Preparation,electrical, mechanical and thermal properties of composite bipolar plate for a fuel cell

A novel composite bipolar plate for a polymer electrolyte fuel cell has been prepared by a bulk-moulding compound (BMC) process. The electrical resistance of the composite material decreases from 20 000 to 5.8 mΩ as the graphite content is increased from 60 to 80 wt.%. Meanwhile, the electrical resistance of composite increases from 6.5 to 25.2 mΩ as the graphite size is decreased from 1000 to 177 μm to less than 53 μm. The thermal decomposition of 5% weight loss of composite bipolar plate is higher than 250 °C. The oxygen permeability of the composite bipolar plate is 5.82×10⁻⁸ (cm³/cm² s) when the graphite content is 75 wt.%, and increases from 6.76×10⁻⁸ to 3.28×10⁻⁵ (cm³/cm² s) as the graphite size is longer or smaller than 75 wt.%. The flexibility of the plate decreases with increasing graphite content. The flexural strength of the plate decreases with decrease in graphite size from 31.25 MPa (1000–177 μm) to 15.96 MPa (53 μm). The flexural modulus decreases with decrease of graphite size from 6923 MPa (1000–177 μm) to 4585 MPa (53 μm). The corrosion currents for plates containing different graphite contents and graphite sizes are all less than 10⁻⁷ A cm⁻². The composite bipolar plates with different graphite contents and graphite sizes meet UL-94V-0 tests, and the limiting oxygen contents are higher than 50. Testing show that composite bipolar plates with optimum composition are very similar to that of the graphite bipolar plate.     

Residual stress measurement of a 316l stainless steel bead-on-plate specimen utilising the contour method

This paper describes the mapping of transverse residual stresses within a single bead-on-plate round robin test specimen. The purpose of these measurements was to quantify the magnitude and shape of the residual stress field arising from a single weld bead laid down on an austenitic stainless steel plate. Measurements were made through the thickness of the specimen using the contour method. The contour method is a new destructive, stress relaxation method allowing the full field residual stress to be measured. Results from these measurements show transverse tensile residual stresses over 150 MPa below the plate surface along the length of the weld bead with peak stresses of up to 210 MPa close to the weld stop position. Finally, as these measurements are insensitive to local microstructure variations within the specimen (i.e. texture or variations in lattice parameter), they are useful in helping to validate diffraction based residual stress measurements made within this round robin measurement program.     

Preparation and properties of high performance nanocomposite bipolar plate for fuel cell

This study aims at developing lightweight and high performance composite bipolar plates for use in polymer electrolyte membrane fuel cells (PEMFCs). The thin polymer composite bipolar plates (the thickness <1.5 mm) containing of vinyl ester resin, graphite powder, organoclay have been fabricated by bulk molding compound (BMC) process. Organoclay was prepared by ionic exchange of montmorillonite (MMT) with three different molecular weight (M_w) of poly(oxypropylene)-backboned diamine intercalating agents. Results indicate that the basal spacing and content of MMT varied with M_w of POP-diamines are critical in determining the resultant mechanical properties for bipolar plates. Flexural strength of MMT composite plates was increased from 30.21 to 45.66 MPa by adding 2 phr of MMT. The flexural strength of the plate was also ca. 38% higher than the pristine graphite plate as the basal spacing of MMT was increased from 1.71 to 5.43 nm. Meanwhile, the unnotched impact strength of the composite plates was increased from 58.11 to 80.21 J m⁻¹. The unnotched impact strength of the plate was ca. 30% higher than that of the original graphite plates as the basal spacing of MMT was increased from 1.71 to 5.43 nm. The limiting oxygen index (LOI) and the UL-94 test revealed that the bipolar plate possesses excellent flame retardant with LOI >50 and UL-94-V0. The thermal decomposition temperature of each MMT composite plate is also higher than 250 °C. In addition, the bulk electrical conductivity of the bipolar plate with different MMT contents and basal spacing of MMT is higher than 100 S cm⁻¹. The corrosion current is less than 10⁻⁷ A cm⁻². Results confirm that the addition of MMT leads to a significant improvement on the performance of the composite bipolar plate.     

