Contribution of different sources to the pollution of wet weather flows in combined sewers

Experiments performed on "Marais" catchment, in central Paris, aimed to follow up the quality of wet weather flows from the entry to the exit of a combined sewer network. SS, VSS, COD, BOD5, Cd, Cu, Pb, Zn concentrations were measured for an important number of rain events in roof, yard, street runoff, as well as in dry and wet weather flows at the catchment outlet. Mass entry-exit totals, at the scale of the catchment, were calculated over 31 rain events in order to evaluate the contribution of different types of runoff, of sanitary sewage and of sewer sediments to the total wet weather pollutant loads at the catchment outlet. The erosion of in-sewer pollutant stocks was found to be the main source of particles and of organic matter in wet weather flows, whereas heavy metal loads mainly originated from roof runoff, due to the corrosion of metallic roofs. Particles eroded inside the sewer during rain events were found to be quite different from the particles constituting the main part of sewer sediments: they are organic and biodegradable, with rather important settling velocities and seem to accumulate during dry weather periods. A change of the chemical form of heavy metals was noticed during the transport in the sewer and it is suspected that a fraction of the dissolved metals from the runoff is adsorbed on sewer sediments.     

合流制溢流调蓄处理工艺效果评估及优化对策

针对初期雨水及合流制溢流水质和水量波动大而引起的调蓄工程处理能力不足、运行能耗高及难以有效收集高负荷合流制溢流污水等问题,通过对不同时期进入调蓄工程的合流制溢流水质和水量特征的分析,结合调蓄工程处理工艺的沿程水质分析,考察了"微砂高效沉淀池+接触氧化池+D型滤池"工艺对合流制溢流的实际处理效果。结果表明,初期雨水及合流制溢流均呈水质和水量波动大、高氨氮、低COD的特征,氨氮是调蓄处理工艺出水水质达标的关键指标;同时,生化处理单元进水COD浓度低的特征不利于接触氧化池的生物挂膜,降低了工艺的实际处理能力。因此建议:(1)在接触氧化池后设置混凝加药装置,以保证出水SS和TP达标排放;(2)接触氧化池采用多点进水方式,并预留碳源投加装置;(3)增加精确曝气控制系统,实现节能降耗。     

A waste characterisation procedure for ADM1 implementation based on degradation kinetics

In this study, a procedure accounting for degradation kinetics was developed to split the total COD of a substrate into each input state variable required for Anaerobic Digestion Model n°1. The procedure is based on the combination of batch experimental degradation tests (“anaerobic respirometry”) and numerical interpretation of the results obtained (optimisation of the ADM1 input state variable set). The effects of the main operating parameters, such as the substrate to inoculum ratio in batch experiments and the origin of the inoculum, were investigated. Combined with biochemical fractionation of the total COD of substrates, this method enabled determination of an ADM1-consistent input state variable set for each substrate with affordable identifiability. The substrate to inoculum ratio in the batch experiments and the origin of the inoculum influenced input state variables. However, based on results modelled for a CSTR fed with the substrate concerned, these effects were not significant. Indeed, if the optimal ranges of these operational parameters are respected, uncertainty in COD fractionation is mainly limited to temporal variability of the properties of the substrates. As the method is based on kinetics and is easy to implement for a wide range of substrates, it is a very promising way to numerically predict the effect of design parameters on the efficiency of an anaerobic CSTR. This method thus promotes the use of modelling for the design and optimisation of anaerobic processes.     

Biodegradability of organic matter associated with sewer sediments during first flush

The high pollution load in wastewater at the beginning of a rain event is commonly known to originate from the erosion of sewer sediments due to the increased flow rate under storm weather conditions. It is essential to characterize the biodegradability of organic matter during a storm event in order to quantify the effect it can have further downstream to the receiving water via discharges from Combined Sewer Overflow (CSO). The approach is to characterize the pollutograph during first flush. The pollutograph shows the variation in COD and TSS during a first flush event. These parameters measure the quantity of organic matter present. However these parameters do not indicate detailed information on the biodegradability of the organic matter. Such detailed knowledge can be obtained by dividing the total COD into fractions with different microbial properties. To do so oxygen uptake rate (OUR) measurements on batches of wastewater have shown itself to be a versatile technique. Together with a conceptual understanding of the microbial transformation taking place, OUR measurements lead to the desired fractionation of the COD. OUR results indicated that the highest biodegradability is associated with the initial part of a storm event. The information on physical and biological processes in the sewer can be used to better manage sediment in sewers which can otherwise result in depletion of dissolved oxygen in receiving waters via discharges from CSOs.     

