热处理对SiCp/Al-Cu-Mg基复合材料力学性能的影响

用粉末冶金法制备了SiCp/Al-Cu-Mg基复合材料,研究了SiC颗粒体积分数、Mg在基体合金中的含量(质量分数)以及热处理工艺对SiCp/Al-Cu-Mg复合材料的力学性能的影响.结果表明,热处理工艺、SiC颗粒的加入和在基体合会中的Mg含量,都能明显提高复合材料的硬度和强度.9v01%SiC/Al-4wt%Cu-1.2wt%Mg复合材料的力学性能最好,其硬度和强度由热处理前的101.3 HV0.02和285 MPa提高到热处理后的151.5 HV0.02和372 MPa.     

镁基纳米混杂复合材料的高温动态拉伸响应三维模拟

采用三维代表体元方法,并考虑界面内聚力,对碳纳米管和纳米SiC混杂增强AZ91D镁合金基复合材料在25～300℃动态拉伸响应进行三维数值模拟,并将模拟结果与实验数据进行比较.结果表明,在不同温度下,该纳米复合材料整体动态拉伸性能随着碳纳米管和纳米SiC颗粒的总体积分数和混杂体积分数比的增加而提高.在总体积分数为1.0％...     

粒度和界面原子调控对SiC/Al复合材料强度的影响

SiC/Al复合材料作为一种轻质高强材料,因其优异的物理化学性能被外界广泛关注。本研究利用分子动力学方法,构建了不同SiC粒径的SiC/Al复合材料模型,根据拉伸变形模拟结果得出更小的SiC粒径有利于材料获得更高的抗拉强度。随着拉伸形变的逐渐增加,SiC颗粒在沿拉伸方向的两侧与Al基体发生分离从而产生孔隙,再从孔隙缺陷处产生位错形核并扩展至Al基体内形成塑性形变。在调节SiC/Al界面上C、Si的占位情况后,界面富Si的条件下结合更强,孔隙产生的难度增大从而对SiC/Al复合材料产生强化作用。     

反复塑性变形对SiC_p/AZ31镁基复合材料组织和性能的影响

采用反复塑性变形(RPW)技术,结合挤压工艺制备出SiC颗粒增强AZ31镁基复合材料,研究了循环次数(RPW次数)对SiC_p/AZ31镁基复合材料显微组织和性能的影响.结果表明,反复塑性变形具有明显的AZ31基体晶粒细化、SiC_p细化和分散作用,能显著提高SiC_p/AZ31复合材料的抗拉强度和硬度,并改善其塑性.在SiC_p的体积分数为4%时,经RPW为300次的热挤压后,AZ31基体晶粒粒径达到最小值20 μm,SiC_p被粉碎成3 μm以下的微粒,且弥散分布于合金基体中,复合材料的室温抗拉强度和硬度(HV)达到或接近最大值,分别为359 MPa和107.     

Si粉粒径及其添加量对SiC陶瓷材料结构和性能的影响

将平均粒径为75 μm和48 μm、质量分数为0%~8%的Si粉分别添加到SiC陶瓷材料中,在1550℃下保温3 h烧成,研究Si粉粒径及其添加量对SiC陶瓷材料烧结性能、力学性能和显微结构的影响。结果表明:添加不同粒径及质量分数的Si粉可改善SiC陶瓷材料的显微结构,提高其烧结性能和力学性能;在一定范围内,较小粒径的Si粉更有利于形成均匀、致密的SiC烧结体,大幅提升SiC陶瓷材料的性能;当Si粉粒径为48 μm且添加的质量分数为4%时,SiC陶瓷材料的烧结性能和力学性能较优,其体积密度和显气孔率分别为2.58 g/cm3和13.5%,抗弯强度和洛氏硬度分别为25 MPa和115 HRB。      

有限元模拟SiC增强Al基复合材料的力学行为

采用有限元方法和轴对称单胞模型模拟了增强体(SiC)形状、体积分数以及不同基体类型对铝基复合材料力学行为的影响。模拟结果表明:增强体的加入会阻碍基体的塑性流变,使基体内发生非均匀变形,在增强体尖角处出现应力集中;椭圆柱形增强体对基体塑性变形的阻力最大,传递载荷的能力最强,因此强化效果最好。在一定范围内,随着增强体体积分数的增加,基体与增强体之间的比表面积增大,有利于载荷的传递;增强体体积分数的增加导致颗粒间距减小,几何必须位错自由运动的路径减少,复合材料的强度也随之增加。此外,不同类型基体自身的塑性流变能力不同,Al-Zn-Mg基体强度最高,在拉伸变形过程中,受到增强体的阻碍作用最大,会有更多的载荷从基体传递到增强体,以Al-Zn-Mg为基体的复合材料的强度最高。     

