了镍铁渣粉-硅灰-水泥胶砂试件的力学性能。结果表明：镍铁渣粉-水泥复合胶凝材料的标准稠度用水量、凝结时间均与镍铁渣粉掺量呈正相关,而镍铁渣粉-水泥胶砂试件的抗压强度、抗折强度均与镍铁渣粉掺量呈负相关,且镍铁渣粉的掺量不宜大于30%;硅灰能有效改善镍铁渣粉-硅灰-水泥胶砂试件的内部结构,提高其强度,且镍铁渣粉与硅灰的总掺量不宜大于30%,镍铁渣粉和硅灰的质量比不宜小于1。     

钢渣粉对PVA纤维水泥基复合材料力学性能与韧性的影响

利用钢渣粉等质量替代20％、40％、60％、80％的水泥制备了PVA纤维水泥基复合材料胶砂试件,并进行了抗折、抗压试验和薄板四点弯曲试验,分析了钢渣粉对PVA纤维水泥基复合材料力学性能和韧性的影响.结果表明:随着钢渣粉掺量的增加,试件的抗折、抗压强度均呈下降趋势,且抗压强度损失较抗折强度快;当钢渣粉掺量为20％时,试件...     

粗集料强度对混凝土抗折强度的影响

试验研究了4种粗集料(碎石、钢集料、砂浆、页岩陶粒)与3种抗压强度等级水泥砂浆基体组合的混凝土的抗折强度及其发展规律.结果表明,粗集料与水泥砂浆基体的协调性对混凝土抗折强度影响十分显著.当粗集料强度和弹性模量与水泥砂浆基体相匹配时,增加粗集料强度可提高混凝土抗折强度,但粗集料强度和弹性模量过高反而会因较大的应力集中而降低混凝土抗折强度;当粗集料强度比水泥砂浆基体抗压强度低时,单纯通过增大水泥砂浆基体抗压强度来提高混凝土抗折强度的效果不明显;粗集料与水泥砂浆基体在抗压强度和弹性模量上的差异对混凝土抗折强度及其发展规律有很大影响.只有在两者相互协调的基础上,才能充分发挥粗集料和水泥砂浆基体的作用.     

Thaumasite form of sulfate attack in limestone cement mortars: A study on long term efficiency of mineral admixtures

Concrete and mortar made from limestone cement may exhibit a lack of durability due to the formation of thaumasite. The addition of minerals that improve the concrete durability is expected to slow down the formation of thaumasite. In this work the effect of natural pozzolana, fly ash, ground granulated blastfurnace slag and metakaolin on the thaumasite formation in limestone cement mortar is examined. A limestone cement, containing 15% w/w limestone, was used. Mortar specimens were prepared by replacing a part of limestone cement with the above minerals. The specimens were immersed in a 1.8% MgSO₄ solution and cured at 5 and 25 °C. The status of the samples after a storage period of 5 years was reported based on visual inspection, compressive strength, mass measurements, ultrasonic pulse velocity measurements and analytical techniques. It is concluded that the use of specific minerals, as partial replacement of cement, inhibits thaumasite formation in limestone cement mortar.     

掺矿渣粉和减水剂的HEMC水泥砂浆力学性能

研究了掺矿渣粉和高效减水剂的羟乙基甲基纤维素改性水泥砂浆的力学性能（包括抗压强度、抗折强度、弹性模量、粘结抗拉强度）及其与新拌砂浆体积密度和硬化砂浆孔隙率的关系。掺加减水剂、矿渣粉和羟乙基甲基纤维素后,砂浆的抗压强度与新拌砂浆体积密度和硬化砂浆孔隙率密切相关,抗折强度与之部分相关,粘结抗拉强度则与之无关。减水剂和矿渣粉可增加砂浆的密实度,减小孔隙率,从而使砂浆的抗压强度、抗折强度、粘结抗拉强度和弹性模量得到提高;羟乙基甲基纤维素虽可保持砂浆的粘结抗拉强度稳定,但却使抗压强度和弹性模量降低,减小剂、矿渣 粉和羟乙基甲基纤维素的共同作用,即增加了砂浆的粘结抗拉强度,又使砂浆有足够的抗压强度、抗折强度和弹性模量,当羟乙基甲基纤维素掺量被抑制在一定范围内时,砂浆便可用作混凝土桥面材料及其修补材料。     

不同粒径废玻璃粉对水泥胶砂力学性能的影响

采用3种粒径(20、200、2 000目)的废玻璃粉等体积取代水泥胶砂中的标准砂,体积取代率分别为5%、10%、15%、20%,研究玻璃粉粒径和掺量对水泥胶砂的抗压强度和抗折强度的影响,并对玻璃粉水泥胶砂强度随龄期的变化规律进行了分析讨论。结果表明:不同粒径玻璃粉水泥胶砂的强度随玻璃粉掺量的变化规律存在较大的差异;在玻璃粉掺量相同的情况下,掺入较大粒径玻璃粉的水泥胶砂强度明显降低,玻璃粉粒径越小,强度降低程度越小,当玻璃粉粒径达到微米级,水泥胶砂的抗压强度和抗折强度均显著提高;玻璃粉水泥胶砂的抗压强度随龄期增长,早期强度增加的较快,后期发育增速变缓,而抗折强度早期增长的幅度较大,后期发育比较平缓。     

