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以异丙烯膦酸(IPPA)、丙烯酸(AA)和丙烯酸羟丙酯(HPA)为单体,水为溶剂,过硫酸铵为引发剂合成了IPPA/AA/HPA三元共聚物,并对其阻垢和缓蚀性能进行了研究,结果表明,IPPA/AA/HPA共聚物不仅具有优异的阻垢分散性能,而且对碳钢也有很好的缓蚀作用,是一种性能优良的新型高效水处理剂。 相似文献
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膦酰基羧酸共聚物阻垢分散剂的研究进展 总被引:9,自引:1,他引:9
介绍了近20年来膦酰基羧酸共聚物阻垢分散剂——大分子有机磷酸的研究现状和进展情况。重点罗列了以不饱和有机磷酸单体为原料制备膦酰基羧酸共聚物阻垢分散剂,在合成工艺和阻垢、分散及缓蚀性能评价等方面所取得的研究成果,并提出了膦酰基羧酸共聚物阻垢分散剂今后的主攻方向和发展趋势。 相似文献
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异丙烯膦酸—丙烯酸共聚物的阻垢效果 总被引:14,自引:2,他引:12
本文以异丙烯膦酸和丙烯酸为单体,合成了异丙烯膦酸-丙烯酸共聚物,探讨了共聚物浓度,pH值,钙离子浓度及温度对共聚物阻垢性能的影响,探讨了共聚物对氧化铁分散能力的影响。结果表明,异丙烯膦酸-丙烯酸共聚物不仅具有优异的阻垢性能,而且对氧化铁具有较好的分散能力,是一种良好的水质稳定剂。 相似文献
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《应用化工》2019,(7)
以马来酸酐(MA)、丙烯酸羟丙酯(HPA)和2-丙烯酰胺-2-甲基丙基膦酸(AMPP)为原料,在引发剂作用下,合成了膦酰基聚羧酸共聚物(MHAP),采用正交实验对其合成工艺条件进行了优化,并进行了阻硫酸钡垢性能评价和阻垢机理探讨。结果表明,当单体MA、HPA和AMPP摩尔比为7∶1. 5∶1、反应时间为5 h、反应温度为80℃,引发剂加量为各单体总质量的6%,其在(70±2)℃,恒温16 h,MHAP用量为200 mg/L,MHAP对Ba SO4的阻垢率达到92. 68%,并具有良好的耐温能力。MHAP对Ba SO4垢的作用机理主要是晶格畸变、螯合增溶、低剂量阈值效应。 相似文献
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《应用化工》2022,(7)
以马来酸酐(MA)、丙烯酸羟丙酯(HPA)和2-丙烯酰胺-2-甲基丙基膦酸(AMPP)为原料,在引发剂作用下,合成了膦酰基聚羧酸共聚物(MHAP),采用正交实验对其合成工艺条件进行了优化,并进行了阻硫酸钡垢性能评价和阻垢机理探讨。结果表明,当单体MA、HPA和AMPP摩尔比为7∶1. 5∶1、反应时间为5 h、反应温度为80℃,引发剂加量为各单体总质量的6%,其在(70±2)℃,恒温16 h,MHAP用量为200 mg/L,MHAP对Ba SO4的阻垢率达到92. 68%,并具有良好的耐温能力。MHAP对Ba SO4垢的作用机理主要是晶格畸变、螯合增溶、低剂量阈值效应。 相似文献
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以三氯化磷、丙酮和冰乙酸为原料合成异丙烯膦酸(IPPA)单体,并在以水为溶剂,过硫酸铵为引发剂的条件下,与丙烯酸(AA)、丙烯酸羟丙酯(HPA)反应制得了异丙烯膦酸-丙烯酸-丙烯酸羟丙酯三元共聚物。并对其阻垢和缓蚀性能进行了评定。结果表明:该共聚物不仅具有优良的阻垢分散性能,而且对碳钢也有很好的缓蚀作用,是一种性能优异的新型水质稳定剂。 相似文献
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采用次磷酸盐-过硫酸铵引发体系,一步合成了多批次膦酸共聚物。在合成共聚物的同时讨论其分散性能的影响因素。加入相同的铁离子量,分散剂对氧化铁的分散性能越好,则溶液越浑浊,用分光光度计测出的透光率就越低。实验表明:AA/AMPS/MA三种单体配比、引发剂过硫酸铵-次磷酸钠浓度、共聚物合成温度及反应时间对氧化铁的分散性能都存在影响。 相似文献
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Joël Despres Manfred Koebel Oliver Krcher Martin Elsener Alexander Wokaun 《Applied catalysis. B, Environmental》2003,43(4):389-395
The influence of NO on the adsorption and desorption of NO2 on BaO/TiO2 has been studied under lean conditions. The adsorption of NO2 involves the disproportionation of NO2 into an adsorbed nitrate species and NO released to the gas phase with a 3:1 ratio,Three different nitrate species form on the catalyst: surface nitrates on the TiO2 support, surface nitrates on BaO, and bulk barium nitrate. The stability of the three species in different gas feeds was investigated by temperature-programmed desorption (TPD).
