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The gas-liquid and solids-liquid mass transfer characteristics of a slurry reactor with vibratory agitation have been studied in gas-liquid-solids three phase systems. It has been found that the rates of mass transfer between both the gas-liquid and the solids-liquid phases are influenced by the solids concentration and the gas flow rate if the solids concentration and the gas flow rate exceed 5 to 10% by volume and about 0.2 cm/s, respectively. 相似文献
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Apparent mass transfer coefficients for solid dissolution in a liquid with and without a chemical reaction were experimentally determined in a fixed bed three phases reactor with downward cocurrent gas and liquid flows. The chemical system selected was benzoic acid, sodium hydroxide in aqueous solution, and atmospheric air. Continuous gas, pulse and dispersed bubble regimes were studied and the results were correlated obtaining apparent mass transfer coefficient as a function of liquid and fluid volumetric flow. It was found that gas flow effect on mass transfer coefficient was small over continuous gas and dispersed bubble regimes, but appreciable over pulse regime. Additionally, it was found that the mathematical model that best described the mass transfer process under pulse regime, by using the increment factor due to the instantaneous chemical reaction, is the film theory 相似文献
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Sachin Y. Chinnapa Reddy Ashok N. Bhaskarwar 《Chemical Engineering Communications》2000,178(1):103-127
A model to predict conversions in a froth bed reactor has been developed. The model is then compared against the available experimental data on the oxidation of sodium sulfide in a foam bed contactor. The predictions using the present model are also compared against those based on the model of a foam bed reactor developed earlier. The predictions using the present model agree fairly well with the experimental data and, in some cases, are even in better quantitative agreement than the previous single stage model of a foam bed reactor. The case of significant surface resistance due to surfactant has also been analyzed theoretically, obtaining analytical solutions for the concentration profile and fractional gas absorption in a liquid froth shell. 相似文献
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采取隔板将传统的气-液-固三相反应器均分成互不相通的多腔室,利用计算机控制电磁阀交替开闭,对各腔室进行周期通气,从而实现反应器的振荡操作,本文研究了振荡周期、操作气速和腔室数对反应器溶氧传质系数的影响.结果表明,振荡周期对溶氧传质系数有很大影响,随腔室数、操作气速的增加,反应器最佳振荡周期明显缩短,不论是双腔室、三腔室还是四腔室,随操作气速的增加,最佳振荡周期均以相同的斜率直线下降,与稳态操作相比,多腔室动态操作可以比较有效地提高反应器的溶氧传质系数.但腔室数对动态操作溶氧传质系数的影响不明显 相似文献
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LOCAL LIQUID SIDE MASS TRANSFER MODEL IN AIRLIFT LOOP REACTOR AND SELF-ASPIRATED REVERSED FLOW JET LOOP REACTOR 总被引:1,自引:0,他引:1
Combining Higbie's penetration theory and Kolmogoroff's theory of isotropic turbulence, a small-scale isotropic mass transfer model for the local liquid side mass transfer coefficients in a gas-liquid two-phase airlift loop reactor and a self-aspirated reversed flow jet loop reactor has been developed. Good agreement with the experimental data suggests a general applicability of the proposed model in these reactors. 相似文献
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多相机械搅拌气升式环流反应器中的气液传质 总被引:3,自引:0,他引:3
由空气水玻璃珠(ρ=2630kg/m3,dp=25μm)构成三相体系,在内置机械搅拌桨的内循环反应器中进行实验。实验条件:表观气速Ug0.5~19.0cm/s,固含量εs1%、2%、4%(质量分数),搅拌桨速度为0~1200r/min。结果表明总体积传质系数KLa随气体表观气速和搅拌速度增加而增加。总能量耗散速率同时受通气能量耗散速率与搅拌机械能量耗散速率的影响。搅拌转速一定时,搅拌机械能量耗散速率随表观气速的增加而下降。从能量角度考虑,表观气速和搅拌速度的选择应有一个良好的匹配。存在固体颗粒时,传质系数KLa与传质界面面积a均得到改进。对于25μm玻璃珠体系,KLa值随固含率变化,其最大值的产生在2%固含率左右,固含率继续增加,则KLa降低。最后对KLa固含率及能量耗散速率作了关联。 相似文献
