A study of Canadian diffuse and total solar radiation data—II Monthly average hourly horizontal radiation

Optimum collector slope for a liquid base active solar heating system employing flat-plate collectors was investigated. The optimum collector slope was studied as a function of (a) collector area, (b) yearly total heating load and (c) the ratio of space heating load to service hot water load. Collectors facing equator only were considered. Such a system was studied in four different Canadian locations having widely different climates. Under the above conditions, optimum collector slope varied with the amount of collector area employed. The optimum collector slope was invariant with the yearly total load itself, or the space heating to hot water load ratio. Contrary to the widely held belief, for the four locations investigated, the optimum collector slope varied from lat. − 10° to lat. + 15°; depending upon f_y, the fraction of load supplied by the solar system. When f_y is in 10–20 per cent range, optimum collector slope is lat. − 10° and increases almost linearly to lat.+ 15° at f_y in 80 per cent range. Consequently, when the fraction of load by the solar system is low, a flat roof may be profitably employed. On the other hand, when the fraction by the solar system is high, a south facing (for northern hemisphere) vertical wall may be profitably employed.     

Collector cum storage solar water heaters with and without transparent insulation material

The integrated collector–storage solar water heaters are less expensive and can offer the best alternative for domestic applications particularly to small families to meet hot water requirements. The top heat losses of such solar water heaters are quite high during the night and the temperature of stored hot water is considerably reduced unless covered with extra insulating cover in the evening which is a cumbersome job. The transparent insulation material widely used in Europe for space heating can also minimize top heat losses, if used in such solar water heaters. For this purpose, two units of solar collector cum storage water heaters have been designed to study the relative effect of TI for retaining solar heated hot water for a night duration. Both units were identical in all respects except one of them was covered with TIM. The theoretical exercise was carried out to evaluate design parameters of ISC which revealed total heat loss factor (U_L) 1.03 W/m² K with TIM glazed against 7.06 W/m² K with glass glazed. The TIM glazed has been found to be quite effective as compared to glass glazed SWH and yielded hot water at higher temperature by 8.5 to 9.5°C the next morning. The storage efficiency of such solar water heaters has been found to be 39.8% with TIM glazed as compared to 15.1% without TIM. The TIM glazing means not having to cover the ISC solar water heater with a separate insulator cover in the evening and thus makes its operation much simpler.     

Effects of auxiliary heater on annual performance of thermosyphon solar water heater simulated under variable operating conditions

A thermosyphon solar water heating system with electric auxiliary heater was simulated using the TRNSYS simulation program. Location of the auxiliary heater, inside the storage tank or connected in series between the system and the user, was studied using the TMY meteorological data for Los Angeles, California. Simulations were performed for two different water load temperatures (60 and 80°C) and for two types of daily hot water volumes (250 and 150 l). Four types of daily hot water consumption profiles were used in the present study, namely; the widely used Rand profile, continuous, evening and morning profiles. Also, the simulation is extended to cover the effects of thermal and optical properties of the flatplate collector and the volume of the storage tank. The results show that if water is drawn on a schedule corresponding to the Rand draw profile, the system operates with higher efficiency when the auxiliary heater is located in the storage tank than when the auxiliary heater is outside the storage tank. When operated with each of the other three draw schedules, however, better performance is achieved by locating the auxiliary heater outside the tank. The increase in solar fraction depends on the load profile and volume, temperature setting, as well as the quality of the collector and the storage tank volume. When the values of the parameters F_R(τα)_n and F_RU_L are changed from 0.8 and 16 kJ/h m²°C to 0.6 and 30 kJ/h m²°C, the solar fraction decreases by approximately 40–50%.     

