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The removal of low-molecular-weight benzoic acid (benzoic acid, p-toluic acid, and salicylic acid)-derived and aniline (aniline, 4-chloroaniline, and 2,6-dimethylaniline)-derived organic compounds through adsorptive micellar flocculation (AMF) with anionic surfactants (sodium dodecyl sulfate, SDS) and aluminum sulfate was demonstrated. The interactions between SDS and the organic compounds were studied using 1H nuclear magnetic resonance (NMR) spectroscopy. Batch AMF experiments were conducted to study the influence of several factors on target pollutant removal. For benzoic acid derivatives, the removal rate was improved by increasing the SDS and Al concentrations, while increases in the concentrations of the organic pollutant tended to decrease the removal rate. The highest removal efficiencies were observed with p-toluic acid (95.4%) > salicylic acid (84.5%) > benzoic acid (76.5%) under weakly acidic conditions due to the greater hydrophobicity of p-toluic acid and the complexation of the Al salts and the salicylic acid. The removal rates of the aniline derivatives were positively related to the SDS concentration and negatively related to the pH. At a pH of 3.0, the highest removal rates of aniline, 4-chloroaniline, and 2,6-dimethylaniline (91.3%, 98.0%, and 97.6%, respectively) were observed. For aniline compounds, charge neutralization between the SDS anions and aniline cations dominated the removal process. These findings provide new insights for the development of further applications of AMF for the removal of benzoic acid and aniline derivatives. 相似文献
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B. C. Edwards 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1969,19(5):141-146
A proprietary water-soluble organic polymer (polymeric flocculant) of high molecular weight has been used to remove sediment from cooling water systems; current explanations of the mechanism are inadequate. A new flow-cell has been designed to study sediment-flocculant interactions under simulated practical conditions. Quantitative measurements of the conditions required for sediment removal in the flow-cell together with flocculation tests on the same systems have been made. The effects of an inorganic coagulant on the removal mechanism have also been studied. Sediment removal is interpreted in terms of flocculation theory; flocculation of a dispersed phase is found to be essential to the removal process. 相似文献
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选用聚合氯化铝(PAC)和KMnO4、MnO2进行复配处理微污染水。考察了复配比例、复配成分、反应时间对絮凝效果的影响以及絮凝沉降性能。试验结果表明:KMnO4、MnO2与PAC具有极好的复配效果,复配后浊度及有机碳总量(TOC)去除率进一步提高,絮凝沉降性能也得到改善。在浊度去除方面,要达到92.33%的去除率,复配絮凝剂比单独投加PAC节省36.8%的投加量。在TOC去除方面,单独投加15 mg/L的PAC仅能达到17.2%的去除率,而投加15.8 mg/L的复配絮凝剂则能达到47.6%的去除率。在絮凝沉降性能方面,当浊度去除要求相同时,复配絮凝剂可缩短27%~50%的反应时间。 相似文献
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A new flocculant was synthesized through the modification of sodium alginate with thiosemicarbazide. In the preparation, amino thiourea groups which had excellent adsorption properties for heavy metal ions were introduced to the flocculant. The structure of the flocculant was confirmed by elemental analysis, Fourier transform infrared, UV spectrophotometry, nuclear magnetic resonance, and thermal analysis. The flocculation behaviors of the flocculant for three heavy metal ions were investigated. The results showed that the removal rates of the flocculant for Pb2+, Cd2+, and Cu2+ reached up to 97.8%, 86.3%, and 80.0%, respectively, and the flocculation capacities were as high as 489, 215, and 160 mg/g, respectively. The excellent adsorption was ascribed to the double effects of electronic interaction and chelation between the flocculant and heavy metal ions. The flocculant had particular flocculation selectivity for Pb2+ in the mixed heavy metal ion solutions containing Cd2+or Cu2+, respectively. The flocculation process corresponded to Langmuir isotherm model, the flocculation kinetics agree with pseudo second order. The flocculant had potential applications for treatment of wastewater. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46577. 相似文献
