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1.
E. N. Frankel E. A. Emken V. L. Davison 《Journal of the American Oil Chemists' Society》1966,43(5):307-311
Iron pentacarbonyl is a powerful isomerization agent of unsaturated fatty esters. Highly conjugated fats are obtained when
polyunsaturated fatty esters are treated with an excess Fe(CO)5 to form complexes followed by decomposition of the complexes with FeCl3. Iron tricarbonyl complexes were prepared in 80 to 95% yields from methyl linoleate, linolenate and polyunsaturated fatty
esters of soybean, linseed and safflower oils by heating at 180–185C with 2 moles Fe(CO)5 per mole ester under nitrogen pressure. Decomposition of these complexes with FeCl3 resulted in 90 to 97% conjugation of the polyunsaturated fatty esters mainly in the alltrans configuration. Isolatedtrans unsaturation reached levels of 18 to 30%. Methyl oleate yielded 74%trans unsaturation but no complex of iron carbonyl was obtained.
Presented in part at AOCS meeting in Houston, 1965.
No. Utiliz. Res. Dev. Div., ARS, USDA. 相似文献
2.
《分离科学与技术》2012,47(8):1139-1146
Purification of waste cooking oils (palm oil and soybean oil) using supercritical carbon dioxide (scCO2) extraction has been investigated. The purified oils were characterized by their acid value, conjugated diene value, total polar compound measurements, and high-performance size exclusion chromatography. Using optimal extractions conditions of 353.15 K, 20 MPa, and CO2 flow rate of 40 g/min, 80% of the oil was recovered and the purified oil compositions and properties were very close to those of the fresh oils. At higher pressures or lower temperatures, the separation efficiency of the scCO2 extraction was significantly reduced. 相似文献
3.
Preparation of conjugated soybean oil and other natural oils and fatty acids by homogeneous transition metal catalysis 总被引:2,自引:0,他引:2
Richard C. Larock Xiaoyang Dong Steven Chung Ch. Kishan Reddy Laurie E. Ehlers 《Journal of the American Oil Chemists' Society》2001,78(5):447-453
The use of as little as 0.1 mol% [RhCl(C8H14)2]2, 0.25 mol% PtCl2(PPh3)2, or 0.5 mol% RuHCl(CO)(PPh3)3, where Ph = phenyl, catalyzes the isomerization of soybean oil to conjugated soybean oil under mild reaction conditions and
in high yields. No hydrogenation products are detected with any of these catalysts. Preliminary physical tests have shown
that the conjugated soybean oil has exceptional drying properties and the resulting coatings exhibit good solvent resistance.
The [RhCl(C8H14)2]2 catalyst provides similarly high yields of other conjugated vegetable oils, conjugated linoleic acid, and conjugated ethyl
linoleate. Other rhodium catalysts, such as RhCl(PPh3)3, have also been found to be effective for the conjugation of ethyl linoleate. 相似文献
4.
E. N. Frankel R. A. Awl J. P. Friedrich 《Journal of the American Oil Chemists' Society》1979,56(12):965-969
The use of Cr(CO)6 was investigated to convert polyunsaturated fats intocis unsaturated products. With methyl sorbate, the same order of selectivity for the formation ofcis-3-hexenoate was demonstrated for Cr(CO)6 as for the arene-Cr(CO)3 complexes. With conjugated fatty esters, the stereoselectivity of Cr(CO)6 toward thetrans, trans diene system was particularly high in acetone. However, this solvent was not suitable at elevated temperatures required to
hydrogenatecis, trans- andcis, cis-conjugated dienes (175 C) and nonconjugated soybean oil (200 C). Reaction parameters were analyzed statistically to optimize
hydrogenation of methyl sorbate and soybean oil. To achieve acceptable oxidative stability, it is necessary to reduce the
linolenate constituent of soybean oil below 1–3%. When this is done commercially with conventional heterogenous catalysts,
the hydrogenated products contain more than 15%trans unsaturation. By hydrogenating soybean oil with Cr(CO)6 (200 C, 500 psi H2, 1% catalyst in hexane solution), the product contains less than 3% each of linolenate andtrans unsaturation. Recycling of Cr(CO)6 catalyst by sublimation was carried through three hydrogenations of soybean oil, but, about 10% of the chromium was lost
in each cycle by decomposition. The hydrogenation mechanism of Cr(CO)6 is compared with that of arene-Cr(CO)3 complexes.
