Ce–Nd codoping effect on the structural and optical properties of TiO2 nanoparticles

We report the changes in the structural and optical property of TiO₂ nanoparticles on codoping Ce–Nd ions. X-ray diffraction clearly demonstrates the structural changes occurring in the codoped TiO₂ nanoparticle. Oxygen defects disturb the TiO bonds in the TiO₆ octahedra and result in the shifting and broadening of the Raman E_g peak. Pure TiO₂ nanoparticles show absorption peak in the UV region. However, codoped TiO₂ nanoparticles exhibit absorption peaks in the visible region corresponding to the f–d and f–f electronic transition of Ce³⁺ and Nd³⁺ in the crystalline environment of TiO₂. The visible emission peaks of pure and codoped TiO₂ nanoparticles are mainly associated with oxygen vacancies. Incorporation of cerium intensifies the visible emission peaks of TiO₂ nanoparticles. On the other hand, codoping of Nd forms some non radiative recombination centres and increases the possibility of emission energy transfer among dopants, defects, thereby quenching the intensity of the visible emission peaks.     

The effect of γ-irradiation on the optical properties of polyoxymethylene compacts

The effects of -irradiation on the optical properties of polyoxymethylene (POM) compacts are studied at room temperature. A UV-visible spectrometer is used to study the optical absorbency in the wavelength range 200–1100 nm. The optical energy of both direct and indirect transitions as well as the energy band tail E is determined as a function of exposure dose. The results obtained showed that the POM compacts became brittle as the -radiation dose reaches 5 Mrad. In the meanwhile, the wavelength of the optical band tail g increases to a maximum at 2 Mrad and the energy band tail E reaches 5 eV at the same dose. Both direct and indirect energies of transition decrease with the irradiation dose. The results can be explained on the basis of -irradiation-induced changes due to cross-linking in the POM.     

Post annealing effect on structural and optical properties of ZnO thin films derived by sol–gel route

Zinc oxide thin films have been spun coated on p-Si (100) substrates by sol–gel route. These films were annealed at different annealing temperatures from 300 to 1,000 °C in the oxygen ambient. In this way a suitable annealing temperature window for the sol–gel derived ZnO films exhibiting minimum defects (points and dislocations) and better quality (crystal and optical) was investigated. The structural and optical features of ZnO thin films have been examined by X-ray diffraction, atomic force microscopy, UV–Vis spectroscopy, and photoluminescence spectra. The results revealed that the crystallization in the films initiated at 300 °C, improved further with annealing. All the deposited films exhibited wurtzite phase with c-axis orientations. The variations in the position of characteristic (002) peak, stress, strain and lattice parameters are investigated as a function of annealing temperature. The optical band gap is not significantly affected with annealing as observed by UV–Vis transmission spectroscopy. The Photoluminescence spectra exhibited three luminescence centers. The near band edge esmission was observed in UV region which enhanced with the heat treatment, is an indication of improvement in the optical quality of films. The other two visible emissions are related to native defects in ZnO lattice were appeared only for higher annealing (≥700 °C).     

The effect of Ta on structure and magnetic properties in Fe–N films

Microstructure and magnetic properties of Fe–Ta–N alloy films near the eutatic composition were studied. The four systematic alloy films with different Ta content were prepared by reactive sputtering. The dependence of structures and magnetic properties on Ta and annealing were investigated by VSM and X-ray diffraction. It is found that Ta atoms replace Fe in α-Fe lattice and have strong affinity for nitrogen, which inhibits the formation of γ-Fe₄N phase in Fe–Ta–N films. The TaN phase precipitates in grain boundaries and suppresses the growth of α-Fe(N) crystalline during annealing. Coercivity varies with the change of microstructure.     

Synthesis,characterization and studies on optical properties of hierarchical ZnO–CdS nanocomposites

Cadmium sulfide coated zinc oxide hierarchical nanocomposites have been synthesised at room temperature by a simple solution based method. CdS nanoparticles were deposited on the surface of ZnO without using any surfactant, ligand or chelating agents. The nanocomposites were synthesised using different concentrations of thioacetamide, cadmium salts, and also by varying the reaction time. After characterization of the nanocomposites, optical properties were investigated by UV–visible diffuse reflectance and photoluminescence spectroscopy techniques. It was found that band gap of the ZnO–CdS nanocomposites is tunable between 2.42 and 3.17 eV.     

