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《Ceramics International》2023,49(15):25261-25268
A new type of glass-ceramic BaO–CaO–Al2O3–SiO2 (BCAS) was developed to join Al2O3 ceramics, adding TiO2 to the glass-ceramics can promote the crystallization behavior of the glass-ceramics. Through the observation of the joints, rutile TiO2 whiskers can grow on the surface of Al2O3 ceramics, and the grown TiO2 whiskers are one-dimensional needle-like whiskers growing in different directions in the joints, providing mechanical support for the joints. The aspect ratio of TiO2 whiskers was changed by controlling the addition of TiO2, and the crystallization behavior and microstructure of the joints were studied. The experimental results show that when the amount of TiO2 added is 10% (wt%), the density of TiO2 whiskers in the joint is the largest, the strengthening effect on the joint is the best, and the shear strength can reach 94.33 MPa. 相似文献
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Al<,2>O<,3>-SiO<,2>-ZrO<,2>系耐火材料应用范围广,特别被用作陶瓷辊,具有力学强度高、抗热震性能优良、耐碱类化合物侵蚀和高温蠕变率低的特性.Al<,2>O<,3>-SiO<,2>-ZrO<,2>系耐火材料性能很大程度上取决于其结晶相和玻璃相的总量和化学成分,采用定量XRPD和XRF研究了原料中Al<,2>O<,3>/SiO<,2>比和氧化铝颗粒尺寸分布对结晶相和玻璃相的总量及其化学成分的影响.耐火材料由莫来石、刚玉、ZrO<,2>的多晶体和总量各异的玻璃相组成.莫来石含量及其晶胞参数和成分随烧成温度改变,但主要受原料中Al<,2>O<,3>/SiO<,2>比的影响. 相似文献
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YANG Daoyuan GUO Xinrong ZHONG Xiangchong University of Science technology Beijing P. R. Chinaa Zhengzhou University Henan province P. R. China. 《中国耐火材料》2004,13(2):21-23
1IntroductionMgO·Al2 O3spinelisanimportantceramicmaterialextensivelyusedinrefractoriesindustry ,especiallyforapplicationsathightemperaturecriticalareaswherether malshockresistanceandslagpenetrationresistanceareprimaryrequisites[1] .ButlittleinformationaboutMgO·Al2 O3spinelfibershasbeenreportedinliterature .Inthiswork ,itisfoundthatwhenpressedspecimenscomposedofpulverizedMg Al Omaterialwithappropriateoxide metalratioarefiredat 15 0 0℃for 6hoursundercon trolledatmosphere ,MgO·Al2 O3spi… 相似文献
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《Ceramics International》2020,46(5):6205-6211
This study utilized the single hot thermocouple technique to examine the dissolution behavior of lumped magnesium oxide (MgO) in CaO–Al2O3–SiO2 ternary slags. The aluminum oxide (Al2O3) content in the slag (C/S = 1) varied from 10% to 30%; the MgO sphere with a diameter of 1 mm was placed in molten slags at 1,550 °C. Results showed that the dissolution rate decreased as the Al2O3 content increased up to 20%. Over 20% Al2O3, MgAl2O4 was formed at the interface of MgO and it did not fully melt at 30% Al2O3. The dissolution behavior and the formation of MgAl2O4 were analyzed by a phase diagram provided by Factsage 7.0 software. In the case of less than 20% Al2O3 content, apparent sphere radii were measured; the shrinking core model was then applied to understand the dissolution mechanism. The dissolution rate of both slags was controlled by boundary layer diffusion. The dissolution rate at 20% Al2O3 slag appeared to fit the behavior to the boundary layer diffusion, although it deviated during the middle stage of the dissolution because of MgAl2O4 formation. The 10% Al2O3 slag fitted well to the boundary layer diffusion curve; the obtained diffusion coefficient was 0.94 × 10−9 m2/s. 相似文献
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The glass structure, wetting behavior and crystallization of BaO–Al2O3–B2O3–SiO2 system glass containing 2–10 mol% Al2O3 were investigated. The introduction of Al2O3 caused the conversion of [BO3] units and [BO4] units to each other and it played as glass network former when the content was up to 10 mol%, accompanied by [BO4] → [BO3]. The stability of the glass improved first and then decreased as Al2O3 increased from 2 to 10 mol%, the glass with 5 mol% Al2O3 being the most stable one. The wetting behavior of the glasses indicates that excess Al2O3 leads to high sealing temperature. The glass containing 5 mol% Al2O3 characterized by a lower sealing temperature is suitable for SOFC sealing. Al2O3 improves the crystallization temperature of the glass. The crystal phases in the reheated glasses are mainly composed of Ba2Si3O8, BaSiO3, BaB2O4 and BaAl2Si2O8. Al2O3 helps the crystallization of BaSiO3 and BaAl2Si2O8. 相似文献
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María A. Vicerich Viviana M. Benitez María A. Sánchez Catherine Especel Florence Epron Carlos L. Pieck 《加拿大化工杂志》2020,98(3):749-756
