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《Inorganic chemistry communications》2000,3(5):251-254
Reaction of Co(II) perchlorate hexahydrate and anhydrous Co(II) chloride with the ligand 2-(2′-pyridyl)quinoxaline (L) leads to the formation of the novel five- and six-coordinated complexes CoLCl2(DMF) (1) and [CoL2(H2O)2](ClO4)2·H2O·2CH3OH (2), correspondingly. The crystal structures of the above complexes show a trigonal bipyramidal geometry around the metal atom for complex 1 and a distorted octahedral geometry for complex 2. 相似文献
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X-ray crystallography reveals four isostructural lanthanide polymeric solids, [Ln2(atp)3(H2O)2]·dmf·4H2O (atp = 2-aminoterephthalate; dmf = N,N′-dimethylformamide; Ln = La (1), Ce (2), Pr (3) and Nd (4), respectively) that are obtained from the solvothermal synthesis which are crystallized in an interesting 3D polymeric framework with a (4,4,6)-linked {42·84}{44·62}2{48·66·8}2 fsy net topology. Upon excitation at 350 nm, they all show the solid state ligand-centered luminescences but both 2 and 3 also exhibit the weak lanthanide-based characteristic emissions in the visible region at room temperature. The cyclic voltammetric investigation indicates that 2 exhibits appreciable electrochemical activity for formaldehyde. 相似文献
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Meriem Ayed Safa Thabet Amor Haddad 《Journal of Inorganic and Organometallic Polymers and Materials》2014,24(2):291-301
Two inorganic–organic hybrid supramolecular compounds based on polyoxometalates formulated as (C4H8NH2)4[Mo8O26] (1) and (NH4)Na2[AsIIIMo6O21(O2CCH2NH3)3]·8H2O (2) have been synthesized by conventional solution method and characterized by infrared, UV–Vis and single-crystal X-ray diffraction analyses. Thermal analysis was performed to study their thermal stability. The atomic arrangement in compound (1) can be described as inorganic layers built by [Mo8O26]4?, pyrrolidinium cations are embedded into layers. The fascinating structural feature of compound (2) is that the glycine molecules are bounded to two edge-sharing Mo centers via their carboxylate functionality leading to functionalized heteropolymolybdate [AsIIIMo6O21(O2CCH2NH3)3]3?, extensive net hydrogen bonds between cations and anions contribute to the crystal packing. The electrochemical behavior of compound (2) has been studied. 相似文献
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Karen Valencia G. Hernández-Gordillo Agileo Oros-Ruiz Socorro Rodil Sandra E. 《Topics in Catalysis》2021,64(1-2):121-130
Topics in Catalysis - Alpha phase bismuth oxide (α-Bi2O3) microparticles were prepared through the annealing at 600 °C of basic bismuth nitrate [Bi6O6(OH)2(NO3)4·2H2O]... 相似文献
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以Triton X-100/n-C10H21OH/H2O体系W/O微乳液为基础,分别以K8[Ce(Ⅳ)W10O33]·32H2O 和Pb(NO3)2水溶液代替组分水制备W/O微乳液.然后将两种微乳液混合,得到黄色沉淀的Pb4[Ce(Ⅳ)W10O33]·32H2O纳米粒子,同时有少量纳米管生成.经电镜分析所得Pb4[Ce(Ⅳ)W10O33]·32H2O纳米粒子为粒径低于5 nm的圆球状颗粒,所得Pb4[Ce(Ⅳ)W10O33]·32H2O纳米管管长约为50 nm,管径约为5 nm.并用TG-DTA和Raman对该化合物进行了表征. 相似文献
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《Inorganic chemistry communications》2000,3(11):579-584
A novel and large heteropolyanion [(BiW9O33)3Bi6(OH)3(H2O)3V4O10]12− has been synthesized by reaction of sodium metavanadate with Na9[BiW9O33]·16H2O in acetate buffer solutions (at pH 4.8). The present anion has a trilobal structure in which three α-B {BiW9O33} units are connected to each other by an unique core [Bi6(OH)3(H2O)3V4O10]15+. A central bismutate/vanadate-mixed core comprises three sets of two types of the BiO6 pentagonal pyramid, the edge-sharing VO5 square-pyramidal triad, and a VO4 tetrahedron. 相似文献
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研究了柠檬酸与正丁醇在Ce(SO4)2·4H2O/ NH2SO3H复配催化剂催化作用下制备柠檬酸三丁酯的工艺条件。实验结果表明Ce(SO4)2·4H2O/ NH2SO3H催化合成柠檬酸三丁酯的最佳反应条件为:醇酸摩尔比为4.0∶1,催化剂用量为1.5%(以柠檬酸质量计),m[Ce(SO4)2·4H2O]∶m(NH2SO3H)=2∶1,反应温度为150 ℃,反应时间为7 h,酯化率>98.5%,精制后产品纯度>99.5%。 相似文献
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Lenka Klištincová Erik Rakovský Peter Schwendt Gustav Plesch R. Gyepes 《Inorganic chemistry communications》2010,13(11):1275-1277
