Predicting efficiency of solar powered hydrogen generation using photovoltaic-electrolysis devices

Hydrogen fuel for fuel cell vehicles can be produced by using solar electric energy from photovoltaic (PV) modules for the electrolysis of water without emitting carbon dioxide or requiring fossil fuels. In the past, this renewable means of hydrogen production has suffered from low efficiency (2–6%), which increased the area of the PV array required and therefore, the cost of generating hydrogen. A comprehensive mathematical model was developed that can predict the efficiency of a PV-electrolyzer combination based on operating parameters including voltage, current, temperature, and gas output pressure. This model has been used to design optimized PV-electrolyzer systems with maximum solar energy to hydrogen efficiency. In this research, the electrical efficiency of the PV-electrolysis system was increased by matching the maximum power output and voltage of the photovoltaics to the operating voltage of a proton exchange membrane (PEM) electrolyzer, and optimizing the effects of electrolyzer operating current, and temperature. The operating temperature of the PV modules was also an important factor studied in this research to increase efficiency. The optimized PV-electrolysis system increased the hydrogen generation efficiency to 12.4% for a solar powered PV-PEM electrolyzer that could supply enough hydrogen to operate a fuel cell vehicle.     

Optimized photovoltiac system for hydrogen production

Hydrogen, which can be produced by water electrolysis, can play an important role as an alternative to conventional fuels. It is regarded as a potential future energy carrier. Photovoltaic arrays can be used in supplying the water electrolysis systems by their energy requirements. The use of photovoltaic energy in such systems is very suitable where the solar hydrogen energy systems are considered one of the cleanest hydrogen production technologies, where the hydrogen is obtained from sunlight by directly connecting the photovoltaic arrays and the hydrogen generator. This paper presents a small PV power system for hydrogen production using the photovoltaic module connected to the hydrogen electrolyzer with and without maximum power point tracker. The experimental results developed good results for hydrogen production flow rates, in the case of using maximum power point tracker with respect to the directly connected electrolyzer to the photovoltaic modules.     

Optimization of Solar Hydrogen Systems Based on Hydrogen Production Cost

Hydrogen is regarded as a potential future energy carrier. It can be produced by the electrolysis of water with the required power supplied by a photovoltaic module. The hydrogen in this study was produced using a hydrogen generator with a solid polymer electrolyte. The required power was supplied by a photovoltaic module rated at 3.4 V, 27.45 A. The experimental system was designed and constructed so that the photovoltaic module was directly coupled to the hydrogen generator. The system characteristics: quantity of hydrogen produced, current/voltage output characteristics of the PV module, PV module and H₂ generator temperatures were measured and analyzed. A method to design a solar hydrogen energy system, providing the most cost effective hydrogen generation, was developed. In this method, the design point is chosen based on the irradiance during system operation under rated capacity. The data supplied by the experimental system clearly showed the importance of considering the ratio of photovoltaic module cost to hydrogen generator cost when designing an optimum solar hydrogen system.     

Hydrogen production by methanol aqueous electrolysis using photovoltaic energy: Algerian potential

Hydrogen is considered as the most promising energy carrier for providing a clean, reliable and sustainable energy system. It can be produced from a diverse array of potential feed stocks including water, fossil fuels and organic matter. Electrolysis is the best option for producing hydrogen very quickly and conveniently. Water electrolysis as a source of hydrogen production has recently gained much attention since it can produce high purity hydrogen and can be compatible with renewable energies. Besides the water electrolysis, aqueous methanol electrolysis has been reported in several studies. The aqueous methanol electrolysis proceeds at much lower voltage than that with the water electrolysis. As a result of the substantially lower operating voltage, the energy efficiency for methanol electrolysis can be higher than that for water electrolysis. In this paper, we are interesting to methanol electrolysis in order to produce hydrogen. The relation linking hydrogen production rate to the power needed to electrolyse a unit volume of aqueous methanol solution has been determined. Using this relation, the potential of hydrogen from aqueous methanol solution using a PV solar as the energy system has been evaluated for different locations in Algeria.     