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Gas-liquid and liquid-solid mass transfer coefficients were obtained in a draft tube bubble column slurry reactor (abbreviated as DTBCSR) from the measurements of gas absorption and ion-exchange, respectively. Oxidation of sulfur dioxide on activated carbon was carried out in the same reactor. The effects of gas flowrates, diameters of draft tube and solid concentrations were investigated. These results were compared with those in a bubble column slurry reactor without draft tube (abbreviated as BCSR). Minimum gas velocities for complete suspension of solid particles in DTBCSR were lower than those in BCSR. Gas-liquid and liquid-solid mass transfer coefficients in DTBCSR were higher than those in BCSR. Both coefficients were almost independent of solid loadings. Reaction rates in DTBCSR were higher than those in BCSR and a stirred slurry reactor (abbreviated as SSR) except for lower gas flow rates and smaller particles. 相似文献
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Fundamental characteristics of hydrodynamics and mass transfer have been measured in an air lift slurry reactor with a draft tube. The solid suspension capacity, i.e., the critical solid holdup, the gas holdup and the volumetric gas-liquid mass transfer coefficient were measured in the two draft tube columns of 0.1485 and 0.10?m in diameter. Four activated carbon beads ranging in size from 0.25 to 2.19?mm in average diameter were utilized as suspended solids in the experiments.
The critical solid holdup in the draft tube slurry column is found to be much greater than that in the conventional bubble column. An empirical correlation is developed to account for the critical solid holdup behavior in the draft tube column. The gas holdup in the draft tube column agrees well with that in the bubble column. The overall gas-liquid mass transfer coefficient, k1awas measured by the oxygen probe method. The effect of solid holdup on k1a is found to be negligible in the present system. The empirical equation is developed to correlate k1a in the draft tube slurry reactor. 相似文献
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气升式内循环蜂窝陶瓷反应器(IAL-CHS)的氧传质性能测定结果表明,IAL-CHS反应器与普通气升式反应器相比氧传递能力更强,氧传质效果更好,氧转移效率更高。进行清水充氧试验分别采用0.006、0.018、0.025、0.05、0.10、0.15、0.20 m.3h-1的曝气强度,最初IAL-CHS反应器的氧传递系数(Kla)20与曝气强度呈正相关,在0.1m3.h-1的曝气强度下氧传质系数增至最大值,之后再提高曝气强度反应器的氧传递系数反而降低。然而反应器的氧转移效率EO2值始终随着曝气强度的升高而减少。 相似文献
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Liquid-solid mass transfer coefficients in a three phase draft tube fluidized bed reactor have been measured using spherical ion exchange particles. The particle diameters ranged from 655 to 1119μm and solids volume fractions of approximately 5 and 10% were employed in water at 28°C. The experimental data can be successfully correlated using a Reynolds number derived using Kolmogoroffs theory of isotropic turbulence, although it is doubtful whether isotropic turbulence actually prevails in the fluidized bed over the range of conditions employed. Comparison with correlations determined for bubble columns and gas-liquid fluidized beds is performed. A model which considers the draft tube reactor as comprising two distinct fluid mechanical regions is developed to explain the apparently lower values of mass transfer coefficients obtained in a draft tube as opposed to conventional fluidized bed reactor. 相似文献
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The influence of suspended fine particles of differing adsorbing capacity (activated carbon, avicell cellulose, SiO2, and molecular sieves) on the liquid-film mass transfer coefficient κL, was examined experimentally in a stirred cell of well-defined gas-liquid interfacial area by chemical methods. The greatest effect on κL was observed with the activated carbon (about a threefold increase). An addition of glycerine in excess of 2.5 × 10-3 k mol/m3, which was adsorbed on the particles preferentially, removed this increase in κL totally. Amongst other particles, only avicell cellulose showed measureable effects. The increase in κL values was inversely proportional to the temperature and the stirring speed, and the particle loading was found to be immaterial after a certain value. When the reaction rate increased (hence, when the thickness of dissolved gas-rich layer decreased) by gradual addition of a homogeneous catalyst (i.e. Co++ for sulphite oxidation), the effect of particles on κL decreased and eventually it disappeared. 相似文献
