共查询到20条相似文献,搜索用时 156 毫秒
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导电聚合物的合成和应用前景 总被引:4,自引:0,他引:4
本文对导电聚合物的性能,一般的合成方法如链聚合法和分步骤合法,特殊的合成方法如电化学合成和光化学聚合作了较详细的评述。介绍了氧化或还原试剂掺合进这些聚合物中,被称为掺杂剂的类型和掺杂方法。最后介绍了这些新材料的某些应用领域以及存在的问题。 相似文献
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高密度聚乙烯导电塑料的性能研究 总被引:5,自引:0,他引:5
研究了导电炭黑的品种、含量和炭黑并用对高密度聚乙烯性能的影响。以脉动态硫化对改善HDPE/导电炭黑复合材料物性的影响。结果表明,炭黑并用能有效降低生产成本,而且保持了材料的性能,HG-4型电导炭黑填充HDPE具有很好的导电性,动态硫化法可以克服复合材料物性差的弱点,并能保持改性材料的高导电性;在HG-4型炭黑含量为7份时,材料的拉伸强度为13MPa,断裂伸长率为350%,体积电阻率为2.1Ω·m。 相似文献
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聚合物/碳纳米管的研究进展 总被引:6,自引:0,他引:6
碳纳米管具有独特的结构,优异的力学性能、热稳定性与导电性能,与聚合物并用可开发出多种新型复合材料,评述利用直接混合法、原位聚合法与超声波处理法制备聚合物/碳纳米管材料,并讨论该复合材料的力学性能,光电性能与磨擦学性能。 相似文献
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采用正交设计方法在HAKKE SYSTEM-40密炼机上对两种不同类型导为黑进行了加工工艺条件探索。结果表明,采用压辊式密炼方法,炭黑能在基体中均匀分民得材料拉伸强度及断理解伸长率高,室温电阻率较大,强剪切力对特异对炭黑及炉法炭黑链状结构具有不程度的破坏;转子类型、转子速度、混炼温度混炼时间对LLDPE/EVA/CB复合物导电性能的影响依次减弱。 相似文献
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PET/PBT共混导电复合材料的研究 总被引:1,自引:0,他引:1
采用DSC(差示扫描量热法)对PET/PBT合金的相容性进行了研究,探讨了导电炭黑加入量对PET/PBT合金的导电性能与力学性能的影响。结果表明,PET/PBT共混物在非晶区相容而在晶区不相容或部分相容,导电炭黑填充PET/PBT合金的渗流阈值为15%,导电炭黑的填充对合金的力学性能有负面的影响。 相似文献
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浅色云异导电颜料制备工艺研究 总被引:1,自引:0,他引:1
用化学共沉积法方法在微细云母基片上包覆 Sno2-Sb2O3半导体化合物,经煅烧制得一种新型浅色导电颜料,克服了纯SnO2或SbO3导电颜料易聚焦,难分散的缺点,且大大降低成本。了影响颜料性能的各种因素。 相似文献
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导电聚苯胺复合纤维的研制 总被引:3,自引:0,他引:3
利用氧化聚合法,在室温、常压下快速将苯胺聚合在极性纤维表面,从而赋予纤维优良的导电性能,其表面电阻达到10 ̄3Ω/cm。同时对导电性能的耐洗牢度进行了初步研究。 相似文献
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Paulina Streimikyte Pranas Viskelis Jonas Viskelis 《International journal of molecular sciences》2022,23(4)
The scientific community and industrial companies have discovered significant enzyme applications to plant material. This rise imparts to changing consumers’ demands while searching for ‘clean label’ food products, boosting the immune system, uprising resistance to bacterial and fungal diseases, and climate change challenges. First, enzymes were used for enhancing production yield with mild and not hazardous applications. However, enzyme specificity, activity, plant origin and characteristics, ratio, and extraction conditions differ depending on the goal. As a result, researchers have gained interest in enzymes’ ability to cleave specific bonds of macroelements and release bioactive compounds by enhancing value and creating novel derivatives in plant extracts. The extract is enriched with reducing sugars, phenolic content, and peptides by disrupting lignocellulose and releasing compounds from the cell wall and cytosolic. Nonetheless, depolymerizing carbohydrates and using specific enzymes form and release various saccharides lengths. The latest studies show that oligosaccharides released and formed by enzymes have a high potential to be slowly digestible starches (SDS) and possibly be labeled as prebiotics. Additionally, they excel in new technological, organoleptic, and physicochemical properties. Released novel derivatives and phenolic compounds have a significant role in human and animal health and gut-microbiota interactions, affecting many metabolic pathways. The latest studies have contributed to enzyme-modified extracts and products used for functional, fermented products development and sustainable processes: in particular, nanocellulose, nanocrystals, nanoparticles green synthesis with drug delivery, wound healing, and antimicrobial properties. Even so, enzymes’ incorporation into processes has limitations and is regulated by national and international levels. 相似文献
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Mechanisms Governing Anaphylaxis: Inflammatory Cells,Mediators, Endothelial Gap Junctions and Beyond