Effect of weld angle and axial load on the creep failure behaviour of an internally pressurised thick walled CrMoV pipe weld

This paper describes the results of a finite element investigation of the effects of the weld interface angle and end load on the creep failure behaviour of an internally pressurised thick walled pipe weld, using a steady-state approach with an axisymmetric three-material weld model. The material properties used were those for a (1/2)Cr (1/2)Mo (1/4)V: 2(1/4)Cr 1Mo weldment service-exposed at 565°C but with data obtained at 640°C. The failure lives for each weld situation were predicted from the obtained peak rupture stresses, with a range of weld angles and axial loading. Although the effects are small, there are definite trends. The results obtained have shown that with low or moderate end load, there is a consistent increase in failure life with increasing weld angle. However, when the end load is high, the failure lives slightly reduce with increasing weld angle, θ, when θ>15°. The results presented are useful in the general understanding of the geometry/loading influence on the weld performance in power plant pipelines.     

Performance of an aluminate cement /graphite conductive composite bipolar plate

Aluminate cement/graphite conductive composite bipolar plates were prepared by mould pressing at room temperature. The effects of the graphite content, the mould pressing pressure and mould pressing time on the electrical conductivity and the flexural strength of composite are discussed. The electrical conductivity and the flexural strength of the composite bipolar plates with 60 wt.% graphite content, prepared with a mould pressing pressure of 5 MPa for 10 min, is >100 S cm⁻¹ and 20 MPa, respectively and can be improved by optimizing the mould pressing conditions, especially mould pressing time. The water content of the composite bipolar plate with different graphite contents was also investigated. The water content of the composite bipolar plate is about 6 wt.% with a graphite content of 60 wt.%. This composite bipolar plate contains capillary pores and has hydrophilicity, which is different from other composite bipolar plates. Therefore, it possesses an inner humidifying function and can use the water produced at the cathode for humidifying the proton exchange membrane during the operation of a PEMFC. In addition, the H₂ permeability of the composite bipolar plate is low.     

Creep constitutive equations for parent,Type IV,R-HAZ,CG-HAZ and weld material in the range 565–640 °C for Cr–Mo–V weldments

Creep deformation and rupture data over the temperature range 565–640 °C for the parent, Type IV, refined-heat affected zone, coarse grained-heat affected zone and weld materials, associated with a 0.5Cr–0.5Mo–0.25V ferritic steel parent material welded with a 2.25Cr–1Mo steel, has been collected and used to determine a constitutive equation parameter set. The constitutive equation parameter set has been generated for use in a future investigation to analyse a welded medium-bore branched vessel tested at 590 °C; and, also to permit extrapolation and interpolation over the temperature range 565–640 °C.     

Comparison of biodiesel production from crude Jatropha oil and Krating oil by supercritical methanol transesterification

This work compared the production of biodiesel from two different non-edible oils with relatively high acid values (Jatropha oil and Krating oil). Using non-catalytic supercritical methanol transesterification, high methyl ester yield (85–90%) can be obtained in a very short time (5–10 min). However, the dependence of fatty acid methyl ester yield on reaction conditions (i.e., temperature and pressure) and the optimum conditions were different by the source of oils and were correlated to the amount of free fatty acids (FFAs) and unsaturated fatty acid content in oils. Krating oil, which has higher FFAs and unsaturated fatty acid content, gave higher fatty acid methyl ester yield of 90.4% at 260 °C, 16 MPa, and 10 min whereas biodiesel from Jatropha oil gave fatty acid methyl ester yield of 84.6% at 320 °C, 15 MPa and 5 min using the same molar ratio of methanol to oil 40:1. The product quality from crude Krating oil met the biodiesel standard. Pre-processing steps such as degumming or oil purification are not necessary.     

