超细粉掺和料对高性能混凝土强度提高的影响

通过对不同组分的高性能混凝土的强度试验,研究了超细粉掺合料(以下简称FC料)对高性能混凝土强度的影响;从微观孔结构角度分析了掺入FC料的混凝土强度提高的机理.结果表明,FC料可以大幅度提高混凝土的强度和密实保水性,且在混凝土中使用FC料存在一个最佳掺量问题,不同龄期的最佳掺量不同.     

超细粉掺和料对高性能混凝土强度提高的影响

通过对不同组分的高性能混凝土的强度试验,研究了超细粉掺合料(以下简称FC料)对高性能混凝土强度的影响;从微观孔结构角度分析了掺入FC料的混凝土强度提高的机理.结果表明,FC料可以大幅度提高混凝土的强度和密实保水性,且在混凝土中使用FC料存在一个最佳掺量问题,不同龄期的最佳掺量不同.     

玄武岩纤维超高性能混凝土力学性能试验

为了降低超高性能混凝土中水泥的用量,制备绿色超高性能混凝土,研究了玄武岩纤维对超高性能混凝土力学性能的影响,提出了力学性能最优的低水泥用量超高性能混凝土配合比和玄武岩纤维的最佳掺量.采用粉煤灰和硅灰以不同比例组合作为水泥的替代材料制备超高性能混凝土,分析了添加纤维和不添加纤维试件的和易性、力学性能和微观结构.结果表明,当粉煤灰和硅灰混杂替代水泥比例达50%时,其力学性能与原试件强度相当;掺加0.1%玄武岩纤维的试件其力学性能高于掺加0.2%和0.3%纤维和没有掺加纤维试件的力学性能.     

蒸养超细粉煤灰高性能混凝土性能试验研究

研究蒸养条件下超细粉煤灰高性能混凝土的强度、弹性模量和应力-应变行为以及体积稳定性和耐久性能,结合微观测试手段,探讨超细粉煤灰在蒸养条件下的作用效应及其机制.试验结果表明,超细粉煤灰能显著提高混凝土的蒸养适应性,蒸养超细粉煤灰高性能混凝土的后期强度、弹性模量具有较好的增长率.与普通蒸养混凝土相比,蒸养超细粉煤灰高性能混凝土的脆性降低,塑性变形能力明显增强,干燥收缩明显降低,且抗氯离子渗透性能显著提高.超细粉煤灰可改善蒸养条件下混凝土的内部水化产物组成及其孔结构,降低混凝土的孔隙率,提高混凝土耐久性.     

聚丙烯纤维和高效减水剂双掺对铁尾矿粉泡沫混凝土抗冻性能的影响

铁尾矿粉泡沫混凝土由铁尾矿粉、水泥、粉煤灰、高性能矿物掺合料、泡沫剂、聚丙烯纤维、聚羧酸系高效减水剂等制成.本实验研究了聚丙烯纤维和聚羧酸系高效减水剂双掺对铁尾矿粉泡沫混凝土抗冻性能的影响及其微观结构,实验结果表明,聚丙烯纤维和聚羧酸系高效减水剂双掺大大提高了铁尾矿粉泡沫的抗冻性能,使铁尾矿粉泡沫混凝土的孔微观结构有了明显的改善.     

基于耐久性的结构混凝土研究

针对混凝土结构的耐久性问题,对结构混凝土的劣化进行了研究,并进而分析了高强混凝土、高性能混凝土以及高性能混凝土结构之间的相关关系,建立了高性能混凝土结构的方案模型,为进一步的工作提供了理论基础.     

FC料对混凝土抗渗抗冻性能的影响

通过抗渗抗冻系列试验 ,研究了FC料对提高混凝土抗渗抗冻性能的影响 ,并从微观结构角度分析了混凝土宏观性能提高的机理 .试验表明 ,在混凝土中掺用适量FC料 ,抗渗能力可达到S2 5以上 ,抗冻标号超过D30 0 ,完全可以实现绿色高性能混凝土的目标     

硫酸盐环境混凝土动弹性模量及微观研究

针对西部重盐渍土地区混凝土的耐久性问题,以内掺复合掺合料制成的高性能细石混凝土和普通硅酸盐水泥以及抗硫酸盐水泥制成的高性能细石混凝土作为研究对象,在硫酸钠溶液中进行干湿循环后,通过对动弹性模量的测量以及对混凝土SEM形貌分析,结果表明,在干湿交替的恶劣环境中,抗硫酸盐水泥混凝土的抗侵蚀性能并不比普通水泥混凝土好;掺加复合掺和料的高性能细石混凝土对硫酸盐侵蚀有较好的抵抗性能;掺加矿物掺合料能够与混凝土内部的不利成分Ca(OH)2发生二次水化反应,生成有利的C-S-H凝胶,有效改善混凝土的微观结构;并给出了在盐渍土地区拌制混凝土的建议.     