Optimum collector slope for residential heating in adverse climates

Optimum collector slope for a liquid base active solar heating system employing flat-plate collectors was investigated. The optimum collector slope was studied as a function of (a) collector area, (b) yearly total heating load and (c) the ratio of space heating load to service hot water load. Collectors facing equator only were considered. Such a system was studied in four different Canadian locations having widely different climates. Under the above conditions, optimum collector slope varied with the amount of collector area employed. The optimum collector slope was invariant with the yearly total load itself, or the space heating to hot water load ratio. Contrary to the widely held belief, for the four locations investigated, the optimum collector slope varied from lat. ? 10° to lat. + 15°; depending upon f_y, the fraction of load supplied by the solar system. When f_y is in 10–20 per cent range, optimum collector slope is lat. ? 10° and increases almost linearly to lat.+ 15° at f_y in 80 per cent range. Consequently, when the fraction of load by the solar system is low, a flat roof may be profitably employed. On the other hand, when the fraction by the solar system is high, a south facing (for northern hemisphere) vertical wall may be profitably employed.     

Preparation and properties of CdS/CdTe thin film solar cell produced by periodic pulse electrodeposition technique

CdS/CdTe solar cells have been prepared by periodic pulse electrodepositionmethod. 10.8% efficient cell was made with open circuit voltage (V_oc)≈753mV, short-circuit current (J_sc)≈23.6 mA/cm² and fill factor (FF)≈0.61. Current-voltage-temperature measurments showed the variation of ideality factor (A) from 1.88 at 344 K to 4.49 at 202 K whereas voltage factor (α) was almost constant above 276 K. The junction transport is possibly dominated by a tunneling mechanism. Capacitance measurements gave the value of diffusion potential as 1.2 eV, ionized charged density as 5.9 × 10¹⁵ cm⁻³ and number of interface states (N_IS) as 2.8 × 10¹¹ cm⁻² eV⁻¹ at zero volt bias. Measurements of open circuit voltage (V_oc) with temperature gave the value of barrier height as 1.42 eV.     

Geometric optimization of trapezoidal thermoelectric heat pump considering contact resistances through genetic algorithm

An alternate option for improving the performance of the thermoelectric heat pump (TEHP) is the variation in thermoelectric leg configuration. In this paper, the thermodynamic model based on first and second law of thermodynamics for an exoreversible TEHP including influence of Thomson effect as well as leg geometry on the coefficient of performance and heating load of the device has been developed and optimized. Modified expressions have been derived analytically for dimensionless heating load, irreversibilities, figure of merit, energy, and exergy efficiency. The effects of operating and geometry parameters such as shape parameter (A_c/A_h), temperature ratio (T_c/T_h), Thomson effect, thermal and electrical contact resistances on the coefficient of performance, and heating load of the TEHP have been analysed. The results indicate that the Thomson effect has adverse effect on heating load of the system. The optimal parameters obtained through GA optimization process have been compared with the optimal parameters obtained through analytical method which proved the validity of GA optimization method for optimization of TEHP. After the testing, the GA optimization has been performed to determine the optimum parameters corresponding to maximum energy efficiency and maximum heating load. It was found that the GA population converges quickly after 20 runs only which proved the GA as time and cost‐effective optimization tool. This study will be useful for designing of practical TEHP systems of different leg geometries.     

Improvement of Voc using carbon added microcrystalline Si p-layer in microcrystalline Si solar cells

We have developed carbon added p-type microcrystalline silicon for the improvement of the open circuit voltage (V_oc) of microcrystalline Si solar cells. V_oc and fill factor (FF) shows the presence of optimum amount of carbon, [C]/[Si] of about 3.0%. Excess amount of carbon deteriorates the crystallinity of the p-layer accompanied by a decrease in V_oc and FF.By using this carbon added p-layer, we have improved solar cell performance. V_oc and FF are increased from 0.527 to 0.548 V and from 0.724 to 0.756 V, respectively, for a thickness of 1.3 μm. For a thickness of 2.5 μm, we obtained solar cell with an efficiency of 8.6%.     