Development of a high-temperature-resistant mortar by using slag and pumice

The effects of high temperatures up to 900 °C on the mechanical properties and the microstructure of cement-based pumice mortars incorporating different amounts of ground granulated blast furnace slag (GGBFS) were investigated in this study. The residual compressive and flexural strength of mortar specimens were determined after exposure to high temperatures. The results have indicated that the effect of GGBFS incorporation on high-temperature resistance of pumice mortar is shown significantly at 900 °C. At this temperature level, the mortar containing 80% GGBFS exhibited only 23% and 28% compressive strength loss when cooled in air and water, respectively, where as mortars without GGBFS lost almost 70% of their strength. Furthermore, none of the GGBFS incorporated mortar specimens showed compressive strength loss up to 600 °C when cooled in air. The most severe conditions in terms of strength loss due to high temperatures were flexural loading and water cooling case.     

Use of diatomite as partial replacement for Portland cement in cement mortars

The aim of the present study is to investigate the use of diatomite as a partial replacement for cement in the production of cement mortar. Diatomite was used at 0%, 5%, 10% and 15% replacement by weight for cement while sand and water quantities were kept constant. Compressive and flexural strength, freeze–thaw resistance, sulfate resistance, water absorption and dry unit weight of the mortars were determined. The compressive and flexural strength decreased with increasing diatomite content for all curing periods. However the compressive strength of the cement mortar which was produced with 5% diatomite content complied with the minimum specified value of given in the standards. Diatomite replacement generally increased the compressive strength of the cement mortar after 25 freezing and thawing cycles. Water absorption of the mortars decreased with the increase of diatomite content except the mortar containing of 15% diatomite. Dry unit weight of the cement mortar was lower than the control mortar because of high porosity of diatomite. The expansion of the cement mortar bars immersed in 5% sodium sulfate solution decreased with increasing diatomite content and generally the sulfate resistance of the mortars was higher than that of the control mortar.     

胶粉对砂浆抗折抗压性能的影响

探讨了废旧轮胎胶粉的细度和掺量对水泥砂浆抗折抗压强度的影响。研究结果表明：胶粉的掺入会降低水泥砂浆的抗折抗压强度并随胶粉掺量的加大而减小。在等掺量的条件下,胶粉越细,砂浆的抗折抗压强度越低。     

硫酸和硫酸钠混合溶液对砂浆的腐蚀作用

用普通硅酸盐水泥和硫铝酸盐水泥的混合水泥以及磨细高炉矿渣和聚合物乳液配制了4种水泥砂浆,研究了这些水泥砂浆试样在1%(质量分数,下同)硫酸加10%硫酸钠的混合溶液中浸泡不同时间后的质量变化和强度变化.结果发现,混合溶液对4种水泥砂浆都具有强烈的腐蚀作用.磨细高炉矿渣能显著提高砂浆的耐腐蚀性能;进一步添加聚合物乳液(聚胶比为10%),则砂浆的抗表面剥落性能有很大改善,其中尤以苯丙乳液与丁苯乳液的混合乳液改性砂浆效果更好,但添加聚合物乳液会导致砂浆的抗压强度大大降低.此外,水泥砂浆试样在混合溶液及清水中浸泡后,它们的抗压强度比值要比它们的抗折强度比值对硫酸/硫酸钠腐蚀介质更为敏感.     

Mechanical properties and microstructure of multilayer graphene oxide cement mortar

This study reports on the effects of multilayer graphene oxide (MGO) on compressive strength, flexural strength, and microstructure of cement mortar. The cement mortar was prepared with type P. II. 52.5 Portland cement, standard sand, and MGO. Four mixes were prepared with inclusion of MGO (0%, 0.02%, 0.04%, and 0.06% by weight of cement). The testing result shows that the compressive of GO-cement mortar increased by 4.84%–13.42%, and the flexural strength increased by 4.37%–8.28% at 3 d. GO-cement mortar’s compressive strength and flexural strength at 7 d increased by 3.84%–12.08% and 2.54%–13.43%, respectively. MGO made little contribution to the increases of compressive strength and flexural strength of cement mortar at 28 d. The results of X-ray diffraction (XRD), scanning electron microscope (SEM), and nitrogen (N₂) adsorption/desorption tests show that the types of hydration products and crystal grain size did not change after adding MGO. Still, it can help to improve the microstructure of the cement mortar via regulating hydration products and can provide more condensed cores to accelerate hydration. Furthermore, the regulating action of MGO for the microstructure of cement mortar at an early age was better than that at 28 d.