锌元素对钎焊态3003铝合金显微组织与性能的影响

研究了Zn含量对经过模拟钎焊处理的3003铝合金显微组织、力学性能和电化学性能的影响规律.透射电镜(TEM)结果表明:Zn合金化对合金微观组织尤其是析出相的形貌影响不明显,三种合金的析出相均为较规则的近球形颗粒,Zn含量增大会使析出相的密度增大.用能谱分析仪(EDS)分析了含Zn铝合金的基体和析出相的成分,结果表明基体中含有Zn元素,而析出相中不合Zn元素,证明Zn主要是以固溶体的形式而非相的形式存在于合金中.拉伸试验结果表明:随着Zn含量的增加,合金的拉伸强度会略微提高,延伸率略微下降.用扫描电镜(SEM)对拉伸断口形貌进行了分析,结果表明合金的断裂形式为典型的韧性断裂.在0.5％NaC1溶液中的电化学实验结果表明,当合金中添加质量分数为1.5％的Zn元素,合金的腐蚀电位明显负移,这不利于合金的抗蚀性.随着Zn的质量分数从1.5％增加到1.8％,腐蚀电位变化较轻微,说明Zn含量的增加使合金的腐蚀电位向负方向移动,但是随着Zn含量的增加,这种影响越来越弱.同时,随着Zn含量的增加,腐蚀电流密度逐渐增大,说明Zn含量的增加使合金的抗腐蚀性能减弱.     

Zn含量对AlMgSiCu合金组织和力学性能的影响

使用常规铸锭冶金方法制备了不同Zn含量的AlMgSiCu合金.利用光学显微镜、扫描电镜、拉伸测试和纳米压痕方法研究了Zn含量对铝合金微观组织和力学性能的影响.研究发现Zn元素能够轻微细化AlMgSiCu合金铸态组织.随着合金中Zn含量的增加,铸态铝合金的晶界变宽,晶界析出相增多.Zn的添加未影响铸态合金的相组成和形貌.随Zn含量的增加,铝合金的强度和延伸率呈现先增后降的变化趋势,添加质量分数0.5%Zn可使合金具有最高的强度,而0.75%Zn使合金获得最高延伸率.对含Zn铝合金的纳米压痕测量表明:随着Zn含量的增加,铝合金的弹性模量呈现逐步降低的趋势.     

铸轧3003深冲料用铝合金退火工艺研究

采用光学显微镜(OM)和拉伸试验机对铸轧法生产的3003铝合金深冲料成品退火工艺的显微组织和力学性能进行了研究,结果表明,两种工艺方案下生产的3003铝合金沿轧制方向0°的力学性能优于沿轧制方向90°,此差异性随退火温度升高而逐渐减小并趋于一致.铝合金样品经退火处理后的强度急剧降低,变化最大的温度区间处于280～300...     

Ti元素对7072铝合金显微组织与性能的影响

通过透射电镜、扫描电镜、拉伸试验和电化学测试等方法,系统研究了Ti元素的添加对模拟钎焊态7072铝合金热传输材料的显微组织、不同条件下力学性能与电化学性能的影响规律.透射电镜分析表明,Ti元素的添加对晶粒尺寸的影响微弱,且对析出相的析出有抑制作用.力学试验结果表明,Ti元素对钎焊态合金的高温力学性能有很大的影响.常温下含Ti合金的拉伸力学性能与无Ti合金相近.但在150℃测试时,屈服强度可提高5.5 MPa,抗拉强度和延伸率基本不变.在200℃测试时,抗拉强度可提高近10 MPa,屈服强度和延伸率略有下降.电化学试验结果表明,添加Ti元素能提高钎焊态7072铝合金的抗腐蚀性能,可使7072铝合金在0.5%NaCl溶液、3.5%NaCl溶液和1M NaCl+0.3M H2O2溶液中的腐蚀电位分别正移8.3mV、11 mV和8.5 mV.     