Concentrator silicon solar cells from silicon industry rejects

Two types of silicon (Si) substrates (40 n-type with uniform base doping and 40 n/n⁺ epitaxial wafers) from the silicon industry rejects were chosen as the starting material for low-cost concentrator solar cells. They were divided into four groups, each consisting of 20 substrates: 10 are n/n⁺ and 10 are n substrates, and the solar cells were prepared for different diffusion times (45, 60, 75 and 90 min). The fabricated solar cells on n/n⁺ substrates (prepared with a diffusion time of 75 min) showed better parameters. In order to improve their performances, particularly the fill factor, 20 new solar cells on n/n⁺ substrates were fabricated using the same procedure (the diffusion time was 75 min)—but with four new front contact patterns. Investigation of current–voltage (I–V) characteristics under AM 1.5 showed that the parameters of these 20 new solar cells have improved in comparison to previous solar cells' parameters, and were as follows: open-circuit voltage (V_OC=0.57 V); short circuit current (I_SC=910 mA), and efficiency (η=9.1%). Their fill factor has increased about 33%. The I–V characteristics of these solar cells were also investigated under different concentration ratios (X), and they exhibited the following parameters (under X=100 suns): V_OC=0.62 V and I_SC=36 A.     

p-doped μc-Si:H window layers prepared by hot-wire CVD for amorphous solar cell application

We report on boron-doped μc-Si:H films prepared by hot-wire chemical vapor deposition (HWCVD) using silane as a source gas and trimethylboron (TMB) as a dopant gas and their incorporation into all-HW amorphous silicon solar cells. The dark conductivity of these films was in the range of 1–10 (Ω cm)⁻¹. The open circuit voltage V_oc of the solar cells was found to decrease from 840 mV at low hydrogen dilution H-dil=91% to 770 mV at high H-dil =97% during p-layer deposition which can be attributed to the increased crystallinity at higher H-dil and to subsequent band edge discontinuity between μc-Si:H p- and amorphous i-layer. The short circuit current density J_sc and the fill factor FF show an optimum at an intermediate H-dil and decrease for the highest H-dil. To improve the conversion efficiency and the reproducibility of the solar cells, an amorphous-like seed layer was incorporated between TCO and the bulk p-layer. The results obtained until now for amorphous solar cells with and without the seed layer are presented. The I–V parameters for the best p–i–n solar cell obtained so far are J_sc=13.95 mA/cm², V_oc=834 mV, FF=65% and η=7.6%, where the p-layers were prepared with 2% TMB. High open circuit voltages up to 847 mV could be achieved at higher TMB concentrations.     

A method for estimating the optimum load resistance of a silicon solar cell used in terrestrial power applications

Solar intensity undergoes significant changes from dawn to dusk. Further, the power output of a silicon solar cell is a function of the load resistance. A load resistance (R_m) giving maximum conversi n efficiency at mid-day becomes less efficient at other times of the day under reduced intensity levels. The load resistance must be optimised to derive maximum overall power output for the whole day, taking intensity variations into account. A method for estimating the optimum load resistance (R_opt) is presented here. It is also shown that considerable improvement in the output of a terrestrial power system could be achieved at solar intensities 100 MW cm².     