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An experimental investigation was done on oxygen transfer into laminar flows of whole blood and saline downstream of an abrupt pipe expansion. This was used as the experimental model for regions of separated flow in the arterial system. The flow was fully-developed prior to the tube expansion with Reynolds numbers between 160 and 850. The results showed high transfer rates over most of the region downstream of the step, with maximum transfer occurring near the reattachment point. In addition, oscillations of the transfer rate were measured at the larger Reynolds numbers of 450 and 850. 相似文献
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气液环流反应器中基于大、小两类气泡的气相返混模型和气液传质特性 总被引:1,自引:0,他引:1
在矩形卧式多级串联环流反应器中,改变气速和液相表面张力,将气泡分为大气泡和小气泡两大类,进行研究。着重考察了两者对气相返混和气液界面传质的贡献,利用气相大、小气泡的分区模型,传质模型等进行了模拟计算,并提出了“有效气含率”这个新概念 相似文献
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根据肌苷发酵过程主要是溶氧传质控制的结论,本文研究了操作变量和装置结构变量对环流发酵反应器中氧传递的影响,定量地得到气含率,液体循环速度和结构因素对氧传递的关系。对发酵反应器中溶氧浓度分布进行了摸拟计算,依据计算的结果提出了较佳的 D_E/D 和 L_E/D 的结构。 相似文献
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A modified homogeneous mass transfer model based on penetration theory is proposed for the mass transfer enhancement in gas-liquid-liquid systems. The present model assumes the existence of a shuttle mechanism between the organic dispersed phase and the continuous aqueous phase and considers the effect of diffusivity along with the solubility ratio and the dispersed phase holdup. The concept of effective diffusivity for gas in liquid-liquid emulsions has been used to consider the effect of diffusivity on mass transfer enhancement. The proposed model predicts the experimentally obtained enhancement factor with reasonable accuracy and numerical simplicity. Fresh experiments were also conducted to further validate the proposed model. 相似文献
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The electrochemical limiting current method was used to measure mass transfer coefficients with cocurrent upward gas-liquid flow in packed bed electrodes. Liquid-solid and overall gas-solid coefficients were determined from limiting current data in the presence of inert or reactive gas flows with the use of a plug flow model. The presence of inert gas flow increased mass transfer coefficients over those in single-phase flow by a factor of up to 1.7. As a result of boundary layer penetration by gas bubbles, sparging with reactive gas increased mass transfer rates by a factor of up to 3.5. 相似文献
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It is proposed that the transfer of oxygen from the bulk phase to the surface of a burning carbon particle immersed in a fluidized bed of incombustible particles can be characterized by the transfer associated with the interparticulate gas flow enhanced by the fluctuations in the gaseous environment around the burning particle. The enhancement is attributed to the movement of bubbles in the vicinity of the carbon particle and is predicted by a semi-empirical function of the bubble frequency. The resulting expression is incorporated in a recently proposed unsteady-state model for mass transfer (La Nauze et al., Chem. Eng. Sci., 39, 1623-1633 (1984)rpar; The new formulation correctly predicts the order and trends for the mass transfer coefficient for petroleum coke burning in a bed of sand fluidized by air over a wide range of conditions. In order to test the validity of the model, experiments have been performed using a helium/oxygen gas mixture instead of air. The model successfully predicts the mass transfer coefficient for this situation. 相似文献