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以纳米碳纤维/碳毡(CFF)为载体,分别采用碳热氢气还原法和碳热氨气还原法制备了负载型碳化钨、碳氮化钨整体催化剂,XRD结果表明催化剂的活性相分别为W2C和WCxNy, TEM表征发现其粒子尺寸分别为2~40 nm和2~20 nm。采用1 N肼分解推力器评价了上述催化剂的反应性能,W2C/CFF和WCxNy/CFF表现出了相比于Ir/CFF更好的肼分解综合性能:除了初活性略低以外,启动加速性、稳态燃压以及比活性均高于贵金属Ir催化剂。此外,W2C/CFF和WCxNy/CFF催化剂的稳定性明显优于Ir/CFF,这主要是由于CFF载体在贵金属Ir的作用下发生了更显著的甲烷化反应。 相似文献
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《合成纤维工业》2017,(3):35-39
采用发散法,以乙二胺(EDA)为引发核,与丙烯酸甲酯(MA)通过迈克尔加成和酰胺化反应将1.0代聚酰胺-胺(1.0 G PMMAM)接枝到碳纤维织物(CFF)表面,同时将1.0 G PMMAM作为双酚A型环氧树脂(EP)的固化剂,制备了接枝改性CFF/EP复合材料,分析了改性CFF的表面结构及改性前后CFF/EP复合材料的力学性能。结果表明:通过迈克尔加成和酰胺化反应,1.0 G PAMAM被成功地接枝在CFF表面;接枝改性后CFF表面粗糙度增加,沟壑变得更密,且其类石墨的有序结构遭到破坏,无序性增加;接枝改性CFF/EP复合材料的弯曲强度、剪切强度和冲击强度较未改性CFF/EP复合材料分别提高了102%,99%和30%。 相似文献
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以环状对苯二甲酸丁二醇酯(CBT)为原料,采用双螺杆挤出机反应挤出与热压复合法制备了碳纳米管/聚环状对苯二甲酸丁二醇酯/碳纤维织物(MWNTs/pCBT/CFF)复合材料,研究了酸化处理前后MWNTs的加入对CBT开环聚合的影响,以及MWNTs对pCBT基体及pCBT/CFF复合材料力学性能的影响。结果表明:MWNTs的加入降低了CBT的聚合速率,增大了pCBT树脂的低黏度加工窗口;酸化处理后的MWNTs对pCBT基体具有更加明显的增强增韧效果,并有助于改善pCBT基体与CFF的界面结合力,显著提高了pCBT/CFF复合材料的力学性能;加入酸化处理后的MWNTs质量分数1%,得到的MWNTs/pCBT/CFF复合材料的层间剪切强度和弯曲强度分别较pCBT/CFF复合材料提高了17.7%和32.7%。 相似文献
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高白填料氢铝板材与钙粉板材的性能对比及评价 总被引:1,自引:0,他引:1
本文通过试验研究了高白填料氢铝、钙粉及高白填料氢铝与钙粉混合料所制作的人造石板材性能的差异。结果表明,添加了四种不同填料(高白填料氢铝(1^#AH、2^#AH)、钙粉、高白填料氢铝与钙粉混合料(6:4))所制作的人造石板材在以下性能方面存在明显差异:①2^#AH人造石专用料与树脂的混合粘度最低(15900eP),钙粉与树脂混合粘度最高(18500eP);②用钙粉作填料制作的人造石板材透光性很低,在钙粉中加入高白填料氢铝后可使人造石板材的透光性明显提高,但是钙粉板的白度较高(L值=82.76);③在弯曲性能上,高白填料氢铝板材明显优于钙粉板;④在阻燃性能方面,高白填料氢铝(1^#AH、2^#AH)制作的人造石板材的氧指数分别达到43和42.5,钙粉板的氧指数仅为25,加钙粉量为40%的钙粉与高白填料氢铝的混合料制作的人造石板材的氧指数为31。而在拉伸性能、硬度、冲击性能方面相差不大;在耐污性能有所不同,钙粉板对口红的耐污性较好,氢铝、氢铝与钙粉混合料制作的人造石板材对醋和酱油的耐污性比较好。 相似文献
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钛酸铝陶瓷及其研究现状 总被引:3,自引:1,他引:3
本文简述了钛酸铝陶瓷的制备及性能,论述了钛酸铝陶瓷的稳定性、微裂纹、低热膨胀性,讨论了工艺条件及外加剂对钛酸铝材料性能的影响,最后提出了改善钛酸铝陶瓷性能的技术途径。 相似文献
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水泥窑烧成带用镁铁铝尖晶石砖的研制 总被引:3,自引:0,他引:3
为了满足水泥窑烧成带用砖无铬化的要求, 以粒度3.5~1mm、<1mm、<0.088mm的高铁镁 砂和粒度<2mm的铁铝尖晶石为原料,分别讨论了 1500℃、1550℃、1600℃、1650℃的烧成温度和 5%、7%、9%、11%的铁铝尖晶石加入量对镁铁铝尖 晶石砖性能的影响。结果表明:当烧成温度为1600 ℃时,试样已烧结;当铁铝尖晶石加入量为7%时,试 样的耐压强度与粘结强度最高(用粘结强度表征材 料的挂窑皮性)。与直接结合镁铬砖相比,镁铁铝尖 晶石砖在热震稳定性方面更优于直接结合镁铬砖,而 在粘挂窑皮性能方面与其相近。 相似文献
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The effects of alkali treatment with sodium hydroxide on the tensile properties, morphology, thermal degradation, and mass swell of low‐density polyethylene (LDPE)/(chicken feather fibers (CFF)) composites were studied. The LDPE/CFF composites were prepared by using a Z‐Blade mixer at 180oC and a rotor speed of 50 rpm. The LDPE/CFF‐Treated composites exhibited higher tensile strength, Young's modulus, and final decomposition temperature but had lower mass swell percentage and elongation at break than the LDPE/CFF composites. An SEM morphology study showed that the CFF treatment could significantly improve adhesion at the interface and lead to ingress of the fiber into the LDPE phase. Thermogravimetric analysis indicated that the LDPE/CFF‐Treated composites had higher thermal stability than the LDPE/CFF composites. J. VINYL ADDIT. TECHNOL., 20:36–41, 2014. © 2014 Society of Plastics Engineers 相似文献
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A conventional technique for microfluidic droplet generation is Co-axial Flow Focusing(CFF) in which a contraction zone is placed downstream of the dispersed phase nozzle. In this contraction zone, the dispersed-phase(dphase) fluid is pinched off by continuous-phase(c-phase) fluid to generate micro-droplets. Studying the influence of multiple parameters such as the fluids velocities and viscosities, the interfacial tension, and nozzle and orifice diameters on the droplet size is of great importance for the design and application of CFF devices. Thus,development of more complete numerical models is required. In this paper, we show our model is compatible with experimental data and then numerically investigate the effects of aforementioned parameters on the droplet generation in a CFF microfluidic device. Simulation results showed that the c–phase flow rate, viscosity and the interfacial tension had great impacts on the droplet size. The effect of the nozzle diameter on the generated droplet size was small compared to that of the orifice in a CFF device. Using the simulation results, a correlation was also developed and suggested which predicts the droplet size with less than 15% error in a wide range of the introduced dimensionless parameters. 相似文献