Parabolic trough collectors for industrial process heat in Cyprus

The thermal utilization of solar energy is usually confined to domestic hot water systems and somewhat to space heating at temperatures up to 60 °C. Industrial process heat has a considerable potential for solar energy utilization. Cyprus has a small isolated energy system, almost totally dependent on imported fuels to meet its energy demand. The abundance of solar radiation together with a good technological base, created favorable conditions for the exploitation of solar energy in the island. The number of units in operation today corresponds to one heater for every 3.7 people in the island, which is a world record. Despite this impressive record no solar industrial process heat system is in operation today. The main problem for this is the big expenditure required for such a system and the uncertainty of the benefits. The objective of this work was to investigate the viability of using parabolic trough collectors for industrial heat generation in Cyprus. The system is analyzed both thermally and economically with TRNSYS and the TMY for Nicosia, Cyprus, in order to show the magnitude of the expected benefits. The load is hot water delivered at 85 °C at a flow rate of 2000 kg/h for the first three quarters of each hour from 8:00–16:00 h, 5 days a week. The system consists of an array of parabolic trough collectors, hot water storage tank, piping and controls. The optimum collector area for the present application is 300 m², the optimum collector flow rate is 54 kg/m² h and the optimum storage tank size is 25 m³. The system covers 50% of the annual load of the system and gives life cycle savings of about C£6200 (€10800). This amount represent the money saved from the use of the system against paying for fuel. The savings however refer to a non-subsidized fuel price, which will be in effect from 2003. The optimum system can deliver a total of 896 GJ per year and avoids 208 tons of CO₂ emissions to the atmosphere. The effect of various design changes on the system performance was investigated. The E–W tracking system (collector axis aligned in N–S direction) was found to be superior to the N–S one. The required load temperature affects the performance of the system as for higher temperatures the auxiliary energy required is bigger. Also a number of variations in the load use pattern have been investigated and presented in this paper. It was found that the bigger the load (double shift, full hour use pattern) the bigger the collector area required, the greater the first year fuel savings and the greater the life cycle savings of the installation. This means that it is more viable to apply solar industrial process heat to higher energy consumption industries.     

Performance rating method of thermosyphon solar water heaters

A rating method for the thermal performance of thermosyphon solar water heaters was developed. Except that the outdoor test procedure still follows the Taiwan Standard CNS B7277, a system characteristic efficiency η_s^* which is defined as the α₀ value corrected at , was derived so that η_s^* is independent of the ratio. Here, η_s^* can be evaluated by linear regression analysis of the test data. It is found from a series of tests for 31 systems that η_s^* is independent of indeed, and thus can be used to rate the thermal performance of different thermosyphon solar water heaters during the energy-collecting period. The cooling loss during the no-radiation period is rated by the system cooling time constant τ_c. The present rating method associated with the Taiwan Standard CNS B7277 has been implemented for more than three years and is accepted by the Taiwan solar industry.     

System performance and economic analysis of solar-assisted cooling/heating system

The long-term system simulation and economic analysis of solar-assisted cooling/heating system (SACH-2) was carried out in order to find an economical design. The solar heat driven ejector cooling system (ECS) is used to provide part of the cooling load to reduce the energy consumption of the air conditioner installed as the base-load cooler. A standard SACH-2 system for cooling load 3.5 kW (1 RT) and daily cooling time 10 h is used for case study. The cooling performance is assumed only in summer seasons from May to October. In winter season from November to April, only heat is supplied. Two installation locations (Taipei and Tainan) were examined.It was found from the cooling performance simulation that in order to save 50% energy of the air conditioner, the required solar collector area is 40 m² in Taipei and 31 m² in Tainan, for COP_j = 0.2. If the solar collector area is designed as 20 m², the solar ejector cooling system will supply about 17–26% cooling load in Taipei in summer season and about 21–27% cooling load in Tainan. Simulation for long-term performance including cooling in summer (May–October) and hot water supply in winter (November–April) was carried out to determine the monthly-average energy savings. The corresponding daily hot water supply (with 40 °C temperature rise of water) for 20 m² solar collector area is 616–858 L/day in Tainan and 304–533 L/day in Taipei.The economic analysis shows that the payback time of SACH-2 decreases with increasing cooling capacity. The payback time is 4.8 years in Tainan and 6.2 years in Taipei when the cooling capacity >10 RT. If the ECS is treated as an additional device used as a protective equipment to avoid overheating of solar collectors and to convert the excess solar heat in summer into cooling to reduce the energy consumption of air conditioner, the payback time is less than 3 years for cooling capacity larger than 3 RT.     