Treatability of organic fractions derived from secondary effluent by reverse osmosis membrane

Dissolved organic matters (DOMs) from two batches of secondary effluent collected from a local water reclamation plant were fractionated using column chromatographic method with non-ionic resins XAD-8, AG MP-50 and IRA-96. Seven isolated fractions were obtained from the fractionation study and these fractions were quantified using DOC, UV(254) and SUVA values. The fractionation study revealed that the secondary effluent samples comprised about 47.3-60.6% of hydrophobic and 39.4-52.7% of hydrophilic solutes. The treatability of each isolated fraction was investigated by subjecting each fraction to reverse osmosis (RO) treatment individually. It was noted that RO process could achieve high DOC rejections for acid and neutral fractions (ranging from 80% to 98% removal) probably due to the negative charge of RO membrane. The results obtained also indicated that hydrophobicity of DOMs is significant in determining treatability of organic species by RO process. The performance of RO in terms of DOC rejection of un-fractionated secondary effluent was also investigated to assess possible effects of interactions among organic fractions on their treatability by RO process. It was noted that DOC rejection associated with the un-fractionated secondary effluent was generally higher (ranging from 2% to 45%) than the corresponding rejection obtained from each individual fraction isolated from the secondary effluent. This finding suggested there is a beneficial interaction among the fractions that in turn has contributed towards a better overall DOC rejection performance by RO treatment.     

Wastewater quality and pollutant loads in combined sewers during dry weather periods

An observatory of urban pollutants was created in Paris in order to assess, at the urban catchment scale, the quality of sanitary sewage and pollutant loads during dry weather periods in the Paris combined sewer. Investigations were carried out for six urban catchments (varying from 42 to 2580 ha) focusing on a wide range of parameters, including: suspended solids (SS), chemical and biochemical oxygen demand (COD and BOD₅), total organic carbon (TOC), total Kjeldahl nitrogen (TKN), heavy metals (Cd, Cu, Pb, Zn), and aliphatic and polycyclic aromatic hydrocarbons (AHs and PAHs). Despite the marginal intra-site variability of some pollutants, which serves to reflect the impact of point sources, this work attests to the spatial homogeneity, at the physical scales considered, of wastewater quality and pollutant loads within the Paris combined sewer network. These results imply that similar production and transfer processes are occurring within sewers during dry weather periods and strongly suggest that data obtained on one specific catchment could be extrapolated to smaller or larger catchments that display quite similar land use and sewer characteristics.     

COD fractionation of tannery wastewaters--particle size distribution, biodegradability and modeling

This study aims to establish the scientific link between particle size distribution (PSD) and biodegradability of different COD fractions of tannery wastewater, by means of sequential filtration/ultrafiltration, respirometric analysis and model evaluation. PSD profiles were determined in physical segregation experiments, using eight membrane discs, each with different pore sizes between 2 and 1600 nm. Biodegradability-related COD fractionation was determined at each size interval by model simulation and calibration of the corresponding oxygen uptake rate (OUR) profiles. Activated Sludge Model No. 3 (ASM3), modified for direct growth on hydrolysis products, was adopted for evaluation. PSD analyses defined a COD fingerprint with two significant portions at the two ends of size distribution, with 60% of the total COD at the particulate range, 25% at the soluble range and the remaining 15% well distributed among the colloidal range. Comparative evaluation of the sequence of OUR profiles yielded values of applicable model coefficients. It also enabled the assessment of size distribution for each major COD fraction, as an original tool for better interpretation of specific biodegradation characteristics of the selected tannery wastewater. Results also revealed a very slowly biodegradable/residual particulate COD component with a significant inhibitory effect. Model-based evaluation of the OUR profiles enabled quantifying the impact of inhibition in terms of changes in rate coefficients for growth, hydrolysis of soluble COD and endogenous decay.     