3003铝合金中间退火工艺优化研究

采用实验拉力机和金相显微镜对铸轧法生产的3003铝合金幕墙板的力学性能和晶粒组织进行了研究,对3003铝合金大卷中间退火工艺进行了优化.结果表明:3003铝合金大卷进行中间退火时,将工艺设为530℃×9 h+390℃×3.5 h+随炉冷却3.5 h较为合理,能够有效控制晶粒长大,同时使板材的晶粒分布较为均匀,可有效提高...     

微量Zn对Al-Cu-Mg合金力学性能及晶间腐蚀的影响

采用扫描电子显微镜（SEM）、电子背散射衍射（EBSD）、电导率测试及常温拉伸实验,结合剥落腐蚀测试、晶间腐蚀测试和电化学测试研究了微量Zn对Al-Cu-Mg合金组织与性能的影响。试验结果表明,微量Zn的添加明显提高了合金T3态（预拉伸+自然时效）的塑性。随着Zn含量的增加,T3态合金点蚀电位提高,S相、阴极相和铝基体之间的电位差减小,点蚀的形成和晶间腐蚀的传播更加困难,合金的晶间腐蚀敏感性降低。     

冷轧工序对铸轧3003铝合金显微组织和性能的影响

文章研究了冷轧工序对铸轧3003铝合金显微组织和力学性能的影响。结果表明,改善冷轧工艺,在冷轧低道次后进行退火处理而非铸轧后直接退火有利于晶粒等轴均匀化,提高3003铝合金力学性能,成品退火后抗拉强度达到98MPa,延伸率达到49%,使得n值与r值较大,具有较好的拉延性能和冲压性能。     

热处理对汽车散热器用铝合金钎焊带材组织和性能的影响

研究了均匀化和非均匀化处理状态下的不同中间退火工艺对钎焊带材组织和性能的影响。结果表明：在钎焊带芯材3003铝合金铸锭没有均匀化处理时,采用低温再结晶退火,合金的晶粒较大且大小不一;高温快速加热退火,可获得相对细小、均匀的合金晶粒组织。热轧复合前对3003铝合金铸锭进行均匀化热处理,可获得均匀的合金组织和稳定的力学性能。     

均匀化退火对铸轧3003高深冲铝板带组织性能的影响

针对铸轧3003合金铝板带产品深冲性能方面的不足,实验使用铸轧供坯3003铝合金带材,通过两种不同的生产实验方案,在冷轧轧制前对坯料进行520℃～540℃及560℃～580℃均匀化退火,对均匀化退火前后的产品显微组织、力学性能等试验指标分析,验证不同均匀化退火温度对产品金相组织以及冲压力学性能的影响。结果表明,铸轧坯料在560℃～580℃均匀化退火作用下过饱和固溶体大量析出细小均匀的第二相,成品的晶粒组织更加细小均匀,有利于提高材料的的加工性能,同时通过本实验顺利打通了产品批量工业化生产最终工艺路线。     

热交换器用铝合金复合管材的制备新技术

采用自行设计制造的包覆铸造装置成功制备出尺寸为Φ140 mm/Φ110 mm的4045/3003铝合金包覆铸锭,通过反向热挤压将包覆铸锭制备成铝合金复合管材.通过OM、SEM、拉伸实验、剪切实验对界面组织和性能进行了分析和测定.结果表明,利用该装置制备的铝合金包覆铸锭表面质量良好,界面清晰,无气孔、夹杂,界面处元素发生互扩散,并形成约20μm的过渡层,平均抗拉强度为103.3 MPa,抗剪切强度为80.2 MPa,两种合金实现冶金结合.反向热挤压后得到的复合管材,界面处保持了铸态时的层状结构特点.     