Alumina and silica-alumina supported Ru-Pt catalysts were evaluated for the ring opening of naphthenes. Pt, Ru, and Ru-Pt catalysts were prepared by the impregnation of inorganic precursors over γ-alumina and silica-alumina supports. The catalysts were evaluated by temperature programmed reduction (TPR), pyridine temperature programmed desorption (TPD), CO-FTIR, and by test reactions of 33DM1B isomerization, cyclohexane dehydrogenation, cyclopentane hydrogenolysis, and the ring opening of decalin. The strong interaction between the metals (Pt-Ru) was attributed to their reductions occurring simultaneously. The acidity and strength of the acid sites of the monometallic Ru catalyst were higher than those of the monometallic Pt catalyst. The total acidity (Lewis and Brønsted) and the strength of the acid sites were higher for the silica-alumina supported catalysts. The silica-alumina catalysts had 10 times more Brønsted acidity than the γ-alumina ones and an increased activity and selectivity to decalin ring opening products. Supported monometallic Ru had the best performance for the ring opening reaction. 相似文献
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真空条件下,以Al2O3和Al为原料,通过Al2O歧化法制备微细Al2O3/Al复合粉体.XRD和SEM分析表明:在反应温度为1200~1400℃时,随着温度的升高,粉体中氧化铝含量升高;冷凝温度约为550~750℃时,复合粉体中的氧化铝包括稳定晶型和不稳定晶型;冷凝温度约为1100~1300℃时,复合粉体中的氧化铝全部为稳定晶型;冷凝温度约为550~650℃时,复合粉体的平均粒径小于0.5μm;冷凝温度约为750℃时,铝熔化、微粒团聚;冷凝温度约为1100~1200℃时,铝形成铝珠,氧化铝为不规则状、平均粒径小于2μm;冷凝温度约为1300℃时,氧化铝为片状.因此,通过选取合适的反应温度、冷凝温度,可以控制Al2O3/Al复合粉体中氧化铝的含量、晶型和粒径. 相似文献
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《Ceramics International》2020,46(9):13414-13423
The element/phase loss is undesirable but existing during selective laser melting (SLM) of materials with volatile element/phase, which not only changes the material composition but also affects the molten pool flow. In the previous researches, the effect of remelting on the element/phase loss was neglected during the SLM process, instead, laser energy density was thought to be uppermost. In fact, the SLM process fabricates the parts in a manner of line by line and layer by layer, i.e., additive character, and the remelting in the overlap zone occurs during the SLM process. In this paper, three different Al2O3 loss prediction models of SLM Al2O3–Al composite by considering the additive character of SLM and the distribution of the Al2O3 associated with the different molten pool driving forces were developed. By comparing with the experimental results and predicted results, it is found that the Al2O3 is distributed on both sides of the molten pool under the combined action of the Marangoni flow and the evaporation recoil pressure. This kind of Al2O3 distribution enhances the effect of the remelting on the Al2O3 loss, i.e., the remelting brings a logarithmic increase in the Al2O3 loss rate. This determines the final Al2O3 loss rate of the SLMed 3D samples. During this study, although the Al2O3 loss rate of the single-track is only 33%, the loss rate of SLMed 3D samples increases significantly to 97% when the hatching space of 60 μm and scanning speed of 200 mm/s are utilized, i.e., almost no Al2O3 in the 3D sample. Thus, it is more important to reduce the remelting, i.e., overlap rate for reducing the element/phase loss. This study is a benefit for understanding and reducing the element/phase loss in SLM. 相似文献
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研制了添加Al2O3—ZrO2(Y2O3)系易熔混合物细粉碎颗粒的刚玉质陶瓷,并研究其结构和性能。指出利用这种易熔混合物对于制造陶瓷材料是很有前途的。 相似文献
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采用二乙三胺五乙酸(DTPA)为配合剂,以简易的液相法合成出微纳米纤维状Al和Al-Zr前体,煅烧处理制备了棒状α-Al2O3和Al2O3-ZrO2复合陶瓷粉体。同时研究了DPTA∶Al3+质量比、反应温度与时间对陶瓷粉体形态的影响。利用X射线衍射(XRD)、热分析(TG/DSC)以及扫描电子显微镜(SEM)对粉体进行了表征。结果表明:较高的DTPA∶Al3+质量比以及较长的反应时间有利于制备高长径比的纤维棒状Al和Al-Zr配合物前体。合成纳米纤维状α-Al2O3和Al2O3-ZrO2前体的最优条件是反应温度60℃,反应时间5.5h,DTPA∶Al3+比例为1.2∶1。相应地,该前体煅烧后可以制备出棒状α-Al2O3和Al2O3-ZrO2复合陶瓷粉体。 相似文献
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Al2O3-MgO·1.35Al2O3复合浆料的流变特性研究 总被引:1,自引:1,他引:1
测试了高纯板状刚玉粉(Al2O3)、富铝尖晶石粉(MgO@1.35Al2O3)及其复合粉料(Al2O3-MgO@1.35Al2O3)在水溶液中不同pH值下的ζ电位,三者的等电点分别为7.4、~3和5.3.研究了分散剂三聚磷酸钠对复合浆料的ζ电位和流动性的影响,结果表明外加1 wt%溶剂量的三聚磷酸钠可降低复合浆料的ζ电位约40 mV;制备Al2O3-MgO@1.35Al2O3复合浆料的理想pH值范围为9~11;复合浆料中MgO@1.35Al2O3对流变特性的影响比Al2O3的大. 相似文献
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The studies on the linear change,cold MOR and the refractoriness under olad of the Al23-SiO2 based castables which contain andalusite were carried out.The results show that the linear change at over 1400℃ changes from negative value to positive if the castables contain over 10% an-dalusite;the higher the addition of andalusite in the castables,the larger is the expansion;The re-fractoriness under load increase obviously with the increasing of the andalusite content in the casta-bles;meanwhile,cold MOR and cold crushing stuength decrease as a result of the large volume expansion. 相似文献