Production and transport of urban wet weather pollution in combined sewer systems: the “Marais” experimental urban catchment in Paris

An experimental catchment area was set up in the centre of Paris (France) so as to follow up the quality of wet weather flows from the entry to the exit of a combined sewer network. The distinctive characteristic of this site is its location in a town centre and the extent of the equipment used to monitor the water pollution over the whole length of its course through the catchment area. The results obtained show a change in quality between the runoff entering the sewer network and the combined storm water flow at the sewer's outlet, which cannot be explained only by the mixture with domestic wastewater. In particular, an increase was observed in the concentrations of suspended solids (SS), VSS, COD, BOD and Cu, in the proportion of pollutants linked to particles and in the characteristics of the particles. A calculation of the total masses going in and out of the sewer network during a rainfall event shows that the erosion of in-sewer pollution stocks is the main source of particles and of organic matter in wet weather flows, whereas heavy metals loads originated from roof runoff, due to the corrosion of metallic roofs. Particles eroded from the sewer sediments during rain events were found to be quite different from the particles of type A deposits and organic biofilms. Nevertheless, they have mean organic and metallic loads that are of the same order of magnitude as the particles of the organic layer at water sediment interface. A change in the chemical form of heavy metals was noticed during the transport in the sewer and it is suspected that a fraction of the dissolved metals from the runoff is adsorbed on sewer sediments.     

基于SWMM模型的截流倍数环境效应分析

由于对改造建设的重视程度、时序安排、经济条件、改造难度等许多主观和客观因素的限制,许多城市老城区的合流制排水系统保留至今。采用SWMM水力水质模型,对城市合流区的污染物削减情况进行模拟评价,以期为合流制排水系统的截流倍数取值及建设方向提供参考。结果表明,当截流倍数n≥2时,合流制排水系统即可达到分流制排水系统的污染物截流效果;但只有当截流倍数n≥5时,合流制排水系统才能达到分流制排水系统的污染物削减效果。城市合流区需尽快进行合改分建设,或加大末端处理设施的建设。     

Natural attenuation and characterization of contaminants composition in landfill leachate under different disposing ages

Chemical Oxygen Demand (COD) composition in landfill leachate would vary as the disposal time extended. Leachates with different ages were collected from Laogang Refuse Landfill of Shanghai, the largest landfill in China with a placement scale of 7600 t refuse per day. To characterize COD composition in leachate, samples were size-fractioned into suspended fractions (> 0.45 μm), colloid fraction (0.45 μm < fraction < 1 K Da MW) and dissolved fractions (< 1 KDa MW) based on the molecular weight distribution. The fractions < 0.45 μm (including colloid fraction and dissolved fractions) in leachate were further divided into 6 fractions, i.e. hydrophobic bases (Ho-base), hydrophobic acids (Ho-acid), hydrophobic neutral (Ho-neutral), hydrophilic bases (Hi-base), hydrophilic acids (Hi-acid) and hydrophilic neutral (Hi-neutral). It was found that the ratio of TOC/TC in leachate decreased over time, indicating that the percentage of organic matters in leachate decreased as the disposal time extended. It was also observed that the hydrophobic fraction accounted to about 50% of the total matters presented in the fraction < 0.45 μm of all leachate samples. The main components in < 0.45  μm fraction were the Ho-acid, Hi-acid and Hi-base fractions. The percentage of Ho-acid in leachate decreased from 60.8% (2 a) to 43.2% (12 a). In addition, leachate with different ages was categorized into 3 phases according to the results of Principle component analysis (PCA). TOC/COD ranges of leachate in periods I, II and III were 40-54.6%, 16.9-41.3% and 10-38.9%, respectively, indicating that the COD contribution of non-carbon reduction substances increased over time in leachate. Hence, the corresponding landfill leachate treatment process should be modified according to the leachate characterization. The results obtained in this study might provide the important information for modeling, design, and operation of landfill leachate treatment systems.     

Evaluation of biodegradability of NOM after ozonation

The major purpose of this study was to develop a simple procedure to describe the kinetics of biodegradation of natural organic matter (NOM) in drinking water and to use this procedure to evaluate changes in the concentration of biodegradable organic matter during ozonation and biotreatment. The proposed approach quantitatively describes the formation and removal of rapidly and slowly biodegradable fractions of NOM. This study showed that, depending on source water, ozonation of NOM may result in either minimal formation of biodegradable organic carbon (BDOC), or the formation of predominantly rapidly biodegradable NOM, or in the formation of both rapidly and slowly biodegradable NOM. The kinetic data obtained in this study suggest that while conventional biofiltration processes are capable of removing the rapidly biodegradable fraction, slowly biodegradable organic matter would remain in the filter effluent and may cause bacterial regrowth in the distribution system. An addition of a small amount of easily biodegradable carbon ("stimulated" biodegradation) to ozonated water appears to be effective for the removal of slowly biodegradable organic matter.     