Effects of Strip Casting and Annealing on Electrochemical Properties of LPCNi3.55Co0.75Mn0.4Al0.3 Hydrogen Storage Alloys

The effect of thickness (1～10 mm) of the ingots on the electrochemical properties of as-cast and annealed strip cast LPCNi3.55Co0.75Mn0.4Al0.3 hydrogen storage alloys was investigated. It is found that the 0.2 C discharge capacity of as-cast LPCNi3.55Co0.75Mn0.4Al0.3 alloy increases with the increase of the thickness of the ingots. As-cast alloy with the thickness of 10 nun shows better activation property, higher 1C discharge capacity and better cyclic stability than others.It is mainly contributed to its larger unit cell volume and less internal stress. Annealed LPCNi3.55Co0.75Mn0.4Al0.3 alloywith the thickness of 3 mm shows much better comprehensive electrochemical properties than as-cast one; The cyclic stability of the alloy with the thickness of 6 mm and the activation properties of the alloys with the thickness of 3～6 mm are improved after annealing. It is mainly owing to the great release of intemal stress and the decrease fo the segregation of Mn in the alloys.     

Influence of Al-Si additions on mechanical properties and corrosion resistance of Mg-8Li dual-phase alloys

Sheet samples of Mg-8Li,Mg-8Li-3Al,Mg-8Li-3AlSi and Mg-8Li-5AlSi alloys were obtained by hot rolling.Optical microscope,microhardness tester,nanoindentor,X-ray diffractometer and electrochemical analyzer were adopted to investigate the microstructures,micro-mechanical properties and corrosion resistance.Roller was preheated to 150°C before rolling process,and rolling reduction designed was about20% per pass with a total rolling reduction of 84%.The rolled plates were annealed at 200°C for 120 min.The tensile tests were performed at room temperature.Experimental results showed that both the strength and corrosion resistance of theα+βdual-phase of Mg-Li alloy were significantly improved with adding Al-Si elements.The strength enhancement was attributed to the solid solution of Al into theα-Mg matrix and into theβ-Li matrix as well as to the precipitation strengthening of Mg2 Si particles.Besides,the dendrite grains ofα-Mg transformed to equiaxed ones with addition of Al into alloy Mg-Li.     

铸轧3003冷轧工序组织和性能控制

试验和讨论了铸轧3003冷轧工序退火温度与保温时间,冷变形量对该合金板带材再结晶退火后组织与性能的影响规律,提出了一些可获得良好晶粒度和机械性能的控制方法。     

Mechanism of the enhancement of discharge rate property for Nd_(0.8)Mg_(0.2)(Ni_(0.8)Co_(0.2))_(3.8) hydrogen storage alloy by magnetic annealing

For further improving the rate properties of Nd0.8Mg0.2(Ni0.8Co0.2)3.8 hydrogen storage alloy,the alloy was annealed in high mag-netic fields(10 T).The results showed that the electrochemical properties and magnetic properties of Nd0.8Mg0.2(Ni0.8Co0.2)3.8 hydrogen storage alloy were considerably enhanced.And there was no change of the phase composition.The lattice constants of c and c/a ratio increased for the sample magnetically annealed,yielding uniaxial magnetic anisotropy along the c axis.The increase o...     

热处理工艺对低温挤压Zn-15Al锌合金组织及性能的影响

采用拉伸试验和扫描电镜分析技术手段,研究了不同冷却速度对200℃挤压Zn-15Al锌合金的微观组织和室温力学性能的影响.结果表明:经320℃处理1 h后,变形态细小的α(Al)相发生了粗化.经水淬后α(Al)相发生了连续析出,形成了α(Al)+η(Zn)细小的粒状组织,使其强度稍有提高,塑性明显降低.而经空冷后α(Al)相发生了共析分解,形成了细片层状组织,导致其强度提高约1倍,塑性下降约80%.这意味着能够通过热处理工艺来调整变形态Zn-15Al锌合金的力学性能,以满足不同应用领域的要求.     

