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1.
A solution‐processed polymer tandem cell fabricated by stacking two single cells in series is demonstrated. The two bulk‐heterojunction subcells have complementary absorption maxima at λmax ~ 850 nm and λmax ~ 550 nm, respectively. A composite middle electrode is applied that serves both as a charge‐recombination center and as a protecting layer for the first cell during spin‐coating of the second cell. The subcells are electronically coupled in series, which leads to a high open‐circuit voltage of 1.4 V, equal to the sum of each subcell. The layer thickness of the first (bottom) cell is tuned to maximize the optical absorption of the second (top) cell. The performance of the tandem cell is presently limited by the relatively low photocurrent generation in the small‐bandgap polymer of the top cell. The combination of our tandem architecture with more efficient small‐bandgap materials will enable the realization of highly efficient organic solar cells in the near future.  相似文献   

2.
Tandem polymer photovoltaic cells with the subcells having different absorption characteristics in series connection are widely investigated to enhance absorption coverage over the solar spectrum. Herein, we demonstrate efficient tandem polymer photovoltaic cells with the two stacked subcells comprising different band-gap conjugated polymer and fullerene derivative bulk heterojunction in parallel connection. A semitransparent metal layer combined with inorganic semiconductor compounds is utilized as the intermediate electrode of the two stacked subcells to create the required built-in potential for collecting photo-generated charges. The short-circuit current of the stacked cell is the sum of the subcells and the open-circuit voltage is similar to the subcells.  相似文献   

3.
One strategy to harvest wide spectral solar energy is to stack different bandgap materials together in a tandem solar cell. Here, it is demonstrated that CVD grown graphene film can be employed as intermediate layer (IML) in tandem solar cells. Using MoO3‐modified graphene IML, a high open circuit voltage (Voc) of 1 V and a high short‐circuit current density (Jsc) of 11.6 mA cm‐2 could be obtained in series and parallel connection, respectively, in contrast to a Voc of 0.58 V and Jsc of 7.6 mA cm‐2 in single PV cell. The value of Voc (Jsc) in the tandem cell is very close to the sum of Voc (Jsc) attained from two single subcells in series (parallel), which confirms good ohmic contact at the photoactive layer/MoO3‐modified graphene interface. Work function engineering of the graphene IML with metal oxide is essential to ensure good charge collection from both subcells.  相似文献   

4.
A power conversion efficiency of up to 8.91% is obtained for a solution‐processed polymer tandem solar cells based on a large‐bandgap polymer, poly(4,4‐dioctyldithieno(3,2‐b:2′,3′‐d)silole)‐2,6‐diyl‐alt‐(2,1,3‐benzothiadiazole)‐4,7‐diyl) with a polymeric interconnecting layer to electrically connect the front and rear subcells, demonstrating that proper device and interface engineering are can improve the performance of polymer tandem solar cells.  相似文献   

5.
Tandem solar cells (TSCs) comprising stacked narrow‐bandgap and wide‐bandgap subcells are regarded as the most promising approach to break the Shockley–Queisser limit of single‐junction solar cells. As the game‐changer in the photovoltaic community, organic–inorganic hybrid perovskites became the front‐runner candidate for mating with other efficient photovoltaic technologies in the tandem configuration for higher power conversion efficiency, by virtue of their tunable and complementary bandgaps, excellent photoelectric properties, and solution processability. In this review, a perspective that critically dilates the progress of perovskite material selection and device design for perovskite‐based TSCs, including perovskite/silicon, perovskite/copper indium gallium selenide, perovskite/perovskite, perovskite/CdTe, and perovskite/GaAs are presented. Besides, all‐inorganic perovskite CsPbI3 with high thermal stability is proposed as the top subcell in TSCs due to its suitable bandgap of ≈1.73 eV and rapidly increasing efficiency. To minimize the optical and electrical losses for high‐efficiency TSCs, the optimization of transparent electrodes, recombination layers, and the current‐matching principles are highlighted. Through big data analysis, wide‐bandgap perovskite solar cells with high open‐circuit voltage (Voc) are in dire need in further study. In the end, opportunities and challenges to realize the commercialization of TSCs, including long‐term stability, area upscaling, and mitigation of toxicity, are also envisioned.  相似文献   