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《Polymer Composites》2017,38(5):837-845
Green composites, a bio‐based polymer matrix is reinforced by natural fibers, are special class of bio‐composites. Interest about green composites is continuously growing because they are environment‐friendly. This study describes the preparation and mechanical characterization of green composites using polylactic acid (PLA) matrix including chicken feather fiber (CFF) as reinforcement. Extrusion and an injection molding process were used to prepare CFF/PLA composites at a controlled temperature range. CFF/PLA composites with fiber mass content of 2%, 5%, and 10% were manufactured. The effects of fiber concentration and fiber length on mechanical properties of CFF/PLA composites have been studied. Mechanical properties of composites were investigated by tensile, compression, bending, hardness, and Izod impact testing. The results of experiments indicated that Young's modulus, compressive strength, flexural modulus, and hardness of the PLA reinforced CFF composites are higher but tensile strength, elongation at break, bending strength and impact strength of them are lower than pure PLA. The results indicate that these types of composites can be used for various applications. POLYM. COMPOS., 38:837–845, 2017. © 2015 Society of Plastics Engineers 相似文献
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Winniberg lvarez-Len Irasema Mendieta Evangelina Delgado-Gonzlez Brenda Anguiano Carmen Aceves 《International journal of molecular sciences》2021,22(16)
Neuroblastoma (Nb), the most common extracranial tumor in children, exhibited remarkable phenotypic diversity and heterogeneous clinical behavior. Tumors with MYCN overexpression have a worse prognosis. MYCN promotes tumor progression by inducing cell proliferation, de-differentiation, and dysregulated mitochondrial metabolism. Cyclophosphamide (CFF) at minimum effective oral doses (metronomic therapy) exerts beneficial actions on chemoresistant cancers. Molecular iodine (I2) in coadministration with all-trans retinoic acid synergizes apoptosis and cell differentiation in Nb cells. This work analyzes the impact of I2 and CFF on the viability (culture) and tumor progression (xenografts) of Nb chemoresistant SK-N-BE(2) cells. Results showed that both molecules induce dose-response antiproliferative effects, and I2 increases the sensibility of Nb cells to CFF, triggering PPARγ expression and acting as a mitocan in mitochondrial metabolism. In vivo oral I2/metronomic CFF treatments showed significant inhibition in xenograft growth, decreasing proliferation (Survivin) and activating apoptosis signaling (P53, Bax/Bcl-2). In addition, I2 decreased the expression of master markers of malignancy (MYCN, TrkB), vasculature remodeling, and increased differentiation signaling (PPARγ and TrkA). Furthermore, I2 supplementation prevented loss of body weight and hemorrhagic cystitis secondary to CFF in nude mice. These results allow us to propose the I2 supplement in metronomic CFF treatments to increase the effectiveness of chemotherapy and reduce side effects. 相似文献
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Preparation of pseudocapacitor electrodes via electrodeposition of polyaniline on nonwoven carbon fiber fabrics 下载免费PDF全文
Aniline has been polymerized via electrodeposition onto various nonwoven carbon fiber fabric (CFF) substrates for use as a pseudocapacitive electrochemical capacitor. Four types of CFF were initially tested for double layer capacitance before polyaniline deposition, and again for specific capacitance after deposition. A binder‐free CFF was selected for further analysis due to its high capacitance change following PANI deposition (three orders of magnitude). The aniline monomer concentration, deposition potential, and deposition time were varied and resulting materials were characterized using chrono‐potentiometry, cyclic voltammetry, and scanning electron microscopy. The deposition potential range yielding highest capacitance was found to be between 0.744 and 0.777 V. A solution concentration of 0.5M aniline at a 20 min deposition time resulted in the highest specific capacitance (>80 F/g based on total electrode mass and >300 F/g based on PANI mass) within this study. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43315. 相似文献