BaO+3NO2→NO+Ba(NO3)2.
The reverse reaction of the NO2 disproportionation has also been observed. If NO is added to the feed, nitrates previously formed on the sorbent will decompose into NO2. Therefore, the above chemical equation should be considered as an equilibrium reaction. Applying this finding to the NOx storage and reduction catalyst means that NO probably reacts with the previously formed nitrates yielding NO2 as an intermediate product. This NO2 is subsequently reduced by the reducing agents (hydrocarbons and CO) present during the regeneration period. 相似文献
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AA/MA/AM/MM多元共聚物阻垢性能的研究 总被引:12,自引:3,他引:9
合成了AA/MA/AM/MM多元共聚物,并对所得产品进行了碳酸钙静态阻垢实验,探讨了共聚物的分子量,投加量,溶液的pH值,温度、恒温时间等因素与共聚物阻垢率的关系,利用扫描电子显微镜观测了碳酸钙晶形的变化,结果表明,AA/MA/AM/MM多元共聚物阻垢性能较好,该共聚物使碳酸钙晶形发生了畸变。 相似文献
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Timur V. Voskoboinikov Hai-Ying Chen Wolfgang M. H. Sachtler 《Applied catalysis. B, Environmental》1998,19(3-4):279-287
Fe/ZSM-5 catalysts with high Fe loading (Fe/Al1) have been prepared by sublimation of FeCl3 onto H-ZSM-5 samples of different Si/Al ratios. They catalyze NOx reduction with hydrocarbons in an excess of O2 and H2O. TPR shows that the Fe in the zeolite cavities is different from Fe2O3 particles. Naked Fe3+ ions are absent; oxo-ions, which are equally well reducible by CO and H2, prevail. A minority of the Fe complexes lose oxygen upon mere heating to 500°C; some of the reduced sites are reoxidized only by N2O. The population of oxo-complexes that lose oxygen by heating depends on the Si/Al ratio, this dependence is in qualitative agreement with the model of (2+) charged binuclear ions [HO–Fe–O–Fe–OH]2+. Upon reacting with NO, the bridging O atom is transferred and NO2 is formed. This step is not rate limiting for active catalysts with high Al/Si ratio and high Fe loading, but it becomes critical with zeolites of low Al/Si ratio. 相似文献
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The tensile modulus of PP/nanoclay/CaCO3 hybrid ternary nanocomposite was analyzed using composite models. Rule of mixtures, inverse rule of mixtures, modified rule of mixtures (MROM), Guth, Paul, Counto, Hirsch, Halpin–Tsai, Takayanagi, and Kerner–Nielsen models were developed for three‐phase system containing two nanofillers. Among the studied models, inverse rule of mixtures, Hirsch, Halpin–Tsai, and Kerner–Nielsen models calculated the tensile modulus of PP/nanoclay/CaCO3 ternary nanocomposite successfully compared with others. Furthermore, the Kerner–Nielsen model was simplified to predict the tensile modulus by volume fractions of nanofillers. Also, Takayanagi model was modified for the current ternary system. The developed Takayanagi model can predict the tensile modulus using Young's modulus and volume fractions of matrix and nanofillers. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
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Shin-ichiro Fujita Agus Muhamad Satriyo Guo Cheng Shen Nobutsune Takezawa 《Catalysis Letters》1995,34(1-2):85-92
Precursors of Cu/ZnO catalysts with various Cu/Zn molar ratios were prepared by a coprecipitation method. It was found that amorphous copper hydroxycarbonate and sodium zinc carbonate were intermediates for the formation of various precursors such as hydrozincite, malachite and aurichalcite. Aurichalcite having a high Cu/Zn ratio was prepared from a mechanical mixture of these intermediates. 相似文献