Gain measurement and upconversion analysis in Tm3+, Ho3+ co-doped alumino-zirco-fluoride glass

The small signal gain coefficients were measured in Tm³⁺,Ho³⁺ co-doped alumino-zirco-fluoride glass. A gain of 15%/cm at 2.05 μm was obtained for pump power density of 42 kW/cm². The temperature increase of the glass was found to be more than 150 K with this pump power, which was estimated from a comparison between fluorescence intensities of Tm^{3+ 3} F₄-³H₆ and Ho^{3+ 5} I₇-⁵I₈. An upconversion rate constant of 12.5×10^-17 cm³ sec^-1 from a coupled (Tm^{3+ 3}F₄, Ho^{3+ 5}I₇) level to a coupled (Tm^{3+ 3}H₅, Ho^{3+ 5}I₆) level was determined by fitting the experimentally obtained gain coefficients to the calculated one which takes into consideration any temperature increase     

Emission cross sections and spectroscopy of Ho3+ laserchannels in KGd(WO4)2 single crystal

The spectroscopic properties of Ho³⁺ laser channels in KGd(WO₄)₂ crystals have been investigated using optical absorption, photoluminescence, and lifetime measurements. The radiative lifetimes of Ho³⁺ have been calculated through a Judd-Ofelt (JO) formalism using 300-K optical absorption results. The JO parameters obtained were Ω₂=15.35×10^-20 cm², Ω ₄=3.79×10^-20 cm², Ω₆ =1.69×10^-20 cm². The 7-300-K lifetimes obtained in diluted (8·10¹⁸ cm^-3) KGW:0.1% Ho samples are: τ(⁵F₃)≈0.9 μs, τ( ⁵S₂)=19-3.6 μs, and τ(⁵F₅ )≈1.1 μs. For Ho concentrations below 1.5×10²⁰ cm^-3, multiphonon emission is the main source of non radiative losses, and the temperature independent multiphonon probability in KGW is found to follow the energy gap law τ_ph ^-1(0)=βexp(-αΔE), where β=1.4×10^-7 s^-1, and α=1.4×10³ cm. Above this holmium concentration, energy transfer between Ho impurities also contributes to the losses. The spectral distributions of the Ho³⁺ emission cross section σ_EM for several laser channels are calculated in σ- and π-polarized configurations. The peak a σ_EM values achieved for transitions to the ⁵I₈ level are ≈2×10^-20 cm² in the σ-polarized configuration, and three main lasing peaks at 2.02, 2.05, and 2.07 μm are envisaged inside the ⁵I₇→⁵I₈ channel     

High current p/p+-diamond Schottky diode

Epitaxial p-type Schottky diodes have been fabricated on p⁺ -substrate. While the activation energy of the epitaxial layer conductivity is 390 meV, that of the substrate is only 50 meV. At forward bias the substrate conductivity dominates above 150°C, leading for a 5×10^-5 cm² area contact to a series resistance of 14 Ω at 150°C reducing to 8 Ω at 500°C. To our knowledge, this is the lowest series resistance reported so far for a diamond Schottky diode enabling extremely high current densities of 10³ A/cm and a current rectification ratio at ±2 V of 10⁵ making these diodes already attractive as high temperature rectifiers     

Formation of 0.05-μm p+-n and n+-pjunctions by very low (<500 eV) ion implantation

The current-voltage (I-V) characteristics of ultrashallow p⁺ -n and n⁺-p diodes, obtained using very-low-energy (<500-eV) implantation of B and As, are presented. the p⁺-n junctions were formed by implanting B⁺ ions into n-type Si (100) at 200 eV and at a dose of 6×10¹⁴ cm^-2, and n⁺-p junctions were obtained by implanting As⁺ ions into p-type (100) Si at 500 eV and at a dose 4×10¹² cm^-2. A rapid thermal annealing (RTA) of 800°C/10 s was performed before I-V measurements. Using secondary ion mass spectrometry (SIMS) on samples in-situ capped with a 20-nm ²⁸Si isotopic layer grown by a low-energy (40 eV) ion-beam deposition (IBD) technique, the depth profiles of these junctions were estimated to be 40 and 20 nm for p⁺-n and n⁺-p junctions, respectively. These are the shallowest junctions reported in the literature. The results show that these diodes exhibit excellent I-V characteristics, with ideality factor of 1.1 and a reverse bias leakage current at -6 V of 8×10^-12 and 2×10^-11 A for p⁺-n and n⁺-p diodes, respectively, using a junction area of 1.96×10^-3 cm²     

Avalanche phenomena in 4H-SiC p-n diodes fabricated by aluminum orboron implantation