Photofermentative hydrogen production using purple non-sulfur bacteria Rhodobacter sphaeroides O.U.001 in an annular photobioreactor: A case study

For meeting the increasing demand of energy, biohydrogen production is to be considered in higher yield. Biohydrogen can be produced both by dark and photofermentative process. In this study, the photofermentative pathway is followed by using dl malic acid (IUPAC name: 2-hydroxybutanedioic acid, molecular weight: 134.08744 g mol^?1, molecular formula: C₄H₆O₅) as carbon source. Pure strain of purple non-sulfur (PNS) bacteria: Rhodobacter sphaeroides strain O.U.001 was studied to produce biohydrogen using the photobioreactor. The photobioreactor was constructed aiming the uniform light distribution. The objective of this study was to investigate the performance of 1 L annular photobioreactor operating in indoor conditions. The highest rate of hydrogen production was obtained at 92 h. In the designed photobioreactor, using Rhodobacter sphaeroides strain O.U.001 (initial dl malic acid concentration of 2.01 g L^?1) at an initial pH of 6.8 ± 0.2, temperature 32 ± 2 °C, inoculum volume 10% (v/v), inoculum age of 48 h, 250 rpm (rotation per minute) stirring and light intensity of 15 ± 1.1 W m^?2, the average H₂ production rate was about 6.5 ± 0.1 mL H₂ h^?1 L^?1 media and yield 4.5 ± 0.05 mol of H₂ mol^?1 of dl malic acid. Luedeking–Piret model was applied for the data fitting to determine the relationship between the cell growth and photofermentative hydrogen production. The photofermentative hydrogen production by this PNS bacterium was found to be microbial mixed growth associated function.     

Isolation and characterization of two soil derived yeasts for bioethanol production on Cassava starch

Two ethanol-producing yeast strains, CHY1011 and CHFY0901 were isolated from soil in South Korea using an enrichment technique in a yeast peptone dextrose medium supplemented with 5% (w v^?1) ethanol at 30 °C. The phenotypic and physiological characteristics, as well as molecular phylogenetic analysis based on the D1/D2 domains of the large subunit (26S) rRNA gene and the internally transcribed spacer (ITS) 1 + 2 regions suggested that they were novel strains of Saccharomyces cerevisiae. During shaking flask cultivation, the highest ethanol productivity and theoretical yield of S. cerevisiae CHY1011 in YPD media containing 9.5% total sugars was 1.06 ± 0.02 g l^?1 h^?1 and 95.5 ± 1.2%, respectively, while those for S. cerevisiae CHFY0901 were 0.97 ± 0.03 g l^?1 h^?1 and 91.81 ± 2.2%, respectively. Simultaneous saccharification and fermentation for ethanol production was carried out using liquefied cassava (Manihot esculenta) starch in a 5 l lab-scale jar fermenter at 32 °C for 66 h with an agitation speed of 2 Hz. Under these conditions, S. cerevisiae CHY1011 and CHFY0901 yielded a final ethanol concentration of 89.1 ± 0.87 g l^?1 and 83.8 ± 1.11 g l^?1, a maximum ethanol productivity of 2.10 ± 0.02 g l^?1 h^?1 and 1.88 ± 0.01 g l^?1 h^?1, and a theoretical yield of 93.5 ± 1.4% and 91.3 ± 1.1%, respectively. These results suggest that S. cerevisiae CHY1011 and CHFY0901 have potential use in industrial bioethanol fermentation processes.     

Free convection frost growth in a narrow vertical channel

Processes involving heat transfer from a humid air stream to a cold plate, with simultaneous deposition of frost, are of great importance in a variety of refrigeration equipment. In this work, frost growth on a vertical plate in free convection has been experimentally investigated. The cold plate (0.095 m high, 0.282 m wide) was placed in a narrow (2.395 m high, 0.01 m deep) vertical channel open at the top and bottom in order to permit the natural circulation of ambient air. The cold plate temperature and the air relative humidity were varied in the −40 to −4 °C and 31–85% range, respectively, with the air temperature held fixed at 27 °C (±1 °C). The main quantities (thickness, temperature and mass of frost, heat flux at the cold plate), measured during the time evolution of the process, are presented as functions of the input parameters (relative humidity and cold plate temperature); in particular, the role exerted by the plate confinement on the frost growth is discussed. Data are recast in order to identify compact parameters able to correlate with good accuracy frost thickness, mass and density data.     