The effect of strontium on the mechanical properties of aluminum–silicon alloy

Technical Physics Letters - We have studied the influence of strontium additives on the microstructure and mechanical properties of an aluminum alloy with 15 wt % silicon prepared by directional...     

The effect of Ge implantation dose on the optical properties of Ge nanocrystals in SiO(2)

Ge nanocrystallites (Ge-nc) embedded in a SiO(2) matrix are investigated using Raman spectroscopy, photoluminescence and Fourier transform infrared spectroscopy. The samples were prepared by ion implantation with different implantation doses (0.5, 0.8, 1, 2, 3 and 4) × 10(16)?cm(-2) using 250?keV energy. After implantation, the samples were annealed at 1000?°C in a forming gas atmosphere for 1?h. All samples show a broad Raman spectrum centred at w≈304?cm(-1) with a slight shift depending on the implantation doses. The Raman intensity also depends on the Ge(74+) dose. A maximum photoluminescence intensity is observed for the sample implanted at room temperature with a dose of 2 × 10(16)?cm(-2) at 3.2?eV. Infrared spectroscopy shows that the SiO(2) films moved off stoichiometry due to Ge(74+) ion implantation, and Ge oxides are formed in it. This result is shown as a reduction of GeO(x) at exactly the dose corresponding to the maximum blue-violet PL emission and the largest Raman emission at 304?cm(-1). Finally, the Raman spectra were fitted with a theoretical expression to evaluate the average size, full-width at half-maximum (FWHM) and dispersion of Ge-nc size.     

Structural, vibrational, optical and magnetic properties of sol–gel derived Nd doped ZnO nanoparticles

Nd doped ZnO (Zn_1-xNd_xO, x = 0.0, 0.03, 0.06 and 0.10) nanoparticles were prepared by sol–gel method. Phase identification and effect of Nd ions substitution in ZnO lattice were confirmed by Rietveld analysis of XRD patterns. UV–Visible absorption spectra of pure and Nd doped ZnO nanoparticles showed the variation of the band gap in the range of 3.31–3.26 eV. The FTIR analysis of pure and Nd doped ZnO nanoparticles exhibited similar patterns in Zn/Nd–O bond length as obtained from the Rietveld refinement. Raman analysis confirmed the formation of a wurtzite structure wherein the local structure of ZnO nanoparticles is distorted due to Nd substitution. Magnetization-magnetic field hysteresis curves for pure and Nd doped ZnO nanoparticles revealed diamagnetic and paramagnetic behaviour, respectively. The paramagnetic behaviour of doped ZnO nanoparticles increased with increasing Nd concentration. However, the weak ferromagnetic behaviour of doped ZnO nanoparticles is observed after subtracting paramagnetic components, whereas the ferromagnetic behavior increased up to x = 0.06 samples, which further declined for x = 0.10 sample due to competition between paramagnetic and ferromagnetic ordering. The reduction in the ferromagnetic behavior for x = 0.10 sample indicates that the solubility limit of Nd atoms in ZnO lattice has been reached and paramagnetically coupled Nd atoms increased due to the increasing secondary phases.     

MgO–TiO2–ZnO–CaO ceramics: effect of milling process on dielectric properties

The effect of grain size on the dielectric properties of MgO–TiO₂–ZnO–CaO ceramics is investigated. Attrition milling is chosen to obtain nanometre particle size from micrometre particle size powders. Additionally, the present study is focused on the effect of the nature of milling balls on ε_r, tanδ, and the temperature coefficient of capacitance (abbreviated as TCC). For that, three kinds of balls are tested: Ф1, Ф2 or Ф5 mm stabilised zirconia balls. For the samples milled by Ф2 mm balls for 10 h, the ceramics sintered at 1,270 °C showed favorable dielectric properties with ε_r = 22.6, tanδ = 1.3 × 10^?5, and TCC = 19.1 ppm/°C.     

Investigation of the iron doping on the structural,optical, and magnetic properties of Fe-doped ZnO nanoparticles synthesized by sol–gel method

Journal of Materials Science: Materials in Electronics - In this work, the compatibility of zinc oxide for spintronic applications motivated the development of single-phase Fe/ZnO nanostructures by...     