Samantha Minh Thy Nguyen Chase Preston Rupprecht Aaisha Haque Debendra Pattanaik Joseph Yusin Guha Krishnaswamy 《International journal of molecular sciences》2021,22(15)
Anaphylaxis is a severe, acute, life-threatening multisystem allergic reaction resulting from the release of a plethora of mediators from mast cells culminating in serious respiratory, cardiovascular and mucocutaneous manifestations that can be fatal. Medications, foods, latex, exercise, hormones (progesterone), and clonal mast cell disorders may be responsible. More recently, novel syndromes such as delayed reactions to red meat and hereditary alpha tryptasemia have been described. Anaphylaxis manifests as sudden onset urticaria, pruritus, flushing, erythema, angioedema (lips, tongue, airways, periphery), myocardial dysfunction (hypovolemia, distributive or mixed shock and arrhythmias), rhinitis, wheezing and stridor. Vomiting, diarrhea, scrotal edema, uterine cramps, vaginal bleeding, urinary incontinence, dizziness, seizures, confusion, and syncope may occur. The traditional (or classical) pathway is mediated via T cells, Th2 cytokines (such as IL-4 and 5), B cell production of IgE and subsequent crosslinking of the high affinity IgE receptor (FcεRI) on mast cells and basophils by IgE-antigen complexes, culminating in mast cell and basophil degranulation. Degranulation results in the release of preformed mediators (histamine, heparin, tryptase, chymase, carboxypeptidase, cathepsin G and tumor necrosis factor alpha (TNF-α), and of de novo synthesized ones such as lipid mediators (cysteinyl leukotrienes), platelet activating factor (PAF), cytokines and growth factors such as vascular endothelial growth factor (VEGF). Of these, histamine, tryptase, cathepsin G, TNF-α, LTC4, PAF and VEGF can increase vascular permeability. Recent data suggest that mast cell-derived histamine and PAF can activate nitric oxide production from endothelium and set into motion a signaling cascade that leads to dilatation of blood vessels and dysfunction of the endothelial barrier. The latter, characterized by the opening of adherens junctions, leads to increased capillary permeability and fluid extravasation. These changes contribute to airway edema, hypovolemia, and distributive shock, with potentially fatal consequences. In this review, besides mechanisms (endotypes) underlying IgE-mediated anaphylaxis, we also provide a brief overview of IgG-, complement-, contact system-, cytokine- and mast cell-mediated reactions that can result in phenotypes resembling IgE-mediated anaphylaxis. Such classifications can lead the way to precision medicine approaches to the management of this complex disease. 相似文献
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以中低温煤焦油轻油和重油为实验原料,采用常压蒸馏获得170~200℃、200~240℃、240~270℃、270~300℃、300~320℃、320~340℃、340~360℃和360~390℃煤焦油馏分油;利用配有油品加氧制冷进样系统的ICP-OES测定了21种微量元素在馏分油中的含量,考察了不同馏分油中元素的分布情况。研究表明:在原煤焦油中,未发现Ag、Mg、Mo、Na、Ni、Fe、Mn、Cr及Ti元素,含量较高的元素有Sn、P、Al、Pb、Si,其中Sn元素在轻油和重油中的含量分别为11.78μg/g和14.04μg/g;在所有馏分油中,未发现Al、Mo、Fe、Mn、Cr及Ti元素,含量比较高的元素有Si、Sn、Na、Zn、Pb,特别是Si、Na、Sn、Zn、Ni、Pb及B元素可以有效富集于馏分油中。可能的原因是Ca、Fe、Mg、Al等金属以不同的盐类形态存在,在煤焦油脱水及<170℃蒸馏过程中,这些金属盐类会被部分带出,导致其在馏分油中的含量未富集或未检出;通过关联金属元素在馏分油中的分布与其组成的关系,馏分油中元素的分布可能与酚类化合物、杂环化合物和蒸馏温度等相关。酚类化合物及杂环化合物可能与Ag、B、Cu、Mo、Sn、Na、Zn、Ca、Pb等金属形成络合物或卟啉配合物,蒸馏温度一方面可以破坏Sn、Cd、Pb、Zn、Cu、Ca、Pb等元素在馏分油中的结合力,另一方面也可以促进这些元素与馏分油中的含氧、含氮等化合物更好地发生化合反应,进而影响金属元素在馏分油中的含量分布。 相似文献
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Recent advances in synthesis, physical properties and applications of conducting polymer nanotubes and nanofibers 总被引:1,自引:0,他引:1
Yun-Ze Long Meng-Meng Li Changzhi Gu Meixiang Wan Jean-Luc Duvail Zongwen Liu Zhiyong Fan 《Progress in Polymer Science》2011,36(10):1415-1442