The decavanadate with a novel glycine–glycinato complex of copper (II) in the cationic part, (NH4)2[Cu2(H2O)4(NH3CH2COO)2(NH2CH2COO)2]H2V10O28·6H2O (1), has been prepared and characterized by elemental analysis, infrared and EPR spectroscopies. The triplet X band EPR spectrum of powdered sample evidenced magnetic interaction between the Cu(II) atoms in the dimeric unit which is probably realized through the bridging water molecules in this part of the complex. A single crystal X-ray diffraction study revealed that the structure of 1 contains cationic copper complex with a rare Cu(H2O)2Cu double bridge. In this cation, a simultaneous bidentate N, O– and monodentate O– coordination of glycine to the same central atom was observed for the first time. 相似文献
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Feilong Hu Xianhong Yin Yan Mi Shanshan Zhang Weiqiang Luo Yue Zhuang 《Inorganic chemistry communications》2009,12(12):1189-1192
Two novel copper(II) complexes, namely [Cu(phen)(L)2]·6H2O (1) and [Cu(phen)3]·(ClO4)2 (2) have been synthesized under mild condition (HL = 5-methyl-1H-pyrazole-3-carboxylic acid, phen = 1,10-phenanthroline). We report the structural evidence of discrete water decamer conformation in the solid state. These units are found to act as supramolecular glue in the aggregation of mononuclear copper(II) complex to give a three-dimensional network through hydrogen-bonding. The preliminary investigation on the thermal behavior and the anion exchange property of the complexes are presented. 相似文献
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Nargis Anwar Timothy McCormac Jean Daniel Compain Pierre Mialane Anne Dolbecq Fathima Laffir 《Electrochimica acta》2012
A functionalised Fe-substituted Keggin Na14[Fe4(C2O4)4(H2O)2(SbW9O33)2]·60H2O type POM termed “Fe4Ox4” has been successfully immobilised onto carbon electrode surfaces through the employment of conducting polypyrrole films and the layer-by-layer (LBL) technique. For the POM doped polypyrrole films the redox systems associated with the POM's tungsten-oxo framework was not apparent upon redox cycling, however a reversible redox couple associated with the FeIII/II redox system was clearly seen within the pH range 2–7. Organised multilayer assemblies were constructed by the employment of the layer by layer (LBL) technique through alternating anionic Fe4Ox4 layers and cationic RuII metallodendrimers with poly(diallyldimethylammonium chloride) (PDDA) employed as an initial base layer. Stable redox couples associated with both the FeIII/II and tungsten-oxo framework, for the Fe4Ox4 POM, and the RuIII/II for the metallodendrimer, were clearly observed upon layer construction and redox switching within the pH domain of 2–7. The resulting multilayer assembly showed good stability towards redox cycling. Further investigations into the multilayer assembly were undertaken by determining it is charge transfer resistance using AC-impedance voltammetry. The layer also showed catalytic ability towards the reduction of H2O2 at pH 6.5. 相似文献
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《广州化工》2021,49(6)
以1,3,5-均苯三甲酸(H_3BTC)、2-[1-(2-吡嗪基)乙缩醛腙(L_a)、醋酸钴、为原料采用水热法合成了配合物[Co_3(BTC)_2(L_b)_2(CH_3CH_2OH)_2·4H_2O]_n(1)(L_b=2-乙酰基吡嗪缩水合肼)。配合物晶体属单斜晶系,空间群C2/c。X-射线单晶衍射结果表明:两个Co~(2+)离子与氧原子、氮原子配位,均为变形八面体构型。席夫碱配体在配位过程中分解为2-乙酰基吡嗪缩水合肼,BTC~(3-)配体全部去质子化且以μ_4-的配位模式将两个Co~(2+)连接成6-连接的三维结构。晶胞参数:a=15.146(9)?,b=13.417(8)?,c=23.564(18)?,β=90.087(8)°,V=4789(5)?~3,Z=4。 相似文献
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《Inorganic chemistry communications》2000,3(6):313-315
AgCN·2AgNO3 (1) contains a linear [AgCN]∞ chain that essentially retains the characteristics of neat silver cyanide, with two Ag–ONO2 fragments weakly bound to each head-turned-tail disordered cyanide group (Ag2–C1=2.598(4) Å). In AgCN·2AgClO4·2H2O (2), the [AgCN]∞ chain takes a zigzag configuration with Ag(H2O) fragments attached to both sides, resulting in a μ4-η1κC:η1κN coordination mode for each ordered cyanide ion. The zigzag chains are cross-linked by O–H⋯O hydrogen bonds to form a close-packing of elongated hexagonal channels, with ordered perchlorate anions accommodated in double columns inside each channel. 相似文献