Presented in part at Seventh Conference on Catalysis in Organic Syntheses, Chicago, Illinois, June 5–7, 1978. 相似文献
5.
E. N. Frankel Helen M. Peters E. P. Jones H. J. Dutton 《Journal of the American Oil Chemists' Society》1964,41(3):186-191
Iron pentacarbonyl is an effective homogeneous catalyst for the reduction of polyunsaturated fats. Hydrogenation of soybean oil and its methyl esters has been achieved at 180C, hydrogen pressures of 100-1,000 psi, and 0.05–0.5 molar concentrations of catalyst. Analyses of partially reduced products show considerable isomerization of double bonds, reduction of linolenate and linoleate with little or no increase in stearate, and accumulation ofcis,trans- andtrans, trans-conjugated dienes, and isolatedtrans monoenes. The unreduced trienes include diene conjugated fatty esters. The nonconjugated dienes contain large amounts oftrans and nonalkali conjugatable unsaturation. Considerable scattering of double bonds is evident in different fractions between the C4 and C16 positions. Complex formation between iron carbonyl and unsaturated fats is also indicated. The course of the homogeneous hydrogenation catalyzed by iron pentacarbonyl appears similar to the heterogeneous catalytic reaction. Metal carbonyls are well known for their isomerizing effects and their ability to form stable complexes with olefins. These homogeneous complexes provide suitable model systems to study the mechanism of catalytic hydrogenation of fats. 相似文献
6.
Fatty acid methyl esters, derived from vegetable oils or animal fats and better known as biodiesel, have received considerable attention because of their environmental benefits and the limited resources of fossil fuels. Most biodiesel is usually produced by the transesterification of vegetable oils with methanol in the presence of a catalyst. This study reports on the preliminary results of using alkaline earth metal-doped zinc oxide as a heterogeneous catalyst for transesterification of soybean oil. The highest catalytic activity was obtained with ZnO loaded with 2.5 mmol Sr(NO3)2/g, followed by calcination at 873 K for 5 h. When the transesterification reaction was carried out at reflux of methanol (338 K), with a 12:1 molar ratio of methanol to soybean oil and a catalyst amount of 5 wt.%, the conversion of soybean oil was 94.7%. Besides, tetrahydrofuran (THF), when used as a co-solvent, could increase the conversion up to 96.8%. However, the recovered catalyst exhibited the lower catalytic activity with a conversion of soybean oil of 15.4%. Furthermore, DTA-TG, IR and the Hammett indicator method were employed for the catalyst characterizations. 相似文献
7.
H. N. Cheng Mason W. Rau Michael K. Dowd Michael W. Easson Brian D. Condon 《Journal of the American Oil Chemists' Society》2014,91(8):1461-1469
There is current interest in reducing the trans fatty acids (TFA) in hydrogenated vegetable oils because consumption of foods high in TFA has been linked to increased serum cholesterol content. In the interest of understanding the TFA levels, hydrogenation was carried out in this work on soybean oil and cottonseed oil at two pressures (2 and 5 bar) and 100 °C using commercially available Ni, Pd, and Pt catalysts. The TFA levels and the fatty acid profiles were analyzed by gas chromatography. The iodine value of interest is ~70 for all-purpose shortening and 95–110 for pourable oil applications. In all cases, higher hydrogen pressures produced lower levels of TFA. In the range of 70–95 iodine values for the hydrogenated products, the Pt catalyst gave the least TFA, followed closely by Ni, and then Pd, for both oils. For all three catalysts at 2- and 5-bar pressures and 70–95 iodine values, cottonseed oil contained noticeably less TFA than soybean oil; this is probably because cottonseed oil contains a lower total amount of olefin-containing fatty acids relative to soybean oil. Approximate kinetic modeling was also done on the hydrogenation data that provided additional confirmation of data consistency. 相似文献
8.
A new process for the acyclic diene metathesis of vegetable oils utilizing Grubbs’ ruthenium catalyst (Cy3P)2Cl2Ru = CHPh has been developed. The higher molecular weight oligomers obtained can be separated from the unreacted oil and the
lower molecular weight alkene by-products easily. The reaction proceeds in the absence of solvent, with very low catalyst
concentrations (0.1 mole %) under moderate temperatures and low pressures. This process does not require the stringent exclusion
of water and oxygen that the previous method (Me4Sn plus WCl6) required. Low pressures appear to favor polymerization by removing the alkene by-products. The metathesis reaction has been
shown to be effective for many unsaturated vegetable oils, although some cases require oil pretreatment with silica gel. This
process is effective on a 2–200 g scale. Chromatographic separation and characterization of metathesized soybean oil indicate
that the process involves intermolecular and intramolecular carbon-carbon double-bond formation. 相似文献
9.
