Mechanical properties and microstructure of high strength concrete containing polypropylene fibres exposed to temperatures up to 200 °C

High strength concrete has been used in situations where it may be exposed to elevated temperatures. Numerous authors have shown the significant contribution of polypropylene fibre to the spalling resistance of high strength concrete. This investigation develops some important data on the mechanical properties and microstructure of high strength concrete incorporating polypropylene fibre exposed to elevated temperature up to 200 °C. When polypropylene fibre high strength concrete is heated up to 170 °C, fibres readily melt and volatilise, creating additional porosity and small channels in the concrete. DSC and TG analysis showed the temperature ranges of the decomposition reactions in the high strength concrete. SEM analysis showed supplementary pores and small channels created in the concrete due to fibre melting. Mechanical tests showed small changes in compressive strength, modulus of elasticity and splitting tensile strength that could be due to polypropylene fibre melting.     

Effect of high temperatures on high performance steel fibre reinforced concrete

After being subjected to different elevated heating temperatures, ranging between 105 °C and 1200 °C, the compressive strength, flexural strength, elastic modulus and porosity of concrete reinforced with 1% steel fibre (SFRC) and changes of colour to the heated concrete have been investigated.The results show a loss of concrete strength with increased maximum heating temperature and with increased initial saturation percentage before firing. For maximum exposure temperatures below 400 °C, the loss in compressive strength was relatively small. Significant further reductions in compressive strength are observed, as maximum temperature increases, for all concretes heated to temperatures exceeding 400 °C. High performance concretes (HPC) start to suffer a greater compressive strength loss than normal strength concrete (NSC) at maximum exposure temperatures of 600 °C. It is suggested that HPC suffers both chemical decomposition and pore-structure coarsening of the hardened cement paste when C-S-H starts to decompose at this high temperature. Strengths for all mixes reached minimum values at 1000 or 1100 °C. No evidence of spalling was encountered. When steel fibres are incorporated, at 1%, an improvement of fire resistance and crack [F.M. Lea, Cement research: retrospect and prospect. Proc. 4th Int. Symp. On the Chemistry of Cement, pp. 5-8 (Washington, DC, 1960).] resistance as characterized by the residual strengths were observed. Mechanical strength results indicated that SFRC performs better than non-SFRC for maximum exposure temperatures below 1000 °C, even though the residual strength was very low for all mixes at this high temperature. The variations with colour, which occured, are associated with maximum temperatures of exposure.     

Effects of fibre type and matrix structure on the mechanical performance of self-compacting micro-concrete composites

The compatibility of matrix and fibre properties is one of the key parameters in the successful design of fibre reinforced cementitious composites. In order to achieve the desired performance, the properties of each constituent of composite should be properly configured. The aim of this study was to investigate the performance of two polymer based micro-fibres (polypropylene and polyvinyl alcohol) in different matrices (high strength and comparatively low strength with fly ash incorporation) which were designed to contain considerably high amounts of fibres (1% by volume) while maintaining their self-compactability. The fresh state thixotropic behaviour of fibre reinforced matrices was minimised by proper adjustment of water/cementitious material ratio and admixture dosage. The mechanical properties (first crack strength and displacement, flexural strength and relative toughness) of prismatic composite samples were compared by three point flexural loading test. The typical behaviours of selected composites and collapse mechanisms of PP and PVA fibres in these matrices were characterised by microstructural studies. It was concluded that, a high strength matrix with a high strength fibre give the best performance from the view point of flexural strength and toughness performance. However, incorporation of fly ash did not cause a significant reduction in composite performance possibly due to its enhancing effect on matrix–fibre interface adhesion. The possibilities and suggestions to further improve the performance of the composites were also discussed.     

Thermal and mechanical properties of fiber reinforced high performance self-consolidating concrete at elevated temperatures

This paper presents the effect of temperature on thermal and mechanical properties of self-consolidating concrete (SCC) and fiber reinforced SCC (FRSCC). For thermal properties specific heat, thermal conductivity, and thermal expansion were measured, whereas for mechanical properties compressive strength, tensile strength and elastic modulus were measured in the temperature range of 20–800 °C. Four SCC mixes, plain SCC, steel, polypropylene, and hybrid fiber reinforced SCC were considered in the test program. Data from mechanical property tests show that the presence of steel fibers enhances high temperature splitting tensile strength and elastic modulus of SCC. Also the thermal expansion of FRSCC is slightly higher than that of SCC in 20–1000 °C range. Data generated from these tests was utilized to develop simplified relations for expressing thermal and mechanical properties of SCC and FRSCC as a function of temperature.     

