Interactions in the LiPO3 — MoO3, NaPO3 — MoO3, and KPO3 — MoO3 systems

The MPO₃ — MoO₃ (M=Li, Na, K) pseudobinary systems have been examined by differential thermal analysis and x-ray phase analysis. The phase diagrams have been derived, and the temperatures and compositions of the eutectics have been determined. The compounds have been examined by x-ray phase analysis, infrared spectroscopy, and diffuse reflection spectroscopy. The conductivity and optical properties of the compounds MMoO₂(PO₄) (M=Li, Na, K) have been determined. The coordinates of the liquidus lines have been used to calculate the activities of the components in the MPO₃ — MoO₃ systems. Those activities show large negative deviations from ideal solutions. This indicates strong interaction between particles in the liquid state. Translated from Poroshkovaya Metallurgiya, Nos. 3–4(412), pp. 33–40, March–April, 2000.     

Ca3La(BO3)3中Dy3+的光致发光

研究了Ca3La(BO3)3基质中Dy^3 的发射光谱和激发光谱。结果表明，强的激发峰值为351nm、367nm和386nm；Dy^3 的488nm和578nm发射的最佳浓度均为xDy=0．03；Dy^3 发射的黄光和蓝光强度比(用Y／B表示)随Dy^3 浓度的增加而逐渐增大；Dy^3 的^4F9/2→^6H15/2、^6H13/2跃迁发射的浓度猝灭机理均为电偶极-电偶极相互作用；同时还探讨了Ce^3 对Dy^3 发光的敏化作用。     

Dy^3＋在（LaO）3BO3和（GdO）3BO3中的光致发光

研究了Ｄｙ＾３＋在（ＬａＯ）３ＢＯ３和（ＧｄＯ）３ＢＯ３中的光致发光;探讨了基质晶体结构、稀土离子ＲＥ＾３＋的电荷半径比（Ｚ／ｒ）和Ｄｙ＾３＋含量对（Ｄｙ＾３＋）发光强度及发光颜色的影响;分析了（ＧｄＯ）３ＢＯ３中Ｂｉ＾３＋对Ｄｙ＾３＋发光的敏化作用及Ｄｙ＾３＋４Ｆ９／２→＾６Ｈ１３／２超灵敏跃迁发射的自身浓度猝灭机理。     

Ca3La3（BO3）5基质中Tb^3＋的光致发光

在２５４ｎｍ紫外光激发下，研究了Ｃａ３Ｌａ３（ＢＯ３）５基质中Ｔｂ＾３＋的激发光谱，发光光谱、发光寿命与Ｔｂ＾３＋的４ｆ＾８→４ｆ＾７５ｄ＾１允许迁的激发带位于２３０～２６０ｎｍ光谱区，故Ｔｂ＾３＋能很好地吸收激活能而发光，成为一种有发展前途的绿粉。Ｃｅ＾３＋可能与Ｔｂ＾３＋争夺激活能而猝灭Ｔｂ＾３＋的发光，一定量的Ｄｙ＾３＋能敏化Ｔｂ＾３＋的发光。     

Effects of Ce3＋ , Nd3＋ , Gd3＋, Tb3＋ and Lu3＋ ions on Formation of CaCO3

The effects of lanthanides at various concentrations on CaCO3 crystal growth were studied by X-ray diffraction (XRD), infrared spectra (IR), X-ray photoelectric energy spectra (XPS) and inductively coupled plasma mtms spectrometry (ICP-MS). It was found that the calcite, a stable form of CaCO3 in thermodynamics, is the predominant species. The research indicates that lanthanide ions (Ln3 ) can partly substitute the Ca2 in the lattice of CaCO3 crystals, and change the crystal characterization and direct the ordinal growth of CaCO3 crystals.     

Photoluminescence of Dy~(3 ) Ions in Ba_3La(BO_3)_3

Dy3 isanimportantactivator .Ithasbeenexten sivelyappliedinmanyluminescentmaterials .Inre centyears ,someresearchershavestudiedthespec trumcharacteristicsofluminescentmaterialsdopedDy3 [1～ 6 ] andhaveobtainedsomemeaningfulre sults .InordertodevelopnewfluorescentmaterialsanddiscussthephotoluminescentruleofDy3 inthecomplexborate ,thispaperstudiesthephotolumines centcharacteristicsofDy3 inBa3La(BO3) 3host ,anddiscussestheinfluenceofthecharge to radiusratio(z/r)ofrareearthionRE3 andthecon…     

3 200 m3高炉工程施工管理

论述了3 200 m3高炉工程的施工原则、施工管理、施工机械管理的具体内容.通过严格的管理,保证施工进度、工程质量和安全文明施工.     

3 200 m3高炉工程经营管理

经营管理是企业管理重要工作之一,经营管理水平的高低,直接影响企业和工程项目的经济效益.在3 200 m3高炉工程建设中围绕工程合同,搞好经营计划、预算的审查,避免工程项目款项超拨失控现象.     