Integrated approach for textile industry wastewater for efficient hydrogen production and treatment through solar PV electrolysis

Combining solar PV based electrolysis process and textile dyeing industry wastewater for hydrogen production is considered feasible route for resource utilization. An updated experimental method, which integrates resource availability to assess the wastewater based hydrogen production with highlights of wastewater treatment, use of solar energy to reduce the high-grade electricity for electrolysis (voltage, electrode materials) efficiency of the process was employed. Results showed that maximum pollutant removal efficiency in terms of conductivity, total dissolved solids, total suspended solids, biological oxygen demand, chemical oxygen demand, hardness, total nitrogen and total phosphorus were obtained from ≅73% to ≅96% at 12 V with steel electrode for pollutant load. The maximum input voltage was found at 3 V for the best efficiency i.e. 49.6%, 67.8% and 57.1% with carbon, steel and platinum electrodes respectively. It was observed that with high voltage (12 V) of the electrolyte the rate of production of hydrogen was higher with carbon, steel and platinum electrodes. However, the increase in the efficiency of the production of hydrogen was not significant with high voltage, may be due to energy loss through heat during extra-over potential voltage to the electrodes. Hence, this integrated way provides a new insight for wastewater treatment and hydrogen energy production simultaneously.     

Dynamic modeling of a photovoltaic hydrogen fuel cell hybrid system

The objective of this paper is to mathematically model a stand-alone renewable power system, referred to as “Photovoltaic–Fuel Cell (PVFC) hybrid system”, which maximizes the use of a renewable energy source. It comprises a photovoltaic generator (PV), a water electrolyzer, a hydrogen tank, and a proton exchange membrane (PEM) fuel cell generator. A multi-domain simulation platform Simplorer is employed to model the PVFC hybrid systems. Electrical power from the PV generator meets the user loads when there is sufficient solar radiation. The excess power from the PV generator is then used for water electrolysis to produce hydrogen. The fuel cell generator works as a backup generator to supplement the load demands when the PV energy is deficient during a period of low solar radiation, which keeps the system's reliability at the same level as for the conventional system. Case studies using the present model have shown that the present hybrid system has successfully tracked the daily power consumption in a typical family. It also verifies the effectiveness of the proposed management approach for operation of a stand-alone hybrid system, which is essential for determining a control strategy to ensure efficient and reliable operation of each part of the hybrid system. The present model scheme can be helpful in the design and performance analysis of a complex hybrid-power system prior to practical realization.     

Development of hybrid photovoltaic-fuel cell system for stand-alone application

In this paper we present firstly the different hybrid systems with fuel cell. Then, the study is given with a hybrid fuel cell–photovoltaic generator. The role of this system is the production of electricity without interruption in remote areas. It consists generally of a photovoltaic generator (PV), an alkaline water electrolyzer, a storage gas tank, a proton exchange membrane fuel cell (PEMFC), and power conditioning units (PCU) to manage the system operation of the hybrid system. Different topologies are competing for an optimal design of the hybrid photovoltaic–electrolyzer–fuel cell system. The studied system is proposed. PV subsystem work as a primary source, converting solar irradiation into electricity that is given to a DC bus. The second working subsystem is the electrolyzer which produces hydrogen and oxygen from water as a result of an electrochemical process. When there is an excess of solar generation available, the electrolyzer is turned on to begin producing hydrogen which is sent to a storage tank. The produced hydrogen is used by the third working subsystem (the fuel cell stack) which produces electrical energy to supply the DC bus. The modelisation of the global system is given and the obtained results are presented and discussed.     

Solar and wind energy in Poland as power sources for electrolysis process - A review of studies and experimental methodology

The production of hydrogen is still a major challenge, due to the high costs and often also environmental burdens it generates. It is possible to produce hydrogen in emission-free way: e.g. using a process of electrolysis powered by renewable energy. The paper presents the concept of a research, experimental stand for the storage of renewable energy in the form of hydrogen chemical energy with the measurement methodology. The research involves the use of proton exchange membrane electrolysis technology, which is characterized by high efficiency and flexibility of energy extraction for the process of electrolysis from renewable sources. The system consist of PV panel, PEM electrolyzer, battery, programmable logic controller system and optional a wind turbine. Preliminary experimental tests results have shown that the electrolyzer can produce in average 158.1 cc/min of hydrogen with the average efficiency 69.87%.     

Effect of partial shading conditions on off-grid solar PV/Hydrogen production in high solar energy index regions

In present work, the effect of partial shading on off-grid solar PV/hydrogen production in solar energy has been studied. The study was designed to stimulate future work in this area and to help demonstrate PV/hydrogen production. Four different electrodes in the study were coated and used in PV/Hydrogen Production. Pt anode and four different cathode materials which were Cu, Cu/Ni, Cu/NiBi and Cu/NiMo were used in the study. Data obtained from 105 W PV panel via automation system installed at ATU University, Adana, in Turkey were used for data of days representing different seasons by electrolysis experiment. The experiments were carried out between 08:00 and 16:00. The main contribution of this study is to produce hydrogen by using a part of the electrical energy gained from the solar panels, and at the same time to reveal the effect of the electrical energy produced by the partial shading of the panels on the hydrogen production. Furthermore, the effect of cathode material type was investigated for the impact of partial shading on hydrogen production. Results showed that Cu/NiMo has better hydrogen production efficiency than Cu/Ni, Cu/NiBi. The lowest efficiency was observed in the bare Cu electrode.     