Post-fire residual mechanical properties of concrete made with recycled concrete coarse aggregates

This paper presents results of an experimental study on the residual mechanical performance of concrete produced with recycled coarse aggregates, after being subjected to high temperatures. Four different concrete compositions were prepared: a reference concrete made with natural coarse aggregates and three concrete mixes with replacement rates of 20%, 50% and 100% of natural coarse aggregates by recycled concrete coarse aggregates. Specimens were exposed for a period of 1 h to temperatures of 400 °C, 600 °C and 800 °C, after being heated in accordance with ISO 834 time–temperature curve. After cooling down to ambient temperature, the following basic mechanical properties were then evaluated and compared with reference values obtained prior to thermal exposure: (i) compressive strength; (ii) tensile splitting strength; and (iii) elasticity modulus. Results obtained show that there are no significant differences in the thermal response and post-fire mechanical behaviour of concrete made with recycled coarse aggregates, when compared to conventional concrete.     

High temperature behaviour of self-consolidating concrete: Microstructure and physicochemical properties

This paper presents an experimental study on the properties of self-compacting concrete (SCC) subjected to high temperature. Two SCC mixtures and one vibrated concrete mixture were tested. These concrete mixtures come from the French National Project B@P. The specimens of each concrete mixture were heated at a rate of 1 °C/min up to different temperatures (150, 300, 450 and 600 °C). In order to ensure a uniform temperature throughout the specimens, the temperature was held constant at the maximum temperature for 1 h before cooling. Mechanical properties at ambient temperature and residual mechanical properties after heating have already been determined. In this paper, the physicochemical properties and the microstuctural characteristics are presented. Thermogravimetric analysis, thermodifferential analysis, X-ray diffraction and SEM observations were used. The aim of these studies was in particular to explain the observed residual compressive strength increase between 150 and 300 °C.     

The synthesis and characterisation of reactive poly(p-phenylene terephthalamide)s: A route towards compression stable aramid fibres

Herein we report on the synthesis of reactive poly(p-phenylene terephthalamide) (PPTA) oligomers and the preparation and characterisation of aramid fibres thereof. Methacrylate and maleimide reactive end-groups were found to be sufficiently stable in H₂SO₄ at 85 °C and they were used to prepare reactive PPTA oligomers. Lyotropic spin-dopes could be prepared with up to 20 wt% of reactive oligomer (M_n = 3900 g mol⁻¹) and this modification did not interfere with the fibre spinning process and had no effect on the fibre tensile properties. The as-spun fibres did indeed show a modest (+0.1 GPa) improvement in compression strength. A high temperature treatment at 380 °C resulted in fibres which all show a significant increase in compressive strength over their as-spun precursors, i.e. from 0.7 to 0.9 GPa. When fibres were treated at 430 °C the compression values of the oligomer-modified fibres dropped somewhat, whereas unmodified PPTA displayed a compressive strength of 1.1 GPa. Other favourable fibre properties such as modulus and tenacity were not compromised.     

Properties of hybrid fibre reinforced shell for investment casting

In order to improve the properties of silicon sol shell for investment casting process, a varying content of hybrid fibres (aluminium silicate and polypropylene) was introduced into slurry for preparation of fibre-reinforced shell in the present work. The bending strength, self-load deformation at elevated temperature, and the permeability of fibre-reinforced shell specimens were investigated and the fracture surfaces of shell specimens were observed by SEM. The results show that the bending strength of green shell increases with content of fibres in it. The maximum bending strength of 4.96 MPa was obtained in the fired shell with 0.6 wt% hybrid fibres addition. The high temperature self-loaded deformation of specimens of shell reinforced with a hybrid fibre addition above 0.6 wt% is higher than that of the unreinforced. However, the shell with a hybrid fibre addition up to 0.4 wt% exhibits the lower self-loaded deformation at high temperature compared to the unreinforced. It is also found that the permeability of shell specimens can be improved by hybrid fibres addition. Based on the fracture surfaces observation using a scanning electron microscope (SEM), the failure mode of the green shell reinforced with hybrid fibres is identified as fibre rupturing from the substrate of shell specimens, and/ or debonding from adhesive film surrounding it in shell. Even though the specimens of shell being fired at 900 °C for 2 h, the same failure features also exist in the fracture surfaces of specimens. This indicates that the specimens of shell can still be reinforced with aluminium silica fibres (residue of hybrid fibres) for their interpenetrating fibres network structure although go through firing.     