This article summarizes and reviews the various preparation methods, physical properties, and potential applications of one-dimensional nanostructures of conjugated polyaniline (PANI), polypyrrole (PPY) and poly(3,4-ethylenedioxythiophene) (PEDOT). The synthesis approaches include hard physical template method, soft chemical template method, electrospinning, and lithography techniques. Particularly, the electronic transport (e.g., electrical conductivity, current-voltage (I-V) characteristics, magnetoresistance, and nanocontact resistance) and mechanical properties of individual nanowires/tubes, and specific heat capacity, magnetic susceptibility, and optical properties of the polymer nanostructures are presented with emphasis on size-dependent behaviors. Several potential applications and corresponding challenges of these nanofibers and nanotubes in chemical, optical and bio-sensors, nano-diodes, field effect transistors, field emission and electrochromic displays, super-capacitors and energy storage, actuators, drug delivery, neural interfaces, and protein purification are also discussed. 相似文献
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松香是一类产量丰富、价格低廉的可再生林产资源,被广泛地应用于食品、农业、橡胶、油墨、涂料等领域。松香的三环二萜结构具有超强的疏水性,通过催化异构、Diels-Alder加成等手段引入亲水基团可制备高附加值、易生物降解的绿色表面活性剂。本文从阴离子、阳离子、非离子和两性离子表面活性剂4个大类对松香基表面活性剂应用的文献及专利进行综述,重点分析了羧酸盐、磺酸盐、硫酸盐和磷酸盐4种阴离子型表面活性剂和季铵盐阳离子型表面活性剂,多元醇型和聚氧乙烯型非离子表面活性剂,以及甜菜碱型和氧化胺型两性离子表面活性剂。剖析松香基表面活性剂产业化开发的新技术及新产品概况,提出松香基表面活性剂替代传统表面活性剂的潜在应用领域。同时,对松香基表面活性剂的研究发展与产业化发展进行了评价与展望。 相似文献
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Mostafa Khodakarami 《Polymer-Plastics Technology and Engineering》2017,56(18):2019-2042
Separation and purification techniques are applied in many important fields, such as in the medical, chemical, metallurgical, environmental, and pharmaceutical industries. Recent advances in separation science and the urgent need for highly selective purification have necessitated a rapid progress with respect to the reagents, chemicals, and surfactants used in separation processes to attain a high efficiency and selectivity. Polymeric materials have attracted considerable interest, and they have been widely used as extractants, catalysts, and modifiers, in separation and purification processes. This review outlines the recent advances in the use of novel polymers, natural and synthetic, in different separation and purification techniques. Various separation techniques such as chromatography, crystallization, precipitation, distillation, electrophoresis, filtration, and mineral processing methods are discussed, and the polymers used in each method are described in terms of their properties, structure, and function. The application of polymers shows great promise in achieving a highly efficient separation, especially in the areas of membrane separation and water purification. The rational design of new multifunctional polymers with triggered functions presumably presents new opportunities for the development of advanced separation methods. 相似文献
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Coals from Luquan, Yunnan Province, China, have high contents of cutinite and microsporinite, with an average of 55 and 33.5 vol%, respectively, (on a mineral-free basis). The coals are classified as cutinitic liptobiolith, sporinite-rich durain, cutinite-rich durain, and sporinitic liptobiolith. These four liptinite-rich coals are often interlayered within the coal bed section and vary transversely within the coal bed. The vitrinite content varies from as low as 1.6-20.5% (mineral-free basis), and it is dominated by collodetrinite, collotelinite, and corpogelinite. The maceral composition may be attributed to the type of the peat-forming plant communities. Moreover, the Luquan coals are characterized by high contents of volatile matter, hydrogen, and