6.
This paper re‐examines the impact of atmospheric absorption bands on series‐connected multijunction cell design, motivated by the numerous local efficiency maxima that appear as the number of junctions is increased. Some of the local maxima are related to the bottom subcell bandgap and are already well understood: As the bottom subcell bandgap is varied, a local efficiency maximum is produced wherever the bottom cell bandgap crosses an atmospheric absorption band. The optimal cell designs at these local maxima are generally current matched, such that all subcells have nearly the same short‐circuit current. Here, we systematically describe additional local maxima that occur wherever an upper subcell bandgap encounters an atmospheric absorption band. These local maxima are not current matched and become more prevalent as the number of junctions increases, complicating the solution space for five‐junction and six‐junction designs. A systematic framework for describing this complexity is developed, and implications for numerical convergence are discussed. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

7.
All-polymer solar cells (all-PSCs) possess distinguished advantages of excellent morphology stability, thermal stability, and mechanical flexibility. Tandem solar cells, by stacking two sub-cells, can absorb more photons in a wider wavelength range and can reduce thermal losses. However, limitation of polymer acceptors with suitable bandgaps hinders the development of tandem all-PSCs. Herein, highly efficient tandem all-PSCs are fabricated by employing two polymerized small molecular acceptors (PSMAs) of wide bandgap PIDT (1.66 eV) in the front cell and narrow bandgap PY-IT (1.4 eV) in the rear cell. The two sub-cells with the polymer donors of PM7 in front cell and PM6 in rear cell show high open circuit voltage (Voc) of 1.10 V for the front cell and 0.94 V for the rear cell. By rational device optimizations, the best power conversion efficiency of 17.87% is achieved for the tandem all-PSCs with high Voc of 2.00 V. 17.87% is one of the highest efficiency for the all-PSCs, and 2.00 V is one of the highest Voc for all the tandem organic solar cells. Moreover, the tandem all-PSCs show excellent thermal and light-soaking stability compared with their small-molecule counterparts. The results provide insight to the potential of bandgap tuning in PSMAs, and indicate that the tandem architecture is an effective strategy to boost performance of the all-PSCs.  相似文献   

8.
The syntheses are reported of the title polymeric alkoxyPBD derivative 5 and the dipyridyl analogue 12 using Suzuki coupling reactions of 1,4‐dialkoxybenzene‐2,5‐diboronic acid with 2,5‐bis(4‐bromophenyl)‐1,3,5‐oxadiazole, and its dipyridyl analogue, respectively. Thermal gravimetric analysis shows that polymers 5 and 12 are stable up to 370 °C and 334 °C, respectively. Films of polymer 5 spun from chloroform solution show an absorption at λmax = 367 nm, and a weaker band at 312 nm, and strong blue photoluminescence at λmax = 444 nm. The photoluminescence quantum yield (PLQY) was found to be 27 ± 3 %. For polymer 12 , the absorption spectra reveal bands of equal intensity at λmax = 374 and 312 nm, with PL at λmax = 475 nm. Device studies using polymer 12 were hampered by its instability under illumination and/or electrical excitation. Polymer 5 is stable under these conditions and acts as an efficient electron‐transporting/hole‐blocking layer. For devices of configuration ITO/PEDOT/MEH‐PPV/polymer 5 /Al an external quantum efficiency of 0.26 % and brightness of 800 cd/m2 was readily achieved: orange emission was observed, identical to the MEH‐PPV electroluminescence.  相似文献   