Effect of fibre type and geometry on maximum pore pressures in fibre-reinforced high strength concrete at elevated temperatures

This paper presents results of an experimental and statistical study which investigates the effect of fibre type and geometry on the amount of maximum pore pressures measured at different depths in fibre-reinforced high strength concrete (HSC) exposed to elevated temperatures. Polypropylene, polyvinyl alcohol and steel fibres of varying lengths and diameters were used. Pore pressure measurements showed that addition of organic fibres regardless of the type significantly contributes to pore pressure reduction in heated HSC. Polypropylene fibres were more effective in mitigating maximum pore pressure development compared to polyvinyl alcohol fibres while steel fibres had a slightly low effect. Longer organic fibres of length 12 mm with smaller diameters of 18 μm showed better performance than shorter ones of length 6 mm with larger diameters of 28 and 40 μm. Based on experimental observations and using statistical analysis, a relationship to predict maximum pore pressures in heated concrete was developed.     

Explosive spalling and residual mechanical properties of fiber-toughened high-performance concrete subjected to high temperatures

In this paper, an experimental investigation was conducted to explore the relationship between explosive spalling occurrence and residual mechanical properties of fiber-toughened high-performance concrete exposed to high temperatures. The residual mechanical properties measured include compressive strength, tensile splitting strength, and fracture energy. A series of concretes were prepared using OPC (ordinary Portland cement) and crushed limestone. Steel fiber, polypropylene fiber, and hybrid fiber (polypropylene fiber and steel fiber) were added to enhance fracture energy of the concretes. After exposure to high temperatures ranged from 200 to 800 °C, the residual mechanical properties of fiber-toughened high-performance concrete were investigated. For fiber concrete, although residual strength was decreased by exposure to high temperatures over 400 °C, residual fracture energy was significantly higher than that before heating. Incorporating hybrid fiber seems to be a promising way to enhance resistance of concrete to explosive spalling.     

Flexural properties after exposure to elevated temperatures of a ground granulated blast furnace slag concrete incorporating steel fibers and polypropylene fibers

Experiments were carried out to investigate the flexural properties of fiber‐reinforced ground granulated blast furnace slag (GGBFS) concrete after exposure to high temperatures. On the basis of experimental observation, the effect of GGBFS content, the steel fiber dosage, the polypropylene (PP) fiber dosage, and the strength grade on the residual strength of concrete after exposure to elevated temperatures were systematically examined. Test data indicate that exposure to high temperatures causes deterioration in the flexural strength of concrete; inclusion of GGBFS, PP fibers, and steel fibers, all effectively improve the residual flexural strength of concrete after fire. The optimum amounts of GGBFS, PP fibers, and steel fibers are identified respectively for better fire resistance of concrete. The strength losses of concretes characterized by different strength grades are very close to one another. Equations are proposed to predict the residual flexural strength of concrete incorporating GGBFS, PP fibers, and steel fibers after being heated to temperatures up to 800°C. Copyright © 2013 John Wiley & Sons, Ltd.     

Moisture transport in heated concrete, as studied by NMR, and its consequences for fire spalling

During the past 30 years concrete has developed enormously in both strength and durability. A drawback of these improvements is the increased risk of explosive spalling in case of fire. The moisture inside the concrete plays an important role in the spalling mechanism. In order to study the moisture migration inside concrete during intense heating, a dedicated nuclear magnetic resonance (NMR) setup was built. This setup can be placed inside a 1.5-T MRI scanner.With this setup one-dimensional moisture profiles can be measured while the concrete sample is heated up to 250 °C. Besides concrete, measurements were performed on fired-clay brick and calcium-silicate brick.The results show that water inside the concrete sample is superheated to a temperature of 170 °C, which results in an increased pressure inside the concrete. A model was developed to predict the movement of the observed drying front.     