Preparation and characterization of new microporous stretched membrane for lithium rechargeable battery

The microporous membrane based on poly(vinylidene fluoride) (PVdF) is prepared with phase inversion method. In addition to phase inversion process, solvent pre-evaporation and uni-axial stretching processes were introduced to enhance tensile strength and ionic conductivity of the membrane.The tensile strength of the membrane after 200% stretching was about 52 MPa, which is four times higher than that of the membrane without stretching. The ionic conductivity of the membrane soaked with liquid electrolyte was also increased from 6.1 × 10⁻⁵ to 8.6 × 10⁻⁴ S cm⁻¹ at room temperature by taking the stretching process.     

Characterization of the cold ductility degradation after aging in centrifugally cast 20Cr32Ni+Nb alloy tube

The mechanical properties (yield stress, ultimate tensile stress and elongation) of alloy 20Cr32Ni + Nb subject to isochronal aging at temperatures between 670 and 820 °C for 200 h were investigated using samples extracted from a centrifugally cast tube. The results confirm the occurrence of embrittlement in the aged samples, with maximum embrittlement observed around 770 °C without significant gain in strength.     

Electricity generation and microbial community structure of air-cathode microbial fuel cells powered with the organic fraction of municipal solid waste and inoculated with different seeds

The organic fraction of municipal solid waste (OFMSW), normally exceeding 60% of the waste stream in developing countries, could constitute a valuable source of feed for microbial fuel cells (MFCs). This study tested the start-up of two sets of OFMSW-fed air-cathode MFCs inoculated with wastewater sludge or cattle manure. The maximum power density obtained was 123 ± 41 mW m⁻² in the manure-seeded MFCs and 116 ± 29 mW m⁻² in the wastewater-seeded MFCs. Coulombic efficiencies ranged between 24 ± 5% (manure-seeded MFCs) and 23 ± 2% (wastewater-seeded MFCs). Chemical oxygen demand removal was >86% in all the MFCs and carbohydrate removal >98%. Microbial community analysis using 16S rRNA gene pyrosequencing demonstrated the dominance of the phylum Firmicutes (67%) on the anode suggesting the possible role of members of this phylum in electricity generation. Principal coordinate analysis showed that the microbial community structure in replicate MFCs converged regardless of the inoculum source. This study demonstrates efficient electricity production coupled with organic treatment in OFMSW-fueled MFCs inoculated with manure or wastewater.     

A novel Al and Y codoped ZnO/n-Si heterojunction solar cells fabricated by pulsed laser deposition

Al and Y codoped ZnO (AZOY) transparent conducting oxide (TCO) thin films were first deposited on n-Si substrates by pulsed laser deposition (PLD) to form AZOY/n-Si heterojunction solar cells. However, the properties of the AZOY emitter layers are critical to the performance of AZOY/n-Si heterojunction solar cells. To estimate the properties of AZOY thin films, films deposited on glass substrates with various substrate temperatures (T_s) were analyzed. Based on the experimental results, optimal electrical properties (resistivity of 2.8 ± 0.14 × 10^?4 Ω cm, carrier mobility of 27.5 ± 0.55 cm²/Vs, and carrier concentration of 8.0 ± 0.24 × 10²⁰ cm^?3) of the AZOY thin films can be achieved at a T_s of 400 °C, and a high optical transmittance of AZOY is estimated to be >80% (with glass substrate) in the visible region under the same T_s. For the AZOY/n-Si heterojunction solar cells, the AZOY thin films acted not only as an emitter layer material, but also as an anti-reflected coating thin film. Thus, a notably high short-circuit current density (J_sc) of 31.51 ± 0.186 mA/cm² was achieved for the AZOY/n-Si heterojunction solar cells. Under an AM1.5 illumination condition, the conversion efficiency of the cells is estimated at only approximately 4% (a very low open-circuit voltage (V_oc) of 0.24 ± 0.001 V and a fill factor (FF) of 0.51 ± 0.011) without any optimization of the device structure.     

