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从生胶种类、炭黑用量、增塑剂种类及硫化体系对EPDM性能的影响进行了研究。结果表明,选取75份EPDM8550与50份EPDM4869并用,N550炭黑40份与导电炭黑20份并用时,加入增塑剂石蜡油,选用不溶性硫磺0.5、TRA 0.3、DM 1.5、BZ 1.0、DTDM 2.0的硫化体系制备的EPDM门尼粘度较低,具备良好的物理机械性能和导电性能。 相似文献
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采用溶液插层法与双辊混炼法制备了顺丁橡胶/炭黑/有机蒙脱土(BR/CB/OMMT)纳米复合材料,用透射电子显微镜(TEM)以及X射线衍射(XRD)方法对复合材料的亚微观结构进行了表征,并研究了复合材料的力学特性、耐磨耗性能以及硫化特性。结果表明:BR/CB/OMMT为插层型纳米复合材料;在OMMT含量小于4份时,BR/CB/OMMT纳米复合材料具有优异的力学性能和耐磨耗性能;OMMT起到了硫化促进剂的作用,降低了BR的焦烧时间(TS)和正硫化时间(T90);低填充量OMMT可提高复合材料的交联密度。 相似文献
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制备环氧度为15%的环氧化溶聚丁苯橡胶(ESSBR),以其作为大分子偶联剂对白炭黑/顺丁橡胶(BR)复合材料进行改性,研究白炭黑/ESSBR/BR复合材料的性能,并与偶联剂Si69/白炭黑/溶聚丁苯橡胶(SSBR)/BR复合材料进行对比。结果表明,白炭黑/ESSBR/BR复合材料的白炭黑分散性、拉伸性能、抗湿滑性能和耐磨性能均有不同程度的提高,滚动阻力降低,且无挥发性有机化合物的排放,该复合材料可用于轮胎胎面胶。 相似文献
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研究炭黑的种类及用量、硫化体系、硫化条件和天然橡胶(NR)/顺丁橡胶(BR)并用比等因素对NR/BR复合材料抗裂口增长性能的影响。结果表明:当炭黑用量在一定范围内时,炭黑的种类和用量影响NR/BR复合材料的抗裂口增长性能;随着促进剂NS用量的增大或硫化时间的延长,NR/BR复合材料抗裂口增长性能变差;适当提高硫化温度或增大硫黄用量,NR/BR复合材料的抗裂口增长性能提高;NR/BR并用比、炭黑分布或硫化体系不同时,NR/BR复合材料的抗裂口增长性能都有差异性。 相似文献
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摘要:研究了填料种类和用量、硫化体系、硫化条件和NR与BR的并用比等因素对NR/BR复合材料抗裂口增长性能的影响。结果表明:对于NR/BR复合材料,炭黑用量在一定范围内时,炭黑用量和种类影响硫化胶的抗裂口增长性能;随着促进剂用量提高或延长硫化时间,抗裂口增长性能变差;而适当提高硫化温度或硫磺用量,NR/BR复合材料的抗裂口增长性能提高;NR/BR并用比、炭黑分布或硫化体系不同时,NR/BR复合材料的耐裂口增长性能都有差异性。 相似文献
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以三元乙丙橡胶(EPDM)为主体橡胶,通过添加石蜡油以及EPDM与聚烯烃弹性体(POE)和顺丁橡胶(BR)并用来制得耐低温性能优良的CRH2和CRH3型动车组用U形外风挡胶料,并测试U形外风挡涂层性能。结果表明:添加石蜡油可以提高外风挡胶料的耐低温性能,但会影响U形外风挡漆膜与母材的附着力,石蜡油用量不宜超过10份;EPDM与BR和POE并用可以获得耐低温性能(耐-55 ℃低温)、耐屈挠性能和物理性能优异的U型外风挡胶料,制得的U型外风挡适合在较寒冷的环境下使用。 相似文献
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Considering the properties of silicon rubber, ethylene–propylene–diene monomer (EPDM), and cis‐polybutadiene rubber (BR), a blend made by a new method was proposed in this article; this blend had thermal resistance and good mechanical properties. The morphology of the blend was studied by SEM, and it was found that the adhesion between the phases of BR, EPDM, and polysiloxanes (silicon rubber) could be enhanced, and the compatibility and covulcanization were good. The influence of the mass ratio of peroxide and silica on the mechanical properties and thermal resistance of the blend was studied. The results showed that the mechanical properties and thermal resistance of the blend were improved when silicon rubber/BR/EPDM was 20/30/50, dicumyl peroxide/sulfur was 2.5/2.5, and the amount of silica was 80 phr. The integral properties of rubber blend had more advantages than did the three rubbers. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 4462–4467, 2006 相似文献
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Electrically conductive composites comprised of ethylene propylene diene monomer (EPDM) rubber and steel fibers were prepared by an open mill mixing method. Fibers of two distinctly different lengths (5 mm and several meters) were used and the influence of these fibers on electrical conductivity, mechanical, thermal, and physical properties of the composites was investigated. Composites with different compositions were prepared by varying the loading levels of fibers from 20–100 phr (parts per hundred parts of rubber). Homogeneity of the composites was determined using scanning electron microscopy. Further analysis included the measurement of resistance, hardness, tensile strength, tear strength, rebound resilience, etc. The results of the analysis revealed that the addition of steel fibers rendered conductivity to the otherwise insulating EPDM rubber even at small loading levels, however, the length appears to have negligible effect on conductivity. In case of short fibers, the resistance of composites was observed to decrease from > 40 MΩ (Initial value of EPDM rubber) to 25 KΩ at a loading level of 20 phr with a further significant decrease of the order of 103, that is around 18 Ω at 100 phr. Composites with long fibers exhibited resistance in the range of 15 kΩ–70 Ω at loading levels between 30 and 100 phr. The conductivity of the sample is observed to be altered negligibly on ageing. Mechanical properties such as hardness, tensile, and tear strength were observed to be enhanced in case of composites except resilience which decreased by 29 % in comparison to EPDM rubber. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