Microstructures and mechanical properties of Al 2519 matrix composites reinforced with Ti-coated SiC particles

Ti-coated SiC_p particles were developed by vacuum evaporation with Ti to improve the interfacial bonding of SiC_p/Al composites. Ti-coated SiC particles and uncoated SiC particles reinforced Al 2519 matrix composites were prepared by hot pressing, hot extrusion and heat treatment. The influence of Ti coating on microstructure and mechanical properties of the composites was analyzed by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The results show that the densely deposited Ti coating reacts with SiC particles to form TiC and Ti₅Si₃ phases at the interface. Ti-coated SiC particle reinforced composite exhibits uniformity and compactness compared to the composite reinforced with uncoated SiC particles. The microstructure, relative density and mechanical properties of the composite are significantly improved. When the volume fraction is 15%, the hardness, fracture strain and tensile strength of the SiC_p reinforced Al 2519 composite after Ti plating are optimized, which are HB 138.5, 4.02% and 455 MPa, respectively.     

搅拌铸造SiCp/Al-7.0%Si复合材料的三维微观组织模拟

对搅拌铸造法制备SiC颗粒（SiCp）增强Al-7．0％Si（质量分数）复合材料的微观组织形成过程进行了模拟研究,建立了常规凝固条件下相应的宏观传热、等轴枝晶形核、生长以及颗粒推移的三维计算模型,采用一种改进的CA（cellular automaton）方法与有限差分法耦合进行数值计算,研究了不同颗粒体积分数对复合材料宏观传热、微观组织以及颗粒分布的影响．为了验证模拟结果,浇注了阶梯形金属型和砂型试样．结果表明,模拟得到的复合材料颗粒分布及微观组织与实验结果吻合良好．随着颗粒体积分数的增加,凝固时间逐渐缩短,基体晶粒逐渐细化,颗粒分布趋向均匀．     

Effects of volume fraction of SiC particles on mechanical properties of SiC/A1 composites

SiC particle reinforced pure aluminum composites were fabricated using a powder metallurgy method. The effect of the volume fraction of the SiC particles on the mechanical properties of the composites was studied by both model simulation and experiment. The results indicate that the yield strength and tensile strength increase, but the elongation decreases with the increase in the volume fraction of the SiC particles. Both the modified shear lag model and the multi-scale model predicted yield strength and normalized elongation show similar evolution trends with the experimental data. However, the modified shear lag model underestimates the yield strength due to the ignorance of the strengthening mechanisms caused by grain refinement and dislocations interaction by the introduction of the SiC particles, and the multi-scale model overestimates the normalized elongation due to the ignorance of the pores distributed in the matrix.     

脉冲电流频率对预制缺陷TC4钛合金性能的影响

为了研究脉冲电流频率对预制缺陷TC4钛合金组织性能的影响规律,首先采用室温预拉伸制备含孔洞缺陷的TC4试样,然后选取不同频率的脉冲电流对预制缺陷的TC4试样进行通电处理,对比通电前后板材内部的显微孔洞和基体组织的变化情况,并对处理后的试样进行二次室温拉伸获得力学性能参数。结果表明：当脉冲电流频率从0升至140Hz时,TC4内部孔洞体积分数由2.21%下降至0.86%,屈服强度由916.7MPa提高到990.9MPa,抗拉强度由951.2MPa增加至997.5MPa,延伸率提高64.86%;当脉冲电流频率从140Hz提高到160Hz时,内部孔洞体积分数反而增至1.99%,屈服强度和抗拉强度则分别下降到975.1MPa和988.5MPa,延伸率降低了37.70%。显微孔洞体积分数几乎决定了预制缺陷TC4钛合金的力学性能。     

Effects of SiC Volume Fraction and Particle Size on the Deposition Behavior and Mechanical Properties of Cold-Sprayed AZ91D/SiCp Composite Coatings

AZ91D/SiC_p composite coatings were fabricated on AZ31 magnesium alloy substrates using cold spraying. The effects of SiC volume fraction and particle size on the deposition behavior, microhardness, and bonding strength of coatings were studied. The mean sizes of SiC particles tested were 4, 14, and 27 μm. The results show that fine SiC particles (d _0.5 = 4 μm) are difficult to be deposited due to the bow shock effect. The volume fraction of SiC particles in composite coatings increases with the increasing SiC particle size. The microhardness and bonding strength of composite coatings also show increases compared with AZ91D coatings. The volume fractions of SiC particles in the original powder were set at 15, 30, 45, and 60 vol.%. The corresponding contents in composite coatings are increased to 19, 27, 37, and 51 vol.%, respectively. The microhardness of composite coatings also increases as the volume fraction of SiC particles increases.     