Improved electrochemical capacitive characteristics of the carbon nanotubes grown on the alumina templates with high pore density

Specific capacitances of the carbon nanotube (CNT) electrodes are significantly enhanced by using the nanoporous alumina templates with high pore density and uniform pore diameter. Well-ordered nanoporous alumina templates were fabricated by a two-step anodization method by applying a constant voltage of 25.0 V or 20.0 V in sulfuric acid solution. The cylindrical pore diameter and pore density of the templates prepared at the anodizing voltage of 25.0 V or 20.0 V were 53 ± 1 nm and 3.1 × 10¹⁰ cm⁻² or 38 ± 2 nm and 3.8 × 10¹⁰ cm⁻², respectively. The CNTs with uniform diameters of 44 ± 2 nm in the 53 nm pores and of 32 ± 5 nm in the 38 nm pores, respectively, were grown on the porous alumina template. For the electrochemical double layer capacitors (EDLCs), the aluminum metal below the porous alumina layer was used as a current collector for the CNT electrode without any binding material. The EDLC characteristics were analyzed by measuring the capacitances from cyclic voltammograms and the charge–discharge curves. A maximum value of 175 F g⁻¹ was achieved for the specific capacitances of the CNT electrodes prepared on the alumina templates with high pore density.     

Bioethanol production by a flocculent hybrid,CHFY0321 obtained by protoplast fusion between Saccharomyces cerevisiae and Saccharomyces bayanus

Fusion hybrid yeast, CHFY0321, was obtained by protoplast fusion between non-flocculent-high ethanol fermentative Saccharomyces cerevisiae CHY1011 and flocculent-low ethanol fermentative Saccharomyces bayanus KCCM12633. The hybrid yeast was used together with the parental strains to examine ethanol production in batch fermentation. Under the conditions tested, the fusion hybrid CHFY0321 flocculated to the highest degree and had the capacity to ferment well at pH 4.5 and 32 °C. Simultaneous saccharification and fermentation for ethanol production was carried out using a cassava (Manihot esculenta) powder hydrolysate medium containing 19.5% (w v^?1) total sugar in a 5 l lab scale jar fermenter at 32 °C for 65 h with an agitation speed of 2 Hz. Under these conditions, CHFY0321 showed the highest flocculating ability and the best fermentation efficiency for ethanol production compared with those of the wild-type parent strains. CHFY0321 gave a final ethanol concentration of 89.8 ± 0.13 g l^?1, a volumetric ethanol productivity of 1.38 ± 0.13 g l^?1 h^?1, and a theoretical yield of 94.2 ± 1.58%. These results suggest that CHFY0321 exhibited the fermentation characteristics of S. cerevisiae CHY1011 and the flocculent ability of S. bayanus KCCM12633. Therefore, the strong highly flocculent ethanol fermentative CHFY0321 has potential for improving biotechnological ethanol fermentation processes.     

Optical probing of anisotropic heat transport in the quantum spin ladder Ca9La5Cu24O41

A transient thermal imaging technique is used to monitor heat diffusion at the surface of the antiferromagnetic spin ladder material Ca₉La₅Cu₂₄O₄₁. This material shows highly anisotropic thermal conductivity due to a large uni-directional magnetic heat transport along the ladders. The thermal conductivity is measured using optical heating as well as electrical heating, yielding 37 ± 3 W m^?1 K^?1 for the fast (ladder) direction and 2.5 ± 0.5 W m^?1 K^?1 for the slow direction, respectively. The fast direction result is in agreement with the thermal conductivity measured using other dynamic methods, but about 60% lower than the thermal conductivity measured using steady state methods.     