锌电积过程中锰元素对铝阴极的电化学行为影响

传统湿法炼锌工艺采用纯铝板作为阴极,但随着锌精矿品位的降低,电解液中杂质离子含量增大,造成阴极腐蚀消耗增加.本文以铝锰合金为研究对象,研究锰作为添加元素,与铝形成良好铝锰合金阴极材料的电化学行为,进一步提高铝阴极的耐蚀性和电催化活性.采用交流阻抗、阴极极化曲线、恒电流极化曲线、塔菲尔曲线等分析方法,探讨不同Mn元素含量对铝锰合金在40℃恒温条件,Zn²⁺ 65 g·L^-1和H₂SO₄ 150 g·L^-1溶液中电化学行为的影响.研究结果表明:相比纯铝电极,添加Mn元素的铝锰合金电极的耐蚀性普遍提高,腐蚀电流均减小;随着Mn含量的增加,腐蚀电流逐步降低,腐蚀电位与Mn含量增加无明显变化规律;当Mn质量分数为1.5%时腐蚀电流达最低(1.11 mA·cm^-2),腐蚀电位最小(-1.0954 V);零电势下,表观电流密度i₀受Mn元素的添加影响显著,i₀随Mn含量增加呈现出先增大后减小的趋势,在Mn质量分数1.5%时达到最大值3.7462×10^-16 mA·cm^-2,远大于纯铝电极4.8027×10^-33 mA·cm^-2,整体变化幅度明显,电极的电催化活性得到提高;不同电流密度下的析氢过电位和纯铝电极的整体接近,电化学过程均为电化学传质步骤控制.综合考虑电极材料的耐蚀性和电催化活性,含Mn质量分数1.5%的铝锰合金可作为理想的电积锌阴极使用.     

Zn?In LDHs在Zn?Ni二次电池中的电化学性能

采用水热法制备Zn?In LDHs,并且将其作为锌镍二次电池的新型负极材料。利用扫描电镜（SEM）和X射线衍射仪（XRD）对制备的Zn?In LDHs进行了形态和微观结构的分析。通过循环伏安（CV）、Tafel极化曲线和恒电流充电放电测试研究了Zn?In LDHs作为锌镍电池负极材料的电化学性能。形貌表征发现制备的Zn?In LDHs呈现出六边形片状结构,电化学性能研究结果表明Zn?In LDHs应用到Zn–Ni二次电池中具有很好的循环可逆性能和抗腐蚀性能,恒电流充电放电测试结果分析可知,Zn?In LDHs电极表现出了较为优异的循环稳定性以及充放电特性。经过100次循环后,循环保持率可以达到92.25%。      

Microstructure and mechanical properties of Mg-7Zn-3Al alloy with Nd and Y additions

The effects of combined addition of 0.6 wt.% Nd and 0.4 wt.% Y on the microstructure and mechanical properties of Mg-7Zn-3Al alloy were investigated.The results indicated that the Nd and Y addition led to obvious dendrite coarsening.However,it could modify the morphology and distribution of-Mg 32(Al,Zn) 49 intermetallics.Moreover,Al 2 REZn 2 phase could be introduced into the alloy with the Nd and Y addition.With the effective second-phase strengthening,the ultimate tensile strength and elongation in as-cast state can be improved by the Nd and Y addition.After ageing treatment,the alloy with the Nd and Y addition exhibited better precipitation strengthening effects by forming finer MgZn 2 and Mg 32(Al,Zn) 49 precipitates into the-Mg matrix.As a result,the yield and ultimate strength of Mg-7Zn3Al-0.6Nd-0.4Y alloy could be increased to 182 and 300 MPa by peak-ageing treatment.     

Influence of minor Zr and Ti on microstructures and properties of Al–8·6Zn–2·5Mg–2·2Cu alloys

Abstract

The effect of minor Zr and Ti elements on microstructures and properties of Al–8·6Zn–2·5Mg–2·2Cu alloys was investigated. The results show that there is no significant change in the grain size by simultaneous addition of Zr and Ti as compared to individual additions of Zr or Ti to Al–8·6Zn–2·5Mg–2·2Cu alloy. The ability of restraining recrystallisation of Al–8·6Zn–2·5Mg–2·2Cu–0·16Zr–0·04Ti alloy is weaker than that of alloy Al–8·6Zn–2·5Mg–2·2Cu–0·16Zr alloy, since Ti and Zr have a poisoning interaction. The corresponding tensile properties, hardness and stress corrosion cracking resistance of the Al–8·6Zn–2·5Mg–2·2Cu–0·16Zr alloy were decreased by addition of Ti.