粉煤灰海工高性能混凝土耐久性试验

结合课题,采用规定的试验方法对掺与不掺粉煤灰的三个配合比混凝土的耐久性进行了试验研究和对比分析.结果表明,掺一定量粉煤灰的混凝土提高了混凝土的抗渗性和抗氯离子渗透能力,同时也提高了混凝土的抗冻融性能,对混凝土碱骨料反应也有一定的抑制作用,掺一定量优质粉煤灰的高性能混凝土,其抗硫酸盐的性能较好,而混凝土的抗碳化能力并没有明显减弱.因此,掺一定量粉煤灰的混凝土可改善混凝土的微观结构,从而使海工高性能混凝土具有良好的耐久性能.     

粉煤灰沉珠超高性能混凝土研究

基于颗粒密实紧密堆积原理通过修正的Andereson和Anderson模型方程,采用粉煤灰沉珠作为胶凝材料部分取代硅酸盐水泥配制出超高性能混凝土。研究了沉珠掺量为20%、25%和30%情况下超高性能混凝土的流动度和力学性能,同时通过湿密度试验验证不同沉珠掺量的超高性能混凝土干密实度,并通过XRD、DTG和SEM对沉珠超高性能混凝土的组成及微观结构进行分析。结果表明:粉煤灰沉珠和普通粉煤灰相比具有更加优异的滚珠效应以及减水效应,当沉珠掺量为20%时,混凝土扩展度提高了8.5%,28d抗压强度可达到169.3 MPa;粉煤灰沉珠作为优质矿物掺合料,采用紧密堆积理论可以配制成工作性能优异的沉珠超高性能混凝土。     

轻骨料性能对界面区微观结构的影响

目的研究不同吸水率轻骨料制备的混凝土中骨料-水泥石界面区的微观形貌、水化产物的钙硅质量比、水泥石的显微硬度以及孔结构等性能参数．方法采用扫描电镜（SEM）、X射线能谱分析（EDXA）、显微硬度以及孔结构等试验手段,并与普通骨料混凝土进行对比分析．结果轻骨料-水泥石界面区各项性能均优于普通骨料,轻骨料吸水率越大、表面越粗糙,界面区水泥石结构越致密,孔结构呈细化趋势,低、中、高吸水率轻骨料-水泥石界面区显微硬度较普通骨料分别提高15．8％、79．6％和96．3％,界面增强层厚度为40～60μm,并且,中、高吸水率陶粒混凝土中,距骨料-水泥石界面-10～0μm范围内具有一个明显的内增强层．结论轻骨料性能对界面区水泥石微观结构具有显著影响,中、高吸水率轻骨料可使界面区结构得以改善．     

配制高性能混凝土的材料选用及试验研究

高性能混凝土是混凝土发展的趋势.介绍了高性能混凝土的定义、性能,分析了其组成材料的基本要求,阐述了选用的基本原则.通过试验,对高性能混凝土的配制进行了研究.     

A Review of the Effects of Fly Ash on Durability of Concrete:Hydration Chemistry and Microstructure

Fly ash (FA) is widely used in construction industry as a pozzolanic material for its economic and environmental advantages. However,the variety and the complexity of the chemical composition of FA make it difficult to control the quality in engineering practice. Especially the durability of FA concrete has to be considered in the design. This durability is strongly influenced by the internal chemistry and the microstructure of cement paste. The aim of this article is to present a review on the effect of FA on the durability of concrete with particularly focus on the hydration chemistry and the development of microstructure. Meanwhile,existing hydration models for hydration kinetics and microstructure development of concrete blended with FA is discussed. The results of this research will provide a modelling perspective for predicting durability of concrete when FA is used as a blending material in the mixtures.     