Joana V. Barbosa Fernanda Oliveira Jorge Moniz Fern?o D. Magalh?es Margarida M. S. M. Bastos 《Journal of the American Oil Chemists' Society》2012,89(12):2215-2226
This work evaluated the use of allyl fatty acid esters derived from vegetable oil (palmitic acid, soybean and sunflower oils) as reactive coalescing agents in a waterborne latex system. Allyl fatty acid derivatives (AFAD) from vegetable oils were synthesized by two different processes. The synthesis was monitored by IR-spectroscopy and the final product characterized by FT-IR, GC–MS, 1H and 13C NMR. The presence of conjugated double bonds in the aliphatic chain was confirmed, which is a determinant for the proposed autoxidative latexes drying mechanism. Each of the AFAD were subsequently added to a standard acrylic emulsion, in order to study its potential as reactive coalescing agent. The minimum film-forming temperature (MFT), glass transition temperature (T g), drying time and rubbing resistance to solvents were evaluated. The results showed that, when added to water-borne acrylic resins, an AFAD acts as a non-volatile plasticizer capable of autoxidative crosslinking with itself. 相似文献
10.
Sarah L. Booth Kenneth W. Davidson Alice H. Lichtenstein James A. Sadowski 《Lipids》1996,31(7):709-713
Dihydro-vitamin K1 is a dietary form of vitamin K1 (phylloquinone) produced during the hydrogenation of vegetable oils. To determine if dihydro-vitamin K1 is present in plasma following dietary intake of a hydrogenated fat, eight healthy adults consumed each of two diets containing
30% of calories from fat, of which 20% was either soybean oil or a partially hydrogenated soybean oil-based stick margarine.
Of the fats and oils analyzed, dihydro-vitamin K1 was only found in the hydrogenated products. The soybean oil diet contained 180 ±12 μg (mean±SD) of vitamin K1/day and nondetectable levels of dihydro-vitamin K1, whereas the stick margarine diet contained 199±7 μg of vitamin K1/day and 23±2 μg of dihydrovitamin K1/day. After consuming each diet for five weeks, plasma dihydro-vitamin K1 concentrations were higher (P=0.002) in all eight subjects when consuming the stick margarine diet (0.56 ±0.33 nmol/L) compared to the soybean oil diet
(0.12±0.11 nmol/L). There was no significant change in plasma vitamin K1 concentrations when the two diets were compared. In conclusion, dihydro-vitamin K1 is detectable in plasma following dietary intake of a hydrogenated vitamin K1-rich vegetable oil. 相似文献
11.
Kyu-Wan Lee Cheng Hailan Jin Yinhua Young-Wun Kim Keun-Woo Chung 《Korean Journal of Chemical Engineering》2008,25(3):474-482
Vegetable oils are a major source of many base chemicals. Unfortunately, most vegetable oils exhibit lower thermal and oxidation
stability because of double bonds and even worse low-temperature behaviors. These physical and chemical properties can be
improved by various chemical modifications. The catalytic hydrogenation of soybean oil (SBO) over 25% Ni/SiO2 and 5% Pt/C is one of them, and the epoxidation of soybean oil and reduced soybean oil (RSBO) was carried out by using 30%
of hydrogen peroxide and acetic acid in the presence of conc. sulfuric acid, and/or acidic Amberlyst 15 resin catalyst. Various
alcohols and amines were added to the epoxidized soybean oil (ESBO) in the hope of improving lubricant properties. The reaction
products were carefully analyzed by means of 1H-NMR, FT-IR spectroscopies and GC-MS spectrometry. This paper covers the epoxidation of virgin and RSBOs, alcoholysis and
amidation of ESBO and SBO. Finally, the structures of cross linked products synthesized from ESBO and SBO with 1,6-hexamethylendiamine
were proposed. 相似文献
12.