Generation of high-pressure hydrogen for fuel cell electric vehicles using photovoltaic-powered water electrolysis

Increasing the utilization of electric drive systems including hybrid, battery, and fuel cell electric vehicles (FCEV) will reduce the usage of petroleum and the emission of air pollution by vehicles. The eventual production of electricity and hydrogen in a renewable fashion, such as using solar energy, can achieve the long-term vision of having no tailpipe emissions, as well as eliminating the dependence of the transportation sector on dwindling supplies of petroleum for its energy. Before FCEVs can be introduced in large numbers, a hydrogen-fueling infrastructure is needed. This report describes an early proof-of-concept for a distributed hydrogen fueling option in which renewably generated, high-pressure hydrogen is dispensed at an FCEV owner’s home. In an earlier report we described the design and initial characterization of a solar photovoltaic (PV) powered electrolyzer/storage/dispensing (ESD) system that was a proof-of-concept for a single FCEV home fueling system. In the present report we determined the efficiency and other operational characteristics of that PV-ESD system during testing over a 109-day period at the GM Proving Ground in Milford, MI, at a hydrogen output pressure of approximately 2000 psi (13.8 MPa). The high pressure was achieved without any mechanical compression via electrolysis. Over the study period the photovoltaic solar to electrical efficiency averaged 13.7%, the electrolyzer efficiency averaged 59%, and the system solar to hydrogen efficiency averaged 8.2% based on the hydrogen lower heating value. A well-documented model used to evaluate solar photovoltaic power systems was used to calculate the maximum power point values of the voltage, current, and power of our PV system in order to derive the coupling factor between the PV and ESD systems and to determine its behavior over the range of environmental conditions experienced during the study. The average coupling factor was near unity, indicating that the two systems remained coupled in an optimal fashion. Also, the system operated well over a wide range of meteorological conditions, and in particular it responded quickly to instantaneous changes in the solar irradiance (caused by clouds) with negligible effect on the overall efficiency. During the study up to 0.67 kg of high-pressure hydrogen was generated on a sunny day for fueling FCEV. Future generations of high-pressure electrolyzers, properly combined with solar PV systems, can offer a compact, efficient, and environmentally acceptable system for FCEV home fueling.     

Efficient STEP (solar thermal electrochemical photo) production of hydrogen – an economic assessment

A consideration of the economic viability of hydrogen fuel production is important in the STEP (Solar Thermal Electrochemical Photo) production of hydrogen fuel. STEP is an innovative way to decrease costs and increase the efficiency of hydrogen fuel production, which is a synergistic process that can use concentrating photovoltaics (CPV) and solar thermal energy to drive a high temperature, low voltage, electrolysis (water-splitting), resulting in H₂ at decreased energy and higher solar efficiency. This study provides evidence that the STEP system is an economically viable solution for the production of hydrogen. STEP occurs at both higher electrolysis and solar conversion efficiencies than conventional room temperature photovoltaic (PV) generation of hydrogen. This paper probes the economic viability of this process, by comparing four different systems: (1) 10% or (2) 14% flat plate PV driven aqueous alkaline electrolysis H₂ production, (3) 25% CPV driven molten electrolysis H₂ production, and (4) 35% CPV driven solid oxide electrolysis H₂ production. The molten and solid oxide electrolysers are high temperature systems that can make use of light, normally discarded, for heating. This significantly increases system efficiency. Using levelized cost analysis, this study shows significant cost reduction using the STEP system. The total price per kg of hydrogen is shown to decrease from $5.74 to $4.96 to $3.01 to $2.61 with the four alternative systems. The advanced STEP plant requires less than one seventh of the land area of the 10% flat cell plant. To generate the 216 million kg H₂/year required by 1 million fuel cell vehicles, the 35% CPV driven solid oxide electrolysis requires a plant only 9.6 mi² in area. While PV and electrolysis components dominate the cost of conventional PV generated hydrogen, they do not dominate the cost of the STEP-generated hydrogen. The lower cost of STEP hydrogen is driven by residual distribution and gate costs.     