Mechanical properties and microstructure of Portland cement concrete prepared with coral reef sand

The feasibility of using coral reef sand (CRS) in Portland cement concrete is investigated by testing the mechanical property and microstructure of concrete. The composition, structure and properties of the CRS are analyzed. Mechanical properties and microstructure of concrete with CRS are studied and compared to concrete with natural river sand. The relationship between the microstructure and performance of CRS concrete is established. The CRS has a porous surface with high water intake capacity, which contributes to the mechanical properties of concrete. The interfacial transition zone between the cement paste and CRS is densified compared to normal concrete with river sand. Hydration products form in the pore space of CRS and interlock with the matrix of cement paste, which increases the strength. The total porosity of concrete prepared with CRS is higher than that with natural sand. The main difference in pore size distribution is the fraction of fine pores in the range of 100 nm.     

The Microstructure and Performance of a Cement Matrix Composite Material

Through the DSC , XRD , SEM and other experimental methods , the microstructure characteristics of reactive powder concrete( RPC ) are discussed, The results show that RPC has a super high perfomance because of its lower ratio of water-binder, high pock density , optimum hydration products mixture and being strengthened by steel fiber. The high performance results from the special hydration microstructure of RPC, and its superperformance can be well explained by the centrum partile hypothesis.     

Effectiveness of Surface Coatings Against Intensified Sewage Corrosion of Concrete

Three different kinds of coatings were coated on the concrete surface, and the changes in appearance, surface roughness, microstructure and components of coatings in artificial sewage were investigated. In addition, the strength, micrograph, mineral compositions and pore structure of concrete specimens after removing coatings were also studied. The results show that epoxy coal tar pitch coating(ECTPC) has the best effect of protecting concrete from the sewage corrosion. After being immersed in sewage for 90 days, the compressive strength of concrete coated with ECTPC is still as high as that of specimen immersed in water, and the cement paste has a high CH content and dense structure with low porosity, which mainly accounts for its excellent barrier property and certain antibacterial function. Cement-based bactericidal coating(CBC) also has good effectiveness to sewage corrosion of concrete. The strength and microstructure of concrete coated with CBC in sewage are still significantly superior to those of uncoated concrete. Although cement-based capillary crystalline waterproofing coating(CCCWC) is a good waterproof material, it is not suitable for the corrosion resistance of concrete in sewage. After 2 months corrosion, almost all of the CH crystals in coating reacted with the metabolic acid substance by microbes. Therefore, the strength and pore structure of concrete coated with CCCWC are only slightly superior to those of uncoated concrete. Overall, the protective effect of cement-based inorganic coatings is relatively poor.     

磷渣活化制备加气混凝土的研究

研究了以黄磷炉渣为主要原料制备加气混凝土的工艺技术,探讨了配方、工艺参数对材料性能的影响.研究结果表明:与传统的粉煤灰、砂加气混凝土相比,磷渣加气混凝土可以在较少采用水泥和石灰的前提下获得高强度,这种优势可以弥补其容重偏大和粉磨能耗高的不足.     

夏热冬冷地区不同新型墙体材料试验研究

以安徽省两淮矿区固体废弃物粉煤灰和煤矸石制备的烧结煤矸石空心砖、粉煤灰混凝土空心砌块（内填XPS板）、粉煤灰蒸压加气混凝土砌块三种新型围护结构材料为研究对象,将上述三种新型墙体材料砌成模拟实验房,与传统粘士实心砖同条件下进行热工性能对比试验研究,并进行微观结构机理分析,结果表明三种新型墙体材料保温隔热性能具有明显的提高,可作为夏热冬冷地区自保温砌块应用。     

混合型集料优质轻混凝土的微观结构

本项研究用混合型集料配制出了表观密度等级为1800,抗压强度等级为CL50的优质轻混凝土。通过试验及检测分析,所研制的轻混凝土具有低容重、高密实度、高强度、抗渗等优良的理化性能。研究中采用X射线衍射(XRD)、扫描电镜(SEM)、差热(DTA)等手段,对所配混合型集料优质轻混凝土微观结构的具体类型及转化,微观结构与各项理化性能之间的关系,进行了全面的研究和测定。从微观的角度解释了其优良性能的根源,为进一步优化轻混凝土的理化性能提供了依据。