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壳聚糖絮凝剂处理水源水中有机物的试验研究 总被引:9,自引:0,他引:9
研究了壳聚糖絮凝剂的絮凝特性,进行了壳聚糖絮凝剂跟无机絮凝剂复合絮凝对水源水中浊度和有机物去除的试验。实验结果表明,复合絮凝能够相互促进各自的絮凝性能,显著提高有机物的去除效果,并使除浊和去除有机物得到了统一。在壳聚糖絮凝剂分别与三种常用无机絮凝剂(硫酸铝、氯化铁和聚合铝铁)的复合絮凝的效果的实验表明,其中聚合铝铁跟壳聚糖的复合絮凝剂的效果最好,在最佳条件下,其浊度、CODMn和UV254的去除率分别达到了97%、44%和55%。 相似文献
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以聚丙烯酰胺为主链,接枝二乙胺,合成叔胺型絮凝剂(改性聚丙烯酰胺絮凝剂),对含油废水进行处理,探讨了不同搅拌速度、搅拌时间、絮凝剂以及反应物的浓度、pH值、沉降时间对COD去除效率的影响。结果表明,在改性絮凝剂用量为2.5 mL/L、pH值为6、水利条件为快速搅拌(180 r/min)4 min、慢速搅拌(90 r/min)10 min,高岭土投入量为7.5 g/L以及絮凝沉降时间为30 min的最佳絮凝条件下,改性絮凝剂对含油废水COD的去除率达到80.2%,效果较为理想。 相似文献
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聚硅硫酸锌絮凝剂的制备工艺研究 总被引:1,自引:1,他引:0
以硅酸钠、硫酸锌和硫酸为原料合成了聚硅硫酸锌,研究了SiO2浓度、Zn与Si物质的量比、硅酸活化pH值、硅酸聚合时间、B与Si物质的量比等因素对聚硅硫酸锌絮凝性能的影响,得到聚硅硫酸锌絮凝剂的最佳制备工艺为:SiO2的质量分数为5%、Zn与Si物质的量之比为2.0、硅酸活化pH值1.11、聚硅酸聚合时间为1.5 h、B与Si物质的量之比为0.6。在最佳制备工艺下制备的絮凝剂用量为0.5 mL/L时,除浊率达到最大值96.1%,结果表明聚硅硫酸锌絮凝效果较好,除浊性能高,具有较强的应用性。 相似文献
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《分离科学与技术》2012,47(3):583-593
Abstract In the present communication, experiments were conducted to investigate the efficiency of mucilage isolated from fruits of Coccinia indica for the treatment of simulated textile wastewater samples containing direct dyes, direct fast scarlet (DFS) and direct fast yellow (DFY) and vat dyes, golden yellow (GY) and nyanthrene yellow (NY). This mucilage (Ku) is an ecofriendly and low cost anionic polysaccharide capable of reducing color from textile effluent through flocculation process. The flocculation efficiency of Ku was improved by grafting polyacrylamide onto it. The copolymer thus obtained (Ku‐g‐PAM) showed much better flocculation capacity than that of its precursor by reducing the flocculant dose and treatment time to half. The results showed that the maximum removal was obtained at acidic pH with both the flocculants. Statistical analysis showed that the change in percent removal with pH was highly significant in case of direct dyes while it was significant in case of vat dyes removal. The plausible mucilage‐dye interaction and flocculation mechanism has been discussed. 相似文献
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Removal of Direct Yellow 27 Dye by Ionic Flocculation: The Use of an Environmentally Friendly Surfactant
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Ricardo Paulo Fonseca Melo Eduardo Lins de Barros Neto Maria Carlenise Paiva de Alencar Moura Tereza Neuma de Castro Dantas Afonso Avelino Dantas Neto Shirlle Katia da Silva Nunes 《Journal of surfactants and detergents》2017,20(2):459-465
The presence of dyes is one of the main contributors to the organic load in textile effluents. In this study a mixture of surfactants, produced from animal/vegetable fats, was used to remove the Direct Yellow 27 dye from a synthetic wastewater through an ionic flocculation process. It was evaluated the effect of contact time, temperature, and surfactant concentration on dye removal efficiency. It was also evaluated the kinetics, equilibrium, and diffusion mechanism of the process. The kinetics of the process was well described by both Pseudo-second order and Elovich models. The transport of dye molecules to the surfactant flocs is controlled by the external layer. Equilibrium data showed a good fit to the Langmuir model. A removal rate of 93% was achieved in a single stage, after 5 h of contact time. 相似文献
