WATER FLOW AND BINDER MIGRATION DURING DRYING OF COATED PAPER

The aim of this study has been to develop a mathematical model for water flow and binder migration in coated paper. The model can be used for simulation of the stages starting after the coating applicator including infrared and air drying sections. On the basis of the model the moisture, temperature and binder distribution can be determined across the paper thickness. Approximating equations concerning the paper properties are used in the model. We have measured the diffusion coefficient between the water and binder substances. Representative numerical examples are presented for separate and combined infrared and air drying processes.     

Drying and collapse of hollow latex

Hollow latex particles are used as white pigments for paints and paper coatings. In the coating dispersion, each hollow particle is filled with water. As the coating dries, water vacates the latex, leaving an air-filled void sized to scatter light (~0.5 μm) within each particle. Examinations of dried coatings reveal that hollow particles can collapse, decreasing their light scattering efficiency. Cryogenic scanning electron microscopy (cryoSEM) was used to characterize the microstructure of coatings containing hollow latex during drying. Images suggest latex voids empty after air invades into the coating interstitial space and collapse occurs late in the drying process. The effects of temperature (10–60°C), humidity (20–80%), and binder concentration (0–30 wt%) on particle collapse were also studied through SEM of dried coating surfaces. High drying temperature, high humidity, and low binder concentrations promoted collapse. For hollow latex particles with porous shell walls, temperature and humidity had little effect, whereas binder increased collapse. From these results, a theoretical model is proposed. During drying, diffusion of water from the particle creates a vacuum inside the latex. The vacuum is either relieved by nucleation of a gas bubble from the dissolved air in the water-filled particle or it causes the particle to collapse by buckling.     

The Effect of Intense Air Drying on Material Distribution and Quality in Coated Papers

The aim of this study was to find out what will happen to paper coating quality and material gradients if coating is dried in one air dryer at a high convection rate (150 kg/m²h). Different printing papers were coated, calendered and printed with pilot machines. The binder and pigment gradients of the coated, and also printed, samples were analyzed with LIPS (Laser Induced Plasma Spectrometry). It was found that drying affects the migration of starch, but not latex. Total air drying can be used to dry printing papers, if air temperature, velocity and moisture content can be separately controlled. The control of web temperature is more important for paper quality formation in a coater drying section than that of evaporation rate.     

HEATING/DRYING OF PAPER SHEET WITH GAS-FIRED INFRARED EMITTERS—PILOT MACHINE TRIALS

On-line heating/drying of paper sheet with gas-fired infrared emitters is investigated through pilot machine trials and theoretical analysis. The results indicate that significant enhancements in drying of uncoated paper can be achieved with the application of gas-fired infrared emitters. The theoretical model predicts the pilot machine data closely. Thus, the theoretical model developed can be used as a valuable tool to predict the increase in machine speed or drying rate with the incorporation of gas-fired infrared emitters in the drying section.     

明胶软胶囊干燥特性的研究

在对流干燥实验台上进行了明胶软胶囊干燥特性的实验,研究了加热空气温度、风速、湿度对干燥过程的影响规律。实验结果表明,提高加热空气的温度,虽然提高了传热速率,但在第2降速阶段干燥速率下降,导致最终含水质量分数反而偏高;随着加热空气风速的提高,传热速率增加,干燥速率在第1降速阶段呈现加快趋势,软胶囊的最终含水质量分数稍有降低;而加热空气湿度的变化,对传热过程影响很小,但随着加热空气湿度的降低,干燥速率提高,使得最终含水质量分数明显降低。通过研究软胶囊的干燥特性,为制药工业中软胶囊的生产提供合理指导,对优化干燥过程、降低能耗、提高产品质量和经济效益具有重要意义。     

HEATING/DRYING OF PAPER SHEET WITH GAS-FIRED INFRARED EMITTERS—PILOT MACHINE TRIALS

On-line heating/drying of paper sheet with gas-fired infrared emitters is investigated through pilot machine trials and theoretical analysis. The results indicate that significant enhancements in drying of uncoated paper can be achieved with the application of gas-fired infrared emitters. The theoretical model predicts the pilot machine data closely. Thus, the theoretical model developed can be used as a valuable tool to predict the increase in machine speed or drying rate with the incorporation of gas-fired infrared emitters in the drying section.     