The effect of meta-halloysite on alkali–aggregate reaction in concrete

Damage to concrete structures may occur as a result of internal effects. Alkali silica reaction (ASR) is a long term reaction between alkalis and reactive aggregate present in the concrete. The reaction product is sodium–potasium–calcium silica gel, able to absorb water, resulting in the expansion and cracking of concrete. The key problem is to find the right method for mitigating the internal damage. This paper presents the results of an investigation into the effectiveness of calcined halloysite (meta-halloysite) in improving the resistance to alkali-silica reaction (ASR). The pozzolanic reactivity of meta-halloysite was also evaluated using Thermo-Gravimetric Analysis. Microstructures of mortar bars were observed by Scanning Electron Microscopy coupled with Energy Dispersive X-ray Spectroscopy (EDS) to investigate the location and chemical composition of ASR gel. The results from this study showed satisfactory level of pozzolanic reactivity when cement was partially replaced by meta-halloysite. It was demonstrated that a 20% addition of meta-halloysite are able to mitigate ASR and lower expansion of mortar bars with reactive aggregate to a safe level of not more than 0.1% at 14 days. Microstructural observations of the specimens containing meta-halloysite indicated the presence of a calcium–alkali–silicate–hydrate gel. But fewer reaction products and with different composition than those forming in the pastes without mineral additives are present.     

Aluminium nitride–molybdenum ceramic matrix composites: influence of molybdenum concentration on the mechanical properties

Aluminium nitride–molybdenum ceramic matrix composites are produced by hotpressing a mixture of two powders. Mechanical properties of a series of samples are measured in order to study the effect of molybdenum phase on the behaviour of composite. Three-point bend strength increases from a value of 270 MPa for pure aluminium nitride to 571 MPa for a composite containing 40% by volume of metallic phase. Fracture toughness measured by the single-edged precracked beam (SEPB) technique, is also increased as a function of molybdenum concentration. From 2.3 MPam^1/2 for pure AlN we obtain a value of 6.9 MPam^1/2 in the case of composite containing 40% by volume of metallic phase. This very important increase in the mechanical properties of AIN-Mo composites is attributed to higher mechanical properties of molybdenum and an adherent interface between AIN and Mo grains. This revised version was published online in November 2006 with corrections to the Cover Date.     

Influence of Yttrium on optical,structural and photoluminescence properties of ZnO nanopowders by sol–gel method

Undoped and Yttrium doped ZnO nanopowders (Zn_1−xY_xO, 0 ⩽ x ⩽ 0.05) were prepared by sol–gel method and annealed at 500 °C for 4 h under air atmosphere. The prepared nanopowders were characterized by powder X-ray diffraction, energy dispersive X-ray spectra, UV–Visible spectrophotometer and Fourier transform infrared spectroscopy. The EDS analysis confirmed the presence of Y in the ZnO system. Both atomic and weight percentages were nearly equal to their nominal stoichiometry within the experimental error. XRD measurement revealed the prepared nanoparticles have different microstructures without changing a hexagonal wurtzite structure. The calculated average crystallite size decreased from 26.1 to 23.2 nm for x = 0–0.02 then reached 24.1 nm for x = 0.05. The change in lattice parameters was demonstrated by the crystal size, bond length, micro-strain and the quantum confinement effect. The observed blue shift of energy gap from 3.36 eV (Y = 0) to 3. 76 eV (Y = 0.05) (ΔE_g = 0.4 eV) revealed the substitution of Y³⁺ ions into ZnO lattice. The presence of functional groups and the chemical bonding are confirmed by FTIR spectra. The appreciable enhancement of PL intensity with slight blue shift in near band edge (NBE) emission from 396 to 387 nm and a red shift of green band (GB) emission from 513 to 527 nm with large reduction in intensity confirm the substitution of Y into the ZnO lattice. Y-doped ZnO is useful to tune the emission wavelength and hence is appreciable for the development of supersensitive UV detector.     