Modelling of organic matter degradation in constructed wetlands for treatment of combined sewer overflow

Subsurface vertical flow constructed wetlands (CWs) have been found to be a useful system to treat combined sewer overflow (CSO). The study presented uses numerical simulation to increase the understanding of the fundamental processes of COD degradation in CWs for CSO treatment. The multi-component reactive transport module CW2D was used for the simulation study. The simulation results showed that the measured behaviour of the system can only be modelled when COD adsorption is considered as additional process. A new parameter set for CW2D for modelling CSO treatment is presented. A range of values for COD adsorption parameters, COD fractionation and bacteria concentrations were estimated by an identifiability analysis. For the simulation a step wise approach was developed. On the one hand a lysimeter study was used for calibration and validation, and on the other hand field and lab-scale experiments were used for validation. Single-event simulations as well as long-term simulations were carried out. For the single-event simulations (lysimeter and field studies) a good match between measured and simulated data could be achieved. However, the long-term simulations showed that there is a need for further investigations mainly due to the uncertainties during long dry periods between the loadings.     

Optimal planning of decentralised storage tanks to reduce combined sewer overflow spills using particle swarm optimisation

The present study suggests an optimised method for planning multiple decentralised storage tanks which are designed to reduce combined sewer overflow (CSO) spills. Particle swarm optimisation (PSO) was applied for the optimal planning of the storage tanks in terms of location distribution and sizing. The framework for the storage optimal planning suggested in this study includes developing a simplified mathematical model that is, along with the PSO algorithm, for optimisation. In order to reduce the computational burden of PSO’s inherent iterative solution-searching process a simplified mathematical model was developed to simulate the complex hydraulic flows of a sewer network. Then, the optimisation model with the PSO algorithm was connected interactively with the mathematical model. A case study network was simulated to analyse its application in the planning of distributed CSO storage tanks, and the best available scenarios were suggested.     

A new concept for the fractionation of DOM as a basis for its combined chemical and biological characterization

To overcome the problem of non-specific interactions during the preparative fractionation of dissolved organic matter (DOM) for its combined chemical and biological characterization, the concept of standardized fractions (SFs) was developed. The concept is based on the calibration of the fractionation systems with suitable standards for the experimental definition of SFs, and the subsequent preparative fractionation of DOM samples according to the predefined SFs. Undesired non-specific interactions can thus be minimized experimentally. It was applied to the fractionation methods size exclusion chromatography (SEC) and multistage ultrafiltration (mst-UF). A brownwater sample and an effluent from a sewage treatment plant were fractionated. The two methods performed rather differently which was evidenced both by the polydispersity of the resulting fractions as well as sum parameter fractionation patterns. Consequently, the interpretation of data obtained from the chemical-physical as well as biological analysis must always consider the limitations and particularities of the fractionation method employed.     

Multiobjective optimisation algorithm for sewer network rehabilitation

Understanding of deterioration mechanisms in sewers helps asset managers in developing prediction models for estimating whether or not sewer collapse is likely. Effective utilisation of deterioration prediction models along with the development and use of life cycle maintenance cost analysis contribute to reducing operation and maintenance costs in sewer systems. This article presents a model for life-cycle maintenance planning of deteriorating sewer network as a multi-objective optimisation problem that treats the sewer network condition and service life as well as life-cycle maintenance cost (LCMC) as separate objective functions. The developed model utilises Markov chain model for the prediction of the deterioration of the network. A multi-objective genetic algorithm is used to automatically locate an appropriate maintenance scenario that exhibits an optimised tradeoff among conflicting objectives. Monte Carlo simulation is used to account for LCMC uncertainties. The optimisation algorithm provides an improved opportunity for asset managers to actively select near-optimum maintenance scenario that balances life-cycle maintenance cost, condition and service life of deteriorating sewer network. A case study is used to demonstrate the practical features of developed methodology.     