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In recent times, there is an increasing need for effective control of electromagnetic pollution, which can avoid excessive radiation effects on the human body. Microwave absorption materials are attracting wide research interests to reduce electromagnetic pollution due to the rapid development of electronic equipment. In this study, Nitrile butadiene rubber (NBR)/ethylene propylene diene monomer rubber (EPDM) were mixed with multiwalled carbon nanotubes (MWCNT) to prepare microwave absorbing materials. The distribution of fillers, AC conductivity, complex permittivity, and microwave absorption performance of the composites were systematically investigated. It found that the AC conductivity, both real and imaginary parts of the permittivity were significantly improved in the composite with the increasing ratio of MWCNT contents. The NBR/EPDM/MWCNT composites with eight parts per hundred concerning with rubber (phr) MWCNT had a minimum reflection loss (RLmin) of −48.1 dB at the optimum thickness of 2.07 mm. Importantly, the adding sequence of MWCNT and plasticizer dioctyl phthalate (DOP) to the rubber matrix is found to play an important role in determining the distribution of fillers and the structure of polymer blends. The composite with plasticizer added before MWCNT exhibited a better impedance matching and as a result, achieved a good microwave absorption performance. 相似文献
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Saman Ghaderzadeh Elnaz Esmizadeh Ali Vahidifar Ghasem Naderi Mir Hamid Reza Ghoreishy Tizazu H. Mekonnen 《乙烯基与添加剂工艺杂志》2021,27(4):855-867
A facile approach of using halloysite nanotubes (HNTs) was proposed to address the durability performance demands of natural rubber (NR)/ethylene propylene diene monomer rubber (EPDM) blends and to protect them from the deleterious effects of the service environment including ozone, chemicals, abrasion, and cyclic loading. The introduction of HNTs substantially improved the stability of NR/EPDM when exposed to ozone (over fourfold enhancement with the addition of 5 phr HNTs). Moreover, the HNT-filled NR/EPDM vulcanizates offered approximately 66% reduction in the solvent-mediated swelling in comparison to the unfilled sample. Fatigue life studies showed that the HNT-reinforced NR/EPDM composite could withstand 30% more cycles to failure than the un-reinforced NR/EPDM blend. The effect of various HNT loading on the morphological, mechanical, physical, and rheological properties of nanocomposite vulcanizates based on NR/EPDM was also investigated. The morphological investigations revealed that the introduction of HNT into the NR/EPDM rubber matrix caused a rough morphology in fracture surface and a well-dispersed structure was obtained with the addition of up to 5 phr of HNTs. These findings were further supported by rheological, mechanical, and thermodynamical results. 相似文献
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This research studied the composition and behavior of natural rubber (NR) and ethylene propylene diene monomer (EPDM) blends at various carbon black concentrations (0–30 phr) in terms of electrical resistivity, dielectric breakdown voltage testing, and physical properties. The blends having electrical properties suitable for application in high‐insulation iron crossarms were selected for investigation of compatibility and increased physical properties. The effect of the homogenizing agent concentration on improvement of compatibility of blends was studied by scanning electron microscopy, pulsed nuclear magnetic resonance spectroscopy, and rheology techniques. We also examined mechanical properties such as tensile strength, tear strength, elongation at break, and hardness. The NR/EPDM blends filled with a fixed concentration of silica were investigated for ozone resistance. A carbon black content as high as 10 phr is still suitable for the insulation coating material, which can withstand electrical voltage at 10 kVac. Addition of the homogenizing agent at 5 phr can improve the mechanical compatibility of blends, as evidenced by the positive deviation of shear viscosity of the rubber blend, that is, the calculated shear viscosity being higher than that of experimental data. Moreover, the pulsed NMR results indicated that the spin‐spin relaxation (T2) of all three components of the rubber blend was compressed upon the addition of the homogenizing agent. The ratio of NR/EPDM in the blend to best resist the ozone gas is 80/20 with the addition of silica of 30 phr into the blend. Also, the NR/EPDM filled with silica had a decreased change in thermal and mechanical properties of blends after thermal aging. The synergistic effect of silica content and high NR content (80) in 20 phr EPDM could improve antioxidation by ozone in the absence of a normal antioxidant for natural rubber. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 3401–3416, 2004 相似文献