低黏度水玻璃化学注浆材料试验研究

为解决煤矿深部基岩段微裂隙和孔隙性含水地层注浆困难的问题,对溶液型水玻璃化学注浆材料进行了研究。采用正交试验研究了水玻璃模数、水玻璃体积分数、乙二醇二乙酸酯体积分数对浆液胶凝时间、黏度及浆液固砂体抗压强度的影响。正交试验表明:影响浆液胶凝时间最显著的因素为乙二醇二乙酸酯体积分数;影响浆液黏度及固砂体抗压强度最显著的因素皆为水玻璃体积分数。试验结果表明:采用乙二醇二乙酸酯作为水玻璃的胶凝剂可以得到结石体强度较高(约1MPa)、胶凝时间可调(5~30 min)、黏度较低(≤6 mPa.s)的新型水玻璃浆液。     

温度对水玻璃化学浆胶凝时间的影响研究

为了研究温度对水玻璃化学浆液胶凝时间的影响,选用4种典型水玻璃化学浆液进行试验。使用高低温试验箱调节不同温度进行试验,对试验数据进行拟合分析。试验结果表明,温度对水玻璃化学浆液胶凝时间的影响规律符合Arrhenius关系式。     

全尾砂改性固化力学性能研究

为实现浓缩全尾砂固化堆存,达到地表无害化处理目的,选用矿渣粉、生石灰、工业石膏和膨润土开发尾砂改性固化剂。以三山岛金矿全尾砂为研究对象,测定了尾砂的物化性质;设计了改性固化剂配比试验和正交试验,对固结体强度的影响因素进行了分析,确定了改性固化剂的最佳配比。结果表明:随着生石灰、工业石膏和膨润土占比的增加,尾砂固结体强度变化为先增大后减小,尾砂料浆浓度越大,固结体强度越大;工业石膏的含量变化对尾砂固结体的强度影响最显著;在灰砂比1∶20条件下,适合三山岛全尾砂固结的最佳改性固化剂配比为矿渣粉78.8%、生石灰13%、工业石膏7%、膨润土1.2%。     

水泥-膨润土泥浆固结体力学性能室内试验研究

将不同配合比的水泥-膨润土泥浆养护到一定龄期,对硬化后泥浆固结体的无侧限抗压强度、变形模量以及极限应变等力学性能进行了试验研究,得到了原材料对固结体力学性能的影响规律以及无侧限抗压强度与变形模量之间的关系.结果表明,固结体的无侧限抗压强度主要受水泥影响;极限应变随水泥用量增加而减小,随膨润土用量增加而增大;变形模量随水泥用量增加而增大,但膨润土对变形模量的影响比较复杂;固结体的无侧限抗压强度和变形模量随养护龄期的增长而增加.     

水泥水玻璃浆液在矿井井筒防水堵漏中的应用

为了解决矿井井筒在富水地层中的渗水问题,采用无毒无害且胶凝时间可控的水泥-水玻璃浆液治理矿井井筒的渗水漏水问题。通过室内实验确定酸性条件下水泥水玻璃浆液的胶凝时间和结石体强度。根据井筒渗水地层的地质条件提出井筒壁后注浆的注浆方法以及最佳的浆液配比。研究表明水泥水玻璃可以很好地封堵岩土体的裂隙,阻断地下水的渗流路径,水泥水玻璃浆液可以作为封堵材料用于治理矿井井筒渗水漏水。     

低温环境下添速凝剂的水泥浆凝结特性试验研究

为了解决低温环境下水泥浆液凝结缓慢、结石率低、强度低的问题,采用了理论分析和室内试验的方法,进行低温环境下添水玻璃速凝剂的水泥浆凝结特性试验,研究了0、3、5℃温度和0%、3%、5%、8%、10%、12%水玻璃掺入量对水泥浆液凝结时间、结石率和强度的影响。结果表明:水玻璃能够有效缩短水泥浆液的凝结时间,添水玻璃的水泥浆凝结时间随温度的降低而延长,随温度的升高而缩短;凝结时间随水灰比的增大而延长;结石率随水玻璃掺量的增加而增加,随水灰比的增大而减小;10%水玻璃掺量的水泥浆凝结时间、结石率和强度较好。     