Characterization of CuInSe2/CdS thin-film solar cells prepared using CBD

CuInSe₂/CdS thin-film heterojunction solar cells were fabricated entirely by chemical bath deposition technique. The illuminated J−V characteristics of the devices prepared with different thicknesses of CdS and CuInSe₂ were studied. The typical solar cell parameters obtained for the best cell are: V_oc = 365 mV, J_sc = 12 mA/cm², FF = 61%, and η = 3.1% under an illumination of 85 mW/cm² on a cell of active area 0.1 cm². The J−V and C−V characteristics under dark condition and the spectral response were also studied for the best cell. The diode quality factor obtained is 1.7.     

Influence of alkylpyridine additives in electrolyte solution on the performance of dye-sensitized solar cell

The influence of alkylpyridines additive to an I⁻/I₃⁻ redox electrolyte in acetonitrile on the performance of a bis(tetrabutylammonium)cis-bis(thiocyanato)bis(2,2′-bipyridine-4-carboxylic acid, 4′-carboxylate)ruthenium(II) dye-sensitized TiO₂ solar cell was studied. I–V measurements were performed using more than 30 different alkylpyridines. The alkylpyridine additives showed a significant influence on the performance of the cell. All the additives decreased the short-circuit photocurrent (J_sc), but most of the alkylpyridines increased the open-circuit photovoltage (V_oc) and fill factor (ff) of the solar cell. The results of the molecular orbital calculations suggest that the dipole moment of the alkylpyridine molecules correlate with the J_sc of the cell. These results also suggest that both the size and ionization energy of pyridines correlate with the V_oc of the cell. Under AM 1.5 (100 mW/cm²), the highest solar energy conversion efficiency (η) of 7.6% was achieved by using 2-propylpyridine as an additive, which was more effective than the previously reported additive, 4-t-butylpyridine.     

Determination of the electrical characteristics and thermal behaviour of a c-Si cell under transient conditions for various concentration ratios

An extended study of c-Si cell performance under transient conditions for various concentration ratios, C, between 0.6 and 12.25 is presented. PV cell temperature, T_c, open-circuit voltage, V_oc, and short-circuit current, I_sc, were measured using an experimental set-up based on a solar light simulator. The dependence of V_oc, I_sc, dV_oc/dT_c, dI_sc/dT_c and r_s on T_c was investigated against C. A model was developed to predict T_c. Generalised formulae were proposed for prediction of V_oc and I_sc. Theoretically obtained T_c and V_oc profiles were compared with the measured ones. A good agreement was observed. The time constants of V_oc and T_c profiles were determined experimentally for various C values and lie within ±5% from theoretically predicted time constants. The coefficient dV_oc/dT_c was determined for various C values. The results show a decrease in the absolute value of dV_oc/dT_c against C. A partial recovery of PV cell performance through a ventilation process was tried.     

Influence of aminothiazole additives in I/I3 redox electrolyte solution on Ru(II)-dye-sensitized nanocrystalline TiO2 solar cell performance

The influence of aminothiazole additives in acetonitrile solution of an I⁻/I₃⁻ redox electrolyte on the performance of a bis(tetrabutylammonium)cis-bis(thiocyanato)bis(2,2′- bipyridine-4-carboxylic acid, 4′-carboxylate)ruthenium(II) (N719) dye-sensitized TiO₂ solar cell was studied. The current–voltage characteristics were investigated under AM 1.5 (100 mW/cm²) for nine different aminothiazole compounds. The aminothiazole additives tested had varying influences on the solar cell performance. Most of the additives enhanced the open-circuit photovoltage (V_oc), but reduced the short circuit photocurrent density (J_sc) of the solar cell. Both the physical and chemical properties of the aminothiazoles were computationally calculated in order to determine the reasons that the additive influenced solar cell performance. The larger the calculated partial charge of the nitrogen atom in the thiazole, the higher the V_oc value. The V_oc value increased as the dipole moment of aminothiazoles in acetonitrile increased. Moreover, the V_oc of the solar cell also increased as the size of the aminothiazole molecules decreased. These results suggest that the electron donicity of the aminothiazole additives influenced the interaction with the TiO₂ photoelectrode, which altered the dye-sensitized solar cell performance.     