G. R. List J. W. King J. H. Johnson K. Warner T. L. Mounts 《Journal of the American Oil Chemists' Society》1993,70(5):473-476
A hexane-extracted crude soybean oil was degummed in a reactor by counter-currently contacting the oil with supercritical
CO2 at 55 MPa at 70°C. The phosphorus content of the crude oil was reduced from 620 ppm to less than 5 ppm. Degummed feedstocks
were fed (without further processing,i.e., bleaching) directly to a batch physical refining step consisting of simultaneous deacidification/deodorization (1 h @ 260°C
and 1–3 mm Hg) with and without 100 ppm citric acid. Flavor and oxidative stability of the oils was evaluated on freshly deodorized
oils both after accelerated storage at 60°C and after exposure to fluorescent light at 7500 lux. Supercritical CO2-processed oils were compared with a commercially refined/bleached soybean oil that was deodorized under the same conditions.
Flavor evaluations made on noncitrated oils showed that uncomplexed iron lowered initial flavor scores of both the unaged
commercial control and the CO2-processed oils. Oils treated with .01% (100 ppm) citric acid had an initial flavor score about 1 unit higher and were more
stable in accelerated storage tests than their uncitrated counterparts. Supercritical CO2-processed oil had equivalent flavor scores, both initially and after 60°C aging and light exposure as compared to the control
soybean oil. Results showed that bleaching with absorbent clays may be eliminated by the supercritical CO2 counter-current processing step because considerable heat bleaching was observed during deacidification/deodorization. Colors
of salad oils produced under above conditions typically ran 3Y 0.7R. 相似文献
13.
Yasushi Endo Chieko Hayashi Takashi Yamanaka Koichi Takayose Miki Yamaoka Takuo Tsuno Shigeo Nakajima 《Journal of the American Oil Chemists' Society》2013,90(7):959-964
Acrolein, which is an irritating and off-flavor compound formed during heating of vegetable oils, was estimated by the gas–liquid chromatography (GLC). Several vegetable oils such as high-oleic sunflower, perilla, rapeseed, rice bran, and soybean oils were heated at 180 °C for 480 min and then the concentration of acrolein in the head space gas was determined by GLC. The formation of acrolein was greatest in perilla oil among the tested oils, while it was much lower in rice bran oil and high-oleic sunflower oil. There was a good correlation between the level of acrolein and linolenate (18:3n-3) in the vegetable oils. To investigate the formation of acrolein from linolenate, methyl oleate, methyl linoleate, and methyl linolenate were also heated at 180 °C, and the amounts of acrolein formed from them were determined by GLC. The level of acrolein was the greatest in methyl linolenate. Acrolein was also formed from methyl linoleate, but not from methyl oleate. Acrolein in vegetable oils may be formed from polyunsaturated fatty acids, especially linolenic acid but not from glycerol backbone in triacylglycerols. 相似文献
14.
Reliability of <Superscript>1</Superscript>H NMR Analysis for Assessment of Lipid Oxidation at Frying Temperatures
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The reliability of a method using 1H NMR analysis for assessment of oil oxidation at frying temperatures was examined. During heating and frying at 180 °C, changes of soybean oil signals in the 1H NMR spectrum including olefinic (5.16–5.30 ppm), bisallylic (2.70–2.88 ppm), and allylic (1.94–2.15 ppm) proton signals relative to glyceride backbone CH2 (5.30–5.46 ppm) and aliphatic CH2 (1.05–1.71 ppm) signals showed strong correlations with conventional analytical methods including total polar compounds, polymerized triacylglycerols, and changes of linoleic acid and linolenic acid peaks in gas chromatography. For oils rich in oleic acid, mid‐oleic sunflower oil (NuSun) and high oleic soybean oil, only the olefinic and allylic proton signals are recommended for analysis due to the relatively low intensity of the bisallylic proton signal. Under these heating and frying conditions, signals indicating intermediate oxidation products, hydroperoxides, were not detected while very small signals corresponding to a variety of aldehydes including alkanal, branched alkenal, 2‐alkenal, and aldehydes of conjugated dienes and epoxides were observed. In this study, it was found that the 1H NMR method is a fast, convenient, and reliable analytical method to determine the oxidation state of frying oil. 相似文献
15.