Distribution of SiC particles in semisolid electromagnetic-mechanical stir-casting Al-SiC composite

The distribution of SiC particles in Al-SiC composite can greatly influence the mechanical performances of Al-SiC composite. To realize the homogeneous distribution of SiC particles in stir-casting Al-SiC composite, semisolid stir casting of Al-4.25 vol.%SiC composite was conducted using a special electromagneticmechanical stirring equipment made by our team, in which there are three uniformly-distributed blades with a horizontal tilt angle of 25 ° to mechanically raise the SiC particles by creating an upward movement of slurry under electromagnetic stirring. The microstructure of the as-cast Al-SiC composites was observed by Scanning Electron Mcroscopy(SEM). The volume fraction of SiC particles was measured by image analysis using the Quantimet 520 Image Processing and Analysis System. The tensile strength of the Al-4.25 vol.%SiC composites was measured by tensile testing. Results show that the Al-4.25 vol.%SiC composites with the homogeneous distrbutin of SiC particles can be obtained by the electromagnetic-mechanical stirring casting with the speed of 300 and 600 r·min-1 at 620 °C. The differences between the volume fraction of Si C particles at the top of ingot and that at the bottom are both ~0.04 vol.% with the stirring speed of 300 and 600 r·min-1, which are so small that the distribution of SiC particles can be seen as the homogeneous. The tensile strength of the Al matrix is enhanced by 51.2% due to the uniformly distributed SiC particles. The porosity of the composite mainly results from the solidification shrinkage of slurry and it is less than 0.04 vol.%.     

SiC颗粒对SiC_p/2024复合材料半固态下压缩行为的影响

研究了部分重熔SiCp/2024复合材料的微观组织特征和压缩行为,SiC颗粒体积分数分别为10％和20％。复合材料采用粉末冶金法制备,并经高温挤压得到复合材料棒,挤压比为16:1。挤压态复合材料加热到半固态温区在应变速率为0.012 s-1～0.060 s-1范围内进行单轴压缩试验,研究了SiC颗粒体积分数、加热温度和应变速率对复合材料半固态压缩行为的影响规律。流变学分析表明,部分重熔复合材料类似非牛顿流体,可用Norton-Hoff定律来描述,σ=Kεm值在0.25～0.45范围内。     

金刚石–SiC/Al复合材料的构型设计与导热性能

以SiC和镀钨金刚石增强体为原料制备预制体,通过气压浸渗技术在800 ℃,5 MPa条件下制备金刚石–SiC/Al复合材料。利用扫描电镜、红外热成像仪、激光导热仪等对复合材料性能进行分析,研究SiC和金刚石的含量与粒径比对复合材料构型的影响,从而优化复合材料导热性能。结果表明:在相同的SiC粒径下,金刚石体积分数的增加将使复合材料的导热性能明显提升。当金刚石体积分数为30%时,含F100 SiC的复合材料导热性能最佳,其热导率为344 W/(m?K)。当金刚石体积分数相同,粒径比从0.07增大到0.65时,复合材料导热性能依次提升;且在金刚石体积分数为15%时,复合材料的热导率增幅最大,从174 W/(m?K)增大到274 W/(m?K),增长了57%。通过改善金刚石–SiC/Al复合材料中增强体的含量和粒径比可以调控复合材料构型,充分发挥复合材料的导热潜力。      

搅拌铸造SiC_p/A356复合材料的显微组织及力学性能

采用搅拌铸造技术制备质量分数为15%的SiCp增强A356铝基复合材料,并对所制备的复合材料进行后续热挤压变形。通过金相观察(OM),扫描电镜(SEM)及力学性能测试等手段,对该复合材料显微组织与力学性能进行了研究。结果表明,所制备的复合材料铸态组织中,SiCp较均匀地分布于基体中,SiCp与Al界面处存在Si原子的富集;热挤压变形后,显微气孔等铸造缺陷明显减少,材料致密度显著提高,SiCp沿热挤压方向呈流线分布特征,颗粒均匀分散性明显提高;采用535℃×5h固溶+180℃×5h时效处理后,热挤压棒材的力学性能为:σs=370MPa,σb=225MPa,δ=5.3%,时效后析出强化相大小约为200nm,且弥散分布于基体中;断口分析表明,SiCp/A356铝基复合材料的断裂主要是由基体的塑性断裂及SiCp的断裂导致的。     