9.
It is an effective way to enhance device performance of polymer solar cells (PSCs) by using a tandem structure that combines two or more solar cells. For tandem PSCs, the buffer layer plays an important role in determining the device performance. The most commonly used buffer layers, such as PEDOT:PSS, TiOx, and ZnO, need thermal treatments that are not beneficial for reducing the fabrication complexity and cost of tandem PSCs. It is necessary to develop tandem PSCs fabricated by a thermal-treatment-free process. In this paper, we report high performance thermal-treatment-free tandem PSCs by developing PFN as buffer layers for both subcells. A power conversion efficiency (PCE) of 10.50% and a high fill factor of 72.44% were achieved by stacking two identical PTB7:PC71BM subcells. When adopting a rear PTB7-Th:PC71BM subcell, the highest PCE of 10.79% was further obtained for the tandem devices. The thermal-treatment-free process is especially applicable to flexible devices, in which plastic substrates are usually used.  相似文献   

10.
To fabricate a high‐efficiency polycrystalline thin‐film tandem cell, the most critical work is to make a high‐efficiency top cell ( > 15%) with high bandgap (Eg = 1·5–1·8 eV) and high transmission (T > 70%) in the near‐infrared (NIR) wavelength region. The CdTe cell is one of the candidates for the top cell, because CdTe state‐of‐the‐art single‐junction devices with efficiencies of more than 16% are available, although its bandgap (1·48 eV) is slightly lower for a top cell in a current‐matched dual‐junction device. In this paper, we focus on the development of a: (1) thin, low‐bandgap CuxTe transparent back‐contact; and (2) modified CdTe device structure, including three novel materials: cadmium stannate transparent conducting oxide (TCO), ZnSnOx buffer layer, and nanocrystalline CdS:O window layer developed at NREL, as well as the high‐quality CdTe film, to improve transmission in the NIR region while maintaining high device efficiency. We have achieved an NREL‐confirmed 13·9%‐efficient CdTe transparent solar cell with an infrared transmission of ∼50% and a CdTe/CIS polycrystalline mechanically stacked thin‐film tandem cell with an NREL‐confirmed efficiency of 15·3%. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

11.
We present a merocyanine:C60/zinc phthalocyanine:C60 tandem solar cell, comprising two complementary absorbing bulk heterojunction subcells connected in series. High-efficiency devices were realized in a rather simple tandem setup, consisting of only three organic layers that were successively deposited in an ultrahigh-vacuum chamber. The optimized tandem solar cell features an efficiency of 4.5%, demonstrating a performance improvement by ca. 50% compared to the individual optimized single-junction solar cells. The experimental data are in excellent agreement with optical simulations, assuming an internal quantum efficiency near unity in the optimized tandem device.  相似文献   

12.
Mixed lead–tin triiodide perovskites are promising absorber materials for low bandgap bottom cells in all‐perovskite tandem photovoltaic devices. Key structural and electronic properties of the FAPb1−xSnxI3 perovskite are presented here as a function of lead:tin content across the alloy series. Temperature‐dependent photoluminescence and optical absorption measurements are used to identify changes in the bandgap and phase transition temperature. The large bandgap bowing parameter, a crucial element for the attainment of low bandgaps in this system, is shown to depend on the structural phase, reaching a value of 0.84 eV in the low‐temperature phase and 0.73 eV at room temperature. The parabolic nature of the bowing at all temperatures is compatible with a mechanism arising from bond bending to accommodate the random placement of unevenly sized lead and tin ions. Charge‐carrier recombination dynamics are shown to fall into two regimes. Tin‐rich compositions exhibit fast, monoexponential recombination that is almost temperature‐independent, in accordance with high levels of electrical doping. Lead‐rich compositions show slower, stretched‐exponential charge‐carrier recombination that is strongly temperature‐dependent, in accordance with a multiphonon assisted process. These results highlight the importance of structure and composition for control of bandgap bowing and charge‐carrier recombination mechanisms in low bandgap absorbers for all‐perovskite tandem solar cells.  相似文献   