E. N. Frankel 《Journal of the American Oil Chemists' Society》1970,47(2):33-36
Various arene-Cr (CO)3 complexes and Cr(CO)6 are effective soluble catalysts for the conjugation of polyunsaturated fats. Methyl benzoate-Cr(CO)3 is one of the most active catalysts. The following conjugation levels were obtained: methyl linoleate, 65%; methyl linolenate,
45%; the polyunsaturates in soybean and safflower oils, 73%; and in linseed oil 48%. Conjugated dienes from linoleate were
predominantlycis,trans in configuration. Their double bonds were distributed between C5 and C16 of the fatty acid chain. Hydrogenation and dehydrogenation are side reactions, which seem to limit the yield of conjugated
dienes from methyl linoleate. A conjugation mechanism is proposed that involves allyl-HCr(CO)3 complexes as intermediates undergoing 1,3- and 1,5-hydrogen shifts.
Presented at the AOCS Meeting, San Francisco, April 1969.
No, Utiliz. Res. Dev. Div., ARS, USDA. 相似文献
16.
Xiupin Wang Peiwu Li Wen Zhang Qi Zhang 《European Journal of Lipid Science and Technology》2013,115(3):337-347
The method of headspace coupled with comprehensive two‐dimensional GC–time‐of‐flight MS (HS‐GC × GC–TOF/MS) was applied to differentiate the volatile flavor compounds of three types of pure vegetable oils (sesame oils, peanut oils, and soybean oils) and two types of adulterated oils (sesame oils and peanut oils adulterated with soybean oils). Thirty common volatiles, 14 particular flavors and two particular flavors were identified from the three types of pure oils, from the sesame oils, and from the soybean oils, respectively. Thirty‐one potential markers (variables), which are crucial to the forming of different vegetable oil flavors, were selected from volatiles in different pure and adulterated oils, and they were analyzed using the principal component analysis (PCA) and cluster analysis (CA) approaches. The samples of three types of pure vegetable oil were completely classified using the PCA and CA. In addition, minimum adulteration levels of 5 and 10% can be differentiated in the adulteration of peanut oils and sesame oils with soybean oils, respectively. Practical applications: The objective was to develop one kind of potential differentiated method to distinguish high cost vegetable oils from lower grade and cheaper oils of poorer quality such as soybean oils. The test result in this article is satisfactory in discriminating adulterated oils from pure vegetable oils, and the test method is proved to be effective in analyzing different compounds. Furthermore, the method can also be used to detect other adulterants such as hazelnut oil and rapeseed oil. The method is an important technical support for public health against profit‐driven illegal activities. 相似文献
17.
David L. Compton John R. Goodell Mark A. Berhow James A. Kenar Steven C. Cermak Kervin O. Evans 《Journal of the American Oil Chemists' Society》2017,94(3):397-411
The synthesis of feruloylated coconut oil and feruloylated shea butter were demonstrated in 0.5-L scale, shaken, batch reactions. Ethyl ferulate and the vegetable oil/fat were combined in a 1.0:1.3 mol ratio in the presence of Candida antartica lipase B immobilized on an acrylic resin (Novozym 435) at 60 °C. The transesterification of ethyl ferulate with coconut oil and shea butter reached equilibrium conversions, after 22 days, of 63 and 70%, respectively, with the shea butter transesterifications producing a white precipitate not observed in the coconut oil transesterifications. The faster transesterification rates, equilibrium conversions and white precipitate were shown to result from di- and monoacylglycerols (DAG and MAG) present in the shea butter. The transesterification of ethyl ferulate and coconut oil was also tested in a continuous, enzymatic, packed-bed bioreactor using Novozym 435 at 60 °C to produce feruloylated coconut oil at rates of 0.5–0.9 kg/day over 4.5 months. The feruloylated coconut oil acylglycerol species were identified by LC–MS analysis of transesterification reactions of ethyl ferulate with medium chain triacylglycerol (TAG) standards, C8–C14. The feruloylated vegetable oils possessed an ultra violet (UV) absorbing λ max 328 nm, making them good UVAII absorbers, as defined by the U.S. Food and Drug Administration. The feruloylated coconut oil possessed a 17.5% higher absorption capacity than feruloylated shea butter on a per weight basis. All the feruloylated vegetable oils possessed rapid antioxidant capacity (50% reduction of initial radical concentration <5 min) at the concentrations tested, 0.5–2.5 mM. Feruloylated coconut oil possessed chemical and physical characteristics that suggested it would be fungible for feruloylated soybean oil in current retail formulations. 相似文献
18.