Fabrication of short carbon fibre reinforced SiC multilayer composites by tape casting

Silicon carbide multilayer composites containing short carbon fibres (C_sf/SiC) were prepared by tape casting and pressureless sintering. C fibres were dispersed in solvents and then mixed with SiC slurry to make green C_sf/SiC tape. Triton X-100 was found to be the best one for Toho Tenax HTC124 fibres (with water soluble coating) among BYK-163, BYK-410, BYK-2150, BYK-9076, BYK-9077 and Triton X-100 dispersants. C_sf/SiC multilayer composites containing 5 vol.% fibre (mean fibre length of 3, 4.5, and 6 mm) were obtained. Addition of short C fibres seems to worsen the densification process in the C_sf/SiC multilayer composites, whereas anisotropy shrinkage in C_sf/SiC was also observed. Open pores size was increased slightly after the addition of C fibre but it decreased with the mean fibre length. Mechanical properties were affected by high residual porosity. The addition of short C fibre has not changed the crack deflection at weak interfaces. C_sf/SiC multilayer composites containing longer fibres (4.5 and 6 mm) presented higher elastic modulus, bending strength and Vickers hardness as compared to shorter fibres (3 mm). Improved sintering performance and fibre content are necessary to improve mechanical properties.     

Comparative evaluation of steel mesh, steel fibre and high-performance polypropylene fibre reinforced shotcrete in panel test

In this study, experimental investigations were performed on steel mesh (SM), steel fibre (SF) and high-performance polypropylene fibre (HPPF) reinforced shotcrete (HPPFRS) panels to evaluate performance characteristics such as toughness, flexural ductility, energy absorption and load capacity. The panel tests, in accordance with European specification for sprayed concrete (EFNARC), were made on 18 prismatic specimens having the same mix designs and were cured for 28 days but reinforced with various fibres. In addition, the rebound characteristics of these mixes were determined to compare the actual in situ fibre contents.Test results show that all reinforcements, including HPPFs that are low-modulus fibres, greatly improved the flexural ductility, toughness, and load-carrying capacity of the brittle matrix. It was seen that there was a positive synergy effect between steel and polypropylene fibre in hybrid fibre usage from a performance point of view. According to results, it can be concluded that a hybrid polypropylene-SF can be used alternatively instead of SM and monosteel fibre as a reinforcement in shotcrete applications to get better efficiency in mechanical properties of composite.     

Mechanical and thermomechanical properties of highly basic anion-exchange fibres based on polypropylene containing grafted-on polystyrene

Conclusion The dependence of the mechanical and thermomechanical properties of fibres from polypropylene containing grafted polystyrene and of the anion-exchange fibres based on them on the content of grafted polystyrene in the fibre has been examined.It has been shown that the observed decrease in strength and elastic modulus of the original polypropylene fibre on grafting polystyrene and subsequent polymer-analogous transformations of it is entirely caused by an increase in linear density of the fibres.The animated polystyrene grafted to the polypropylene ensures an increase in the softening point of the anion-exchange fibres of 80 to 100°C as compared with the softening point of the original polyproplene fibre.Translated from Khimicheskie Volokna, No. 4, pp. 28–30, July–August, 1985.     

Corrosion of steel fibre reinforced concrete from the cracks

The corrosion of steel fibres in the cracked section has been under investigation by many researchers since the last 15 years. It is reported widely that in case of steel fibres reinforced concrete (SFRC), corrosion is less active as compared with steel bars. In the cracked section, the durability of the material depends on the performance of the bridging capacity of the fibres embedded in the concrete. The corrosion of the fibres not only could produce the spalling of concrete but it could also reduce the sectional area of the fibres, turning the durability of structures in danger. This study focuses on those two aspects of fibre corrosion. The tests were performed on cracked SFRC samples with 0.5-mm crack mouth openings (CMOs) exposed to marine-like environment for 1 year. The results confirm the small sensitivity of SFRC to corrosion. Surprisingly, they made appear an increase of the flexural strength after corrosion. The factors affecting the corrosion of the fibres and the reasons for the increase in flexural strength after corrosion are discussed.     