13.
Tandem configurations, in which two cells are stacked and connected in series, offer a viable approach to further increase the power conversion efficiency (PCE) of organic solar cells. To enable the future rational design of new materials it is important to accurately assess the contributions of individual subcells. Such accurate measurement of the external quantum efficiency (EQE) of the subcells of two‐terminal organic or polymer tandem solar cells poses specific challenges, caused by two characteristics of these cells, i.e. a sub‐linear light intensity dependence of the current and a field‐assisted charge collection. These properties necessitate that EQE experiments are carried out under representative illumination conditions and electrical bias to maintain short‐circuit conditions for the addressed subcell. We describe a method to determine the magnitudes of the bias illumination and bias voltage during EQE measurements, based on the behavior of single junction cells and optical modeling. The short‐circuit current densities of the subcells obtained by convolution of the EQE with the AM1.5G solar spectrum are consistent with those obtained from optical modeling and correctly predict the current density–voltage characteristics of the tandem cell under AM1.5G conditions.  相似文献   

14.
The emerging field of stacked layers (double‐ and even multi‐layers) in organic photovoltaic cells is reviewed. Owing to the limited absorption width of organic molecules and polymers, only a small fraction of the solar flux can be harvested by a single‐layer bulk heterojunction photovoltaic cell. Furthermore, the low charge‐carrier mobilities of most organic materials limit the thickness of the active layer. Consequently, only part of the intensity of the incident light at the absorption maximum is absorbed. A tandem or multi‐junction solar cell, consisting of multiple layers each with their specific absorption maximum and width, can overcome these limitations and can cover a larger part of the solar flux. In addition, tandem or multi‐junction solar cells offer the distinct advantage that photon energy is used more efficiently, because the voltage at which charges are collected in each sub‐cell is closer to the energy of the photons absorbed in that cell. Recent developments in both small‐molecule and polymeric photovoltaic cells are discussed, and examples of photovoltaic architectures, geometries, and materials combinations that result in tandem and multi‐junction solar cells are presented.  相似文献   

15.
Hybrid dye‐sensitized solar cells are typically composed of mesoporous titania (TiO2), light‐harvesting dyes, and organic molecular hole‐transporters. Correctly matching the electronic properties of the materials is critical to ensure efficient device operation. In this study, TiO2 is synthesized in a well‐defined morphological confinement that arises from the self‐assembly of a diblock copolymer—poly(isoprene‐b‐ethylene oxide) (PI‐b‐PEO). The crystallization environment, tuned by the inorganic (TiO2 mass) to organic (polymer) ratio, is shown to be a decisive factor in determining the distribution of sub‐bandgap electronic states and the associated electronic function in solid‐state dye‐sensitized solar cells. Interestingly, the tuning of the sub‐bandgap states does not appear to strongly influence the charge transport and recombination in the devices. However, increasing the depth and breadth of the density of sub‐bandgap states correlates well with an increase in photocurrent generation, suggesting that a high density of these sub‐bandgap states is critical for efficient photo‐induced electron transfer and charge separation.  相似文献   

16.
To further increase the efficiency of multijunction thin‐film silicon (TF‐Si) solar cells, it is crucial for the front electrode to have a good transparency and conduction, to provide efficient light trapping for each subcell, and to ensure a suitable morphology for the growth of high‐quality silicon layers. Here, we present the implementation of highly transparent modulated surface textured (MST) front electrodes as light‐trapping structures in multijunction TF‐Si solar cells. The MST substrates comprise a micro‐textured glass, a thin layer of hydrogenated indium oxide (IOH), and a sub‐micron nano‐textured ZnO layer grown by low‐pressure chemical vapor deposition (LPCVD ZnO). The bilayer IOH/LPCVD ZnO stack guarantees efficient light in‐coupling and light trapping for the top amorphous silicon (a‐Si:H) solar cell while minimizing the parasitic absorption losses. The crater‐shaped micro‐textured glass provides both efficient light trapping in the red and infrared wavelength range and a suitable morphology for the growth of high‐quality nanocrystalline silicon (nc‐Si:H) layers. Thanks to the efficient light trapping for the individual subcells and suitable morphology for the growth of high‐quality silicon layers, multijunction solar cells deposited on MST substrates have a higher efficiency than those on single‐textured state‐of‐the‐art LPCVD ZnO substrates. Efficiencies of 14.8% (initial) and 12.5% (stable) have been achieved for a‐Si:H/nc‐Si:H tandem solar cells with the MST front electrode, surpassing efficiencies obtained on state‐of‐the‐art LPCVD ZnO, thereby highlighting the high potential of MST front electrodes for high‐efficiency multijunction solar cells. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