Characteristics of p-n junction fabricated by aluminum-ion (Al⁺) or boron-ion (B⁺) implantation and high-dose Al⁺-implantation into 4H-SiC (0001) have been investigated. By the combination of high-dose (4×10¹⁵ cm^-2) Al⁺ implantation at 500°C and subsequent annealing at 1700°C, a minimum sheet resistance of 3.6 kΩ/□ (p-type) has been obtained. Three types of diodes with planar structure were fabricated by employing Al+ or B+ implantation. B ⁺-implanted diodes have shown higher breakdown voltages than Al⁺-implanted diodes. A SiC p-n diode fabricated by deep B+ implantation has exhibited a high breakdown voltage of 2900 V with a low on-resistance of 8.0 mΩcm² at room temperature. The diodes fabricated in this study showed positive temperature coefficients of breakdown voltage, meaning avalanche breakdown. The avalanche breakdown is discussed with observation of luminescence     

Fabrication of planar optical waveguides in LiB3O5 by 2 MeV He+ ion implantation

The fabrication of planar optical waveguides in LiB₃O ₅ is discussed. Using 2-MeV ⁴He⁺ implantation with a dose of 1.5×10¹⁶ ions/cm² at 300 K, the refractive indexes of a 0.2-μm-thick layer 5.1 μm below the crystal surface are reduced to form optical barrier guides. For this ion dose the maximum change from the bulk values of refractive index at a wavelength of 0.488 μm are 1.5%, 5.25%, and 4% for n_x, n_y, and n_z, respectively. The refractive indexes of the guiding region change by less than 0.02% from the bulk values. The dose dependence of the optical barrier height has been measured. A threshold ion dose of about 0.75×10¹⁶ ions/cm² is required to form a refractive index barrier and ion doses higher than about 2.5×10¹⁶ ions/cm². saturate the refractive index decrease. Waveguide propagation losses for annealed single energy implants of dose 1.5×10¹⁶ ions/cm² are dominated by tunneling and are estimated to be ~8.9 dB/cm for the z-cut waveguides used. Multiple energy implants broaden the optical barrier, and losses of <4 dB/cm have been observed     

High voltage 4H-SiC Schottky barrier diodes

Characteristics of 4H-SiC Schottky barrier diodes with breakdown voltages up to 1000 V are reported for the first time. The diodes showed excellent forward I-V characteristics, with a forward voltage drop of 1.06 V at an on-state current density of 100 A/cm². The specific on-resistance for these diodes was found to be low (2×10 ^-3 Ω-cm² at room temperature) and showed a T ^1.6 variation with temperature. Titanium Schottky barrier height was determined to be 0.99 eV independent of the temperature. The breakdown voltage of the diodes was found to decrease with temperature     

Electrical characterization of ultra-shallow junctions formed bydiffusion from a CoSi2 layer

Ultra-shallow p⁺/n and n⁺/p junctions were fabricated using a Silicide-As-Diffusion-Source (SADS) process and a low thermal budget (800-900°C). A thin layer (50 nm) of CoSi₂ was implanted with As or with BF₂ and subsequently annealed at different temperatures and times to form two ultra-shallow junctions with a distance between the silicide/silicon interface and the junction of 14 and 20 nm, respectively. These diodes were investigated by I-V and C-V measurements in the range of temperature between 80 and 500 K. The reverse leakage currents for the SADS diodes were as low as 9×10 ^-10 A/cm² for p⁺/n and 2.7×10^-9 A/cm² for n⁺/p, respectively. The temperature dependence of the reverse current in the p ⁺/n diode is characterized by a unique activation energy (1.1 eV) over all the investigated range, while in the n⁺/p diode an activation energy of about 0.42 eV is obtained at 330 K. The analysis of the forward characteristic of the diodes indicate that the p⁺ /n junctions have an ideal behavior, while the n⁺/p junctions have an ideality factor greater than one for all the temperature range of the measurements. TEM delineation results confirm that, in the case of As diffusion from CoSi₂, the junction depth is not uniform and in some regions a Schottky diode is observed in parallel to the n⁺/p junction. Finally, from the C-V measurements, an increase of the diodes area of about a factor two is measured, and it is associated with the silicide/silicon interface roughness     

Low-temperature fabrication of p+-n diodes with300-Å junction depth

Gas immersion laser doping (GILD) was used to fabricate p⁺ -n diodes with 300-Å junction depth. These diodes exhibit ideality factors of 1.01-1.05 over seven decades of current, reverse leakage current densities ⩽10 nA/cm² at -5-V reverse bias, breakdown voltages above 100 V, and electrical activation of the boron impurity to concentrations approaching 1×10²¹ atoms/cm³. This behavior is achieved without the use of a furnace or rapid thermal anneal     