A Raman spectroscopic method to find binder distribution in electrodes during drying

Lithium ion batteries are used extensively in electronic devices as well as hybrid and electric vehicles. The anode electrode layer in the battery can be fabricated by coating an aqueous dispersion of carbon, binder, and additives, and then drying. During manufacturing, the distribution of the binder through the coating thickness can become nonuniform, which compromises the properties and performance of the battery. In this study, a quantitative method to analyze the binder distribution in the electrode during drying was established. A drying apparatus with an integrated analytic balance and surface-temperature measurement was used to prepare specimens. At specific time points during drying, specimens were removed from the apparatus, quickly frozen, and then freeze-dried. Raman spectroscopy was then used to measure the binder concentration at different points through the cross section of the freeze-dried electrode coating. Scanning electron microscopy was also used to explore the changing microstructure qualitatively. Using a model electrode formulation, the method demonstrated different binder distributions for electrodes dried at 150°C under airflow and room temperature, 20°C, with no airflow. The results also showed continued changes in distribution in the interior of the coating as drying continued.     

Infrared Drying Process of an Experimental Water Painting: Model Predictive Control

This article deals with the experimental control of an infrared drying process of a water based epoxy-amine painting. This approach is based on a unidirectional diffusional modeling of infrared drying phenomena where both heat and mass transfers under shrinkage conditions are accounted for. The control problem is concerned with the tracking of any given trajectory for one of the characteristics (i.e., the temperature or the mean water content) during the drying cycle. This is solved using the well-known model predictive control framework where the nonlinear diffusional model is directly used in the control formulation. Experimental results show the efficiency of the trajectory tracking. This method can be extended for more general constrained control problem.     

长输天然气管道干空气干燥最优长度优化计算

天然气管道建成后必须进行水压试验,使管道内含水量较高,输气管道投产前存在于管道内壁和管道低洼处的液态水对天然气有增湿作用,导致天然气露点在输气管道投产初期不能满足管输要求.为此,投产前需要对天然气管道进行干燥处理.干空气干燥是目前广泛采用的干燥方式,通过建立以干燥时间、压缩机费用、干燥空气费用和压缩机运输安装费用为最小...     

食品和农产品干燥的一种有效方法-红外加热法

农业和食品行业需要能源高效和环境友好的干燥技术,最近红外加热干燥的应用得到广泛研究。作为现代干燥技术的另一种选择,红外干燥具有加热均匀、干燥速率高、干燥时间短、节约能源、产品品质和安全性高等引人注目的优点。研究表明。将红外方法可以减少干燥时间并且节能。与热可以对果蔬实现同步漂烫和干燥,干燥和热风干燥相结合能够有效的减少干燥时间。所开发的红外冷冻相继干燥常规的空气干燥或冷冻干燥相比,更适合于生产高品质的酥脆果蔬片。红外加对稻谷进行同步干燥和杀虫。本文将综述红外加热技术的最新研究和进展。     

Microwave drying of spheres: Coupled electromagnetics-multiphase transport modeling with experimentation. Part I: Model development and experimental methodology

To understand the effects of shape, size and property changes in a spherical sample during microwave drying, a fundamentals-based coupled electromagnetics and multiphase porous media model is developed and associated experimental details are described. Microwave drying of different sized spheres is carried out in a domestic microwave oven operating at 10% power level. Maxwell's equations for electromagnetics are solved inside a three dimensional (3D) microwave oven to obtain the electric field distribution inside the oven cavity and the spheres. The drying samples are treated as a porous media consisting of three phases: solid (skeleton), liquid (water) and gas (water vapor and air). Modes of transport for the fluid phases include capillary flow, binary diffusion between vapor and air, gas pressure driven flow and phase change between liquid water and vapor which is spatially distributed. An elaborate experimental system comprising of infrared camera, optical fiber probe and digital balance is built to validate the model in terms of temperature distribution, point temperatures, gas pressure generation and moisture loss from the samples at different times during the drying process. Results, validation, sensitivity analysis and “what-if” scenarios are presented in the companion paper. The work together would provide tremendous benefits when designing and developing microwave drying processes and products through a novel synergy between physics-based modeling and detailed experimentation.     

Infrared Drying Process of an Experimental Water Painting: Model Predictive Control

Abstract

This article deals with the experimental control of an infrared drying process of a water based epoxy-amine painting. This approach is based on a unidirectional diffusional modeling of infrared drying phenomena where both heat and mass transfers under shrinkage conditions are accounted for. The control problem is concerned with the tracking of any given trajectory for one of the characteristics (i.e., the temperature or the mean water content) during the drying cycle. This is solved using the well-known model predictive control framework where the nonlinear diffusional model is directly used in the control formulation. Experimental results show the efficiency of the trajectory tracking. This method can be extended for more general constrained control problem.     