17.
We developed an active inter-connecting layer (ICL) composed of SnCl2Pc/Al/F16CuPc/ZnPc to achieve an effective organic tandem solar cell consisting of complementary absorbing layers. This ICL provides a new function to improve the light response of the top cell to enhance current matching between bottom cell and top cell. Meanwhile, the ICL is highly transparent and has efficient charge collections to realize electric connection in series. Finally, in the tandem cell, the open-circuit voltage of 1.52 V is obtained that is the summation of the single cells (1.08 V and 0.46 V), and the power conversion efficiency of 3.21% under 100 mW/cm2 is achieved that is higher than those of the single cells.  相似文献   

18.
Triple‐junction solar cells from III–V compound semiconductors have thus far delivered the highest solar‐electric conversion efficiencies. Increasing the number of junctions generally offers the potential to reach even higher efficiencies, but material quality and the choice of bandgap energies turn out to be even more importance than the number of junctions. Several four‐junction solar cell architectures with optimum bandgap combination are found for lattice‐mismatched III–V semiconductors as high bandgap materials predominantly possess smaller lattice constant than low bandgap materials. Direct wafer bonding offers a new opportunity to combine such mismatched materials through a permanent, electrically conductive and optically transparent interface. In this work, a GaAs‐based top tandem solar cell structure was bonded to an InP‐based bottom tandem cell with a difference in lattice constant of 3.7%. The result is a GaInP/GaAs//GaInAsP/GaInAs four‐junction solar cell with a new record efficiency of 44.7% at 297‐times concentration of the AM1.5d (ASTM G173‐03) spectrum. This work demonstrates a successful pathway for reaching highest conversion efficiencies with III–V multi‐junction solar cells having four and in the future even more junctions. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

19.
Polymer solar cells have been fabricated from a recently synthesized low band‐gap alternating polyfluorene copolymer, APFO‐Green2, combined with [6,6]‐phenyl‐C61‐butyric acid methyl ester (PCBM) from organic solutions. External quantum efficiencies (EQEs) of the solar cells show an onset at 850 nm and a peak of > 10 % located at 650 nm, which corresponds to the extended absorption spectrum of the polymer. Photocurrent of 3.0 mA cm–2, photovoltage of 0.78 V, and power conversion efficiency of 0.9 % have been achieved in solar cells based on this new low‐bandgap polymer under the illumination of air mass 1.5 (AM 1.5) (1000 W m–2) from a solar simulator.  相似文献   

20.
Silicon based thin tandem solar cells were fabricated by plasma enhanced chemical vapor deposition (PECVD) in a 30 × 30 cm2 reactor. The layer thicknesses of the amorphous top cells and the microcrystalline bottom cells were significantly reduced compared to standard tandem cells that are optimized for high efficiency (typically with a total absorber layer thickness from 1.5 to 3 µm). The individual absorber layer thicknesses of the top and bottom cells were chosen so that the generated current densities are similar to each other. With such thin cells, having a total absorber layer thickness varying from 0.5 to 1.5 µm, initial efficiencies of 8.6–10.7% were achieved. The effects of thickness variations of both absorber layers on the device properties have been separately investigated. With the help of quantum efficiency (QE) measurements, we could demonstrate that by reducing the bottom cell thickness the top cell current density increased which is addressed to back‐reflected light. Due to a very thin a‐Si:H top cell, the thin tandem cells show a much lower degradation rate under continuous illumination at open circuit conditions compared to standard tandem and a‐Si:H single junction cells. We demonstrate that thin tandem cells of around 550 nm show better stabilized efficiencies than a‐Si:H and µc‐Si:H single junction cells of comparable thickness. The results show the high potential of thin a‐Si/µc‐Si tandem cells for cost‐effective photovoltaics. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

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