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Glen R. Rubin Yuquan Wen Michael S. Loop Timothy W. Kraft 《International journal of molecular sciences》2022,23(8)
The full-field ERG is useful for index rod- or cone-mediated retinal function in rodent models of retinal degeneration. However, the relationship between the ERG response amplitudes and visually guided behavior, such as flicker detection, is not well understood. A comparison of ERG to behavioral responses in a light-damage model of retinal degeneration allows us to better understand the functional implications of electrophysiological changes. Flicker-ERG and behavioral responses to flicker were used to determine critical flicker frequency (CFF) under scotopic and photopic conditions before and up to 90 d after a 10-day period of low-intensity light damage. Dark- and light-adapted ERG flash responses were significantly reduced after light damage. The a-wave was permanently reduced, while the b-wave amplitude recovered over three weeks after light damage. There was a small, but significant dip in scotopic ERG CFF. Photopic behavioral CFF was slightly lower following light damage. The recovery of the b-wave amplitude and flicker sensitivity demonstrates the plasticity of retinal circuits following photopic injury. 相似文献
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《Journal of the European Ceramic Society》2023,43(10):4363-4373
A rapid and low-cost carbon/carbon (C/C) composites preparation method is proposed: graphite prepreg-coated carbon fiber fabric (CFF) is formed by hot pressing, followed by hot isostatic pressing and high temperature graphitization, to prepare C/C composite with low porosity and high crystallinity. In this method, the carbon fiber (CF) mass fraction can be precisely regulated in the range of 40–95% by the impregnation process conditions of CFF in graphite prepreg. The graphite particles in the preform were graphitized and bonded with CFF by high temperature graphitization. Finally, a ZrO2 anti-ablative layer was applied using sol-gel method. The results show that when the CF mass fraction is 50%, the C/C composite with a crystallinity of 92.21 and a porosity of 3.47% can be obtained, with mass ablation rate of 0.23 mg/s and density of 1.62 g/m3. The method can prepare C/C composites with uniform density and high ablation resistance. 相似文献
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Ying Ying Khaw Ching Yern Chee Seng Neon Gan Ramesh Singh Nik Nazri Nik Ghazali Nan-Shang Liu 《应用聚合物科学杂志》2019,136(24):47642
Amphiphilic keratin from chicken feather fiber (CFF) and hydrophilic cellulose were incorporated as fillers into hydrophobic poly(lactic acid) (PLA) polymer blend. This study implemented ionic liquid (IL) of 1-butyl-3-methylimidazolium chloride (BMIMCl) to dissolve the 1 wt % fillers. The composite films were compared with and without the addition of IL prepared from five sets of ratios of CFF to MCC using measuring mixers and compression molding. Thermal analysis showed that increase in CFF composition decreases the glass-transition temperature (T g), and crystallization temperature (T c) as well as increases the degree of crystallinity. PLA composite with the 70/30 ratio of CFF to MCC was found to be the optimum composition in obtaining considerably low T g and high crystallinity. BMIMCl enhanced the miscibility of the composites as observed in scanning electron microscope images and single T g. Apart from creating porous structure and lowering mechanical hardness, BMIMCl also decreased the thermal stability of the PLA composites. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47642. 相似文献