The effect of size of the SiC inclusions in the AlN–SiC composite structure on its electrophysical properties

AlN–SiC–Y₃Al₅O₁₂ composite materials with a high absorption of microwave frequency (27–65 dB/cm) produced by pressureless sintering of mixtures consisting of AlN(2H), Y₂O₃, and SiC (6H) in 46, 4, 50 wt %, respectively, have been studied. The SiC components of the mixtures were used in sizes of 1, 5, and 50 μm. It has been shown that the resistivity of the developed materials depends essentially on the materials structures: sizes of SiC inclusions, distances between them, and state of the interfaces. It has been found that the increase of the SiC inclusions sizes in the material structure from 3 to 7 μm results in the decrease of the resistivity from 10⁴ to 90 Ω·m, and at the decrease of the SiC inclusions sizes from 3 to 0.5 μm there forms a SiC uninterrupted skeleton, which also decreases the resistivity to 210 Ω·m. Thus, composite materials that contain 50 wt % SiC (inclusions sizes of 3 μm) are the most efficient in producing absorbers of microwave radiation. Interlayers of yttrium aluminum garnet, which are located at the SiC grains boundaries, prevent the forming of AlN(2H)–SiC(6H) solid solutions and thus, make it possible to keep high dielectric characteristics of a composite material based on aluminum nitride and afford a high absorption of a microwave radiation.     

The effect of partially stabilized zirconia on the mechanical properties of the hydroxyapatite–polyethylene composites

The effect of partially stabilized zirconia (PSZ) on the mechanical properties of the hydroxyapatite-high density polyethylene composites was studied by investigating the effect of hydroxyapatite and the simultaneous effect of hydroxyapatite and PSZ volume fractions on fracture strength, modulus of elasticity, and absorbed energy in the composite samples. The results showed a decrease in fracture strength, and absorbed energy with an increase in the volume fraction of hydroxyapatite content in the hydroxyapatite-polyethylene samples. Partial replacement of hydroxyapatite with PSZ particles was beneficial in the improvement of both the fracture strength and failure energy values in the composite samples. A transition from ductile to brittle behavior was observed as the volume fraction of ceramic filler particles increased in the samples.     

The effect of rare earth CeO2 on microstructure and properties of in situ TiC/Al–Si composite

In this work, CeO₂ is investigated as an additive for in situ preparation of TiC/Al–Si composite using exothermal dispersion (XD)+casting technology. Experimental results show that CeO₂ at high temperature exhibits the same function as Ce, which is a kind of good modificator. When 0.5 wt.% CeO₂ additive is added, the microstructure of eutectic silicon is significantly changed (the size is greatly reduced). Meanwhile, the amount of TiC particles is increased and the size is reduced. Compared with the composite without added CeO₂, the hardness value (HB) value, tensile strength and tensile elongation are greatly increased. However, under dry sliding friction test, weight loss of the composite is not significantly changed.     

Size effect of Au seeds on structure of Au–Pt bimetallic nanoparticles

Au–Pt bimetallic nanoparticles (NPs) were synthesized by a seeded growth method. Au NPs with different sizes were obtained by reducing HAuCl₄ with butyllithium, and AuPt bimetallic NPs were synthesized by reducing H₂PtCl₆ with oleylamine using the pre-synthesized Au NPs as seeds. The size of Au seeds was found to be a key factor on the structure of Au–Pt bimetallic NPs. Using big Au NP seeds (8 nm or 12 nm) resulted in the formation of Au–Pt dendritic structures. While relatively small Au NPs (3 nm) were used as seeds, the fast atomic diffusion inside relatively small bimetallic NPs will result in an Au–Pt alloy formation.     

The effect of pressure on spontaneous Rayleigh–Brillouin scattering spectrum in nitrogen

In order to study the effect of gas pressure on spontaneous Rayleigh–Brillouin scattering spectrum and verify the validity of Tenti S6 model at pressures up to 8 atm, the spontaneous Rayleigh–Brillouin scattering experiment in nitrogen was performed for a wavelength of 532 nm at the constant room temperature of 296 K and a 90° scattering angle. By comparing the experimental spectrum with the theoretical spectrum, the normalized root mean square deviation was calculated and found less than 2.2%. It is verified that Tenti S6 model can be applied to the spontaneous Rayleigh–Brillion scattering of nitrogen under higher pressures. The results of the experimental data analysis demonstrate that pressure has more effect on Brillouin peak intensity and has negligible effect on Brillouin frequency shift, and pressure retrieval based on spontaneous Rayleigh–Brillouin scattering profile is a promising method for remote of pressure, such as harsh environment applications. Some factors that caused experiment deviations are also discussed.