Low-resistance bandgap-engineeredW/Si1-xGex/Si contacts

Bandgap-engineered W/Si_1-xGe_x/Si junctions (p⁺ and n⁺) with ultra-low contact resistivity and low leakage have been fabricated and characterized. The junctions are formed via outdiffusion from a selectively deposited Si_0.7Ge _0.3 layer which is implanted and annealed using RTA. The Si _1-xGe_x layer can then be selectively thinned using NH₄OH/H₂O₂/H₂O at 75°C with little change in characteristics or left as-deposited. Leakage currents were better than 1.6×10^-9 A/cm² (areal), 7.45×10^-12 A/cm (peripheral) for p⁺/n and 3.5×10^-10 A/cm² (peripheral) for n⁺/p. W contacts were formed using selective LPCVD on Si_1-xGe_x. A specific contact resistivity of better than 3.2×10^-8 Ω cm² for p ⁺/n and 2.2×10^-8 Ω cm² for n⁺/p is demonstrated-an order of magnitude n⁺ better than current TiSi₂ technology. W/Si_1-xGe _x/Si junctions show great potential for ULSI applications     

In-situ low energy BF2+ion doping for silicon molecular beam epitaxy

An experimental study of the p-type ion dopant BF2+ in silicon molecular beam epitaxy (MBE) is described. BF2+ was used to dope MBE layers during growth to levels ranging from 1 × 10¹⁶/cm³to 4 × 10¹⁸/cm³over a growth temperature range of 650°C to 1000°C. The layers were evaluated using spreading resistance, chemical etching, and secondary ion mass spectroscopy. Complete dopant activation was observed for all growth temperatures. Remnant fluorine in the epitaxial layer was less than 2 × 10¹⁶/cm³in all cases. Diffused p-n junction diodes fabricated in BF2+-doped epitaxial material showed hard reverse breakdown characteristics.     

Planar, ion implanted, high voltage 6H-SiC P-N junction diodes

Planar, high voltage (800 V) P-N junction diodes have been fabricated for the first time on N-type 6H-SiC by room temperature boron implantation through a pad oxide deposited within windows etched in an LPCVD field oxide. All the diodes showed excellent rectification with leakage currents of less than 10 nA (~5×10^-5 A/cm² ) until avalanche breakdown. It was found that the breakdown voltage increases with junction depth. The reverse recovery time (t_rr) was measured to be 50 ns for the 800 V diode from which an effective minority carrier life time of 12.5 ns was extracted     

A high breakdown-voltage SiCN/Si heterojunction diode forhigh-temperature applications

Cubic crystalline p-SiCN films are deposited on n-Si(100) substrates to form SiCN/Si heterojunction diodes (HJDs) with a rapid thermal chemical vapor deposition (RTCVD) technique. The developed SiCN/Si HJDs exhibit good rectifying properties up to 200°C. At room temperature, the reverse breakdown voltage is more than 29 V at the leakage current density of 1.2×10^-4 A/cm². Even at 200°C, the typical breakdown voltage of SiCN/Si HJDs is still preserved about 5 V at the leakage current density of 1.47×10^-4 A/cm². These properties are better than the β-SiC on Si HJDs for high temperature applications     

Diode-pumped ytterbium-doped Sr5(PO4)3F laser performance

The performance of the first diode-pumped Yb³⁺-doped Sr ₅(PO₄)₃F (Yb:S-FAP) solid-state laser is discussed. An InGaAs diode array has been fabricated that has suitable specifications for pumping a 3×3×30 mm Yb:S-FAP rod. The saturation fluence for diode pumping was deduced to be 5.5 J/cm ² for the particular 2.8 kW peak power diode array utilized in our studies. This is 2.5× higher than the intrinsic 2.2 J/cm ² saturation fluence as is attributed to the 6.5 nm bandwidth of our diode pump array. The small signal gain is consistent with the previously measured emission cross section of 6.0×10^-20 cm², obtained from a narrowband-laser pumped gain experiment. Up to 1.7 J/cm³ of stored energy density was achieved in a 6×6×44 mm Yb:S-FAP amplifier rod. In a free running configuration, diode-pumped slope efficiencies up to 43% (laser output energy/absorbed pump energy) were observed with output energies up to ~0.5 J per 1 ms pulse. When the rod was mounted in a copper block for cooling, 13 W of average power was produced with power supply limited operation at 70 Hz with 500 μs pulses     

A high-performance InGaAs/InAlAs double-heterojunction bipolartransistor with nonalloyed n+-InAs cap layer on InP(n) grownby molecular beam epitaxy