Yoshihisa Watanabe Osamu Yamada Katsuhisa Fujita Yoshinobu Takegami Toshimitsu Suzuki 《Fuel》1984,63(6):752-755
Hydroliquefaction of Japanese Miike and Taiheiyo coals was carried out using various iron complexes as catalysts in tetralin at 375–445 °C. Iron pentacarbonyl (Fe(CO)5) showed the highest catalytic activity, increasing coal conversion by about 10% at 425 °C under an initial hydrogen pressure of 5 MPa. Amounts of hydrogen transferred to coal increased from 1.4–2.3 wt% of daf coal in the absence of the catalyst to 2.5–4.2 wt% of daf coal in the presence of Fe(CO)5 at 425 °C. 相似文献
19.
Teimoor Mohammadi Jamshid Farmani Zahra Piravi-Vanak 《Journal of the American Oil Chemists' Society》2019,96(5):555-569
The simplest and the most cost-effective way of human milk fat substitute (HMFS) production is formulating of suitable vegetable oils at proper ratios. To do this, the D-optimal mixture design was used to optimize the HMFS formulation. The design included 25 formulations made from refined palm olein (35–55%), soybean oil (5–25%), olive oil (5–20%), virgin coconut oil (5–15%), and fish oil (0–10%). Samples were produced in laboratory and characterized in terms of fatty acid and triacylglycerol (TAG) compositions, free fatty acid content, peroxide value, iodine value, and oxidative stability index (OSI). HMFS samples were also compared with Codex Alimentarius (CA) and Iran National Standards Organization (INSO) standards. Each characteristic of HMFS samples was then expressed as a function of ingredient ratio using regression models. Finally, using numerical optimization, four optimized blends (PB1-PB4) were selected, made in the laboratory (HMFS1-HMFS4), characterized, and compared with CA and INSO standards. The properties of all the optimized blends (except the palmitic acid content of HMFS2 and the monounsaturated fatty acid [MUFA] content of HMFS3) met the standards. HMFS4 showed the highest OSI in Rancimat and the lowest oxidation rate in Schaal oven tests. POL (19.53–21.73%), PPO (20.77–21.73%), OOO (9.11–11.16%), and OPO (8.84–9.46%) were the main (totally about 60%) TAG species found in HMFS samples. In conclusion, the HMFS4 formula (55% palm olein, 13.5% soybean oil, 16% refined olive oil, 15% virgin coconut oil, and 0.5% fish oil) was suggested as the best formula for HMFS production. 相似文献
20.
E. H. Pryde 《Journal of the American Oil Chemists' Society》1979,56(11):719A-725A
Vegetable oils that are important to the chemical industry include both edible and industrial oils, which contribute 24% and
13.5%, respectively, compared to 55% for tallow, to the preparation of surfactants, coatings, plasticizers, and other products
based on fats and oils. Not only the oils themselves but also the fatty acids recovered from soapstock represent a several
billion pound resource. Coconut oil is imported to the extent of 700-1,000 million pounds per year. Its uses are divided about
equally between edible and industrial applications. Safflower oil has a relatively small production, but 15–25% of the oil
goes into industrial products. Soybean oil, the major edible oil of the world, is produced in the United States at the rate
of 11,000 million pounds per year with more than 500 million pounds going into industrial uses, representing 5% of the total
production. Castor oil is imported to the extent of about 100 million pounds per year. Linseed oil production has declined
drastically over the last 25 years but still amounts to about 100 million pounds per year. Oiticica and tung oils are imported
in lesser amounts than castor and linseed oils. New crops that have industrial potential, as well as the traditional vegetable
oil crops, include seed oils from crambe,Limnanthes, Lesquerella, Dimorphotheca, Vernonia, andCuphea plants. Crambe oil contains up to 65% erucic acid. Oil fromLimnanthes contains more than 95% of fatty acids above C18.Lesquerella oil contains hydroxy unsaturated acids resembling ricinoleic acid from castor oil.Dimorphotheca oil contains a conjugated dienol system.Vernonia oils contain as much as 80% epoxy acids. TheCuphea oils contain a number of short chain fatty acids. Of these, crambe,Limnanthes, andVernonia are probably the most developed agronomically. Competition between vegetable oils and petrochemicals for the traditional
fats and oil markets has been marked over the past 25 years, but prices for petrochemicals have accelerated at a greater rate
than those for vegetable oils; and, it is now appropriate to reexamine the old as well as the new markets for fatty acids. 相似文献