Hydrogen production using alkaline electrolyzer and photovoltaic (PV) module

In this paper it is presented hydrogen production using alkaline water electrolysis where a 30 W photovoltaic (PV) module was involved as a source of electric energy. Therefore, the process is without emitting CO₂. There is constructed and tested an alkaline electrolyzer with 50 × 50 × 2 mm Ni metal foam electrodes, 50 × 50 × 0.4 mm Zirphon^® membrane and 25% alkaline (KOH) solution electrolyte. Electrolyzer UI characteristics for natural and forced flow of electrolyte with PV module UI characteristics are presented. The results are in favor of forced flow circulation, and these are better if the flow velocities are higher. Calculated Energy efficiency (based on hydrogen high heating value) for both types of circulation is above 55%. There are much evidence for further improvement of the system components and consequently electrolyzer and system efficiency.     

Dynamic hydrogen production from PV & wind direct electricity supply – Modeling and techno-economic assessment

Renewable hydrogen from water electrolysis could contribute to the defossilization of various energy intensive sectors but continues to suffer from unfavorable economics. Attention is being paid to the direct supply of renewable electricity to electrolyzers; in particular from photovoltaic (PV) and wind units, whose fixed remuneration period has expired. However, detailed analysis of such operating strategies via modeling and simulation of the dynamic behavior of alkaline electrolysis (AEL) and polymer electrolyte membrane electrolysis (PEMEL) is lacking. In this work, an electrolyzer model is developed for both AEL and PEMEL and analyzed for PV and wind power input data sets from the region of northwest Germany. It is shown that key performance indicators (KPI) such as hydrogen production efficiency, electricity utilization rate, product output and net production costs are highly reliant on the shape of transient power input signals as well as the electrolyzers ability to cope with them. PEMEL technology generally has higher electricity utilization rates than AEL, while AEL still achieves relatively large hydrogen production quantities due to its higher efficiency. Thus, the better operational flexibility of PEMEL cannot generally be considered advantageous in terms of hydrogen production quantities – the same applies for economics. The most competitive hydrogen production costs were 4.33 € per kg for the AEL technology with direct electricity supply from old wind farms, which no longer receive fixed remuneration.     

基于新能源发电的电解水制氢直流电源研究

利用新能源发电进行电解水制氢是实现新能源就地消纳和氢能利用的重要途径,以匹配电解水制氢工作特性的制氢电源为研究对象,通过分析质子交换膜电解槽电解电流、温度与电解槽端口电压、能量效率、制氢速度之间的关系,得出制氢电源需具备输出低电流纹波、输出大电流、宽范围电压输出的特性。为满足新能源电解制氢系统需求,提出一种基于Y型三相交错并联LLC拓扑结构的制氢电源方案,该方案谐振腔三相交错并联输出,满足电解槽大电流低纹波工作特性,并采用脉冲频率控制实现谐振软开关,提高变换效率。最后,搭建仿真模型和6 kW模块化实验样机,验证所提出方案的合理性与可行性。     

Solar hydrogen production via alkaline water electrolysis

Electricity generation via direct conversion of solar energy with zero carbon dioxide emission is essential from the aspect of energy supply security as well as from the aspect of environmental protection. Therefore, this paper presents a system for hydrogen production via water electrolysis using a 960 Wp solar power plant. The results obtained from the monitoring of photovoltaic modules mounted in pairs on a fixed, a single-axis and a dual-axis solar tracker were examined to determine if there is a possibility to couple them with an electrolyzer. Energy performance of each photovoltaic system was recorded and analyzed during a period of one year, and the data were monitored on an online software service. Estimated parameters, such as monthly solar irradiance, solar electricity production, optimal angle, monthly ambient temperature, and capacity factor were compared to the observed data. In order to get energy efficiency as high as possible, a novel alkaline electrolyzer of bipolar design was constructed. Its design and operating UI characteristic are described. The operating UI characteristics of photovoltaic modules were tuned to the electrolyzer operating UI characteristic to maximize production. The calculated hydrogen rate of production was 1.138 g per hour. During the study the system produced 1.234 MWh of energy, with calculated of 1.31 MWh , which could power 122 houses, and has offset 906 kg of carbon or an equivalent of 23 trees.     