An InGaAs/InAlAs double-heterojunction bipolar transistor (DHBT) on InP(n) grown by molecular-beam epitaxy (MBE) that exhibits high DC performance is discussed. An n⁺-InAs emitter cap layer was used for nonalloyed contacts in the structure and specific contact resistances of 1.8×10^-7 and 6.0×10^-6 Ω-cm² were measured for the nonalloyed emitter and base contacts, respectively. Since no high-temperature annealing is necessary, excellent contact surface morphology on thinner base devices can easily be obtained. In devices with 50×50-μm² emitter area, common-emitter current gains as high as 1500 were achieved at a collector current density of 2.7×10³ A/cm² . The current gain increased up to 2000 for alloyed devices     

Fabrication and characterization of metal-oxide-semiconductorfield-effect transistors and gated diodes using Ta2O5 gate oxide

N-channel metal oxide semiconductor field effect transistors (MOSFETs) using Ta₂O₅, gate oxide were fabricated. The Ta₂O₅ films were deposited by plasma enhanced chemical vapor deposition. The I_DS-V_DS and I_DS-V_GS characteristics mere measured. The electron mobility was 333 cm²/V·s. The subthreshold swing was 73 mV/dec. The interface trapped charge density, the surface recombination velocity, and the minority carrier lifetime in the field-induced depletion region measured from gated diodes were 9.5×10¹² cm^-2 eV^-1, 780 cm/s and 3×10^-6 sec, respectively. A comparison with conventional MOSFETs using SiO₂ gate oxide was made     

Measurement of the stimulated emission cross section for the 4F3/2-4I13/2transition of Nd3+ in YAlO3 crystal

A method for the simultaneous measurement of the stimulated emission cross section and fluorescence lifetime by studying the relation between laser parameters and the laser relaxation oscillation frequency is discussed. The stimulated emission cross section for the ⁴F_3/2-⁴I_13/2 transition of Nd³⁺ ion in YAP crystal was measured to be (22±1)×10^-20 cm²     

InP/InGaAs HBTs with n+-InP contacting layers grown byMOMBE using SiBr4

InP/InGaAs heterojunction bipolar transistors (HBTs) with low resistance, nonalloyed TiPtAu contacts on n⁺-InP emitter and collector contacting layers have been demonstrated with excellent DC characteristics. A specific contact resistance of 5.42×10^-8 Ω·cm², which, to the best of our knowledge, is the lowest reported for TiPtAu on n-InP, has been measured on InP doped n=6.0×10¹⁹ cm^-3 using SiBr₄. This low contact resistance makes TiPtAu contacts on n-InP viable for InP/InGaAs HBTs     

Tunable Cr4+:YSO Q-switched Cr:LiCAF laser

Tunable passive Q-switching (781 nm to 806 nm at 300 K) of a flash-lamp pumped Cr³⁺:LiCaAlF₆ (Cr:LiCAF) laser with a Cr⁴⁺:Y₂SiO₅ (Cr⁴⁺:YSO) broad-band solid-state saturable absorber has been realized. Typical pulse widths of the Q-switched laser output ranged from 40 ns to 80 ns, depending on the lasing wavelength. Spectral narrowing and reduced beam diameter with the use of the saturable absorber were observed. The ground state and the excited state absorption cross sections of the Cr⁴⁺:YSO absorber were found by bleaching experiments to be (7.0±1.4)×10^-19 cm² and (2.3±0.5)×10^-19 cm² at 694 nm, respectively. Numerical simulation was utilized to simulate the Cr:LiCAF passive Q-switching with Cr⁴⁺ :YSO solid-state saturable absorber     

Steady-state and transient forward current-voltage characteristicsof 4H-silicon carbide 5.5 kV diodes at high and superhigh currentdensities

Steady-state and transient forward current-voltage I-V characteristics have been measured in 5.5 kV p⁺-n-n⁺ 4H-SiC rectifier diodes up to a current density j≈5.5×10 ⁴ A/cm². The steady-state data are compared with calculations in the framework of a model, in which the emitter injection coefficient decreases with increasing current density. To compare correctly the experimental and theoretical results, the lifetime of minority carriers for high injection level, τ_ph, has been estimated from transient characteristics. At low injection level, the hole diffusion length L_pl has been measured by photoresponse technique. For a low-doped n-base, the hole diffusion lengths are L_pl≈2 μm and L_ph≈6-10 μm at low and high injection levels respectively. Hole lifetimes for low and high injection levels are τ_pl≈15 ns and τ_ph≈140-400 ns. The calculated and experimental results agree well within the wide range of current densities 10 A/cm ²3 A/cm². At j>5 kA/cm², the experimental values of residual voltage drop V is lower than the calculated ones. In the range of current densities 5×10³ A/cm²4 A/cm², the minimal value of differential resistance R_d =dV/dj is 1.5×10^-4 Ω cm². At j>25 kA/cm², R_d increases with increasing current density manifesting the contribution of other nonlinear mechanisms to the formation steady-state current-voltage characteristic. The possible role of Auger recombination is also discussed