天然胶乳厚胶膜热风干燥与红外干燥对比研究

采用失重法研究了天然胶乳厚胶膜在热风与红外线两种干燥方式下的干燥过程。研究结果表明,在相同条件下,红外干燥的干燥速率常数远大于热风干燥,采用红外干燥可大大缩短干燥时间,干燥温度和厚度均显著影响干燥过程,红外干燥对温度更敏感。通过动力学拟合结果,得到了干燥动力学方程,可以预测干燥时间。     

Effect of Poly(vinyl alcohol) Adsorption on Binder Segregation during Drying

The effect of poly(vinyl alcohol) adsorption on segregation was quantitatively studied by a model experiment of one–dimension drying and simulated by a mathematical model. It was clear that the adsorption of PVA on alumina particle was a slow process, and the adsorbed binder was not desorbed at higher temperature. PVA segregation can significantly be limited by fully adsorbing the binder before drying. The simulation and experiments agreed very well. The effects of drying temperature, initial concentration of the binder, and thickness of specimen on the surface segregation are discussed quantitatively. Mathematical simulation has a great potential for predicting the segregation of soluble components during drying, especially for such cases as thin films and small granules where it is difficult to determine the distribution of the component directly.     

STUDIES OF STEAM DRYING IN A FLUIDIZED BED

In general, drying processes are described by the quantity of air humidity of the exiting gases. This approach is not possible however by the drying medium of water in steam drying, since the air humidity naturally possesses a constant value of 100%. This paper presents a model which represents the drying processes on the basis of the observation of temperature profiles of the material and energetic balancing of all components involved as well as the wall of the apparatus. The modeling differentiates three intervals: the condensation phase, the 1st drying period and the 2nd drying period. In addition, a validation of the model on the basis of experiments in an experimental plant DN100 belonging to the university is dealt with. The satisfying concurrence of the theoretical and practical results shows that, with the help of the theoretical model, discontinuous steam drying processes can be theoretically described with sufficient accuracy.     

Modelling Diffusion-Limited Drying Behaviour in a Batch Fluidized Bed Dryer

Fluidized bed dryers are often used to extract water from granular materials. When the drying process is mainly limited by the resistance against water transport inside the particle the drying behaviour is said to be diffusion-limited. In the literature there are several models that predict this drying process with very diverging results. In this study a model is set up to arrive at a better prediction for this drying process. The heat and mass transfer in the granular material and the drying air is described. The resulting equations are solved numerically. The model must be extended to incorporate the heat capacity of the dryer.     

Multiphase modeling of intermittent drying using the spatial reaction engineering approach (S-REA)

Several schemes of energy minimization of drying process including intermittent drying have been attempted. Intermittent drying is conducted by applying different heat inputs in each drying period. An effective and physically meaningful drying model is useful for process design and product technology. The lumped reaction engineering approach (L-REA) has been shown previously to be accurate to model the intermittent drying In L-REA, the REA (reaction engineering approach) is used to describe the global drying rate. In this study, the REA is used to model the local evaporation/condensation rate and combined with the mechanistic drying models to yield the spatial reaction engineering approach (S-REA), a non-equilibrium multiphase drying model. The accuracy of the S-REA to model the intermittent drying under time-varying drying air temperature is evaluated here. In order to incorporate the effect of time-varying drying air temperature, the equilibrium activation energy and boundary condition of heat balance implement the corresponding drying settings in each drying period. The results of modeling using the S-REA match well with the experimental data. The S-REA can yield the spatial profiles of moisture content, concentration of water vapor, temperature and local evaporation/condensation rate so that better understanding of transport phenomena of intermittent drying can be obtained. It is argued here that the REA can describe the local evaporation rate under time-varying external conditions well. The S-REA is an effective non-equilibrium multiphase approach for modeling of intermittent drying process.     

Modelling Diffusion-Limited Drying Behaviour in a Batch Fluidized Bed Dryer

ABSTRACT

Fluidized bed dryers are often used to extract water from granular materials. When the drying process is mainly limited by the resistance against water transport inside the particle the drying behaviour is said to be diffusion-limited. In the literature there are several models that predict this drying process with very diverging results. In this study a model is set up to arrive at a better prediction for this drying process. The heat and mass transfer in the granular material and the drying air is described. The resulting equations are solved numerically. The model must be extended to incorporate the heat capacity of the dryer.