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The removal of single macromolecules impurity is the basis study for the promotion of flocculation technology application in the Chinese herbal medicine solution purification. We applied the flocculation process to remove gelatinized starch in solution. Three types of cationic polyacrylamide (CPAM) with different charge density were used for flocculation of gelatinized starch solution. The flocculation performance was evaluated in terms of the amylose removal ratio (AMRR), the amylopectin removal ratio (APRR), total starch removal ratio (TSRR) and supernatant turbidity (ST). The flocs were characterized by sedimentation performance, Fourier transform infrared (FTIR), scanning electron microscope (SEM) and X-ray photoelectric spectroscopy (XPS) method. The experimental results show that the flocculant CN15 has the best performance for gelatinized starch flocculation among three flocculants. According to the characterization analysis, the flocs exhibited an obvious network structure, and it is concluded that hydrogen bonding between N-H in CPAM and C-O in the starch and bridging flocculation played the essential roles in flocculation of the gelatinized starch. 相似文献
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《分离科学与技术》2012,47(15):2516-2527
ABSTRACTEvaluation of various flocculants, selection of suitable flocculant and optimization of process parameters for reduction of colloidal particles have been carried out for lyocell spin bath solution. Maximum turbidity reduction was achieved with polyacrylamide based flocculant. Experiments were carried out using lab jar tests and factorial design of experiment was applied to optimize the flocculation process parameters, i.e., flocculant dosage, mixing time and mixing speed. Operation at optimum conditions reduced turbidity by 80–90% and improved the downstream operation of ion-exchanger by 11%. Without flocculation treatment, surface fouling of ion-exchange resin was observed in Scanning Electron Microscopy. 相似文献
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聚硅酸铝铁(PSAF)作为一种新型无机高分子絮凝剂,在除浊、脱色以及去除有机物方面具有优越的性能。文献报道的浊度、色度以及有机物的最高去除率可分别达97%、98%、87%。控制PSAF性能及稳定性的关键因素是Al/Fe/Si的摩尔比、硅酸浓度、碱化度、熟化时间等;同时,PSAF的絮凝效果还受水体参数的影响。介绍了PSAF的制备、絮凝效果及其影响因素,最后简要概括了当前研究存在的问题。 相似文献
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Subhash Bhatia Zalina Othman Abdul L Ahmad 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2006,81(12):1852-1858
This research paper covers the suitability of the coagulation–flocculation process using Moringa oleifera seeds after oil extraction as a natural and environmentally friendly coagulant for palm oil mill effluent treatment. The performance of M. oleifera coagulant was studied along with the flocculant KP 9650 in removal of suspended solids, organic components and in increasing the floc size. The optimum values of the operating parameters obtained from the laboratory jar test were applied in a pilot‐scale treatment plant comprised of coagulation–flocculation and filtration processes. Pilot‐scale pretreatment resulted in 99.7% suspended solids removal, 71.5% COD reduction, 68.2% BOD reduction, 100% oil and grease removal and 91% TKN removal. In pilot plant pretreatment, the percentage recovery of water was 83.3%, and 99.7% sludge was recovered after dewatering in a filter press. Copyright © 2006 Society of Chemical Industry 相似文献
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