oxygen, and the high values of the atomic hydrogen to carbon ratio as a result of the maceral composition. As compared with the common Chinese coals and the upper continental crust, the Luquan coals are enriched in Li, B, Cu, Ga, Se, Rb, Mo, Ba, Pb, Bi, and U, with averages of 99.9, 250, 111, 24.4, 4.55, 130, 58.8, 1276, 162, 3.85, and 34.1 μg/g, respectively. The SEM-EDX results show that V, Cr, Ga, and Rb occur mainly in clay minerals, and Cu and Pb are associated with clay minerals and pyrite, and Mo and U are mainly in clay minerals and organic matter. Barite and clay minerals are the main carrier of barium. The high B and U contents are probably resulted from deep seawater influence during coal formation. 相似文献
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Nicolas A. Deak Lawrence A. Johnson 《Journal of the American Oil Chemists' Society》2007,84(3):259-268
The effects of extraction temperature and preservation method on the functional properties of soy protein isolate (SPI) were
determined. Four extraction temperatures (25, 40, 60, and 80 °C) were used to produce SPI and yields of solids and protein
contents were determined. Three preservation methods were also tested (spray-drying, freeze-drying, and freezing–thawing)
and compared to fresh (undried) samples for each extraction temperature. No differences in yields of solids and protein were
observed among SPIs extracted at 25, 40, and 60 °C; however, SPI extracted at 80 °C yielded significantly less solids and
protein. Extraction temperature significantly affected SPI functionality. As extraction temperature increased, solubility
and emulsification capacity decreased; surface hydrophobicities, emulsification activities and stabilities, and dynamic viscosities
increased; and foaming properties improved. Preservation method also significantly affected SPI functionality. Drying method
did not affect the denaturation enthalpies of SPIs, but spray-dried SPIs had higher solubilities, surface hydrophobicities,
and emulsification stabilities, and lower viscosities, emulsification activities and rates of foaming than freeze-dried SPI
exhibited. Emulsification and foaming capacities and foaming stabilities were similar for both methods of drying. There was
significant interaction between extraction temperature and preservation method for all functional properties except emulsification
capacity. 相似文献
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Ludmila Martínkov Barbora Kístkov Vladimír Ken 《International journal of molecular sciences》2022,23(7)
Laccases (Lac) and tyrosinases (TYR) are mild oxidants with a great potential in research and industry. In this work, we review recent advances in their use in organic synthesis. We summarize recent examples of Lac-catalyzed oxidation, homocoupling and heterocoupling, and TYR-catalyzed ortho-hydroxylation of phenols. We highlight the combination of Lac and TYR with other enzymes or chemical catalysts. We also point out the biological and pharmaceutical potential of the products, such as dimers of piceid, lignols, isorhamnetin, rutin, caffeic acid, 4-hydroxychalcones, thiols, hybrid antibiotics, benzimidazoles, benzothiazoles, pyrimidine derivatives, hydroxytyrosols, alkylcatechols, halocatechols, or dihydrocaffeoyl esters, etc. These products include radical scavengers; antibacterial, antiviral, and antitumor compounds; and building blocks for bioactive compounds and drugs. We summarize the available enzyme sources and discuss the scalability of their use in organic synthesis. In conclusion, we assume that the intensive use of laccases and tyrosinases in organic synthesis will yield new bioactive compounds and, in the long-term, reduce the environmental impact of industrial organic chemistry. 相似文献