H_3BO_3添加量对CaTiO_3∶Pr~(3+)余辉性能的影响

采用高温固相法合成CaTiO3∶Pr3+,并通过掺杂H3BO3改性。研究样品的发射光谱、发光亮度及余辉时间,探讨H3BO3添加量对CaTiO3∶Pr3+发光强度及余辉性能的影响。结果表明,所添加H3BO3的摩尔分数为15%时,CaTiO3∶Pr3+粉末具有最佳的余辉性能。     

Bi_3PbSr_3Ca_3Cu_4O_y超导体的颗粒超导性

本文对Bi_3PbSr_3Ca_3Cu_4O_y超导体进行了超导电性、磁阻、输运特性等的测量。并利用结构分析等方法,对超导体的颗粒超导性进行了研究。试验观察到了负磁阻效应、回滞和热激活行为,以及颗粒间晶界对输运特性的影响。并对以上结果进行了较详细的分析。     

Luminescence properties of Tm^3＋/Yb^3＋, Er^3＋/Yb^3＋ and Ho^3＋/Yb^3＋ activated calcium tungstate

CaWO4 phosphor activated by the Tm3+/Yb3+,Er3+/Yb3+ and Ho3+/Yb3+ ions were synthesized by a traditional high-temperature solid-state method.The crystal structures and morphologies of the products were characterized by X-ray powders diffraction method(XRD) ,infrared spectra(FT-IR) and scanning electron microscopy(SEM) .The samples were found to show up-conversion luminescence properties.CaWO4 doped with Tm3+/Yb3+ showed blue luminescence characteristic of Tm(III) ion in the range of 460-485 nm,corresponding to the 1G4→3H6 electronic transition.CaWO4 doped with Er3+/Yb3+ showed strong green luminescence at 510-565 nm(2H11/2,4S3/2→4I15/2) and weak red luminescence at 640-685 nm(4F9/2→4I15/2) of Er(III) ion.CaWO4 doped with Ho3+/Yb3+ phosphor emitted green luminescence at 525-560 nm(5S2,5F4→5I8) and red luminescence at 630-670 nm(5F5→5I8) and at 730-770 nm(5S2,5F4→5I7) ,which is the characteristic of Ho(III) ion.     

Eu^3＋在（GdO）3BO3中的发光特性

研究了紫外光（ＵＶ）和阴极射线（ＣＲ）激发下（ＧｄＯ）＿３ＢＯ＿３：Ｅｕ的发光特性及其光谱随组成和结构变化的规律。在这两种激发条件下，（ＧｄＯ）＿３ＰＯ＿３中的Ｅｕ￣（３＋）均能发出明亮的红色荧光。ＣＲ激发下，在加速电压１０～２０ｋＶ、电流密度１～５μＡ／ｃｍ￣２内，Ｅｕ￣（３＋）的发光亮度与电压或电流密度之间均呈良好的线性关系，并具有耐电子束轰击的能力。根据３９５ｎｍＵＶ激发下（Ｇｄ＿（１－ｘ）ＥｕｘＯ）＿３ＢＯ＿３体系中Ｅｕ￣（３＋）的５Ｄ＿１→￣７Ｆ＿１跃迁（５３５ｎｍ）及￣５Ｄ＿ｏ→￣７Ｆ＿２跃迁（６１１ｎｍ）发射强度与Ｅｕ￣（３＋）浓度的关系，证明其浓度猝灭机理分别为电偶极－电偶极相互作用和交换作用。     

3 200 m3高炉工程桩基工程施工

通过解决、处理天钢二期工程桩基施工中遇到的实际问题,总结了桩基施工中常见问题处理方法及预防措施.     

3 200 m3高炉工程质量控制管理

论述了3 200 m3高炉工程质量控制要点、施工质量控制措施和管理办法.建立健全了质量保证体系,强化职工质量意识.通过加强技术、质量管理,使工程质量处于受控状态.施工过程中采用新工艺、新技术,实现了工程创优规划的预期效果.     

3 200 m3高炉工程物资供应管理

介绍了3 200 m3高炉工程建设中的材料供应、物资采购和设备供应等管理制度及执行情况.保证了材料供应优质及时,设备能按安装进度组织到货,使工程顺利进行.     

3 200 m3高炉工程施工技术管理

论述了3 200 m3高炉工程从施工组织设计编制、方案确定、图纸审核至交(竣)工资料整理等各环节的施工技术管理办法及实施情况.总结了成绩,提出了应注意的问题.     

3 200 m3高炉工程安全管理

论述了大型综合项目安全管理内容、要求和办法.运用统计分析的方法,找出安全隐患控制重点,进行检查、控制,消除安全隐患,防止安全事故发生,为施工创造良好的安全环境.