On hydraulic and pollution effects of converting combined sewer catchments to separate sewer catchments

The overall objective of this paper is to contribute to the standing debate concerning the advantages of separate sewer systems compared to traditional combined sewer systems. By a case study this investigation reveals that transformation of part of a town from being serviced with combined sewer systems to become serviced with separate sewer systems decreases the volumes of storm water and pollutants diverted to the waste water treatment plant and discharged as combined sewer overflow. This happens at the expense of an increase in volumes of storm water and pollutant loads diverted to local receiving waters when detention ponds are not built-in the new separate sewer systems. It is concluded that consequences can be fatal for receiving waters, if no retention of pollutants is integrated into the system.     

Aerobic transformations of organic matters in sewer wastewater,a case study of Milan,Italy

Today, we know that not only the sewers carry urban wastewater, but also act as chemical and biological reactors, in which both organic and inorganic substances undergo significant transformations. This article describes a study on the western part of the sewer system of the city of Milan. The hydraulic model of the sewer system was coupled with the chemical and dynamic biological model to assess the extent of the degradation of organic matter in the network. The hydraulic and biological models were calibrated with real data obtained at the entrance of the wastewater treatment plant (WWTP) ‘Milan South’ and assuming standard values of daily per capita loads of COD and BOD₅.     

Biological treatability of dairy wastewaters

Biological treatability of an integrated dairy plant wastewater containing a small fraction of whey-washwaters mixture has been experimentally investigated. Emphasis has been placed on the assessment of the initially inert fraction, S₁ and soluble residual microbial products, S_p. Parallel batch experiments have been conducted to determine the kinetic and stoichiometric coefficients of the degradable COD. The results have shown that the wastewater tested had practically no initially inert fraction, but generated residual microbial products amounting to 6–7% of the initial degradable COD. The results obtained have been fed into a set of equations describing the steady state operation of an activated sludge system with sludge recycle and a relationship indicating the variation of the total effluent COD with the sludge age has been defined for the wastewater tested. It is noted that effluent COD cannot be biologically reduced below 85 mg l⁻¹, regardless of the sludge age, due to generation of residual fractions.     

Characterization of the colloidal organic matter from the Amazonian basin by asymmetrical flow field-flow fractionation and size exclusion chromatography

Colloidal organic matter (COM) collected in small and large watercourse tributaries of the Negro River (Brazil) were fractionated and characterized by an asymmetrical flow field-flow fractionation (AFlFFF) coupled to UV and seven angle laser light scattering (LS) detectors, and by size exclusion chromatography (SEC) coupled with a UV detection. Number and weight average molar masses, weight average gyration radiuses R_Gw and polydispersity indexes were obtained for each sample in two separate runs under conditions optimized for lower and larger size fractions. The results demonstrate the existence of a decrease of size of the colloidal matter when passing from first order streams to higher order rivers. No significant changes were found in size distributions of samples collected during the low and high flow stages at the same site. The influence of selected pre-treatments such as filtration and reverse osmosis pre-concentration on the size and molar mass distributions was also studied.     

Characterization of isolated fractions of dissolved organic matter from natural waters and a wastewater effluent

Dissolved organic matter (DOM) was concentrated from natural waters and the effluent of a wastewater treatment plant using a portable reverse osmosis (RO) system. The humic acid (HA), fulvic acid (FA) and hydrophilic (HyI) fractions were isolated and purified by the XAD-8 resin combined with the cation exchange resin method. The FA fractions predominated in natural waters and accounted for 54-68% of the total amount of dissolved organic carbon (DOC), whereas the HA and HyI fractions constituted, respectively, 13-29 and 9-30% of the total DOC. The effluent of wastewater was almost devoid of HA and the HyI fraction exceeded FA. The elemental compositions of HA and FA were in the ranges typical for natural humic materials, but the HyI fractions did not exhibit humic character. 1H NMR spectra revealed that the HyI fractions were almost devoid of aromatic protons and the aliphatic region featured more sharp signals than HA and FA fractions, indicating that HyI fractions were consisted of more simple compounds and less complex mixtures. The aliphatic functional groups in these fractions of DOM samples followed the order HA < FA HyI. The rate of Cu complexation with the HyI fraction was faster than the rate with the HA or FA fraction of the Suwannee River DOM, implying that copper reacted with relatively weak ligands faster than with strong ligands.