水泥-水玻璃浆液凝固特性试验研究

水泥-水玻璃浆液在灌浆、堵水等工程中具有广泛的应用,而浆液的凝固特性对灌浆、堵水效果具有直接的影响。在对水泥-水玻璃浆液凝结硬化机理分析的基础上,对不同水灰比浆液的胶凝时间和流动度进行了试验研究,并对FDN、SM、NF、UNF-5、柠檬酸、多聚磷酸钠、酒石酸钾钠、酒石酸、磷酸氢二钠等外加剂对浆液凝固特性的影响进行了对比试验研究。在此基础上重点对磷酸氢二钠的缓凝性能进行了试验分析,初步获得了磷酸氢二钠对水泥-水玻璃浆液的凝固性能的影响规律。最后按初凝时间设计了几种水泥-水玻璃浆液的配方。     

新型水玻璃化学注浆材料的试验研究

利用水玻璃作为浆液主剂,对复合浆液的胶凝时间、黏度、抗压强度、水质毒理、SEM、IR、29Si NMR分别进行了研究。试验结果表明：新型复合浆液能实现浆液的胶凝时间可调、黏度低、固砂体力学性能较高的特点;浆液的水质毒理性能表现较为良好;SEM分析得知浆液胶结情况良好;IR及29 Si NMR分析证实,反应产生了硅酸盐的...     

水玻璃化学浆在地面预注浆中的应用研究

为了解决立井井筒深部基岩微裂隙赋存传统颗粒性注浆材料无法注入的问题,对水玻璃化学浆液的基本性质及地面预注水玻璃化学浆的工艺进行了研究。研究表明:水玻璃化学浆液黏度低,可注性好,固结体强度较高,胶凝时间可调,适用于千米级井筒地面预注浆。在杨村矿风井地面预注浆中进行了现场应用,应用结果表明:杨村矿风井井筒深部基岩微裂隙含水地层采用地面预注水玻璃化学浆后,注浆堵水效果良好。     

酸性干湿循环下赤泥-石灰固化镉铅污染土性能

为实现固废资源化利用并达到以废治废,变废为宝的目的,提出采用赤泥-石灰作为固化剂对镉、铅重金属污染土进行固化/稳定化处理,通过酸性干湿循环试验、无侧限抗压强度试验、毒性浸出试验以及微观结构分析,研究不同固化剂配比、污染物浓度、溶液pH值和干湿循环次数对赤泥-石灰固化剂固化污染土的质量损失率、强度变化、毒性浸出浓度以及微观形态的影响。结果表明：在各种条件下,R4C4固化土质量损失率最低;在溶液pH为7干湿循环下,固化土抗压强度随石灰掺量增加而增加,随循环次数的增加先增大后减小,在循环次数为两次时达到峰值;溶液pH值减小时,强度也随之减小;浸出浓度随循环次数以及溶液pH值的增大而增大,在初始浓度为M1时所有试样均满足标准要求;在多次酸性干湿循环后土体出现裂缝,且水化物减少导致结构被破坏。     

Current situation and future trend of China rare earth luminescent material industry

<正>Rare earth luminescent material is one of the most important application sectors of rare earths.China enjoys the exceptional advantage to develop rare earth luminescent material for its abundant rare earth resources.After several decades'endeavor,China's rare earth luminescent material industry,headed by rare earth phosphor for lamp and LED and high efficient rare earth energy-saving light source,has been gradually developed into a scale industry.China has become a major production base of rare earth phosphor for lamps and rare earth     

China rare earth market review

正June 1~10,2014Rare earth market remained weak.Quoted price of rare earth products was similar to that in May.There was no sign of recovery in downstream market.The market of NdFeB magnetic materials and phosphor was depressed.Catalyst,polishing powder and ceramic industries remained inactive.Demand from downstream industry was soft.Consumers purchased on their needs.Suppliers had strong intention to sell.Prices of rare earth products     

Annual Report analysis of Chinese rare earth-related listed companies in 2013

<正>Chinese rare earth-related listed companies have published their 2013 annual reports.It can be understood from their reports that production and operation activities of Chinese rare earth-related companies were still heavily affected by macro economy and industrial policies.They basically followed the steps of national economy.In 2013,world economy recovered slowly but the economy     