Behaviour of Slurry Infiltrated Fibre Concrete (SIFCON) under triaxial compression

Slurry infiltrated fibre concrete (SIFCON) is one of the recently developed construction material that can be considered as a special type of high performance fibre reinforced concrete (HPFRC) with higher fibre content. In the current research, triaxial compressive behaviours of high strength concrete (HSC), HPFRC and SIFCON were investigated. Purposefully, laboratory tests employed on four types of 75 × 150 mm cylindrical specimens with different steel fibres volumes (0, 2, 5 and 10%). All tests were conducted under four different confining pressure levels (0, 5, 15 and 21.5 MPa) according to triaxial conditions. Consequently, stress-strain curves were obtained and governing failure patterns and failure criterions of HSC, HPFRC and SIFCON samples were discussed. According to the results increasing of fibre volumes increases peak stress, energy absorption, toughness and Poisson's ratio while increasing confining pressures increases peak stress, energy absorption and toughness. Also, this may cause concrete to behave as a plastic material.     

Residual stress-strain relationship for concrete after exposure to high temperatures

An experimental research is performed on the complete compressive stress-strain relationship for concrete after heating to temperatures of 100-800 °C. All concrete specimens are ?15 cm × 30 cm standard cylinders, made with siliceous aggregate. The heated specimens are tested at 1 month after they are cooled to room temperature. From the results of 108 specimens with two original unheated strengths, a single equation for the complete stress-strain curves of heated concrete is developed to consider the shape varying with temperature. Through the regression analysis, the relationships of the mechanical properties with temperature are proposed to fit the test results, including the residual compressive strength, peak strain and elastic modulus. Compared with the experimental curves, the proposed equation is shown to be applicable to unheated and heated concrete for different temperatures. In addition, the split-cylinder tests of 54 specimens are also carried out to study the relationship of splitting tensile strength with temperature.     

Heat treatment effects on microstructure and mechanical properties of CVI SiCf/PyC/SiC composites with Cansas-Ⅲ SiC fibers

The microstructure and mechanical properties of CVI-Cansas-III/PyC/SiC composites were systematically investigated after heat treatment under high temperature argon atmosphere, ranging from 1000 °C to 1500 °C, for different time durations. The results showed that the Cansas-III fibres degraded with increasing heat treatment temperature, resulting in degradation of the fibre properties due to pyrolysis of the SiOC phase inside the fibres. The bending strength of the composites remained nearly constant upon heat treatment at 1000 °C and 1250 °C, while a decline in bending strength was observed upon increasing the heat treatment temperature and time, specifically at 1350 °C and above. Moreover, the composites maintained their pseudo-plastic fracture behaviour below 1450 °C, while displaying brittle fracture of the ceramic after 100 h of heat treatment at 1500 °C, due to the complete crystallisation of the fibres.     

Resonant frequency study of tensile and shear elasticity moduli of carbon fibre reinforced composites (CFRC)

The dynamic elastic properties are important characteristics of composite materials. They control the vibrational behaviour of composite structures and are also an ideal tool for monitoring of the development of CFRCs’ mechanical properties during their processing (heat treatment, densification). The present studies have been performed to explore relations between the dynamic tensile and shear moduli and some structural features (viz., fibre fraction, fibre type, porosity, weave pattern of woven reinforcement) of various unidirectional or bi-directional fibre reinforced carbon/carbon composites, made out of PAN- or pitch-based fibres as reinforcements and phenolic resin or coal tar pitch as matrix precursors. The dynamic tensile and in-plane shear moduli were determined from resonant frequencies of a beam with free ends. The longitudinal dynamic Young’s modulus of unidirectional CFRC composites – besides its dependence on the original fibre modulus and fibre volume contents – also reflects changes induced in matrix and fibres by heat treatment. The in-plane shear modulus does not depend on the fibre type but there exists its distinct tendency to increase with increasing fibre fraction. For bi-directionally reinforced composites, the longitudinal tensile modulus is more sensitive to the fabric weave pattern than to the fibre type. Tensile modulus of diagonally cut specimens and in-plane shear modulus of longitudinally cut ones are mutually correlated and, therefore, simultaneously controlled by densification steps and graphitisation heat treatment.