强制气流作用下溶液蒸发过程的传质规律

针对强制气流作用下溶液的蒸发过程,在分析气液相间力学特性的基础上,根据Levich涡流衰减理论和边界层理论,将气流流动状态与相间传质结合,研究了湍流气流横掠液面过程中气液相间的传质变化规律,分析了雷诺数、气流流道结构及普朗特混合长度对传质的影响,得到了气液相间的湍流质扩散系数的变化规律,湍流气流横掠液面条件下的对流传质准则数Sh=0.221Sc1/3Rex1/2. 结果表明,湍流扩散系数、传质系数与气流的流动状态密切相关,气流流道结构对气液相间的传质有重要影响.     

绕管式换热器壳侧降膜流动和相变传热的数值模拟

为了定量描述绕管式换热器壳侧降膜蒸发特性并进而优化换热器结构,建立了绕管式换热器壳侧降膜蒸发过程流动与传热的数值模型。首先对降膜流动过程中流型变化和传热传质机理进行分析;通过对降膜流动过程液膜所受表面张力、重力和剪切力的计算,实现层状流、柱状流和滴状流等不同流型的模拟;通过管壁面和气液交界面的组分守恒建立降膜蒸发过程的传质子模型,并基于传质速率计算得出潜热传热速率。将数值模拟结果与已有文献中实验数据进行了对比,结果显示89%的模拟数据与实验数据偏差不超过25%;模拟结果与实验数据吻合较好。基于提出的模型,对不同工况下的绕管式换热器壳侧降膜蒸发传热传质规律进行了分析。     

降膜结晶分离过程热、质及动量传递的数值模拟(Ⅰ)分区域统一模型

基于混合物理论和实验观察所获得的有关结晶形态及形貌特征 ,建立了描述降膜结晶过程液相区、枝晶状固液两相共存区及固相区的动量、热量和质量传递过程的分区域统一数学模型 .模型的一个重要特点是认为在降膜结晶过程中 ,于熔体液相区和固相区之间存在一薄厚不匀且不断变化的固液两相共存区 .随着结晶过程的进行 ,二相区内固相体积分数不断增加并不断向液相区推移直至完全固化 .二相区的存在为降膜结晶时含杂质低纯度液体提供了在晶层内栖身的场所 ,这可能是产生杂质包藏的实际原因。引入多孔介质传递理论并采用Brinkman扩展的非稳态Darcy方程来描述固液两相区多孔介质内的流体流动 .进一步 ,采用VanDriest修正的Prandtl混合长度模型来描述降膜结晶过程中液体区的湍流流动与传热传质     

水平管降膜吸收局部传热传质特性的数值模拟

为分析滴状和柱状流型下纯水蒸气水平管外降膜吸收过程的局部传热传质特性,建立非稳态数值模型考虑吸收过程中降膜区和管间区内液相的实际流动特征及气液两相的传质,同时对多管排区域采用实际边界条件,且考虑气液两相的传热过程。溶液的液膜Reynolds数范围为11~38。结果表明,与文献实验对比,相同流量下溶液出口浓度和温度的平均相对误差在2%以内;滴状和柱状流型下,降膜区溶液的平均浓度和温度均迅速下降,管间区先上升后下降,降膜区溶液的局部吸收速率分别约为管间区的10倍和7倍;柱状流型下降膜区的吸收速率明显小于滴状流型,管间区相差很小;吸收达到稳定后,滴状流型下溶液的平均浓度和温度变化均大于柱状流型,四排管降膜区溶液的浓度变化量依次增大,温度变化量依次减小。     

膜反转板式降膜吸收过程的理论研究

将板式降膜吸收和膜反转技术相结合,开发了一种新形式的降膜型吸收器,即膜反转板式降膜吸收器.通过对这种吸收器进行流动传热传质分析,建立了描述其物理过程的数学模型,采用流函数将控制方程进行变换,用有限差分法将变换后的方程离散,由TDMA方法编程计算这种膜反转板式降膜吸收器溴化锂溶液降膜吸收的过程,对比分析板式、膜反转板式降膜吸收计算结果表明,在同样的条件下膜反转板式降膜吸收器比板式降膜吸收器传热传质性能更好.     