Density of interface states, excess capacitance and series resistance in the metal–insulator–semiconductor (MIS) solar cells

Dark and illuminatied current–voltage (I–V) characteristics of Al/SiO_x/p-Si metal–insulator–semiconductor (MIS) solar cells were measured at room temperature. In addition to capacitance–voltage (C–V) and conductance–voltage (G–V), characteristics are studied at a wide frequency range of 1 kHz–10 MHz. The dark I–V characteristics showed non-ideal behavior with an ideal factor of 3.2. The density of interface states distribution profiles as a function of (E_ss−E_v) deduced from the I–V measurements at room temperature for the MIS solar cells on the order of 10¹³ cm⁻² eV⁻¹. These interface states were responsible for the non-ideal behavior of I–V, C–V and G–V characteristics. Frequency dispersion in capacitance for MIS solar cells can be interpreted only in terms of interface states. The interface states can follow the a.c. signal and yield an excess capacitance, which depends on the relaxation time of interface states and the frequency of the a.c. signal. It was observed that the excess capacitance C_o caused by an interface state decreases with an increase of frequency. The capacitances characteristics of MIS solar cells are affected not only in interface states but also series resistance. Analysis of this data indicated that the high interface states and series resistance leads to lower values of open-circuit voltage, short-circuit current density, and fill factor. Experimental results show that the location of interface states and series resistance have a significant effect on I–V, C–V and G–V characteristics.     

Highly efficient photon-to-electron conversion with mercurochrome-sensitized nanoporous oxide semiconductor solar cells

Dye-sensitized solar cells based on nanoporous oxide semiconductor thin films such as TiO₂, Nb₂O₅, ZnO, SnO₂, and In₂O₃ with mercurochrome as the sensitizer were investigated. Photovoltaic performance of the solar cell depended remarkably on the semiconductor materials. Mercurochrome can convert visible light in the range of 400–600 nm to electrons. A high incident photon-to-current efficiency (IPCE), 69%, was obtained at 510 nm for a mercurochrome-sensitized ZnO solar cell with an I⁻/I₃⁻ redox electrolyte. The solar energy conversion efficiency under AM1.5 (99 mW cm⁻²) reached 2.5% with a short-circuit photocurrent density (J_sc) of 7.44 mA cm⁻², a open-circuit photovoltage (V_oc) of 0.52 V, and a fill factor (ff) of 0.64. The J_sc for the cell increased with increasing thickness of semiconductor thin films due to increasing amount of dye, while the V_oc decreased due to increasing of loss of injected electrons due to recombination and the rate constant for reverse reaction. Dependence of photovoltaic performance of mercurochrome-sensitized solar cells on semiconductor particles, light intensity, and irradiation time were also investigated. High performance of mercurochrome-sensitized ZnO solar cells indicate that the combination of dye and semiconductor is very important for highly efficient dye-sensitized solar cells and mercurochrome is one of the best sensitizers for nanoporous ZnO photoelectrode. In addition, a possibility of organic dye-sensitized oxide semiconductor solar cells has been proposed as well as one using metal complexes.     

Optimizing the tilt angle of solar collectors

Solar collectors need to be tilted at the correct angle to maximize the performance of the system. In this paper, the annual solar fraction of the system (the fraction of energy that is supplied by solar energy) is used as an indicator to find the optimum inclination angles for a thermosyphon solar water heater installed in northern and southern parts of Jordan. Calculations are carried out using the powerful computer program TRNSYS (Transient System Simulation). The system is assumed to operate with a daily hot water load of 150 l at 55°C flowing during the day according to the widely used Rand consumption profile. The results show that the optimum inclination angle for the maximum solar fraction is about φ+(0→10°) for the northern region (represented by Amman) and about φ+(0→20°) for the southern region (represented by the town of Aqaba). These values are greater than those for maximum solar radiation (which is commonly used as an indicator) at the top of the collector by about 5 to 8°.