Investigation on the thermal decomposition performance and long-term storage performance of HNIW-based PBXs through accelerated aging tests

ABSTRACT

2,4,6,8,10,12-Hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (HNIW)-based polymer-bonded explosives (PBXs) were prepared through an aqueous suspension method using cellulose acetate butyrate (CAB) or fluorine rubber F₂₃₁₁ as a binder. Then the variation rules of mass, surface micro-topography, mechanical properties, thermal decomposition performance, detonation velocity and mechanical sensitivity of the samples before and after accelerated aging tests for different durations were measured. Then the variables of the samples that before and after accelerated aging tests for different durations, will be measured, these variables including the variation rules of mass, surface micro-topography, mechanical properties, thermal decomposition performance, detonation velocity, and mechanical sensitivity. The PBX columns showed an acceptable mass loss of less than 1%, after accelerated aging tests. The surface of the PBX samples became more and more uneven as the aging duration prolonged, which was in a good agreement with the order of mass loss. Moreover, the tensile strength, the thermal stability, the detonation velocity and the mechanical sensitivity of the samples were not significantly affected by the aging process, suggesting that the PBXs remained valid after an accelerated aging test at 60°C for 60 days. A further estimation using the modified Arrhenius equation revealed that the storage life at ambient temperature (20°C) of the HNIW-based PBXs was over 10 years, which satisfies the application demands for explosives.     

加氢反应器加速寿命试验研究

对DC10 2加氢反应器服役 5 80 0 0h后的随机试块所加工的焊缝试样在两种温度下进行热处理和冲击试验。结果表明在两种热处理工艺下 ,焊缝材料均产生不同程度的脱脆现象。提出了针对服役材料的加速步冷试验曲线 ,一次修正步冷试验和二次修正步冷试验结果表明 ,该修正步冷曲线能加速材料老化 ,达到加速寿命试验的目的     

Oxidation stability of IGP series hydraulic oils

Chemistry and Technology of Fuels and Oils -     

Treatment of polymer-compounded hydraulic oils by ultrafiltration

Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 11, pp. 11–13, November, 1989.     

油料储运场所安全管理的人性化工作方法

介绍了做好油料储运场所安全管理人性化工作的方法：作为安全管理者应建立健全安全法规，并严格按规章制度办事；鼓励员工学习，以提高安全素质；关爱员工的工作和生活；以身作则，用人格的魅力感召员工：强化安全教育和监督，从而减少事故的发生。     

Electrophysical properties of synthetic lubricating oils and hydraulic fluids

Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 1, pp. 19–23, January, 1988.