水平管降膜吸收局部传热传质特性的数值模拟

为分析滴状和柱状流型下纯水蒸气水平管外降膜吸收过程的局部传热传质特性,建立非稳态数值模型考虑吸收过程中降膜区和管间区内液相的实际流动特征及气液两相的传质,同时对多管排区域采用实际边界条件,且考虑气液两相的传热过程。溶液的液膜Reynolds数范围为11~38。结果表明,与文献实验对比,相同流量下溶液出口浓度和温度的平均相对误差在2%以内;滴状和柱状流型下,降膜区溶液的平均浓度和温度均迅速下降,管间区先上升后下降,降膜区溶液的局部吸收速率分别约为管间区的10倍和7倍;柱状流型下降膜区的吸收速率明显小于滴状流型,管间区相差很小;吸收达到稳定后,滴状流型下溶液的平均浓度和温度变化均大于柱状流型,四排管降膜区溶液的浓度变化量依次增大,温度变化量依次减小。     

气液降膜流动中液相速度波动及其传质研究

为了研究降膜流动的动力学性质及其对气液传质过程的影响,在气液逆流的不同气液流动条件下采用激光多普勒(1aser Doppler anemometer,简称LDA)测量了降膜流动的液相速度分布和瞬时速度波动.和以往假定液膜外侧为自由表面,液膜表面处剪切力为零的Nusselt模型进行了比较,LDA测量结果表明气液逆流时降膜流动的最大液相速度出现在液膜表面之内,并且是以近界面区域的速度波动为特征的流动.在相同的降膜装置中进行了乙醇稀溶液的解吸实验,液相传质系数的实验测量值是渗透理论预测值的1～2倍.实验结果表明液相界面区域的速度波动加快了气液界面的表面更新速率,减小了传质阻力,强化了气液界面的传质过程.考虑液膜波动特征对气液接触情况的影响,从气液两相接触时间的角度出发,修正了渗透理论对液相平均传质系数的预测,预测结果和实验结果相吻合.     

流态化结晶过程中晶体生长的湍流传质模型

根据流态化结晶过程的流体处于湍流运动的事实,将多相湍流理论应用于晶体的生长过程,建立该过程的湍流传质动力学模型.模型计算与实验数据比较表明,湍流传质模型对扩散传质控制的晶体生长过程是可靠的.     

疏水性聚丙烯中空纤维膜中n-甲酰吗啉膜吸收含苯废气过程模拟

以疏水性聚丙烯中空纤维膜为气液膜接触器,n-甲酰吗啉水溶液为吸收剂,研究了膜气体吸收工艺分离C6H6/N2的传质过程. 在非润湿条件下,建立了膜气体吸收C6H6传质微分模型,模拟了C6H6在疏水性聚丙烯中空纤维膜管程及膜孔内的传质过程,并对C6H6的吸收速率进行预测. 结果表明,在实验条件下,膜气体吸收C6H6的速率为(0.89~6.13)′10-2 mg/(m2×s),微分模型对吸收速率预测的平均误差为1.9%,能准确描述中空纤维膜吸收C6H6的过程.     

平板降膜溶液除湿再生过程实验研究及模型验证

在平板降膜溶液除湿/再生实验平台上,以LiCl水溶液作为除湿溶液,实验研究了空气、溶液的入口参数对空气出口参数的影响,并根据实验数据得到了耦合传热传质系数的关联式,为NTU-Le模型提供了重要的数据支持,同时将实验数据与NTU-Le传热传质模型计算所得的数据进行比较,来验证NTU-Le传热传质模型在平板降膜溶液除湿/再生过程中的适用性和准确度。结果显示:实验数据和模型计算值之间的偏差均在10%以内,表示NTU-Le模型适用于平板降膜溶液除湿/再生过程。     

GAS ABSORPTION INTO WAVY AND TURBULENT NON-NEWTONIAN FALLING LIQUID FILMS IN A WETTED-WALL COLUMN

Average Him thickness and liquid-side mass transfer coefficient for the absorption of oxygen in wavy and turbulent power-law model falling liquid films are measured. Considerable reduction in (he film thickness with resulting increase in the mass transfer coefficient are obtained as compared to that predicted by the theoretical laminar flow equation assuming no slip at the wall.     

Friction and heat and mass transfer for turbulent pseudoplastic non-newtonian fluid flows in rough pipes

Friction factor and heat and mass transfer coefficient correlations are developed for turbulent pseudoplastic (purely viscous or inelastic) non-Newtonian fluids flowing through rough pipes. A correlation for friction factor which is applicable in the region of transition from the smooth to the fully-rough regime is proposed. It is obtained by adding the two correlations for the limiting situations, i.e. smooth pipes and fully-rough pipes. The predictions of the proposed correlation are compared with published experimental data and other previous correlations. A model for heat and mass transfer is developed on the basis of the Levich three-zone model. It is found that the proposed model is capable of predicting satisfactorily heat and mass transfer coefficients for Newtonian and pseudoplastic non-Newtonian fluid flow in rough pipes.     