Market opportunities and challenges for rare earth polishing powder

正1.Status of rare earth polishing powder Rare earth polishing powder with high content of cerium oxide began to replace iron oxide for glass polishing and became one of the key materials in glass polishing process since 1940.Compared with traditional iron oxide,rare earth polishing powder has many advantages,such as fast polishing rate,high polishing quality and long service life.It can achieve good surface quality and improve operation conditions.For example,in lens polishing,the polishing work that cerium     

Baotou Research Institute of Rare Earths developed a new RE alloy preparation technology

正Pyrometallurgy Laboratory of Baotou Research Institute of Rare Earths had independently developed a new preparation technology of rare earth alloy for NdFeB.The alloy can remarkably enhance the coercivity of NdFeB magnet but also evidently reduce the production cost of the magnet.The new master alloy was prepared in the kA pilot-scale electrolytic cell by the independent technology.The rare earth master alloy can be used as the raw material for NdFeB.Compared     

矿用防爆轴流对旋主要通风机叶片ANSYS模态分析及应用

高效节能矿用防爆对旋主要通风机的叶片是主要通风机运行的关键部件,叶片在运行时不断受到气流的作用力,从而使叶片产生振动,当叶片振动的频率与叶片的固有频率接近时,容易产生共振从而导致叶片的断裂。一旦叶片断裂时,对主要通风机的安全运行产生致命的影响,从而导致矿山、化工等企业发生重大事故,将会产生不可估量的损失。基于有限元分析软件ANSYS,对高效节能矿用防爆轴流对旋主要通风机叶片进行模态分析及产生对应的六阶模态频率,对主要通风机叶片的运行频率、固有频率及产生的共振问题进行了原理分析,并且解决了叶片频率共振的问题,从而为主要通风机叶片结构设计提供理论依据,并对主要通风机叶片的安全运行提供保障。     

2013 NdFeB export analysis

<正>China totally exported nearly 24,000 tonsof NdFeB products during 201 3,including 18,825 tons of permanent magnet,valued USD 1.34 billion at an average price of 71.4 USD/kg;3,277 tons of NdFeB magnetic powder,valued USD 1 01 million at an average price of 30.9 USD/kg;1,334 tons of strip casting ribbon,with total export value of USD 74million at an average price of 55.3 USD/kg;and 586     

Market and recycling of NiMH battery

<正>Market status and future trend of NiMH battery1.Global market of small NiMH battery Global market size of small NiMH batteries declined year on year since 2011.The trend will continue to 2018,at the rate of 5%to 10%annually.Demand for small NiMH batteries will be stable gradually.Many electrical apparatuses are powered by the built-in lithium battery today,which is the main reason for the shrunk market of small NiMH batteries.But,for some products,small NiMH     

China rare earth market review

正September 1-10,2014 Affected by the National Day holiday,rare earth transaction was stagnant and the market showed a weak steady state.As there was no good news for downstream market,some products with flat demand would likely rally slightly for some time to     

唐口煤矿深部复杂开采工作面瓦斯分源涌出规律研究

研究工作面瓦斯涌出规律对工作面瓦斯治理有重要意义。为了得到唐口煤矿深部3号煤层复杂开采条件下工作面回采时期瓦斯涌出时空演化规律,选取6304工作面作为对象,采用实测方法研究6304工作面瓦斯涌出规律。结果表明:6304工作面瓦斯涌出量为6.534 m³/min,其中煤壁占34.27%,落煤占29.62%,采空区占36.11%;沿工作面倾向由低到高,瓦斯浓度整体为上升趋势,其中1—76号架工作面瓦斯浓度小于0.20%,76—102号架瓦斯浓度上升明显,最大为0.387%;上隅角的后部采空区是工作面的瓦斯主要涌出源,上隅角1号测点瓦斯浓度0.78%,上隅角周边3号、5号、7号、8号、9号测点瓦斯浓度平均为0.643%;周期来压时,上隅角瓦斯相对平时较高。研究为针对性的瓦斯分源监控与灾害防治提供基础。