SiCp/ZA27复合材料的界面结构及耐磨性研究

通过扫描电镜和高分辩透射电镜观察，经选区电子衍射和微区化学成分分析，研究了SiCp／ZA27复合材料的界面结构及耐磨性。结果表明，SiC颗粒均匀地分布于ZA27合金中，界面结合良好，SiCp颗粒周边存在着大量的CuZn4化合物。CuZn4依附于SiC颗粒形核，沿SiC晶面长大速率大于垂直于SiC晶面的长大速率。SiC颗粒显著地提高了ZA27合金的耐磨性。当SiC颗粒含量达30％时，耐磨性提高了126．5倍。     

Quantification of microdamage phenomena during tensile straining of high volume fraction particle reinforced aluminium

Particle reinforced composites are produced by infiltrating ceramic particle beds with 99.99% Al. Resulting materials feature a relatively high volume fraction (40–55 vol. pct) of homogeneously distributed reinforcement. The evolution of damage during tensile straining of these composites is monitored using two indirect methods; namely by tracking changes in density and in Young's modulus. Identification and quantification of the active damage mechanisms is conducted on polished sections of failed tensile specimens; particle fracture and void formation in the matrix are the predominant damage micromechanisms in these materials. The damage parameter derived from the change in density at a given strain is found to be one to two orders of magnitude smaller than the parameter based on changes in Young's modulus. A simple micromechanical analysis inspired by the observed damage micromechanisms is used to correlate the two indirect measurements of damage. The predictions of this analysis are in good agreement with experiment.     

Microstructure and thermal conductivity of copper matrix composites reinforced with mixtures of diamond and SiC particles

The thermal conductivity of diamond hybrid SiC/Cu,diamond/Cu and SiC/Cu composite were calculated by using the extended differential effective medium (DEM) theoretical model in this paper.The effects of the particle volume fraction,the particle size and the volume ratio of the diamond particles to the total particles on the thermal conductivity of the composite were studied.The DEM theoretical calculation results show that,for the diamond hybrid SiC/Cu composite,when the particle volume fraction is above 46% and the volume ratio of the diamond particles to the SiC particles is above 13:12,the thermal conductivity of the composite can reach 500 W·m-1·K-1.The thermal conduc-tivity of the composite has little change when the particle size is above 200μm.The experimental results show that Ti can improve the wettability of the SiC and Cu.The thermal conductivity of the diamond hybrid SiCTi/Cu is almost two times better than that of the diamond hybrid SiC/Cu.It is feasible to predict the thermal conductivity of the composite by DEM theoretical model.     

SiCw和纳米SiCp混杂增强铝基复合材料的制备与评价

采用湿成型法制备了体积分数可以调节的碳化硅晶须与纳米碳化硅颗粒混杂的预制块,确定了挤压铸造法制备混杂增强铝基复合材料的工艺参数.通过扫描电镜和透射电镜分析发现:复合材料中晶须与纳米颗粒分布均匀,并与基体合金的界面结合良好,无界面反应物和孔洞;与基体合金相比,混杂增强复合材料的抗拉强度和弹性模量明显增高,延伸率降低;在晶须体积分数一定时,随纳米SiC颗粒体积分数的增加,复合材料的抗拉强度升高.     

SiC纳米颗粒增强A356铸造合金的表征(英文)

通过搅拌铸造制备SiC纳米颗粒增强A356铝合金复合材料,并研究其显微组织和力学性能。密度测量发现试样的孔隙度较低,且孔隙度随SiC颗粒体积分数的增加而增加。通过光学显微镜和透射电镜观察材料的显微组织,发现弥散的颗粒分布均匀。材料的拉伸强度和弹性模量随加入纳米SiC颗粒的增加而提高,而延展性有所降低。当SiC纳米颗粒的加入量为3.5%时,复合材料的屈服强度和极限抗拉强度达到最高。断口分析表明,拉伸断裂试样为相对韧性断裂。