Mass transfer ambiguities in swirling pipe flows

A mathematical model of mass transfer in the boundary layer of swirl flow is developed. The equations obtained for Sherwood number and mass transfer coefficient generalize the equations obtained by Levich for the flat plate to the case of mass transfer in axisymmetrical swirl flow. For the first time it is shown that, in swirl flows, the mass transfer is not completely controlled by integral flow parameters (Reynolds number and the swirl number) but depends essentially on the type of vortex symmetry. The left-handed helical vortices generate wake-like swirl flows and increase mass transfer in comparison with axial flows. The right-handed helical vortices generate jet-like swirl flows, which can decrease mass transfer.     

竖直管外降膜吸收传热传质过程强化的研究

对LiBr溶液在光滑管和四种换热强化管竖直管外降膜吸收过程进行了实验研究，得到了实验条件下的最佳管型，分析了非绝热吸收过程中传热传质相互作用，相互影响的关系，建立了竖直管外降膜吸收热－质传递过程的数学模型，并对该过程进行了数值计算，模型计算值与实验结果的比较证明该模型具有较好的适用性。     

GAS ABSORPTION INTO WAVY AND TURBULENT FALLING LIQUID FILMS IN A WETTED-WALL COLUMN

Experiments are conducted for gas absorption in a long wetted-wall column. Liquid-side mass transfer coefficients are measured for absorption of CO₂ and O₂ into falling water films on the outside of a stainless steel pipe 2.72 cm OD and 183 cm absorption length. The liquid film Reynolds number ranges from 129 to 10500 which encompasses the wavy-laminar, wavy-transition and turbulent flow regimes. The experimental data are correlated by a dimensionless equation of the form kt = (k_tD) (v²/g) ^1/3 = a-Re^p-Sc^1/2. The correlation is well supported by a viscosity-damped turbulence model at the gas-liquid interface which tends to confirm that viscosity is probably the major mechanism causing eddy damping and not surface tension as proposed by Levich and Davies. The form of the above correlation also represents previous experimental work at different temperatures and for different gases quite well.     

Liquid—liquid mass transfer in systems agitated by submerged jets

Mass transfer across a plane interface has been investigated for liquid—liquid systems, with the liquid phases agitated by vertically opposed, submerged jets, one in each phase. Mass transfer coefficients were determined for the systems ethyl acetate—water and butanol—water, and for the transfer of dissolved helium between water and toluene, and toluene between toluene and water. The latter two solutes provided a wide range of molecular diffusion coefficients. When turbulent eddies penetrated to the interface the mass transfer coefficients were found to be proportional to D^0.5, and could be represented by the Levich-Davies mass transfer model for mass transfer between turbulent liquids. The characteristic turbulence velocities in this model were related to the velocities of the liquids from the jet nozzles, and to the equipment dimensions (e.g. the distances of the jets from the interface, the radius of the vessel and the diameters of the jet nozzles) by an expression based on the hydrodynamic behaviour of jets.For the low interfacial tension system butanol—water, a flat disc had to be placed in the interface at the region of jet impingement, to prevent disruption of the interface, but, even so, only a limited range of jet flow rates could be used. Only at the highest flow rates were turbulent conditions obtained, and most of the experimental mass transfer coefficients for this system were between the values predicted by the Levich-Davies model and the Levich “three-zone” model for boundary layer flow.     

HEAT TRANSFER IN A SUBCOOLED WATER FILM FALLING ACROSS A HORIZONTAL HEATED TUBE

A numerical simulation and an experimental study were carried out for sensible heat transfer for a subcooled water film falling across a horizontal heated tube. A laminar model and a turbulent model were adopted to calculate the heat transfer coefficient. The whole wetting zone on the tube surface was divided into two zones: the top stagnation zone and the lateral free film flow zone. The initial boundary conditions for the free film flow zone were determined by calculating the fluid and the temperature fields in the stagnation zone. A modified wall function method was used for the turbulent model. The comparisons between the experimental data and the numerical solutions show that the experimental data agree reasonably well with the laminar model solutions. Finally, two simple correlations were proposed for predicting the convective heat transfer of a falling film for engineering applications.     

T型微通道内吸收H_2S实验研究

在水力学直径为1.00 mm的方形T型微通道内,采用质量分数为40%的N-甲基二乙醇胺(MDEA)吸收含有体积分数为0.12%的H2S混合气体。实验发现,在微通道内可以获得很高的H2S脱除效率,在气液体积比为200∶1时,其脱除效率可以达到99.5%。在微通道内的H2S传质过程中,H2S传质的阻力主要集中在气侧,而且气侧体积传质系数随着气体和液体表观速率的增加而增加。提出了在过渡区的二相流型中,气侧体积传质系数的量纲一经验关联式,其计算值和实验值吻合得很好。通过比较发现,微通道比其他传统设备的气侧体积传质系数高出1—2个数量级。