100 t/a-Scale demonstration of direct dimethyl ether synthesis from corncob-derived syngas

Direct conversion of biomass-derived syngas (bio-syngas) to dimethyl ether (DME) at pilot-scale (100 t/a) was carried out via pyrolysis/gasification of corncob. The yield rate of raw bio-syngas was 40–45 Nm³/h with less than 20 mg/Nm³ of tar content when the feedrate of dried corncob was 45–50 kg/h. After absorption of O₂, S, Cl by a series of absorbers and partial removal of CO₂ by the pressure-swing adsorption (PSA) unit sequentially, the obtained bio-syngas (H₂/CO≈1) was directly synthesized to DME over Cu/Zn/Al/HZSM-5 catalyst in the fixed-bed tubular reactor. CO conversion and DME space-time yield (STY) were 67.7% and 281.2 kg/m_cat³/h respectively at 260 °C, 4.3 MPa and 3000 h^?1(GHSV, syngas hourly space velocity). Synthesis performance would be increased if the tail gas (H₂/CO > 2) was recycled to the reactor when GHSV was 650–3000 h^?1.     

Targeted brain hypothermia induced by an interstitial cooling device in the rat neck: Experimental study and model validation

Targeted brain hypothermia has the potential to prevent cerebral ischemia injury during open heart and neck surgeries or after traumatic head injury. In this study, in vivo experiments were performed to test the performance of a newly developed cooling device in an inexpensive animal model. Rat brain hypothermia was induced by inserting an interstitial cooling device in the rat neck muscle and placing the device on the common carotid artery to cool the arterial blood supplied to the brain. Coolant was circulating inside the cooling device to achieve either mild or moderate temperature reductions at the surface of the device. Temperatures were measured inside the rat brain tissue, as well as on the head skin surface. For the mild cooling (cooling device surface temperature was 18.7 ± 4.5 °C), the temperature reductions were 2.2 ± 0.6 °C, 2.1 ± 0.6 °C, 1.9 ± 0.6 °C and 1.6 ± 0.9 °C at sites of brain-5 mm, brain-2 mm, skull, and scalp, respectively. After the surface temperature was further decreased to 12.8 ± 2.8 °C (moderate cooling), the temperature reduction in the head increased more than 85% to 3.7 ± 3.2 °C, 3.7 ± 3.0 °C, 3.3 ± 2.5 °C and 2.5 ± 1.0 °C, respectively. The experimental data were also used to validate a previously developed theoretical model for humans. Experimentally measured geometrical and physiological parameters of the rat neck and brain were substituted into the scaled-down theoretical model to simulate the temperature distribution in the rat neck and brain. The theoretically predicted brain temperatures showed a good agreement with the experiment data. We believe that this study is the first step in developing a reliable cooling device to achieve fast cooling and to control rewarming in future clinical studies and to benefit a large patient population.     

Sintered porous heat sink for cooling of high-powered microprocessors for server applications

This paper experimentally investigates the sintered porous heat sink for the cooling of the high-powered compact microprocessors for server applications. Heat sink cold plate consisted of rectangular channel with sintered porous copper insert of 40% porosity and 1.44 × 10^?11 m² permeability. Forced convection heat transfer and pressure drop through the porous structure were studied at Re ? 408 with water as the coolant medium. In the study, heat fluxes of up to 2.9 MW/m² were successfully removed at the source with the coolant pressure drop of 34 kPa across the porous sample while maintaining the heater junction temperature below the permissible limit of 100 ± 5 °C for chipsets. The minimum value of 0.48 °C/W for cold plate thermal resistance (R_cp) was achieved at maximum flow rate of 4.2 cm³/s in the experiment. For the designed heat sink, different components of the cold plate thermal resistance (R_cp) from the thermal footprint of source to the coolant were identified and it was found that contact resistance at the interface of source and cold plate makes up 44% of R_cp and proved to be the main component. Convection resistance from heated channel wall with porous insert to coolant accounts for 37% of the R_cp. With forced convection of water at Re = 408 through porous copper media, maximum values of 20 kW/m² K for heat transfer coefficient and 126 for Nusselt number were recorded. The measured effective thermal conductivity of the water saturated porous copper was as high as 32 W/m K that supported the superior heat augmentation characteristics of the copper–water based sintered porous heat sink. The present investigation helps to classify the sintered porous heat sink as a potential thermal management device for high-end microprocessors.