Levelized costs of energy and hydrogen of wind farms and concentrated photovoltaic thermal systems. A case study in Morocco

This work deals with the evaluation of levelized costs of energy and hydrogen of wind farms and concentrated photovoltaic thermal systems. The production of hydrogen is ensured by an alkaline water electrolyser supplied by the electric current generated by the renewable energy sources. The study is carried out on the basis of meteorological data from the Tangier region, in Morocco. Mathematical models are developed to assess the performance and efficiency of renewable sources in terms of energy and hydrogen production for different installed powers. The comparison between the current results and those of previous work shows that the discrepancy did not exceed 6% for both electrical and thermal efficiency of the concentrated photovoltaic/thermal system. The results show that the energy consumption ratios of the electrolyzer are 61 and 64 kWh.kg⁻¹ for wind and solar energy, respectively. Wind and solar hydrogen production efficiencies are also 66 and 62%, respectively. Results show that levelized costs of energy and hydrogen decrease with the increase in installed wind and photovoltaic capacity. The overall results also show that the Tangier region can produce energy and hydrogen at low cost using wind energy compared to concentrated photovoltaic installations. For the hybridization of the two green sources studied, this is highly recommended provided that the capacity of the electrolyzer to be installed is optimal in order to effectively improve the production of hydrogen.     

A photovoltaic-powered water electrolyzer: its performance and economics

A prototype water electrolyzer designed to operate from a solar photovoltaic (PV) array without power conditioning was operated for three months at the Florida Solar Energy Center. A 1 kWpk PV array was used to operate the electrolyzer at internal gas pressure from 0 to 40 psig. Performance of the electrolyzer/PV array was measured and characterized in terms of charge efficiency and power efficiency calculated from the operating data. The economics of residential production of hydrogen for energy purposes were calculated and summarized. While the near-term outlook for this energy storage technique was not found to be favorable, the long-term outlook was encouraging.     

Valorization of the waste heat given off in a system alkaline electrolyzer-photovoltaic array to improve hydrogen production performance: Case study Antofagasta,Chile

The efficiency of an electrolyzer can be improved by preheating the water consumed, which is generally done by means of solar energy in PVT panels. In this research, the first objective is to determine whether it is possible to preheat the consumed water by using the residual heat given off by the electrolyzer itself fed by a PV array, and if the above is met, the second objective consists of quantify the benefits obtained in the performance of the system. The simulation is carried out over a period of one year, considering the meteorological conditions of the city of Antofagasta, Chile. The results indicate that it is possible to constantly maintain the water temperature consumed by the electrolyzer at its nominal value of 80 °C, since the energy contained in the waste heat is about 30 times higher than this hot water demand. Continuous operation at 80 °C compared to operation at variable temperature achieves an annual increase of 0.22% in hydrogen production and an average of 0.33% in electrolyzer efficiency. Moreover, by considering the thermal energy given off by the electrolyzer as useful output of the system, the overall energy efficiency increases by a relative percentage of 13%.     

Researching and adjusting the modes of joint operation of a photoelectric converter and a high pressure electrolyzer

The article describes the experimental studies of hydrogen (oxygen) generation processes by the electrolysis method that were fulfilled with the use of the energy plant model involving a solar energy photovoltaic converter (working surface area is of S = 1.5 m²) and a membrane-less high-pressure electrolyzer (capacity is of 0.002 m³ of hydrogen per hour with an operating pressure of 0.3 MPa). Under experimental studies we have adjusted the modes of joint operating the photoelectric converter and the membrane-less high pressure electrolyzer depending on the changes of solar insolation. We have determined the ways to increase the electrolyzer efficiency. It was found that the level of current density, which determines the electrolyzer efficiency by hydrogen, depends on the solar insolation level. The obtained experimental data, as to adapting an electrolyzer to be feed from a photoelectric converter, give the possibility to develop the algorithms of automatic control of the electrolyzer when it operates in composition of an autonomous energy plant.     

Development of large scale unified system for hydrogen energy carrier production and utilization: Experimental analysis and systems modeling

The world's largest class hydrogen energy carrier production, storage, and utilization system has been operated in order to obtain basic data for practical use of the system using renewable energy. In this system, an alkaline water electrolyzer is combined with hydrogenation reactors to produce methylcyclohexane (MCH). Since electrolyzer behavior directly affects hydrogenation reaction, behaviors of the 150 kW class water electrolyzer against fluctuating electricity inputs were experimentally investigated. The cell stack voltage and hydrogen flow rate changed following temporal changes of the input current, whereas the temperature response was slow due to the large heat capacity of the system. Hydrogenation reactors performance using the hydrogen from the electrolyzer are reported. Then, based on the experiment data, a numerical simulation model for the electrolyzer was developed, which predicts the experimental result using fluctuating electricity very well. Furthermore, using the simulator, the heat utilization from the hydrogenation reaction for the electrolyzer warm-up process was investigated.